JPS63136621A - X-ray exposure mask - Google Patents

X-ray exposure mask

Info

Publication number
JPS63136621A
JPS63136621A JP61283748A JP28374886A JPS63136621A JP S63136621 A JPS63136621 A JP S63136621A JP 61283748 A JP61283748 A JP 61283748A JP 28374886 A JP28374886 A JP 28374886A JP S63136621 A JPS63136621 A JP S63136621A
Authority
JP
Japan
Prior art keywords
ray
thin film
pattern
film
transparent thin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61283748A
Other languages
Japanese (ja)
Inventor
Yukio Iimura
飯村 幸夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dai Nippon Printing Co Ltd
Original Assignee
Dai Nippon Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai Nippon Printing Co Ltd filed Critical Dai Nippon Printing Co Ltd
Priority to JP61283748A priority Critical patent/JPS63136621A/en
Publication of JPS63136621A publication Critical patent/JPS63136621A/en
Pending legal-status Critical Current

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  • Preparing Plates And Mask In Photomechanical Process (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)

Abstract

PURPOSE:To prevent a mask from being deformed due to the compression force of an X-ray absorbing pattern by so forming the thickness of an X-ray transmissible thin film corresponding to an X-ray transmission region that the composite force of the tensile strength corresponding to the lower surface of the pattern and the compression force of the pattern is equalized to the tensile strength of the X-ray transmissible thin film part. CONSTITUTION:One side surface is formed with an X-ray transmissible thin film 2 and the other side surface is removed by etching with a photoresist pattern as a mask to form a protecting film 5. After an X-ray absorbing pattern material layer having a compression stress made of a W film or a Ta film is formed on the film 2, a resist pattern is formed, for example, by a normal electron beam exposure method, and with it as a mask it is dry etched to form an X-ray absorbing pattern 3. The X-ray transmission film of the X-ray transmission region is thinly formed so that the composite tensile strength of the compression force of the pattern 3 and the tensile force of the film 2 of the lower surface is balanced with the tensile force of the film 2.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は微細パターンを高精度に転写するX線露光装置
書−用いるX線露光用マスク(:関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an X-ray exposure mask used in an X-ray exposure apparatus for transferring fine patterns with high precision.

〔従来の技術〕[Conventional technology]

X線露光法は、波長ダ〜jOAの軟X線を線源とし、サ
ブミクロン微細パターンの転写が可能な技術として知ら
れる。
The X-ray exposure method is known as a technique that uses soft X-rays with a wavelength of d~jOA as a radiation source and is capable of transferring submicron fine patterns.

従来からのX線露光用マスクの例としては、第3図に示
すように、引張り力を有するX線透過性薄膜コと、この
薄膜上(:形成されたX線吸収性パターン3と、Slウ
ニ八へ板の一部を除去してなる支持枠ダと、S1ウエ八
基板を部分的に除去する際に使用する保@膜7からなる
X線露光用マスクlがある。
As an example of a conventional X-ray exposure mask, as shown in FIG. There is an X-ray exposure mask 1 consisting of a support frame formed by removing a part of the S1 wafer board and a protective film 7 used when partially removing the S1 wafer board.

〔発明が解決しようとする間踊点〕[The gap that the invention attempts to solve]

一般);、X線吸収性パターンのもつ応力によりマスク
歪が発生することが知られ、例えばに、H,Mull@
r、P、Ti5her  およびW。
It is known that mask distortion occurs due to stress in X-ray absorbing patterns; for example, H, Mull@
r, P, Ti5her and W.

Wlndbraek@l二よる[吸収体応力のX線マス
フ精度に及ぼす影響(Influ@nce  ofab
sorbsr  5tress  outh@ pre
−elslon’ of  x−ray  masks
 )J(Jounal  of  Vacuum  a
nd  5ci−sua@ Technology、B
4((1)、Jan、/F’eb。
Wlndbraek@l2 [Influence of absorber stress on X-ray mass flow accuracy (Influ@nce ofab
sorbsr 5tress outer @ pre
-elslon' of x-ray masks
) J (Journal of Vacuum a)
nd 5ci-sua @ Technology, B
4 ((1), Jan, /F'eb.

