JPS63119415A - Depilatory agent - Google Patents
Depilatory agentInfo
- Publication number
- JPS63119415A JPS63119415A JP26530786A JP26530786A JPS63119415A JP S63119415 A JPS63119415 A JP S63119415A JP 26530786 A JP26530786 A JP 26530786A JP 26530786 A JP26530786 A JP 26530786A JP S63119415 A JPS63119415 A JP S63119415A
- Authority
- JP
- Japan
- Prior art keywords
- depilatory
- polyoxyalkylene
- hair removal
- modified organopolysiloxane
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000002951 depilatory effect Effects 0.000 title abstract description 15
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 125000000217 alkyl group Chemical group 0.000 claims abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims 4
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000006071 cream Substances 0.000 abstract description 7
- 238000002156 mixing Methods 0.000 abstract description 4
- 206010012442 Dermatitis contact Diseases 0.000 abstract 1
- 208000010247 contact dermatitis Diseases 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- -1 polyoxyethylene group Polymers 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000001993 wax Substances 0.000 description 7
- 239000003205 fragrance Substances 0.000 description 6
- 230000007794 irritation Effects 0.000 description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 4
- 206010040880 Skin irritation Diseases 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000036556 skin irritation Effects 0.000 description 4
- 231100000475 skin irritation Toxicity 0.000 description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- CNYFJCCVJNARLE-UHFFFAOYSA-L calcium;2-sulfanylacetic acid;2-sulfidoacetate Chemical compound [Ca+2].[O-]C(=O)CS.[O-]C(=O)CS CNYFJCCVJNARLE-UHFFFAOYSA-L 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 241000700198 Cavia Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241001553290 Euphorbia antisyphilitica Species 0.000 description 2
- 208000010201 Exanthema Diseases 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 235000013869 carnauba wax Nutrition 0.000 description 2
- 239000004203 carnauba wax Substances 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 201000005884 exanthem Diseases 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 241000416162 Astragalus gummifer Species 0.000 description 1
- 102000011782 Keratins Human genes 0.000 description 1
- 108010076876 Keratins Proteins 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000037311 normal skin Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000011076 safety test Methods 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 1
- ZEGFMFQPWDMMEP-UHFFFAOYSA-N strontium;sulfide Chemical compound [S-2].[Sr+2] ZEGFMFQPWDMMEP-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940071127 thioglycolate Drugs 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野コ
本発明は新規な界面活性剤、ざらに詳しくは皮ｒは刺激
性の低い、人体に極めて安全性の高いポリオキシアルキ
レン変性オルガノポリシロキサンを脱毛科基剤中に含有
する脱毛料に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention is a novel surfactant, more specifically, a polyoxyalkylene-modified organopolysiloxane that has low irritation and is extremely safe for the human body. This invention relates to a hair removal agent contained in a hair removal base.
［従来の技術］
従来、脱毛料としては、ワックス状、クリーム状、液状
あるいは粘着テープ状のものが一般的であり、利用され
ている。しかしながらこれら脱毛ｆ４は、通常の皮１ａ
外用剤とは異なり皮膚安全性については若干問題のある
ものが多い。例えば脱毛ワックスｑ場合、一般的にはワ
ックスを融点以上に加温し、液状とした後脱毛する皮膚
上に塗布して固化するのを待ち、固化したワックスと共
に毛を剥がし取る物理的作用を利用した脱毛料であるが
、その基剤としては、ロジン（松脂）が、用いられロジ
ンはアビエチン酸類が主成分であって、これに含士れる
不純物に起因すると思われる刺激があり、塗布した皮膚
が赤く腫れたり水泡ができたりすることがある。また脱
毛クリームや脱毛液は、毛のケラチン構造のＳ−８結合
切断剤をクリーム又は液状基剤中に配合したもので、通
常はチオグリコール酸塩が一般的である。しかしながら
Ｓ−８結合切断剤は、皮膚刺激性の高いものが多く皮膚
安全性の点から考えると問題のあるものが多い。また同
様に粘着テープやシートの場合、その粘着層の成分に起
因すると考えられるカブレを、起こすことが多い。[Prior Art] Conventionally, wax-like, cream-like, liquid-like, or adhesive tape-like products are commonly used as hair removal agents. However, these hair removal f4 are normal skin 1a
Unlike external preparations, many have some issues regarding skin safety. For example, in the case of hair removal wax q, generally the wax is heated above its melting point, liquefied, applied to the skin to be removed, waited for it to solidify, and then the physical action of peeling off the hair together with the solidified wax is used. However, rosin (pine resin) is used as the base, and rosin is mainly composed of abietic acids, which may cause irritation due to impurities contained in it, and may cause irritation to the skin to which it is applied. The area may become red, swollen, or have blisters. Further, depilatory creams and depilatory solutions are those in which an S-8 bond cleaving agent for the keratin structure of hair is blended into a cream or liquid base, and thioglycolate is generally used. However, many S-8 bond cleaving agents are highly irritating to the skin, and many of them are problematic from the viewpoint of skin safety. Similarly, in the case of adhesive tapes and sheets, rashes often occur, which is thought to be caused by the components of the adhesive layer.
