JPS63101469A - Soft composition for writing - Google Patents
Soft composition for writingInfo
- Publication number
- JPS63101469A JPS63101469A JP61247466A JP24746686A JPS63101469A JP S63101469 A JPS63101469 A JP S63101469A JP 61247466 A JP61247466 A JP 61247466A JP 24746686 A JP24746686 A JP 24746686A JP S63101469 A JPS63101469 A JP S63101469A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- paraffin
- writing
- alkylbenzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000012188 paraffin wax Substances 0.000 claims abstract description 10
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005977 Ethylene Substances 0.000 claims abstract description 5
- -1 Polyethylene Polymers 0.000 claims description 16
- 239000004698 Polyethylene Substances 0.000 claims description 9
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 239000000049 pigment Substances 0.000 abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 abstract description 6
- 239000004606 Fillers/Extenders Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000001993 wax Substances 0.000 abstract description 3
- 239000003921 oil Substances 0.000 abstract description 2
- 239000003925 fat Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は筆記用軟質組成物、さらに詳しくはフレオン、
パステル、色鉛筆芯などの比較的軟質で。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a soft writing composition, more specifically a Freon,
Relatively soft materials such as pastels and colored pencil leads.
適当な筆圧で紙に付着した場合付着層面にりん光を発す
る筆記用軟質組成物に関する。The present invention relates to a soft writing composition that emits phosphorescence on the surface of the adhesive layer when it is applied to paper with appropriate writing pressure.
（従来の技術及び発明が解決しようとする問題点）従来
の筆記用軟質組成物は種々のものが提案されてきた。し
かし従来の筆記用軟質組成物には適当な筆圧で紙等に付
着させた場合、その付着層は明るさが不足し、かつりん
光を加味することができなかった。さらに従来の筆記用
軟質組成物は全原料を加熱混合するさい、原料中の顔料
が分散しに＜＜、製品に一様性が欠除する欠点があった
。(Prior Art and Problems to be Solved by the Invention) Various conventional soft compositions for writing have been proposed. However, when conventional soft writing compositions are applied to paper or the like with appropriate writing pressure, the adhesion layer lacks brightness and phosphorescence cannot be added. Furthermore, conventional soft writing compositions have the disadvantage that when all the raw materials are heated and mixed, the pigments in the raw materials are dispersed, resulting in a lack of uniformity in the product.
（問題点を解決する手段）
ポリエチレンワックス、パラフィン、エチレン以外のオ
レフィン化合物のポリマー、アルキルベンゼン、顔料及
びりん片状アルミニウム粉を混練して得られる筆記用組
成物は顔料及びりん片状アルミニウムが分散し易く、こ
れで紙等に付着させて得られる付着層にはりん片状アル
ミニウム粉及び顔料が均一に分散し、これを用いて書い
た場合の着色は明るく、かつりん光を有するとの知見を
得て本発明を完成した。(Means for solving the problem) A writing composition obtained by kneading polyethylene wax, paraffin, a polymer of an olefin compound other than ethylene, alkylbenzene, a pigment, and flaky aluminum powder has a composition in which the pigment and flaky aluminum are dispersed. It was found that the flaky aluminum powder and pigment were uniformly dispersed in the adhesion layer obtained by adhering it to paper, etc., and that when written with this, the coloring was bright and phosphorescent. As a result, the present invention was completed.
（本発明の構成）
本発明の筆記用着色組成物は “ポリエチレン
１０重量部〜５０重量部パラフィン
１０重社部〜５０重量部エチレン以外のオレフィン化
合物のポリマー１０重量部〜５０重量部
りん片状アルミニウム粉 ５重量部〜６０重量部アルキ
ルベンゼン ３重量部〜４０重量部カラーバッチ
５重量部〜３０重量部を含んでなることを
特徴とするものである。(Structure of the present invention) The writing coloring composition of the present invention is “polyethylene
10 parts by weight - 50 parts by weight paraffin
10 parts by weight - 50 parts by weight Polymer of olefin compounds other than ethylene 10 parts by weight - 50 parts by weight Scale-like aluminum powder 5 parts by weight - 60 parts by weight Alkylbenzene 3 parts by weight - 40 parts by weight Color batch 5 parts by weight - 30 parts by weight It is characterized by comprising:
ポリエチレンの分子量はこれと配合される他の原料の種
類により定められるが１００００から４ｏｏｏｏのもの
が目安となる。The molecular weight of polyethylene is determined depending on the types of other raw materials blended with it, but a standard range is from 10,000 to 4oooo.