/916.pコ30)に述べられている。/916. pco 30).

したがりて、従来から、X線吸収性パターンの応力によ
るマスク歪が大きく、超LSIデバイス用のX線露光用
マスクシニ要求される位置精度または長ピツチ精度を満
さない場合がしばしば生じていた。
Therefore, in the past, mask distortion due to stress in the X-ray absorbing pattern was large, and the position accuracy or long pitch accuracy required for X-ray exposure masks for VLSI devices was often not satisfied.

そこで本発明が解決しようとする問題点は、X線吸収性
パターンの応力によるマスク歪を防止したX線露光用マ
スクを提供することにある。
Therefore, the problem to be solved by the present invention is to provide an X-ray exposure mask that prevents mask distortion due to stress in the X-ray absorbing pattern.

〔問題点を解決するための手段〕[Means for solving problems]

本発明者は上記の問題点を解決すべく研究の結果、X線
透過性薄膜の一面側には圧縮力を有するX線吸収性パタ
ーンが設けられ、かつ該X線透過性薄膜の他面側(:は
支持枠が設けられているX線露光用マスクにおいて、該
X、II吸収性パターン下面のX線透過性薄膜領域を凸
とし、この凸部分のX線透過性薄膜と該X線吸収性パタ
ーンとの合成引張り力とX線透過領域のX線透過性薄膜
の引張り力が等しくなるように、凸部分を形成すること
により、位置精度および長ピツチ精度の低下を防止する
ことが可能であることを見い出し、かかる知見(:もと
づいて本発明を完成させたものである。
As a result of research to solve the above-mentioned problems, the present inventor has provided an X-ray absorbing pattern having a compressive force on one side of an X-ray transparent thin film, and the other side of the X-ray transparent thin film. (:: In an X-ray exposure mask provided with a support frame, the X-ray transparent thin film region on the lower surface of the X, II absorptive pattern is made convex, and the X-ray transparent thin film in this convex part and the X-ray absorbing By forming the convex portion so that the combined tensile force with the X-ray pattern and the tensile force of the X-ray transparent thin film in the X-ray transparent area are equal, it is possible to prevent a decrease in positional accuracy and long pitch accuracy. The present invention was completed based on this discovery.

即ち、本発明は、「X線透過性薄膜の一面にX線吸収性
パターンが設けられ、且つ他面側に支持枠が設けられて
いるX線露光用マスクにおいて、X線吸収性パターンの
下面のX線透過性薄膜領域をX線透過領域に対応するX
線透過性薄膜よりも厚膜1:形成し、且つXlfM吸収
性パターンの下面1二対応するX線透過性薄膜部分の膜
厚、及びX線透過領域::対応するX線透過性薄膜部分
の膜厚を、X線吸収性パターンの下面に対応するX線透
過性薄膜部分の引張り力とX線吸収性パターンの圧縮力
の合成力と、X線透過領域に対応するX線透過性薄膜部
分の引張り力がほり等しくなるような膜厚としたことを
特徴とするX線露光用マスク。」を要旨とするものであ
る。
That is, the present invention provides ``an X-ray exposure mask in which an X-ray absorbing pattern is provided on one side of an X-ray transparent thin film and a support frame is provided on the other side; The X-ray transparent thin film area of
Thicker than the radiolucent thin film 1: Thickness of the XlfM absorbing pattern lower surface 12 corresponding to the X-ray transmissive thin film portion, and X-ray transparent region:: The film thickness is determined by the combined force of the tensile force of the X-ray transparent thin film part corresponding to the lower surface of the X-ray absorbing pattern and the compressive force of the X-ray absorbing pattern, and the X-ray transparent thin film part corresponding to the X-ray transparent area. An X-ray exposure mask characterized by having a film thickness such that the tensile forces of the two are equal to each other. ” is the gist.

