JPS63101498A - Bleaching detergent composition - Google Patents
Bleaching detergent compositionInfo
- Publication number
- JPS63101498A JPS63101498A JP24678886A JP24678886A JPS63101498A JP S63101498 A JPS63101498 A JP S63101498A JP 24678886 A JP24678886 A JP 24678886A JP 24678886 A JP24678886 A JP 24678886A JP S63101498 A JPS63101498 A JP S63101498A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- weight
- bleaching
- cloth
- detergent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004061 bleaching Methods 0.000 title claims description 31
- 239000003599 detergent Substances 0.000 title claims description 24
- 239000000203 mixture Substances 0.000 title claims description 19
- -1 alkali metal salt Chemical class 0.000 claims description 23
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 150000001868 cobalt Chemical class 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 6
- 150000002978 peroxides Chemical class 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 125000000623 heterocyclic group Chemical group 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 3
- 229960003330 pentetic acid Drugs 0.000 claims description 3
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 description 23
- 239000004744 fabric Substances 0.000 description 23
- 239000007844 bleaching agent Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 11
- 125000003342 alkenyl group Chemical group 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 7
- 244000269722 Thea sinensis Species 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 239000012190 activator Substances 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 235000006468 Thea sinensis Nutrition 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 235000020279 black tea Nutrition 0.000 description 5
- 239000002738 chelating agent Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 238000002845 discoloration Methods 0.000 description 5
- 238000005562 fading Methods 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 235000013616 tea Nutrition 0.000 description 3
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- ZMJBYMUCKBYSCP-UHFFFAOYSA-N (+)-Erythro-hydroxycitric acid Natural products OC(=O)C(O)C(O)(C(O)=O)CC(O)=O ZMJBYMUCKBYSCP-UHFFFAOYSA-N 0.000 description 2
- CIQJWKNJDQKPPO-UHFFFAOYSA-N 1-chloropiperidine Chemical class ClN1CCCCC1 CIQJWKNJDQKPPO-UHFFFAOYSA-N 0.000 description 2
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 2
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 2
- 235000011180 diphosphates Nutrition 0.000 description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 229960002449 glycine Drugs 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- KQTIIICEAUMSDG-UHFFFAOYSA-N tricarballylic acid Chemical compound OC(=O)CC(C(O)=O)CC(O)=O KQTIIICEAUMSDG-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- SFRLSTJPMFGBDP-UHFFFAOYSA-N 1,2-diphosphonoethylphosphonic acid Chemical compound OP(O)(=O)CC(P(O)(O)=O)P(O)(O)=O SFRLSTJPMFGBDP-UHFFFAOYSA-N 0.000 description 1
- AZXGXVQWEUFULR-UHFFFAOYSA-N 2',4',5',7'-tetrabromofluorescein Chemical compound OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 AZXGXVQWEUFULR-UHFFFAOYSA-N 0.000 description 1
- INJFRROOFQOUGJ-UHFFFAOYSA-N 2-[hydroxy(methoxy)phosphoryl]butanedioic acid Chemical compound COP(O)(=O)C(C(O)=O)CC(O)=O INJFRROOFQOUGJ-UHFFFAOYSA-N 0.000 description 1
- OOOLSJAKRPYLSA-UHFFFAOYSA-N 2-ethyl-2-phosphonobutanedioic acid Chemical compound CCC(P(O)(O)=O)(C(O)=O)CC(O)=O OOOLSJAKRPYLSA-UHFFFAOYSA-N 0.000 description 1
- FEWFXBUNENSNBQ-UHFFFAOYSA-N 2-hydroxyacrylic acid Chemical compound OC(=C)C(O)=O FEWFXBUNENSNBQ-UHFFFAOYSA-N 0.000 description 1
- IECMOFZIMWVOAS-UHFFFAOYSA-N 4,4-dimethylpiperidine Chemical compound CC1(C)CCNCC1 IECMOFZIMWVOAS-UHFFFAOYSA-N 0.000 description 1
- MYWGVBFSIIZBHJ-UHFFFAOYSA-N 4-phosphonobutane-1,2,3-tricarboxylic acid Chemical compound OC(=O)CC(C(O)=O)C(C(O)=O)CP(O)(O)=O MYWGVBFSIIZBHJ-UHFFFAOYSA-N 0.000 description 1
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 241000406668 Loxodonta cyclotis Species 0.000 description 1
- XTRXBOSGRMJASM-UHFFFAOYSA-N N1=NN=C(C=C1)NC(=C(C1=C(C(=CC=C1)S(=O)(=O)O)S(=O)(=O)O)NC1=NN=NC=C1)C1=CC=CC=C1 Chemical class N1=NN=C(C=C1)NC(=C(C1=C(C(=CC=C1)S(=O)(=O)O)S(=O)(=O)O)NC1=NN=NC=C1)C1=CC=CC=C1 XTRXBOSGRMJASM-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 102000005158 Subtilisins Human genes 0.000 description 1
- 108010056079 Subtilisins Proteins 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001334 alicyclic compounds Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- VCNSVJZBSHPMSH-UHFFFAOYSA-N azanium;cobalt;chloride Chemical compound [NH4+].[Cl-].[Co] VCNSVJZBSHPMSH-UHFFFAOYSA-N 0.000 description 1
- KXNQKOAQSGJCQU-UHFFFAOYSA-N benzo[e][1,3]benzothiazole Chemical class C1=CC=C2C(N=CS3)=C3C=CC2=C1 KXNQKOAQSGJCQU-UHFFFAOYSA-N 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- FCRWGDJBFPDQPO-UHFFFAOYSA-N ctk4b2887 Chemical compound Cl[N] FCRWGDJBFPDQPO-UHFFFAOYSA-N 0.000 description 1
- XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 235000013905 glycine and its sodium salt Nutrition 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- GTTBQSNGUYHPNK-UHFFFAOYSA-N hydroxymethylphosphonic acid Chemical compound OCP(O)(O)=O GTTBQSNGUYHPNK-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000009725 powder blending Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 210000001550 testis Anatomy 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
夜五見本
本発明は、漂白活性化剤を含む漂白洗浄剤組成物に関し
、詳しくは1色柄物衣類に対しても安全で、しかも漂白
刃に優九た酸素系漂白洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a bleach cleaning composition containing a bleach activator, and more specifically, to an oxygen bleaching composition that is safe even for one-color patterned clothing and that is superior to bleaching blades. The present invention relates to a cleaning composition.