エチレン以外のオレフィン化合物のポリマーには炭素数
３〜１２のオレフィン化合物のポリマー又はこれらの混
合物が用いられる。As the polymer of an olefin compound other than ethylene, a polymer of an olefin compound having 3 to 12 carbon atoms or a mixture thereof is used.
りん片アルミニウムは市販された慣用のものでよい。The aluminum flakes may be commercially available and conventional ones.
カラーバッチは所望の色の顔料又はこれと体質顔料をパ
ラフィン、ロウ、油脂などを混じたものである。A color batch is a mixture of a pigment of a desired color or an extender pigment with paraffin, wax, oil, etc.
（効果）
本発明のりん光性着色組成物はりん光成分としてアルミ
ニウム粉が均一に混入されているので、本発明の全色相
にわたりこれを用いて紙等に付着させた付着層は色調が
明るく、かつりん光を発することができる。(Effect) Since the phosphorescent coloring composition of the present invention uniformly contains aluminum powder as a phosphorescent component, the color tone of the adhesive layer applied to paper etc. using this composition is bright across all hues of the present invention. , and can emit phosphorescence.
また、製造のさい顔料、体質顔料、アルミニウム粉がよ
く分散し易いので１色調にむらがない。In addition, the pigment, extender pigment, and aluminum powder are easily dispersed during production, so that one color tone is uniform.
実施例
本発明の実施態様を実施例によって説明するが本発明は
これらによって限定されるものではない。EXAMPLES The embodiments of the present invention will be explained by examples, but the present invention is not limited by these examples.
なお、本文中の部及び％は特記しない限り、それぞれ重
量％を示す。In addition, parts and % in the text each indicate weight % unless otherwise specified.
実施例１
下記に示す配合組成割合いで原料を混合したポリエチレ
ン（平均分子量３００００） ３０部（商品名：ユニ
カーＰＥ 日本ユニカー株式会社製）パラフィン
２０（商品名：に−３Ｃ日本
製蝋株式会社製）ポリプロピレン（平均分子量２４００
０）２０（中国石油株式会社！ｌ）
アルミニウム粉
（商品名：５４に５２ １５東洋ア
ルミニウム株式会社製）
アルキルベンゼン ５（商品
名：バンソルブ 三菱油化株式会社ｍｌ）カラーバッチ
１０（大日精化株式会社Ｉ
ｌ）
混合には加熱ミキサーにまずパラフィンを入れて加熱し
てこれを溶融させ、ついでポリプロピレンとポリエチレ
ンとの所定配合量の約半分をその中に徐々に装入しなが
ら均一に溶融させた。Example 1 30 parts of polyethylene (average molecular weight 30,000) (product name: Unicar PE manufactured by Nippon Unicar Co., Ltd.) paraffin prepared by mixing raw materials in the composition ratio shown below
20 (Product name: Ni-3C manufactured by Nippon Seiwa Co., Ltd.) Polypropylene (average molecular weight 2400
0) 20 (Chugoku Oil Co., Ltd.! l) Aluminum powder (Product name: 54 to 52 15 manufactured by Toyo Aluminum Co., Ltd.) Alkylbenzene 5 (Product name: Bansolve Mitsubishi Yuka Co., Ltd. ml) Color batch 10 (Dainichiseika Co., Ltd.) I
l) For mixing, paraffin was first placed in a heating mixer and heated to melt it, and then approximately half of the predetermined blended amounts of polypropylene and polyethylene were gradually charged into the mixer and uniformly melted.