而して本明細?(=おいて「引張り力」および「圧縮力
」とは、薄膜全体としてそれぞれ、引張り状態にある単
位幅当りの全応力〔dynkL〕、および圧縮状態;二
ある単位幅当りの全応力Cdyn/am )を意味する
ものである。
And the main details? (In =, "tensile force" and "compressive force" refer to the total stress per unit width in the tensile state [dynkL] and the total stress per unit width in the compressed state; ).

次に本発明においてX線透過性薄膜として、例えばCV
D法やスパッタリング法により、81ワエ八基板の一面
上に形成したsls N4 e S t N。
Next, in the present invention, as an X-ray transparent thin film, for example, CV
slsN4eStN was formed on one surface of the 81W substrate by the D method or the sputtering method.

8iC,BN等の単層もしくは複合層からなる引張り力
を有する厚0.−〜6μmの薄膜を適用し得る。
8iC, BN, etc. single layer or composite layer with tensile strength and thickness 0. -A thin film of ~6 μm can be applied.

次にXl1I吸収性パターンとして、A u 、 W。Next, A u, W as the Xl1I absorption pattern.

Ta、Mo等の重金属を主成分とした厚さ0. /〜/
、jμmのxg吸収性パターン材料層をX線透過性薄膜
上に蒸着法、スパッタリング法またはCVD法により形
成した後にドライエツチングしてなるものか、或いはX
線透過性薄膜上に例えば厚さs−o〜−〇OAのCr、
Ni、Ti等と厚さ一〇〇〜l、00にのAuを順次蒸
着もしくはスパッタリングしてメッキ下地層を形成した
後1:、このメッキ下地層表面をX線吸収性パターンに
対応する部分が開口したレジストパターンで被覆してか
らレジストパターンの開口部にAuメッキして、しかる
のちレジストパターンを除去してなるものを適用できる
。なお、X線吸収性パターン形成後にメッキ下地層の不
l!部は例えばArガスを用いたスパッタエツチング法
により容易に除去できる。
Thickness: 0.0mm, mainly composed of heavy metals such as Ta and Mo. /〜/
, jμm of xg absorbing pattern material layer is formed on an X-ray transparent thin film by vapor deposition, sputtering, or CVD method, and then dry etched, or
For example, Cr having a thickness of s-o to -0 OA on a radiation-transparent thin film,
After forming a plating base layer by sequentially vapor depositing or sputtering Ni, Ti, etc. and Au to a thickness of 100 to 1,000 mm, the surface of this plating base layer is coated with a portion corresponding to the X-ray absorbing pattern. It is possible to apply a method in which the resist pattern is covered with an open resist pattern, the openings of the resist pattern are plated with Au, and then the resist pattern is removed. It should be noted that after forming the X-ray absorptive pattern, the plating base layer may be damaged! The portion can be easily removed by sputter etching using Ar gas, for example.

〔作 用〕[For production]

X線吸収性パターンの下面のX線透過性薄膜領域をX線
透過領域(=対応するX#透過性薄膜よりも厚膜に形成
し、且つXH吸収性パターンの下面に対応するX線透過
性薄膜部分の膜厚。
The X-ray transparent thin film region on the lower surface of the X-ray absorbing pattern is formed into an X-ray transparent region (= thicker than the corresponding X# transparent thin film, and the X-ray transparent thin film region corresponding to the lower surface of the XH absorbing pattern Film thickness of thin film part.

及びX線透過領域に対応するX線透過性薄膜部分の膜厚
を、X線吸収性パターンの下面に対応するX線透過性薄
膜部分の引張り力とX線吸収性パターンの圧縮力の合成
力と、X線透過領域に対窓するX線透過性薄膜部分の引
張り力がはり等しくなるような膜厚とすることにより、
X”線吸収性パターンの圧縮力によるマスク歪が防止さ
れる。
and the film thickness of the X-ray transparent thin film portion corresponding to the X-ray transparent area, and the combined force of the tensile force of the X-ray transparent thin film portion corresponding to the lower surface of the X-ray absorbing pattern and the compressive force of the X-ray absorbing pattern. By setting the film thickness so that the tensile forces of the X-ray transparent thin film portion opposite to the X-ray transparent area are equal,
Mask distortion due to compressive force of the X''-ray absorbing pattern is prevented.