［発明が解決しようとする問題点］
本発明者らは上記事情に鑑み、皮膚刺激を抑える添加剤
を求めて鋭意研究をかぎねた結果、オルガノポリシロキ
サン系の特定の面活性剤を脱毛ワックス、脱毛クリーム
、脱毛液、脱毛用テープまたはシートなどの脱毛料に配
合すると、驚くべきことにこれら脱毛料による水泡、カ
ブレなどの皮膚刺激を著しく軽減できることを見出し本
発明を成すに至った。[Problems to be Solved by the Invention] In view of the above circumstances, the present inventors conducted intensive research in search of an additive that suppresses skin irritation. The present inventors have surprisingly discovered that when incorporated into hair removal agents such as hair removal creams, depilatory fluids, depilatory tapes, or sheets, skin irritation such as blisters and rashes caused by these hair removal agents can be significantly reduced, and the present invention has been completed.
［問題点を解決するための手段］
すなわち、本発明は、ポリオキシアルキレン変性オルガ
ノポリシロキサンを含有することを特徴とする皮膚刺激
性の低い、人体に極めて安全性の高い脱毛料である。[Means for Solving the Problems] That is, the present invention is a hair removal agent that is characterized by containing a polyoxyalkylene-modified organopolysiloxane, has low skin irritation, and is extremely safe for the human body.
以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明に用いられるポリオキシアルキレン変性オルガノ
ポリシロキサンは、下記一般式［Ａ］乃至［Ｄ］で表さ
れる化合物である。The polyoxyalkylene-modified organopolysiloxane used in the present invention is a compound represented by the following general formulas [A] to [D].
（以下余白）
本発明に用いられるポリオキシアルキレン変性オルガノ
ポリシロキサンの平均分子量は３０００以上を有するも
のが好ましく、更に好ましくは５０００以上である。ま
−な、ポリオキシアルキレン変性オルガノポリシロキザ
ン分子中にポリオキシアルキレン基を２〜８０重量％含
有するものが好ましく、効果発現の面から更に好ましく
は、１１〜５０重量％である。(The following is a blank space) The average molecular weight of the polyoxyalkylene-modified organopolysiloxane used in the present invention is preferably 3,000 or more, more preferably 5,000 or more. Preferably, the polyoxyalkylene-modified organopolysiloxane molecule contains 2 to 80% by weight of polyoxyalkylene groups, and more preferably 11 to 50% by weight from the viewpoint of effect expression.
ポリオキシアルキレン変性オルガノポリシロキサンの配
合量は、脱毛料基剤中の０．１〜５０重景％、好ましく
は０．１〜３０重景％である。The amount of polyoxyalkylene-modified organopolysiloxane blended is 0.1 to 50% by weight, preferably 0.1 to 30% by weight in the hair removal agent base.
本発明の界面活性剤を配合する脱毛ｖｌはいずれのもの
でも良く、脱毛材中の基剤の形態を選ばない。The hair removal vl containing the surfactant of the present invention may be any type, and the form of the base in the hair removal material is not limited.
本発明の脱毛ｔ１は必要により、そのタイプに応じて、
無機粉末、有機粉末、顔ｔ１１樹脂、鉱物、油分、水、
界面活性剤、保湿剤、低級アルコール、増粘剤、香料、
酸化防止剤、キレート剤、色素、防腐防黴剤等、通常皮
膚外用剤に用いられる成分を配合することができる。Depending on the type of hair removal t1 of the present invention, if necessary,
Inorganic powder, organic powder, face T11 resin, mineral, oil, water,
Surfactants, humectants, lower alcohols, thickeners, fragrances,
Ingredients commonly used in external skin preparations, such as antioxidants, chelating agents, pigments, and antiseptic and antifungal agents, can be blended.