従来技胤
漂白剤または漂白剤を配合した衣類用洗剤は、衣類に付
着した皮脂汚れの除去と、紅茶、コーヒー、果汁、血液
等のしみ汚れの除去ができるため、近年好んで使用され
ている。Bleaching agents or laundry detergents containing bleach have become popular in recent years because they can remove sebum stains from clothing and stains from tea, coffee, fruit juice, blood, etc. .
漂白剤には酸化型と還元型があるが、漂白効果が勝れて
いることなどの観点から酸化型漂白剤が常用されている
。酸化型漂白剤はさらに塩素系と酸素系に大別されるが
、前者は被洗物を変退色させるために色柄物に使用でき
ないこと。There are two types of bleach: oxidized and reduced. Oxidized bleach is commonly used because of its superior bleaching effect. Oxidizing bleaches are further divided into chlorine-based and oxygen-based bleaches, but the former cannot be used on colored and patterned items because they cause discoloration and fading of the items being washed.
特有の不快臭があることなどの欠点がある。これに対し
酸素系漂白剤は、塩素系漂白剤に比べて使用しうる範囲
が広い点、塩素系のような不快臭がない点で勝れており
、家庭用漂白剤として好適である。It has drawbacks such as a characteristic unpleasant odor. On the other hand, oxygen bleaches are superior to chlorine bleaches in that they can be used in a wider range of applications and do not have unpleasant odors like chlorine bleaches, and are therefore suitable as household bleaches.
しかしながら、酸素系漂白剤は塩素系漂白剤に比べて一
般に漂白刃が劣り、充分な漂白効果を得るためには、か
なり長時間の処理を要するという欠点がある。However, oxygen bleaches generally have inferior bleaching blades compared to chlorine bleaches, and have the drawback of requiring a considerably long treatment time to obtain a sufficient bleaching effect.
このため従来から、過炭酸塩や過硼酸塩等の過酸化物を
主体とする漂白剤に、テトラアセチルエチレンジアミン
(TAEI))、テトラアセチルグリコールウリル(T
AGU)、ペンタアセチルグルコース(PAG)等の漂
白活性化剤を併用して漂白効果を高めることが行われて
いる。しかし、これらの活性化剤は過炭酸塩や過硼酸塩
と反応して相対的に強い漂白剤である過酸を生成するた
め、これらの活性化剤を使用した場合に色柄物被洗物が
変退色することがある。For this reason, bleaching agents based on peroxides such as percarbonates and perborates have traditionally been used in bleaching agents such as tetraacetylethylenediamine (TAEI) and tetraacetylglycoluril (TAEI).
Bleach activators such as AGU) and pentaacetylglucose (PAG) are used in combination to enhance the bleaching effect. However, these activators react with percarbonates and perborates to produce peracid, which is a relatively strong bleaching agent. The color may change or fade.
2月1oll昨
本発明は、勝れた漂白効果を有し、しかも色柄物衣料に
も安全な漂白洗浄剤組成物を提供することを目的とする
。An object of the present invention is to provide a bleaching detergent composition that has an excellent bleaching effect and is safe for colored and patterned clothing.
又豆立鼠威
本発明の漂白洗浄剤組成物は、以下の(a)、(b)お
よび(c)成分を、あるいはさらに(d)成分を含有す
ることを特徴とする。The bleaching detergent composition of the present invention is characterized by containing the following components (a), (b), and (c), or further, component (d).
(a)水溶液中で過酸化水素を放出する過酸化物0.5
〜30重量%。(a) 0.5 peroxide releasing hydrogen peroxide in aqueous solution
~30% by weight.
(b)複素環内の第2アミノ基の水素原子がハロゲン原
子で置換された含窒素複素脂環式化合物0.1〜30重
量%。(b) 0.1 to 30% by weight of a nitrogen-containing heteroalicyclic compound in which the hydrogen atom of the secondary amino group in the heterocycle is substituted with a halogen atom.
(c)無機コバルト塩0.001〜2重景%。(c) 0.001-2% inorganic cobalt salt.
重量)ニトリロ三酢酸、エチレンジアミン四酢酸、N−
ヒドロキシエチルエチレンジアミン三酢酸、ジエチレン
トリアミン五酢酸またはこれらのアルカリ金属塩0.1
〜10重量%。Weight) Nitrilotriacetic acid, ethylenediaminetetraacetic acid, N-
Hydroxyethylethylenediaminetriacetic acid, diethylenetriaminepentaacetic acid or their alkali metal salts 0.1
~10% by weight.