〔実施例〕〔Example〕

上記の本発明について、以下に実施例をあげて更に具体
的に説明する。
The above-mentioned present invention will be explained in more detail by giving examples below.

第1図(a)〜(d)に、本発明における一実施例の製
造工程を概略断面図):よりて示す。なお、第1図(d
)は、この実施例C二より製造されたX線露光用マスク
の断面図である。
FIGS. 1(a) to 1(d) are schematic sectional views showing the manufacturing process of an embodiment of the present invention. In addition, Fig. 1 (d
) is a cross-sectional view of the X-ray exposure mask manufactured in Example C2.

先ず、第1図(a) E示すように、厚さ0.3〜lI
朋で鏡面研磨されたSiクエ八へ板6上の両面1: C
V D装置1:より引張り応力へρX / O’dyn
/屋を有する厚さ3μmの81N@を形成して、−面側
をX線透過性薄膜コと他面側にフォトレジストパターン
をマスクにして不要部をエツチング除去することにより
保穫膜5を形成した。
First, as shown in Fig. 1(a) E, the thickness is 0.3~lI.
Both sides 1 on the Si Kuehachi plate 6 mirror-polished by my friend: C
V D device 1: more tensile stress ρX/O'dyn
A protective film 5 is formed by forming a 81N film with a thickness of 3 μm and removing unnecessary parts by etching and removing unnecessary parts using an X-ray transparent thin film on the negative side and a photoresist pattern on the other side as a mask. Formed.

次に、第1図(b)に示すよう)二、X線透過性薄膜コ
上にW膜もしくはTagからなり圧縮応力/ X / 
0 ” dny/cI!tを有した厚さ/fimのX線
吸収性パターン材料屑をCVD法もしくはスパッタリン
グ法により形成後、例えば通常の電子線露光法等(=よ
りレジストパターンを形成してそれをマスクにドライエ
ツチングすることによりX線吸収性パターン3を形成し
た。
Next, as shown in FIG. 1(b), a W film or a tag is placed on the X-ray transparent thin film and compressive stress /
After forming X-ray absorptive pattern material scraps having a thickness of 0 ” dny/cI!t by a CVD method or a sputtering method, a resist pattern is formed by, for example, a normal electron beam exposure method, An X-ray absorbing pattern 3 was formed by dry etching using a mask.

さらに、SINとWもしくはTaとの高選択エツチング
が可能な、例えばC1T6 t Ca ’8等のガスを
用いた反応性イオンエツチングにより、W@もしくはT
1膜からなるX線吸収性パターン3をマスクにSiN膜
からなるxm透過性薄gI!−を深さ0.7μmだけエ
ツチング除去した状態を第1図(e)に示す。なお、こ
こでエツチングマスクとしたX線吸収性パターン3は、
高選択ドライエツチングしたため、その膜減りは十分小
さく無視できる。
Furthermore, by reactive ion etching using a gas such as C1T6tCa'8, which allows highly selective etching of SIN and W or Ta, W@ or T
xm-transparent thin gI made of SiN film using X-ray absorbing pattern 3 made of one film as a mask! FIG. 1(e) shows the state in which - has been removed by etching to a depth of 0.7 μm. Note that the X-ray absorbing pattern 3 used as an etching mask here is
Due to highly selective dry etching, the film loss is sufficiently small that it can be ignored.