本発明の脱毛料の剤型は任意であり、固型状、ペースト
状、溶液系、可溶化系、乳化系、粉末分散系、水−油二
層系、水−油一粉末三層系等、どのような剤型でも構わ
ない。The formulation of the hair removal agent of the present invention is arbitrary, and may be solid, paste, solution, solubilized, emulsified, powder dispersion, water-oil two-layer, water-oil/powder three-layer, etc. , any dosage form may be used.
［実施例］
つぎに実施例および比較例をあげて、本発明を具体的に
明らかにする。本発明はこれにより限定さ゛れるもので
はない。配合量は重量％である。[Examples] Next, examples and comparative examples will be given to specifically clarify the present invention. The present invention is not limited thereby. The blending amount is in weight%.
実施例１ 脱毛剤
（１）硫化ストロンチウム ４０．０（
２）一般式［へコのポリオキシアルキレン変性オルガノ
ポリシロキサン
（ポリオキシエチレン基２０重量％、
平均分子量６０００） ５．０（３
） Ｉ−リエタノールアミン １２．５（
４）グリセリン １２．５（５
）スターチ ４．０（６）
トラガカントガム １．５（７）炭
酸マグネシウム １．２（８）亜鉛華
４．０（９）水
１８．３（１０）香料
１．０比較例１
実施例１から（２）のポリオキシアルキレン変性オルガ
ノポリシロキサンを除いた以外は（水に置換）全て実施
例１と同様にして比較例１を得た。Example 1 Depilatory agent (1) Strontium sulfide 40.0 (
2) General formula [Heko's polyoxyalkylene-modified organopolysiloxane (polyoxyethylene group 20% by weight, average molecular weight 6000) 5.0 (3
) I-liethanolamine 12.5 (
4) Glycerin 12.5 (5
) Starch 4.0 (6)
Gum tragacanth 1.5 (7) Magnesium carbonate 1.2 (8) Zinc white 4.0 (9) Water
18.3 (10) Fragrance
1.0 Comparative Example 1 Comparative Example 1 was obtained in the same manner as in Example 1 except that the polyoxyalkylene-modified organopolysiloxane of (2) from Example 1 was removed (substituted with water).
実施例１及び比較例１の脱毛剤を、モルモットの皮膚に
１日１回、３日間の開放塗布を行い、皮膚−次刺激性値
を調べた。The hair removal agents of Example 1 and Comparative Example 1 were applied to the skin of guinea pigs once a day for 3 days, and the skin irritation value was examined.
実施例２ 脱毛クリーム
（１）チオグリコール酸カルシウム ６．０（
２）一般式［Ａ］のポリオキシアルキレン変性オルガノ
ポリシロキサン
（ポリオキシエチレン基４０重量％、
平均分子Ｊｉ！、２００００）
３．０、（３）ラウリル硫酸ナトリウム
０．５（４）水酸化カルシウム １
．５（５）セタノール ５．
０（６）ボ′リエチレングリコール
（分子量６０００） ３．０（７
）炭酸カルシウム ２１．０（８）
香料 ０．１５（９）
精製水 残余製法
（２） （３） （５） （６） （８）を混合溶解し
、混合した（１）（４）（７）（９）の中へ撹拌混合し
てペースト状とする。ホモジナイザーにより充分混合し
、その後、熱交換器にて室温まで冷却して脱毛クリーム
を得た。Example 2 Hair removal cream (1) Calcium thioglycolate 6.0 (
2) Polyoxyalkylene-modified organopolysiloxane of general formula [A] (40% by weight of polyoxyethylene groups, average molecular weight Ji!, 20000)
3.0, (3) Sodium lauryl sulfate
0.5(4) Calcium hydroxide 1
．． 5 (5) Cetanol 5.
0(6) Polyethylene glycol (molecular weight 6000) 3.0(7
) Calcium carbonate 21.0 (8)
Fragrance 0.15 (9)
Purified water Residue production method (2) (3) (5) (6) (8) are mixed and dissolved, and stirred and mixed into the mixed (1) (4) (7) (9) to form a paste. The mixture was thoroughly mixed using a homogenizer, and then cooled to room temperature using a heat exchanger to obtain a hair removal cream.