(a)成分の水溶液中で過酸化水素を生成する過酸化物
としては、過炭酸塩、過硼酸塩1水和物および4水和物
、ならびにピロリン酸塩、クエン酸塩、硫酸ナトリウム
、尿素およびケイ酸ナトリウムの各過酸化水素付加物が
好適である。Peroxides that produce hydrogen peroxide in an aqueous solution of component (a) include percarbonate, perborate monohydrate and tetrahydrate, as well as pyrophosphate, citrate, sodium sulfate, and urea. and hydrogen peroxide adducts of sodium silicate are preferred.
(b)成分の含窒素複素脂環式化合物は、漂白活性化効
果の点から、単独でまたは複数種を併用して漂白洗浄剤
組成物中に0.1〜30重量%、好ましくは0.5〜1
0重量%配合される。含窒素複素脂環式化合物の窒素原
子に結合するハロゲンとしては、塩素、臭素、ヨウ素の
いずれも使用できるが、コスト面からは特に塩素が望ま
しい。これら化合物の具体例としては以下のものが例示
される。From the viewpoint of bleach activation effect, the nitrogen-containing heteroalicyclic compound as the component (b) is contained in the bleach cleaning composition singly or in combination of 0.1 to 30% by weight, preferably 0.1 to 30% by weight. 5-1
0% by weight is added. As the halogen bonded to the nitrogen atom of the nitrogen-containing heteroalicyclic compound, any of chlorine, bromine, and iodine can be used, but chlorine is particularly desirable from the viewpoint of cost. Specific examples of these compounds include the following.
(i)1−クロロ−ピペリジン誘導体
1−クロロ−ピペリジン:
I2
1−クロロ−2−メチル 1−クロロ−3,5−一
ピベリジン: ジメチル−ピペリジン:
(以下余白)
(以下余白)
○H
(ii)モリホルン誘導体
1−クロロモルホリン:
■
Q
(C)成分の無機コバルト塩としては、ハロゲン化物、
硫酸塩、硝酸塩、炭酸塩、酸化物などであり、具体例と
して塩化コバルト、硫酸コバルト、硝酸コバルト、炭酸
コバルト、酸化コバルト、塩化コバルトアンモニウム等
が例示される。(i) 1-Chloro-piperidine derivative 1-chloro-piperidine: I2 1-chloro-2-methyl 1-chloro-3,5-1piperidine: Dimethyl-piperidine:
(Margins below) (Margins below) ○H (ii) Morihorn derivative 1-chloromorpholine: ■ Q (C) Component inorganic cobalt salts include halides,
These include sulfates, nitrates, carbonates, oxides, etc., and specific examples include cobalt chloride, cobalt sulfate, cobalt nitrate, cobalt carbonate, cobalt oxide, and cobalt ammonium chloride.
(c)成分の添加量は、漂白活性化効果の観点から0.
001〜2重量%であり、好ましくは0.001〜0.
5重量%である。The amount of component (c) added is 0.00000000000000000000000000000000000000000000000000000.
001 to 2% by weight, preferably 0.001 to 0.001% by weight.
It is 5% by weight.
本発明の漂白洗浄剤組成物においては、漂白活性化効果
、特に短い処理時間で所期の効果を実現する点から、(
d)成分として以下の特定のアミノ酸系キレート剤を配
合することができる。In the bleach cleaning composition of the present invention, the bleach activation effect, especially from the point of achieving the desired effect in a short processing time, (
The following specific amino acid-based chelating agents can be blended as component d).
(e)キレート剤:ニトリロ三酢酸、エチレンジアミン
四酢酸、N−ヒドロキシエチルエチレンジアミン三酢酸
、ジエチレントリアミン五酢酸またはこれらの塩から選
ばれる少なくとも1種。(e) Chelating agent: at least one selected from nitrilotriacetic acid, ethylenediaminetetraacetic acid, N-hydroxyethylethylenediaminetriacetic acid, diethylenetriaminepentaacetic acid, or salts thereof.
(e)キレート剤は、漂白洗浄剤組成物中に0.1〜1
0重量%、特に0.5〜5重量%配合することが望まし
い。10重量%を越えて配合しても、通常の漂白条件下
では、効果の向上が期待できなし)。(e) The chelating agent is present in the bleaching detergent composition at 0.1 to 1
It is desirable to add 0% by weight, especially 0.5 to 5% by weight. Even if more than 10% by weight is added, no improvement in effectiveness can be expected under normal bleaching conditions).
本発明の漂白洗浄剤組成物はそのまま又は常用の成分、
例えばアニオン界面活性剤やノニオン界面活性剤を加え
て、また、噴霧乾燥法等により得られた粒状洗剤あるい
はこれに添加剤を加えて得た粒状洗剤に(a)成分、(
b)成分は粉体ブレンドし、(C)成分、(d)成分は
噴霧乾燥前の洗剤スラリーに配合するか、(a)、(b
)成分同様に粉体ブレンドすることによって好適に使用
することができる。粒状洗剤としては1通常の衣料用洗
剤などとして用いられるものが使用でき、たとえば、以
下の(1)〜(7)に例示した各成分を含有することが
でき、これらは使途に応じて適宜選択される。粒状洗剤
は、以下に示すような各成分を含むスラリーを1例えば
粒径200〜500pm、見掛は比重0.1.5〜0.
40 g / m Qとなるように噴霧乾燥することに
より得ることができ、また、得られた噴霧乾燥品にさら
に所望の洗剤成分を粉体ブレンドすることもできる。The bleaching detergent composition of the present invention can be used as is or with conventional ingredients,
For example, the (a) component (
Component b) is powder blended, and components (C) and (d) are blended into the detergent slurry before spray drying, or (a) and (b)
) It can be suitably used by powder blending in the same way as the component. As the granular detergent, those used as normal laundry detergents can be used, and for example, they can contain the components listed in (1) to (7) below, which can be selected as appropriate depending on the intended use. be done. The granular detergent is made of a slurry containing each component as shown below, for example, with a particle size of 200 to 500 pm and an apparent specific gravity of 0.1.5 to 0.