ここで、X線吸収性パターンの圧縮力=/Xi Q’(
dyn/c++1) @ / X i o−’Ccn〕
= t x/ 0’(dyn/rx〕とその下面のX線
透過性薄膜の引張り力=7,0×10・(d y n/
cd) @J、θX/ 0−’ (CIILI =J、
OX / 0” (dyn/c!fLlとの合成引張り
力=コ、tt x t o” (ayn/cm)であり
、またX線透過領域において、X線透過性薄膜の引張り
力=1.oxt 1(dyn/m〕*コ、?X10−’
(cm)=2.9×1OICdyn/c!IL〕である
から、この一つの引張り力が釣り合うよう4;、X線透
過領域のX?IQ透過膜が薄く形成されている。
Here, the compressive force of the X-ray absorbing pattern = /Xi Q'(
dyn/c++1) @ / Xio-'Ccn]
= t x/ 0' (dyn/rx) and the tensile force of the X-ray transparent thin film on the lower surface = 7,0
cd) @J, θX/ 0-' (CIILI = J,
OX / 0" (combined tensile force with dyn/c!fLl = ko, tt x t o" (ayn/cm), and in the X-ray transparent region, the tensile force of the X-ray transparent thin film = 1.oxt 1 (dyn/m) *ko, ?X10-'
(cm)=2.9×1OICdyn/c! IL], so that this one tensile force is balanced 4;, X? in the X-ray transparent region. The IQ permeable membrane is formed thinly.

最後1;、保@膜りで保護され【いないS1ウエハ基板
6の部分を裏面からエツチング除去して、第1図(d)
に示すように窓!およびSlからなる支持枠ダを形成し
た。
Finally, the portion of the S1 wafer substrate 6 that is not protected by the protective film is removed by etching from the back side, as shown in Figure 1(d).
window as shown! A support frame consisting of and Sl was formed.

このエツチングの際、X線吸収性パターンを保護するた
めに、テフロン、0リング等からなる治具を使用し、エ
ツチング液としては、20〜30%KOH水溶液やHF
:HNO,:CH,C00H=/ : 、7 : /の
HF系混合液を使用することにより良好に81ウニ八基
板の一部をエツチング除去できる。
During this etching, in order to protect the X-ray absorbing pattern, a jig made of Teflon, O-ring, etc. is used, and the etching solution is a 20-30% KOH aqueous solution or HF.
By using an HF-based mixed solution of :HNO, :CH,C00H=/ : , 7 : /, a part of the 81 Unihachi substrate can be successfully etched away.

上述のようにして、X線透過性薄嘆コの一部にxIII
吸収性パターンJと他面に支持枠弘があり、かつ上記X
線吸収性パターン下面のX線透過性薄膜が凸である第1
図(d) l:示すようなX線露光用マスクlが得られ
た。
As described above, xIII is applied to a portion of the X-ray transparent tube.
There is an absorbent pattern J and a support frame on the other side, and the above X
The first layer has a convex X-ray transparent thin film on the lower surface of the radiation-absorbing pattern.
Figure (d) 1: An X-ray exposure mask 1 as shown was obtained.

上記実施例のマスクを用いてX線露光を行なりたところ
、位置精度および長ピツチ精度の高い画像を焼き付ける
ことができた。
When X-ray exposure was performed using the mask of the above example, an image with high positional accuracy and long pitch accuracy could be printed.

その他の実施例として第2図に示すように、上記実施例
で得られたX線露光用マスクにパイレックスガラス等か
らなる補強枠ざを、例えばエポキシ系接着剤層デを介し
て、支持枠ダに固着してなるX線露光用マスクlがある
As another example, as shown in FIG. 2, a reinforcing frame made of Pyrex glass or the like is attached to the support frame via an epoxy adhesive layer, for example, to the X-ray exposure mask obtained in the above example. There is an X-ray exposure mask l which is fixed to a.