実施例３ 脱毛クリーム
（１）チオグリコール酸カルシウム ８．０
（２）水酸化カルシウム ８．０（
３）沈降炭酸カルシウム １３．０（
４）一般式［Ｂ］のポリオキシアルキレン変性オルガノ
ポリシロキサン
（ポリオキシエチレン基６０重量％、
平均分子量１００００） １０．０
（５）セタノール ６．０
（６）ポリオキシエチレンステアリン酸エーテル （Ｅ
、０．２０モル付加）６．０（７）香料
０．５（８）精製水
残余製法
室温で（１）〜（３）、（８）を混合後、７０°Ｃまで
加温し、このなかに、（４）〜（７）を７０°Ｃで混合
溶解しｔ：ものを撹拌添加した後、室温まで放冷してク
リーム状脱毛料を得た。Example 3 Hair removal cream (1) Calcium thioglycolate 8.0
(2) Calcium hydroxide 8.0 (
3) Precipitated calcium carbonate 13.0 (
4) Polyoxyalkylene-modified organopolysiloxane of general formula [B] (60% by weight of polyoxyethylene groups, average molecular weight 10,000) 10.0
(5) Cetanol 6.0
(6) Polyoxyethylene stearate ether (E
, 0.20 mole addition) 6.0 (7) Fragrance
0.5 (8) Purified water
Remaining manufacturing method After mixing (1) to (3) and (8) at room temperature, heat to 70°C, and mix and dissolve (4) to (7) in this at 70°C. After stirring and adding, the mixture was allowed to cool to room temperature to obtain a cream-like hair removal agent.
実施例４ 脱毛ワックス
（１）ロジン ５８．
０（２）一般式［Ｃ］のポリオキシアルキレン変性オル
ガノポリシロキサン
（ポリオキシエチレン基２０重量％、
ポリオキシプロピレン基１０重１％、
平均分子量４０００） ２５．０
（３）固型パラフィン６０ ２．０
（４）ミツロウ ２．０
（５）カルナバロウ ２．０
（６）キャンデリラロウ ３．０
（７）二酸化チタン ８．０（
８）香料 適量製法
（１）〜（８）を８０℃にて混合溶解し、型に流し込ん
で室’ｊ’ＦＡまで放冷し脱毛ワックスを得た。Example 4 Hair removal wax (1) Rosin 58.
0(2) Polyoxyalkylene-modified organopolysiloxane of general formula [C] (polyoxyethylene groups 20% by weight, polyoxypropylene groups 10% by weight, average molecular weight 4000) 25.0
(3) Solid paraffin 60 2.0
(4) Beeswax 2.0
(5) Carnauba wax 2.0
(6) Candelilla Row 3.0
(7) Titanium dioxide 8.0 (
8) Perfume Appropriate amounts of Preparation Methods (1) to (8) were mixed and dissolved at 80°C, poured into a mold, and left to cool to room 'j'FA to obtain hair removal wax.
比較例４ 脱毛ワックス
（１）ロジン ８３．
０（２）固型パラフィン６０ ２．
０（３）ミツロウ ２．
０（４）カルナバロウ ２．
０（５）キャンデリラロウ ３．
０（６）二酸化チタン ８．
０（７）香料 適量製法
（１）〜（８）を８０℃にて混合溶解し、型に流し込ん
で室温まで放冷し脱毛ワックスを得た。Comparative Example 4 Hair Removal Wax (1) Rosin 83.
0(2) Solid paraffin 60 2.
0 (3) Beeswax 2.
0(4) Carnauba wax 2.
0(5) Candelilla Row 3.
0(6) Titanium dioxide 8.
0(7) Fragrance Appropriate amounts of Preparation Methods (1) to (8) were mixed and dissolved at 80°C, poured into a mold, and allowed to cool to room temperature to obtain a hair removal wax.
実施例５ 脱毛ローション
（１）チオグリコール酸カルシウム ７．０
（２）水酸化ストロンチウム ６．０
（３）硫化ナトリウム １．５
（４）一般式［Ｄ］のポリオキシアルキレン変性オルガ
ノポリシロキサン
（ポリオキシエチレン基５０重量％、
平均分子量１５０００） ５．０
（５）香料 ０．２（
６）ｆｊ製水 残余比較
例２＋ ３＋ ５
実施例２，３．５のシリコン界面活性側を抜去し、精製
水にて置換して、それぞれ比較例２゜３．５の脱毛ｉ１
を調製した。Example 5 Hair removal lotion (1) Calcium thioglycolate 7.0
(2) Strontium hydroxide 6.0
(3) Sodium sulfide 1.5
(4) Polyoxyalkylene-modified organopolysiloxane of general formula [D] (50% by weight of polyoxyethylene groups, average molecular weight 15,000) 5.0
(5) Fragrance 0.2 (
6) fj water production Remaining Comparative Example 2+ 3+ 5 The silicone surface active side of Examples 2 and 3.5 was removed and replaced with purified water, and the hair removal i1 of Comparative Example 2 and 3.5 was removed, respectively.
was prepared.