It can be obtained by spray drying to a weight of 40 g/mQ, and desired detergent components can also be powder-blended to the spray-dried product obtained.
(1)界面活性剤
1)平均炭素数10〜16のアルキル基を有する直鎖ま
たは分岐鎖アルキルベンゼンスルホン酸塩
2) 平均炭素数10〜20の直鎖または分岐鎖のアル
キル基またはアルケニル基を有し、1分子内に平均0.
5〜8モルのエチレンオキサイド、プロピレンオキサイ
ドまたはブチレンオキサイドあるいはエチレンオキサイ
ド/プロピレンオキサイド、=0.1/9.9〜9.9
10.1の比で、またはエチレンオキサイド/ブチレン
オキサイド=0.1/9.9〜9.910.1の比で付
加した、アルキルまたはアルケニルエーテル硫酸塩
3)平均炭素数10ないし20のアルキル基またはアル
ケニル基を有するアルキルまたはアルケニル硫酸塩
4)平均炭素数10〜20のオレフィンスルホン酸塩
5) 平均炭素数10〜20のアルカンスルホン酸塩
6)平均炭素数10〜24の飽和または不飽和脂肪酸塩
7)平均炭素数10〜20のアルキル基またはアルケニ
ル基を有し、1分子中に平均0.5〜8モルのエチレン
オキサイド、プロピレンオキサイドまたはブチレンオキ
サイドあるいはエチレンオキサイド/プロピレンオキサ
イド=0゜1/9.9〜9.910.1の比でまたはエ
チレンオキサイド/ブチレンオキサイド=0.1/9.
9〜9.910.1の比で付加した、アルキルまたはア
ルケニルエーテルカルボン酸塩
8)下記の一般式(A)で表わされるα−スルホ脂肪酸
塩またはエステル
03Z
(式中Yは炭素数1〜3のアルキル基または対イオン、
Zは対イオンである。R1は炭素数10〜20のアルキ
ル基またはアルケニル基を表わす。)
ここで対イオンとしてはナトリウム、カリウム等のアル
カリ金属イオンを挙げることができる。(1) Surfactant 1) Straight-chain or branched alkylbenzene sulfonate having an average carbon number of 10-16 alkyl group 2) Having a straight-chain or branched-chain alkyl group or alkenyl group having an average carbon number of 10-20 On average, 0.
5 to 8 moles of ethylene oxide, propylene oxide or butylene oxide or ethylene oxide/propylene oxide, = 0.1/9.9 to 9.9
Alkyl or alkenyl ether sulfates added in a ratio of 10.1 or in a ratio of ethylene oxide/butylene oxide = 0.1/9.9 to 9.910.1 3) Alkyl groups having an average carbon number of 10 to 20 or an alkyl or alkenyl sulfate having an alkenyl group 4) an olefin sulfonate having an average of 10 to 20 carbon atoms 5) an alkanesulfonate having an average of 10 to 20 carbon atoms 6) a saturated or unsaturated fatty acid having an average of 10 to 24 carbon atoms Salt 7) Having an alkyl group or alkenyl group with an average carbon number of 10 to 20, and an average of 0.5 to 8 moles of ethylene oxide, propylene oxide, or butylene oxide in one molecule, or ethylene oxide/propylene oxide = 0° 1/ At a ratio of 9.9 to 9.910.1 or ethylene oxide/butylene oxide = 0.1/9.
Alkyl or alkenyl ether carboxylic acid salt added at a ratio of 9 to 9.910.1 8) α-Sulfo fatty acid salt or ester represented by the following general formula (A) 03Z (wherein Y is a carbon number of 1 to 3 an alkyl group or a counterion of
Z is a counterion. R1 represents an alkyl group or alkenyl group having 10 to 20 carbon atoms. ) Here, examples of the counter ion include alkali metal ions such as sodium and potassium.
9)平均炭素数10〜20のアルキル基またはアルケニ
ル基を有し、1〜20モルのエチレンオキサイドを付加
したポリオキシエチレンアルキルまたはアルケニルエー
テル
10)平均炭素数6〜12のアルキル基を有し、1〜2
0モルのエチレンオキサイドを付加したポリオキシエチ
レンアルキルフェニルエーテル
11)平均炭素数10〜20のアルキル基またはアルケ
ニル基を有し、1〜20モルのプロピレンオキサイドを
付加したポリオキシプロピレンアルキルまたはアルケニ
ルエーテル12)平均炭素数10〜20のアルキル基ま
たはアルケニル基?有し1〜20モルのブチレンオキサ
イドを付加したポリオキシブチレンアルキルまたはアル
ケニルエーテル
13)平均炭素数10〜20のアルキル基またはアルケ
ニル基を有し、総和で1〜30モルのエチレンオキサイ
ドとプロピレンオキサイドあるいはエチレンオキサイド
とブチレンオキサイドを付加した非イオン性活性剤。エ
チレンオキサイドとプロピレンオキサイドまたはブチレ
ンオキサイドとの比は
0.1/9.9〜9.910.1が適当である。9) Polyoxyethylene alkyl or alkenyl ether having an alkyl group or alkenyl group having an average carbon number of 10 to 20 and added with 1 to 20 moles of ethylene oxide 10) Having an alkyl group having an average carbon number of 6 to 12, 1-2
Polyoxyethylene alkylphenyl ether to which 0 mol of ethylene oxide has been added 11) Polyoxypropylene alkyl or alkenyl ether having an average carbon number of 10 to 20 alkyl or alkenyl groups and to which 1 to 20 mol of propylene oxide has been added 12 ) An alkyl group or alkenyl group having an average carbon number of 10 to 20? Polyoxybutylene alkyl or alkenyl ether with 1 to 20 moles of butylene oxide added 13) An alkyl or alkenyl group having an average of 10 to 20 carbon atoms, and a total of 1 to 30 moles of ethylene oxide and propylene oxide or A nonionic surfactant containing ethylene oxide and butylene oxide. The ratio of ethylene oxide to propylene oxide or butylene oxide is suitably 0.1/9.9 to 9.910.1.
