JPS63124364A - Nonaqueous electrolyte battery - Google Patents
Nonaqueous electrolyte batteryInfo
- Publication number
- JPS63124364A JPS63124364A JP61270734A JP27073486A JPS63124364A JP S63124364 A JPS63124364 A JP S63124364A JP 61270734 A JP61270734 A JP 61270734A JP 27073486 A JP27073486 A JP 27073486A JP S63124364 A JPS63124364 A JP S63124364A
- Authority
- JP
- Japan
- Prior art keywords
- lithium
- battery
- positive electrode
- active material
- tin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011255 nonaqueous electrolyte Substances 0.000 title claims abstract description 10
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 28
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229960004643 cupric oxide Drugs 0.000 claims abstract description 14
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 13
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002131 composite material Substances 0.000 claims abstract description 13
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052802 copper Inorganic materials 0.000 claims abstract description 11
- 239000010949 copper Substances 0.000 claims abstract description 11
- 229910000733 Li alloy Inorganic materials 0.000 claims abstract description 6
- 239000001989 lithium alloy Substances 0.000 claims abstract description 6
- 239000011149 active material Substances 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 4
- 239000007774 positive electrode material Substances 0.000 abstract description 6
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 239000007773 negative electrode material Substances 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011230 binding agent Substances 0.000 abstract description 2
- 239000003792 electrolyte Substances 0.000 abstract description 2
- 229910002804 graphite Inorganic materials 0.000 abstract description 2
- 239000010439 graphite Substances 0.000 abstract description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 abstract description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract 1
- 239000004020 conductor Substances 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 208000028659 discharge Diseases 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 7
- 238000010586 diagram Methods 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- GSJBKPNSLRKRNR-UHFFFAOYSA-N $l^{2}-stannanylidenetin Chemical compound [Sn].[Sn] GSJBKPNSLRKRNR-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
イ、産業上の利用分野
本発明は酸化第二銅を正極活物質とする非水電解液電池
に関するものである。DETAILED DESCRIPTION OF THE INVENTION A. Field of Industrial Application The present invention relates to a non-aqueous electrolyte battery using cupric oxide as a positive electrode active material.
口、従来の技術
酸化第二銅を正極活物質とし、リチウム又はリチウム合
金を負極活物質とする非水電解液電池は例えば特公昭５
９−３３９３５号公報で公知であり、その電池電圧は約
１．４Ｖ程度であるので電子機器の電源に汎用されてい
るアルカリ乾電池、水銀電池或いは銀電池等と互換使用
しうる利点がある。Conventional technology A non-aqueous electrolyte battery using cupric oxide as a positive electrode active material and lithium or a lithium alloy as a negative electrode active material was developed, for example, by
It is known from Japanese Patent No. 9-33935, and since its battery voltage is about 1.4 V, it has the advantage that it can be used interchangeably with alkaline dry batteries, mercury batteries, silver batteries, etc. that are commonly used as power sources for electronic devices.
ところが、この種電池は高率放電において、初期の電池
電圧が落込む、又保存時において電池内に侵入する水分
によってリチウム負極の表面に不働態膜が生成し、内部
抵抗が増大して電池性能が低下すると云った問題がある
。However, in this type of battery, the initial battery voltage drops during high-rate discharge, and a passive film is formed on the surface of the lithium negative electrode due to moisture entering the battery during storage, increasing internal resistance and impairing battery performance. There is a problem that the amount of energy decreases.
ハ、発明が解決しようとする問題点
零発＋３Ａは酸化第二銅を正極活物質とし、リチウム又
はリチウム合金を負極活物質とする非水電解液電池の高
率放電特性及び保存特性の改善を計るものである。C. Problems to be Solved by the Invention Zero-fire +3A aims to improve the high rate discharge characteristics and storage characteristics of a non-aqueous electrolyte battery that uses cupric oxide as a positive electrode active material and lithium or a lithium alloy as a negative electrode active material. It is something to measure.
二、問題点を解決するだめの手段
本発明は酸化第二銅を活物質とする正極ＶＣｊＩｉｉ１
と錫の複合硫化物を添加したこと全要旨とする。2. Means for solving the problems The present invention provides a positive electrode VCjIiii1 using cupric oxide as an active material.
The entire summary is that a composite sulfide of tin and tin was added.
尚、銅と錫の複合硫化物の添加量は正極に対して５〜４
０重量％の範囲が好ましい。In addition, the amount of the composite sulfide of copper and tin added is 5 to 4 to the positive electrode.
A range of 0% by weight is preferred.