溶融後アルミニウム粉、アルキルベンゼンを添加し均一
に溶融した後、カラーバッチを加え、さらに残りのポリ
プロピレンとポリエチレンと均一に組成物になった後板
状に成型し、その成形体を粉砕して射出成型してｔ１４
ｍｍ、長さ２００ｍｍとした。この筆記用軟質組成物（
鉛筆の芯）で白紙の上に適当な筆圧で該筆記用軟質組成
物を付着させたところ付着面はりん光が全面にわたり見
られた。After melting, aluminum powder and alkylbenzene are added and melted uniformly, a color batch is added, and the remaining polypropylene and polyethylene are uniformly formed into a composition, which is then molded into a plate shape, and the molded product is crushed and injection molded. Then t14
mm, and the length was 200 mm. This soft writing composition (
When the soft writing composition was applied to a white paper using an appropriate writing pressure using a pencil lead, phosphorescence was observed over the entire surface of the adhered surface.
実施例２
実施例１に準じて下記配合のもので、実施例１と同じ形
状の筆記用軟質組成物の成形体を赤、黄、緑、黒、青に
ついて製作した。Example 2 According to Example 1, molded bodies of soft writing compositions having the same shapes as in Example 1 were produced in red, yellow, green, black, and blue with the following formulations.
得られたそれぞれの筆記用軟質組成物を通常の筆圧で白
紙に付着させたところ、付着層は明るく、かつ一様なり
ん光が発するのが認められた。When each of the obtained soft writing compositions was applied to white paper using normal writing pressure, it was observed that the adhesion layer was bright and emitted uniform phosphorescence.
ポリエチレン（分子量２４０００） ２０部パラ
フィン １０ポリプロピ
レン（分子量３００００） ３０りん片状アルミニ
ウム ２０アルキルベンゼン
１０カラーバツチ
５実施例３
実施例１に準じて下記配合のもので、実施例１と同じ形
状の筆記用軟質組成物の成形体を赤、黄、緑、黒、青に
ついて製作した。Polyethylene (molecular weight 24,000) 20 parts paraffin 10 polypropylene (molecular weight 30,000) 30 flaky aluminum 20 alkylbenzene
10 color batches
5 Example 3 According to Example 1, molded bodies of soft writing compositions having the same shapes as in Example 1 were produced in red, yellow, green, black, and blue with the following formulations.
得られたそれぞれの筆記用軟質組成物を通常の筆圧で白
紙に付着させたところ、付着層は明るく。When each of the obtained soft writing compositions was applied to white paper using normal writing pressure, the adhesion layer was bright.
かつ一様なりん光が発するのが認められた。It was also observed that phosphorescence was uniformly emitted.
Claims (1)
部〜５０重量部 りん片状アルミニウム粉 ５重量部〜６０重量部 アルキルベンゼン ３重量部〜４０重量部 カラーバッチ ５重量部〜３０重量部 を含んでなることを特徴とする筆記用着色組成物[Claims] Polyethylene: 10 parts by weight - 50 parts by weight Paraffin: 10 parts by weight - 50 parts by weight Polymer of olefin compounds other than ethylene 10 parts by weight - 50 parts by weight Flaky aluminum powder 5 parts by weight - 60 parts by weight Alkylbenzene 3 Colored composition for writing characterized by comprising 5 parts by weight to 40 parts by weight Color batch 5 parts by weight to 30 parts by weight
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61247466A JPS63101469A (en) | 1986-10-20 | 1986-10-20 | Soft composition for writing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61247466A JPS63101469A (en) | 1986-10-20 | 1986-10-20 | Soft composition for writing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63101469A true JPS63101469A (en) | 1988-05-06 |
Family
ID=17163866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61247466A Pending JPS63101469A (en) | 1986-10-20 | 1986-10-20 | Soft composition for writing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63101469A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019119793A (en) * | 2017-12-29 | 2019-07-22 | 株式会社パイロットコーポレーション | Solid writing body and solid writing body set using the same |
-
1986
- 1986-10-20 JP JP61247466A patent/JPS63101469A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2019119793A (en) * | 2017-12-29 | 2019-07-22 | 株式会社パイロットコーポレーション | Solid writing body and solid writing body set using the same |
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