14)平均炭素数10〜20の脂肪酸とショ糖からなる
ショ糖脂肪酸エステル
15)平均炭素数10〜20の脂肪酸とグリセリンから
なる脂肪酸グリセリンモノエステル16)下記の一般式
(B)で表わされるアルキルアミンオキサイド
星
R2−N→0 (B)(式中、R2
は炭素数10〜20のアルキル基またはアルケニル基で
あり、R3,R’は炭素数1〜3のアルキル基である。14) Sucrose fatty acid ester consisting of a fatty acid with an average carbon number of 10 to 20 and sucrose 15) Fatty acid glycerin monoester consisting of a fatty acid with an average carbon number of 10 to 20 and glycerin 16) Alkyl represented by the following general formula (B) Amine oxide star R2-N→0 (B) (in the formula, R2
is an alkyl group or alkenyl group having 10 to 20 carbon atoms, and R3 and R' are an alkyl group having 1 to 3 carbon atoms.
)
17)下記の一般式(C)〜(E)で示されるカチオン
界面活性剤
(以下余白)
(式中、R5,R’、R’、R’のうち少なくとも1つ
は炭素数8〜24のアルキルまたはアルケニル基、他は
炭素数1〜5のアルキル基を示す。又は)zロゲンまた
は、メトルサルフエ−1へを示す。)
(式中、R’、 R’、 R7およびXは前述の通り。) 17) Cationic surfactants represented by the following general formulas (C) to (E) (hereinafter referred to as blank spaces) (wherein, at least one of R5, R', R', and R' has a carbon number of 8 to 24 represents an alkyl or alkenyl group; others represent an alkyl group having 1 to 5 carbon atoms; ) (wherein R', R', R7 and X are as described above.
) (式中、Rs、R’、および又は前述の通り。) (wherein Rs, R', and or as previously described.
R”は炭素数2〜3のアルキレン基、nは1〜20の整
数を示す。)
(2)二価金属イオン捕捉剤
1)オリソリン酸塩、ピロリン酸塩、トリポリリン酸塩
、ヘキサメタリン酸塩、フィチン酸塩などのリン酸塩。R" is an alkylene group having 2 to 3 carbon atoms, and n is an integer of 1 to 20.) (2) Divalent metal ion scavenger 1) Orisophosphate, pyrophosphate, tripolyphosphate, hexametaphosphate, Phosphates such as phytate.
2)エタン−1,1ジホスホン酸、エタン−1,1,2
−トリホスホン酸、エタン−1−ヒドロキシ−1,1−
ジホスホン酸およびその誘導体、エタンヒドロキシ−1
,1゜2−トリホスホン酸、エタン−1,2−ジカルボ
キシ−1,2−ジホスホン酸、メタンヒドロキシホスホ
ン酸などのホスホン酸塩。2) Ethane-1,1 diphosphonic acid, ethane-1,1,2
-triphosphonic acid, ethane-1-hydroxy-1,1-
Diphosphonic acid and its derivatives, ethanehydroxy-1
, 1°2-triphosphonic acid, ethane-1,2-dicarboxy-1,2-diphosphonic acid, methanehydroxyphosphonic acid and the like.
3)2−ホスホノブタン−1,2−ジカルボン酸、1−
ホスホノブタン−2,3,4−トリカルボン酸、α−メ
チルホスホノコハク酸などのホスホノカルボン酸塩。3) 2-phosphonobutane-1,2-dicarboxylic acid, 1-
Phosphonocarboxylic acid salts such as phosphonobutane-2,3,4-tricarboxylic acid and α-methylphosphonosuccinic acid.
4)グリシン、アスパラギン酸、グルタミン酸などのア
ミノ酸塩。4) Amino acid salts such as glycine, aspartic acid, and glutamic acid.
以上、1)〜4)の塩としてはアルカリ金属塩が好適で
ある。As mentioned above, alkali metal salts are suitable as the salts 1) to 4).
5)ポリアクリル酸、ポリフマル酸、ポリマレイン酸、
ポリ−α−ヒドロキシアクリル酸などの高分子電解質。5) Polyacrylic acid, polyfumaric acid, polymaleic acid,
Polyelectrolytes such as poly-α-hydroxyacrylic acid.
6)ジグリコール酸、オキシジコハク酸、カルボキシメ
チルオキシコハク酸、クエン酸、乳酸、酒石酸、シュウ
酸、リンゴ酸、オキシジコハク酸、グルコン酸、カルボ
キシメチルコハク酸、カルボキシメチル酒石酸などの有
機酸塩。塩としてはアルカリ金属塩が好適である。6) Organic acid salts such as diglycolic acid, oxydisuccinic acid, carboxymethyloxysuccinic acid, citric acid, lactic acid, tartaric acid, oxalic acid, malic acid, oxydisuccinic acid, gluconic acid, carboxymethylsuccinic acid, and carboxymethyltartaric acid. As the salt, an alkali metal salt is suitable.