〔発明の効果〕〔Effect of the invention〕

以上詳記したとおり、本発明にかかるX#W光用マスク
は、XffIJ吸収性パターンのもつ圧縮力によって生
じるマスク全を防止しているので、位置精度および長ピ
ツチ精度の高いX線露光が可能である。
As detailed above, the X#W light mask according to the present invention prevents the entire mask from being generated due to the compressive force of the XffIJ absorbing pattern, making it possible to perform X-ray exposure with high positional accuracy and long pitch accuracy. It is.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(、)〜(d)は本発明の実施例の製造工程を示
す断面図、第2図は本発明の他の実施例を示す断面図、
第3図は従来のXMB光用マスクを説明するための断面
図である。 /・・・・・X線露光用マスク コ・・・・・X線透過性薄膜 3・・・・・X線吸収性パターン ダ・・φ・・支持枠 !・・・・・窓 6番・e・・S1ウエハ基板 り・・・・・保護膜 ざ・・・・・補強枠 t・・・・・接着剤層 特許出願人 大日本印刷株式会社 代理人 弁理士 小 西 淳 美 第1図
FIGS. 1(a) to (d) are cross-sectional views showing the manufacturing process of an embodiment of the present invention, FIG. 2 is a cross-sectional view showing another embodiment of the present invention,
FIG. 3 is a cross-sectional view for explaining a conventional XMB light mask. /...X-ray exposure mask...X-ray transparent thin film 3...X-ray absorptive pattern...φ...Support frame! ...Window No.6, e...S1 wafer substrate...Protective film...Reinforcement frame t...Adhesive layer Patent applicant Agent for Dai Nippon Printing Co., Ltd. Patent Attorney Atsushi Konishi Figure 1

Claims (1)

【特許請求の範囲】[Claims] X線透過性薄膜の一面にX線吸収性パターンが設けられ
、且つ他面側に支持枠が設けられているX線露光用マス
クにおいて、X線吸収性パターンの下面のX線透過性薄
膜領域をX線透過領域に対応するX線透過性薄膜よりも
厚膜に形成し、且つX線吸収性パターンの下面に対応す
るX線透過性薄膜部分の膜厚、及びX線透過領域に対応
するX線透過性薄膜部分の膜厚を、X線吸収性パターン
の下面に対応するX線透過性薄膜部分の引張り力とX線
吸収性パターンの圧縮力の合成力と、X線透過領域に対
応するX線透過性薄膜部分の引張り力がほゞ等しくなる
ような膜厚としたことを特徴とするX線露光用マスク。
In an X-ray exposure mask in which an X-ray absorbing pattern is provided on one side of an X-ray transparent thin film and a support frame is provided on the other side, the X-ray transparent thin film region on the lower surface of the X-ray absorbing pattern is formed to be thicker than the X-ray transparent thin film corresponding to the X-ray transparent area, and the film thickness of the X-ray transparent thin film portion corresponding to the lower surface of the X-ray absorbing pattern corresponds to the X-ray transparent area. The film thickness of the X-ray transparent thin film part is determined by the combined force of the tensile force of the X-ray transparent thin film part corresponding to the lower surface of the X-ray absorbing pattern and the compressive force of the X-ray absorbing pattern, and the X-ray transparent area. An X-ray exposure mask characterized by having a film thickness such that the tensile forces of the X-ray transparent thin film portions are approximately equal.
JP61283748A 1986-11-28 1986-11-28 X-ray exposure mask Pending JPS63136621A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61283748A JPS63136621A (en) 1986-11-28 1986-11-28 X-ray exposure mask

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61283748A JPS63136621A (en) 1986-11-28 1986-11-28 X-ray exposure mask

Publications (1)

Publication Number Publication Date
JPS63136621A true JPS63136621A (en) 1988-06-08

Family

ID=17669597

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61283748A Pending JPS63136621A (en) 1986-11-28 1986-11-28 X-ray exposure mask

Country Status (1)

Country Link
JP (1) JPS63136621A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0373950A (en) * 1989-08-14 1991-03-28 Fujitsu Ltd Manufacture of mask for exposing

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0373950A (en) * 1989-08-14 1991-03-28 Fujitsu Ltd Manufacture of mask for exposing

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