又、銅と錫の複合硫化物はＣｕｘＳｎｙｓｚで示される
ものであって、特にＣｕ５ｎＳ２、Ｃｕ５ｎ２Ｓ４或い
はＣｕ２５ｎＳ４が好ましい。Further, the composite sulfide of copper and tin is represented by CuxSnysz, and Cu5nS2, Cu5n2S4 or Cu25nS4 is particularly preferred.
ホ、作 用
酸化第二銅のみ全正極活物質とした場合、高率放電（ｌ
ｋΩ負荷）で約１．２５Ｖの作動電圧全示し、且放電初
期に電圧の落込みが認められる。E. Effect When only cupric oxide is used as the entire positive electrode active material, high rate discharge (l
The total operating voltage was approximately 1.25 V under a kΩ load, and a drop in voltage was observed at the beginning of discharge.
一方銅と錫の複合硫化物のみを正極活物質とした場合に
は高率放電で平担性は悪いものの放電初期に約１．４Ｖ
の作＃電圧を示し、且放電初期の電圧落込みは認められ
ない。但し重量当りの理論エネルギーはリチウム負極と
組合せた場合、酸化第二銅が５７０ ｍＡｈ／Ｐである
のに対し銅と錫の複合硫化物は約５００ ｍＡｈ／＃で
あり、放電容量について云えば酸化第二銅の方が大きい
。On the other hand, when only a composite sulfide of copper and tin is used as the positive electrode active material, the discharge rate is high and the flatness is poor, but the initial discharge voltage is about 1.4V.
shows the operating voltage, and no voltage drop is observed at the beginning of discharge. However, when combined with a lithium negative electrode, the theoretical energy per weight is 570 mAh/P for cupric oxide, while the composite sulfide of copper and tin is about 500 mAh/P. Cupric is larger.
依って、酸化第二銅と、銅と錫の複合硫化物とを併用す
ることにより、放電初期の電圧の落込みがなく、且放電
容量も比較的大きい電池を得ることができる。Therefore, by using cupric oxide and a composite sulfide of copper and tin together, it is possible to obtain a battery that does not have a drop in voltage at the initial stage of discharge and has a relatively large discharge capacity.
又、銅と錫の複合硫化物の放電によって錫が生成し、こ
の錫がリチウム負極と反応して負極表面に錫或いは錫−
リチウム合金の被膜が形成され、リチウムと水との反応
による不働恵膜の生成全阻止し内部抵抗の増大が抑制さ
れる。In addition, tin is generated by the discharge of a composite sulfide of copper and tin, and this tin reacts with the lithium negative electrode to form tin or tin-tin on the negative electrode surface.
A lithium alloy film is formed, completely inhibiting the formation of a passive film due to the reaction between lithium and water, and suppressing an increase in internal resistance.
へ、実施例
実施例１
市販特級の酸化第二銅７０重量優に、添加剤としてのＧ
ｕＳｎ８２２０重量、導電剤としての黒鉛５重量％及び
結着剤としてのフッ素樹脂粉末５重量９６を加えて混合
した後、この混合物全約２トン／ ｃｍ２の圧力で加圧
成型して径１５．０ｍｍ、厚み１．１ ｍｍの成型体金
部、この成型体を２００〜３００℃の温度で熱処理して
正極とする。Examples Example 1 Commercially available special grade cupric oxide 70% G as an additive
After adding and mixing 8220 uSn, 5% by weight of graphite as a conductive agent, and 5% by weight of fluororesin powder as a binder, the mixture was press-molded at a pressure of about 2 tons/cm2 to a diameter of 15.0 mm. , a metal part of the molded body having a thickness of 1.1 mm, and this molded body is heat-treated at a temperature of 200 to 300°C to form a positive electrode.
負極はリチウム板を約０．６ｍｍの厚みに圧延しこのリ
チウム圧延板を径１５．０ｍｍに打抜いたものである。The negative electrode was made by rolling a lithium plate to a thickness of about 0.6 mm, and punching out the rolled lithium plate to a diameter of 15.0 mm.
電解液はプロピレンカーボネートと１゜２ジメトキシエ
タンとの混合溶媒に過塩素酸リチウムを１ｅ、ＴＩ／／
ｌ溶解させ念ものを用い、又セパレータはポリプロピレ
ン不織布を用いて直径２０゜０ｍｍ、厚み２．５ ｍｍ
の本発明電池（Ａｔ）（ｉ７作成した。The electrolyte is 1e of lithium perchlorate in a mixed solvent of propylene carbonate and 1゜2 dimethoxyethane, TI//
l Dissolved material was used, and the separator was made of polypropylene nonwoven fabric with a diameter of 20°0 mm and a thickness of 2.5 mm.
A battery of the present invention (At) (i7) was prepared.