7)アルミノケイ酸塩
一般式
%式%)()
(式中のM′はアルカリ金属、M′はカルシウムと交換
可能なアルカリ土類金属、X13’およびWは各成分の
それぞれのモル数を表わし、一般的にはXは0.7〜1
.5゜yは1〜3、Wは任意の数である。)
で表わされる結晶性アルミノケイ酸塩または無定型アル
ミノケイ酸塩若しくはそれらの混合物。7) Aluminosilicate general formula % formula %) () (In the formula, M' is an alkali metal, M' is an alkaline earth metal exchangeable with calcium, and X13' and W represent the number of moles of each component. , generally X is 0.7 to 1
.. 5°y is 1 to 3, and W is an arbitrary number. ) or amorphous aluminosilicate or a mixture thereof.
(3)アルカリ剤あるいは無機電解質
ケイ酸塩、炭酸塩、硫酸塩。塩としてはアルカリ金属が
好適である。(3) Alkaline agents or inorganic electrolytes silicates, carbonates, sulfates. Alkali metals are preferred as salts.
(4)再汚染防止剤
ポリエチレングリコール、ポリビニルアルコール、ポリ
ビニルピロリドン、カルボキシメチルセルロース。(4) Anti-redeposition agents polyethylene glycol, polyvinyl alcohol, polyvinylpyrrolidone, carboxymethylcellulose.
(5)酵素 プロテアーゼ、リパーゼ、アミラーゼ、セルラーゼ。(5) Enzymes Protease, lipase, amylase, cellulase.
(6)蛍光染料
4.4′−ビス−(2−スルホスチリル)−ビフェニル
塩+ 4.4’−ビス−(4−クロロ−3−スルホスチ
リル)−ビフェニル塩、2−(スチルフェニル)ナフト
チアゾール誘導体、4,4′−ビス(トリアゾール−2
−イル)スチルベン誘導体、ビス(トリアジニルアミノ
)スチルベンジスルホン酸誘導体。(6) Fluorescent dye 4.4'-bis-(2-sulfostyryl)-biphenyl salt + 4.4'-bis-(4-chloro-3-sulfostyryl)-biphenyl salt, 2-(stylphenyl)naphtho Thiazole derivative, 4,4'-bis(triazole-2
-yl) stilbene derivatives, bis(triazinylamino)stilbene disulfonic acid derivatives.
(7)香料1色素
2」ノυ弧釆
本発明によれば、特定の含窒素複素脂環式化合物と無機
コバルト塩とを併用した漂白活性化剤系を使用すること
により、変退色が防止されて色柄物にも安全で、しかも
勝れた漂白効果を有する酸素系の漂白洗浄剤組成物が得
られる。(7) Fragrance 1 Pigment 2" arc button According to the present invention, discoloration and fading are prevented by using a bleach activator system that uses a specific nitrogen-containing heteroalicyclic compound and an inorganic cobalt salt in combination. As a result, an oxygen-based bleaching detergent composition that is safe for colored and patterned items and has an excellent bleaching effect can be obtained.
また、さらに(d)成分として特定のアミノ酸系キレー
ト剤を配合することにより、上記の効果が得られる時間
を大幅に短縮することができ、処理時間を短くすること
ができる。Further, by further blending a specific amino acid-based chelating agent as component (d), the time required to obtain the above effects can be significantly shortened, and the processing time can be shortened.
実施例
以下の各実施例においては、各漂白洗浄剤について、次
の基準により漂白効果および変進色度を評価した6
漂白効果試狼
平織綿布(#100)を市販洗剤(ブルーダイヤ;商標
名)を用いて、洗濯機により浴比30倍で50℃におい
て15分間洗浄した後、5分間脱水する。EXAMPLES In each of the following Examples, the bleaching effect and color change of each bleaching detergent was evaluated according to the following criteria. ) for 15 minutes at 50°C in a washing machine at a bath ratio of 30 times, and then dehydrated for 5 minutes.
再度、同一操作にて洗浄、脱水を行なう。次いで、オー
バーフローすすぎを15分間行った後、5分間脱水する
。オーバーフローすすぎ及び脱水操作を合計5回繰り返
し、その後風乾して前処理布とする。Wash and dehydrate using the same procedure again. Next, overflow rinsing is performed for 15 minutes, followed by dehydration for 5 minutes. The overflow rinsing and dehydration operations are repeated a total of 5 times, and then air-dried to obtain a pretreated cloth.
次に、紅茶0.5%溶液を5分間煮沸させ、この中に上
記前処理布を浴比30倍で浸して30分間煮沸し、更に
40℃で30分放置した後、風乾して試験布(紅茶布)
とする。Next, a 0.5% black tea solution was boiled for 5 minutes, and the pretreated fabric was immersed in it at a bath ratio of 30 times, boiled for 30 minutes, left at 40°C for 30 minutes, and then air-dried. (Tea cloth)
shall be.
そして、以下に示すA法あるいはB法で漂白力試験を行
なう。Then, a bleaching power test is conducted using method A or method B shown below.
[A法]
漂白洗浄剤を、25°C1硬度3°DHの水に濃度が0
.8%となるように添加し、この中に浴比50倍で紅茶
布を浸して30分間放置する。その後、綿メリヤスの清
浄布と、25℃、硬度3’DHの水を加えて浴比30倍
洗剤濃度0.15%に調整し、Terg−0−Tome
ter(U、S、Testing社製)を用い回転数1
20rpmで10分間洗浄する。このように処理した試
験布を洗濯機にて1分間の脱水、1分間のオーバーフロ
ーすすぎ及び1分間の脱水を順次行った後、アイロンが
けにより乾LMして漂白処理布とする。[Method A] Bleach cleaning agent is added to water with a hardness of 3°DH at 25°C to a concentration of 0.