上記の脱毛ｆｉにつき、モルモットを使用した安全性試
験についてに試験結果は、表１の通りである。Regarding the above hair removal fi, the test results are shown in Table 1 regarding the safety test using guinea pigs.
皮）杏−次刺激性の評価は刺激値か０〜２未満し１、は
とんど刺激性が無り、２〜４は刺激性が有ることを示し
ている。Skin) Apricot - The irritation value was 0 to less than 2, with 1 indicating almost no irritation and 2 to 4 indicating irritation.
［発明の効果］
本発明の脱毛材は、皮膚に対して皮膚安全性が高く、通
常の脱毛１１’ｌを使用した場合、皮膚か赤くなったり
水泡ができたりした方でも安心して使うことのできるも
のである。[Effects of the Invention] The hair removal material of the present invention has high skin safety, and can be used with confidence even by those whose skin becomes red or blisters when using a regular hair removal 11'l. It is possible.
特許出願人 株式会社 資 生 堂 手続補正書（自発） 昭和６３年１月２７日Patent applicant Shiseido Co., Ltd. Procedural amendment (voluntary) January 27, 1986
Claims (2)
ンを含有することを特徴とする脱毛料。(1) A hair removal agent characterized by containing a polyoxyalkylene-modified organopolysiloxane.
ンが、下記一般式［Ａ］乃至［Ｄ］で表される化合物よ
り選ばれたものである特許請求の範囲第１項記載の脱毛
料。 ▲数式、化学式、表等があります▼［Ａ］ ▲数式、化学式、表等があります▼［Ｂ］ ▲数式、化学式、表等があります▼［Ｃ］ ▲数式、化学式、表等があります▼［Ｄ］ （式中、Ｒは炭素数１乃至３のアルキル基、又はフェニ
ル基、Ｒ′は水素、又は炭素数１乃至１２のアルキル基
、ｐは１乃至５の整数、ｍは５乃至１００の整数、ｎお
よびｘは１乃至５０の整数、ｔおよびｙは０乃至５０の
整数である。）(2) The hair removal agent according to claim 1, wherein the polyoxyalkylene-modified organopolysiloxane is selected from compounds represented by the following general formulas [A] to [D]. ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [A] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [B] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [C] ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [ D] (wherein, R is an alkyl group having 1 to 3 carbon atoms or a phenyl group, R' is hydrogen or an alkyl group having 1 to 12 carbon atoms, p is an integer of 1 to 5, and m is an integer of 5 to 100. (Integers, n and x are integers from 1 to 50, and t and y are integers from 0 to 50.)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26530786A JPH0676305B2 (en) | 1986-11-07 | 1986-11-07 | Hair removal |
| EP87308972A EP0266921A3 (en) | 1986-11-06 | 1987-10-09 | Skin irritation alleviation agent and composition thereof |
| CA000549069A CA1328813C (en) | 1986-11-06 | 1987-10-09 | Skin irritation alleviation agent and composition thereof |
| US07/442,376 US5470563A (en) | 1986-11-06 | 1989-11-28 | Alleviating skin irritation resulting from applying tacky tapes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26530786A JPH0676305B2 (en) | 1986-11-07 | 1986-11-07 | Hair removal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63119415A true JPS63119415A (en) | 1988-05-24 |
| JPH0676305B2 JPH0676305B2 (en) | 1994-09-28 |
Family
ID=17415378
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26530786A Expired - Fee Related JPH0676305B2 (en) | 1986-11-06 | 1986-11-07 | Hair removal |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0676305B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02290807A (en) * | 1989-04-28 | 1990-11-30 | Shiseido Co Ltd | Hair cosmetic |
| JPH05178722A (en) * | 1991-12-26 | 1993-07-20 | Kao Corp | Oily solid cosmetic |
-
1986
- 1986-11-07 JP JP26530786A patent/JPH0676305B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02290807A (en) * | 1989-04-28 | 1990-11-30 | Shiseido Co Ltd | Hair cosmetic |
| JPH05178722A (en) * | 1991-12-26 | 1993-07-20 | Kao Corp | Oily solid cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0676305B2 (en) | 1994-09-28 |
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