第１図は本発明電池の縦断面図を示し、本発明の要旨と
する正極＋１１は正極缶（２）の内底面に固着せる正極
集電体（３）に圧接されている。一方すチウム負極＋４
１１″ｉ負極缶（６）の内底面に固着せる負極集電体；
６）に圧着されている。（７）はセパレータ、（８）は
絶縁バッキングである。FIG. 1 shows a longitudinal sectional view of a battery according to the present invention, in which a positive electrode +11, which is the gist of the present invention, is pressed into contact with a positive electrode current collector (3) fixed to the inner bottom surface of a positive electrode can (2). On the other hand, lithium negative electrode +4
11″i negative electrode current collector fixed to the inner bottom surface of the negative electrode can (6);
6) is crimped. (7) is a separator, and (8) is an insulating backing.
実 施 例２
添加剤としてＣｕ５ｎＳ２の代わりにＣｕ５ｎ２Ｓ４’
に用いることを除いて他ｌ−ｊ実施例１と同様の本発明
電池（Ａ２）ｉ作成した。Example 2 Cu5n2S4' instead of Cu5nS2 as an additive
A battery of the present invention (A2) was prepared in the same manner as in Example 1 except that it was used for the following.
実 施 例３
添加剤としてＣｕ５ｎＳ２の代わりＫＣｕ２Ｓｎ８４を
用いることを除いて他は実施例１と同様の本発明電池（
Ａ８）を作成した。Example 3 A battery of the present invention was prepared as in Example 1 except that KCu2Sn84 was used instead of Cu5nS2 as an additive.
A8) was created.
比較例ｌ
Ｃｕ５ｎＳ２を添加せず酸化第二銅単独を活物質とする
ことを除いて他は実施例１と同様の比較電池（Ｂ）を作
成した。Comparative Example 1 A comparative battery (B) was prepared in the same manner as in Example 1 except that Cu5nS2 was not added and cupric oxide alone was used as the active material.
比較例２
酸化第二銅を用いずＣｕ５ｎＳ２単独を活物質とするこ
七を除いて他は実施例１と同様の比較電池（Ｑを作成し
た。Comparative Example 2 A comparative battery (Q) was prepared in the same manner as in Example 1 except that cupric oxide was not used and Cu5nS2 alone was used as the active material.
尚、本発明電池及び比較電池はいずれも電池組立後、開
路電圧を下げる目的で電池容量の約４９６を予じめ放電
して完成電池とした。In addition, after the battery of the present invention and the comparative battery were assembled, the battery was pre-discharged to about 496% of the battery capacity for the purpose of lowering the open circuit voltage to obtain a completed battery.
第２図は本発明電池（Ａ１）と比較電池（Ｂ）（Ｃ）と
の温度２５℃、負荷１に、Ｑにおける放電特性比較図を
示し、第２図より本発明電池（Ａ１）は比較電池（Ｂ）
（Ｃ）に比して放電初期の電圧落込みがなく、且高容量
を有することがわかる。Figure 2 shows a comparison diagram of the discharge characteristics of the battery of the present invention (A1) and comparative batteries (B) and (C) at a temperature of 25°C and a load of 1. Battery (B)
It can be seen that, compared to (C), there is no voltage drop at the initial stage of discharge and it has a high capacity.
第３図は銅と錫の複合硫化物の添加量と、電池の放電容
量との関係全示し、添加量としては正極に対して５〜４
０重量％の範囲が好ましいことがわかる。Figure 3 shows the relationship between the amount of copper and tin composite sulfide added and the discharge capacity of the battery.
It can be seen that a range of 0% by weight is preferable.
又、第４図は本発明電池（Ａ１）（Ａ２ ）（Ａ８）と
比較電池（Ｂ）とを温度６０℃、湿度９０％で保存した
時の内部抵抗の径時変化を示す。第４図より本発明電池
は高温、高湿下で保存しても内部抵抗の増大は抑制され
ているのがわかる。Moreover, FIG. 4 shows the change in internal resistance over time when the batteries of the present invention (A1, A2, A8) and the comparative battery (B) were stored at a temperature of 60° C. and a humidity of 90%. From FIG. 4, it can be seen that the increase in internal resistance of the battery of the present invention is suppressed even when stored at high temperature and high humidity.
ト、発明の効果
上述した如く、リチウム又１ｔｉリチウム合金を活物質
とする負極と、非水電解液と、酸化第二銅全活物質とす
る正極とを備えた非水電解液電池において、正極に銅と
錫の複合硫化物を添加することにより高率放電特性及び
保存特性を改善することができるものであり、この種電
池の用途拡大に資するところ極めて犬である。G. Effects of the Invention As described above, in a nonaqueous electrolyte battery comprising a negative electrode made of lithium or a 1ti lithium alloy as an active material, a nonaqueous electrolyte, and a positive electrode made entirely of cupric oxide as an active material, the positive electrode By adding a composite sulfide of copper and tin to the battery, the high rate discharge characteristics and storage characteristics can be improved, which is extremely helpful in expanding the uses of this type of battery.