.. Add the tea cloth to 8% and soak a black tea cloth in the solution at 50 times the bath ratio and leave it for 30 minutes. Then, add a cotton knitted clean cloth and water at 25°C and a hardness of 3'DH to adjust the detergent concentration to 30 times the bath ratio and 0.15%.
ter (U, S, manufactured by Testing) at a rotation speed of 1.
Wash for 10 minutes at 20 rpm. The thus treated test cloth was sequentially dehydrated for 1 minute, overflow rinsed for 1 minute, and dehydrated for 1 minute in a washing machine, and then dried by ironing to obtain a bleached cloth.
上記前処理布、紅茶布及び漂白処理布の反射度を光電式
反射度光度計(Ei、REP)10. Carl Za
iss社製)を用いてそれぞれ測定し、下記式により漂
白効果を求めた。The reflectance of the pretreated cloth, black tea cloth, and bleached cloth was measured using a photoelectric reflectance photometer (Ei, REP). Carl Za
(manufactured by ISS Inc.), and the bleaching effect was determined using the following formula.
漂白効果:濃亘処狐布9返射団布曵瓦、!)11慶刈0
0前処理布の反射度−紅茶布の反射度
[B法コ
漂白洗浄剤を、25℃、硬度3°DIの水に濃度が0.
15%となるように添加し、この中に紅茶布(5an
X 5an )10枚と綿メリヤスの清浄布を加えて浴
比30培とする。Bleaching effect: Dark wading place fox cloth 9 reflective duvet roof tile,! ) 11 Keigari 0
Reflectance of 0 pre-treated cloth - Reflectance of black tea cloth [Method B] A bleaching detergent was added to water with a hardness of 3° DI at 25°C to a concentration of 0.
Add it to make it 15%, and put black tea cloth (5an
Add 10 pieces of X 5an) and a cotton knitted clean cloth to make a bath ratio of 30 medium.
Terg−0−Tometer(IJ、S、Testi
ng社製)を用い回転数12orρmで10分間清浄す
る。このように処理した試験布を洗濯機にて1分間の脱
水、1分間のオーバーフローすすぎおよび1分間の脱水
を順次行なった後、アイロンがけにより原種して漂白処
理布とする。Terg-0-Tometer (IJ, S, Testi
(manufactured by NG Co., Ltd.) at a rotational speed of 12 or ρm for 10 minutes. The thus treated test cloth was sequentially dehydrated for 1 minute, overflow rinsed for 1 minute, and dehydrated for 1 minute in a washing machine, and then ironed to obtain a bleached cloth.
そして、[A法]と同様に漂白処理布の反射度を測定し
、漂白効果を算出する。Then, similarly to [Method A], the reflectance of the bleached cloth is measured, and the bleaching effect is calculated.
ヌ」」口(象
所定の色素(C,1,Reactive Red21)
で染めた布を7X7cm+こ裁断し、この汚染布の四隅
をピンを用いて枠に固定する。この布に実施例及び比較
例の漂白洗浄剤10gをそれぞれふりかけるとともに、
更に水を噴霧し、15分間放置した後、水洗して風乾す
る。乾燥後の布の状態を下記基準で評価し、変退色の程
度を調べた。Mouth (elephant) Specified pigment (C, 1, Reactive Red 21)
Cut the dyed cloth into 7 x 7 cm+ pieces and fix the four corners of this contaminated cloth to the frame using pins. Sprinkle 10 g of the bleaching detergent of the example and comparative example on this cloth, and
After spraying with water and leaving for 15 minutes, wash with water and air dry. The condition of the cloth after drying was evaluated according to the following criteria, and the degree of discoloration and fading was examined.
3点:漂白洗浄剤に接触した部分が著しく変退色し、斑
点状のものが多く認められ
る。3 points: The area that came into contact with the bleaching detergent was significantly discolored and discolored, and many spots were observed.
2点:漂白洗浄剤に接触した部分が変退色し、斑点状の
ものが明確に認められる。2 points: The area that came into contact with the bleaching detergent has discolored and faded, and spots are clearly visible.
1点:漂白洗浄剤に接触した部分がやや変退色し、斑点
状のものがわずかながら認
められる。1 point: The area that came into contact with the bleaching detergent has slightly discolored and faded, and a few spots are observed.
0点:漂白洗浄剤に接触した部分が全く変退色せず、斑
点が全く認められない。0 point: The area that came into contact with the bleach cleaning agent does not change color or fade at all, and no spots are observed.
実施例1
下記の第1表に示した組成の粒状洗剤、水溶液中で過酸
化水素を放出する過酸化物として過炭酸ナトリウムまた
は過硼酸ナトリウム1水和物および活性化剤として1−
クロロ含窒素脂環式化合物と無機コバルト塩を粉体ブレ
ンドし。Example 1 Granular detergent having the composition shown in Table 1 below, sodium percarbonate or sodium perborate monohydrate as the peroxide which releases hydrogen peroxide in aqueous solution and 1- as the activator.
Powder blend of chloronitrogen-containing alicyclic compound and inorganic cobalt salt.
第2表に示す漂白洗浄剤組成物を調製し、漂白試験(A
法)および変退色試験を行なった。得られた結果を第2
表に示す。The bleaching detergent compositions shown in Table 2 were prepared, and the bleaching test (A
method) and discoloration and fading tests were conducted. The obtained results are shown in the second
Shown in the table.
(以下余白)
第」ヨ及
笠淋m皮
履−一北 父企l(重量%)
LAS Na111 7AOS
−Na” 17ゼオライ1〜
(4A型)15
ケイ酸ソーダ 1゜炭酸ソーダ
1゜チノパールCB S
−X*30.2
酵素(アルカラーゼ2.0T)W2O,4水
5ソーダ
部
※1) アルキル基の炭素数12の直鎖アルキルベンゼ
ンスルホン酸ナトリウム
※2) C□4〜.8のα−オレフィンスルホン酸ナ
トリウム
※3)蛍光増白剤(チバガイギー社製)×4)酵素は、
噴霧軸・爆接に粉体ブレンドした。(Leaving space below) No.'Yo and Kasa Rin's sandals - Ikkita's father's plan (% by weight) LAS Na111 7AOS
-Na” 17 Zeolite 1~
(Type 4A) 15 Sodium silicate 1° Sodium carbonate 1° Chinopal CB S
-X*30.2 Enzyme (Alcalase 2.0T) W2O, 4 water
5 soda
Part *1) Sodium linear alkylbenzene sulfonate whose alkyl group has 12 carbon atoms *2) C□4~. 8 Sodium α-olefin sulfonate *3) Fluorescent brightener (manufactured by Ciba Geigy) x4) Enzyme:
Powder blend was applied to the spray shaft and explosion contact.
(以下余白)
実施例2
第1表に示す粒状洗剤に、過炭酸ナトリウムまたは過硼
酸ナトリウム1水和物および活性化剤として1−クロロ
含窒素脂環式化合物と無機コバルト塩、さらにアミノ酢
酸系キレート剤を粉体ブレンドした第3表に示す漂白洗
浄剤組成物を調製し、漂白試験(B法)および変退色試
験を行なった。得られた結果を第3表に示す。(Left below) Example 2 To the granular detergent shown in Table 1, sodium percarbonate or sodium perborate monohydrate, a 1-chloro nitrogen-containing alicyclic compound and an inorganic cobalt salt as an activator, and an aminoacetic acid-based A bleaching detergent composition shown in Table 3 was prepared by blending a chelating agent into powder, and a bleaching test (Method B) and a discoloration/fading test were conducted. The results obtained are shown in Table 3.
(以下余白)(Margin below)
Claims (1)
.5〜30重量%、 (b)複素環内の第2アミノ基の水素原子がハロゲン原
子で置換された含窒素複素脂環式 化合物0.1〜30重量%および (c)無機コバルト塩0.001〜2重量%を含有する
ことを特徴とする漂白洗浄剤組成物。 2、(a)水溶液中で過酸化水素を放出する過酸化物0
.5〜30重量%、 (b)複素環内の第2アミノ基の水素原子がハロゲン原
子で置換された含窒素複素脂環式 化合物0.1〜30重量% (c)無機コバルト塩0.001〜2重量%、(d)ニ
トリロ三酢酸、エチレンジアミン四酢酸、N−ヒドロキ
シエチルエチレンジアミ ン三酢酸、ジエチレントリアミン五酢酸ま たはこれらのアルカリ金属塩0.1〜10重量% を含有することを特徴とする漂白洗浄剤組成物。[Claims] 1. (a) Peroxide that releases hydrogen peroxide in an aqueous solution 0
.. 5 to 30% by weight, (b) 0.1 to 30% by weight of a nitrogen-containing heteroalicyclic compound in which the hydrogen atom of the secondary amino group in the heterocycle is substituted with a halogen atom, and (c) 0.1 to 30% by weight of an inorganic cobalt salt. A bleaching detergent composition characterized by containing 0.001 to 2% by weight. 2. (a) Peroxide 0 that releases hydrogen peroxide in aqueous solution
.. 5 to 30% by weight, (b) 0.1 to 30% by weight of a nitrogen-containing heteroalicyclic compound in which the hydrogen atom of the secondary amino group in the heterocycle is substituted with a halogen atom, (c) Inorganic cobalt salt 0.001 (d) nitrilotriacetic acid, ethylenediaminetetraacetic acid, N-hydroxyethylethylenediaminetriacetic acid, diethylenetriaminepentaacetic acid, or an alkali metal salt thereof, or an alkali metal salt thereof. agent composition.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24678886A JPS63101498A (en) | 1986-10-17 | 1986-10-17 | Bleaching detergent composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP24678886A JPS63101498A (en) | 1986-10-17 | 1986-10-17 | Bleaching detergent composition |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63101498A true JPS63101498A (en) | 1988-05-06 |
Family
ID=17153680
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP24678886A Pending JPS63101498A (en) | 1986-10-17 | 1986-10-17 | Bleaching detergent composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63101498A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012093608A1 (en) * | 2011-01-07 | 2012-07-12 | ケイ・アイ化成株式会社 | Algicidal/microbicidal agent and algicidal/microbicidal method |
-
1986
- 1986-10-17 JP JP24678886A patent/JPS63101498A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012093608A1 (en) * | 2011-01-07 | 2012-07-12 | ケイ・アイ化成株式会社 | Algicidal/microbicidal agent and algicidal/microbicidal method |
CN103298340A (en) * | 2011-01-07 | 2013-09-11 | K·I化成株式会社 | Algicidal/microbicidal agent and algicidal/microbicidal method |
CN103298340B (en) * | 2011-01-07 | 2016-03-30 | K·I化成株式会社 | Kill algae-bactericide and kill algae-method for disinfection |
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