第１図は本発明電池の半断面図、第２図は電池の高率放
電特性図、第３図は銅と錫の複合硫化物の添加量と電池
の放電容量との関係を示す図、第４図は電池の内部抵抗
の経時変化を示す図である。
（１）・・・正極、（２）・・・正極缶、（３）・・・
正極集電体、（４）・・・負極、（６）・・・負極缶、
（６）・・・負極集電体、（７）・・・セパレータ、（
８）・・・絶縁バッキング。FIG. 1 is a half-sectional view of the battery of the present invention, FIG. 2 is a high rate discharge characteristic diagram of the battery, and FIG. 3 is a diagram showing the relationship between the amount of copper and tin composite sulfide added and the discharge capacity of the battery. FIG. 4 is a diagram showing the change over time in the internal resistance of the battery. (1)...Positive electrode, (2)...Positive electrode can, (3)...
Positive electrode current collector, (4)... negative electrode, (6)... negative electrode can,
(6)...Negative electrode current collector, (7)...Separator, (
8)...Insulating backing.
Claims (2)
、非水電解液と、酸化第二銅を活物質とする正極とを備
えるものであって、前記正極に銅と錫の複合硫化物を添
加したことを特徴とする非水電解液電池。(1) A device comprising a negative electrode using lithium or a lithium alloy as an active material, a nonaqueous electrolyte, and a positive electrode using cupric oxide as an active material, the positive electrode comprising a composite sulfide of copper and tin. A non-aqueous electrolyte battery characterized by the addition of additives.
重量％であることを特徴とする特許請求の範囲第（１）
項記載の非水電解液電池。(2) The amount of the composite sulfide added is 5 to 40% relative to the positive electrode.
Claim No. (1) characterized in that it is % by weight.
The non-aqueous electrolyte battery described in .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61270734A JPH0665029B2 (en) | 1986-11-13 | 1986-11-13 | Non-aqueous electrolyte battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61270734A JPH0665029B2 (en) | 1986-11-13 | 1986-11-13 | Non-aqueous electrolyte battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63124364A true JPS63124364A (en) | 1988-05-27 |
| JPH0665029B2 JPH0665029B2 (en) | 1994-08-22 |
Family
ID=17490219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61270734A Expired - Fee Related JPH0665029B2 (en) | 1986-11-13 | 1986-11-13 | Non-aqueous electrolyte battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0665029B2 (en) |
-
1986
- 1986-11-13 JP JP61270734A patent/JPH0665029B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0665029B2 (en) | 1994-08-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3358478B2 (en) | Organic electrolyte secondary battery | |
| WO2015141120A1 (en) | Lithium primary battery | |
| JPS63124364A (en) | Nonaqueous electrolyte battery | |
| JPS63174270A (en) | Nonaqueous electrolyte cell | |
| JP2664469B2 (en) | Non-aqueous electrolyte battery | |
| JP4581454B2 (en) | Non-aqueous electrolyte and lithium secondary battery using the same | |
| JPH0770315B2 (en) | Non-aqueous electrolyte battery | |
| JPS61181072A (en) | Non-aqueous electrolyte battery | |
| JPH01163969A (en) | Nonaqueous electrolyte battery | |
| JP2708887B2 (en) | Non-aqueous electrolyte battery | |
| JPS61107661A (en) | Nonaqueous electrolyte battery | |
| JPS61107662A (en) | Nonaqueous electrolyte battery | |
| JPS63174269A (en) | Nonaqueous electrolyte cell | |
| JPH01227355A (en) | Nonaqueous electrolyte battery | |
| JP2005044682A (en) | Battery | |
| JPH11260353A (en) | Manufacture of nonaqueous electrolyte secondary battery | |
| JPS6151749A (en) | Nonaqueous electrolyte battery | |
| JPH10162808A (en) | Nonaqueous electrolyte battery and manufacture thereof | |
| JP2001093582A (en) | Lithium secondary battery | |
| JPS63148544A (en) | Nonaqueous electrolyte cell | |
| JPS61124059A (en) | Nonaqueous electrolytic liquid cell | |
| JPS60160566A (en) | Nonaqueous electrolyte battery | |
| JPS60150555A (en) | Nonaqueous electrolyte cell | |
| JPS5998460A (en) | Nonaqueous electrolyte battery | |
| JPH067491B2 (en) | Non-aqueous electrolyte battery |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |