JPS6259202A - Powdery coating agent for paddy rice seed - Google Patents

Powdery coating agent for paddy rice seed

Info

Publication number
JPS6259202A
JPS6259202A JP60198574A JP19857485A JPS6259202A JP S6259202 A JPS6259202 A JP S6259202A JP 60198574 A JP60198574 A JP 60198574A JP 19857485 A JP19857485 A JP 19857485A JP S6259202 A JPS6259202 A JP S6259202A
Authority
JP
Japan
Prior art keywords
paddy rice
coating agent
eddp
metalaxyl
calcium peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP60198574A
Other languages
Japanese (ja)
Other versions
JPH0613445B2 (en
Inventor
Hiroshi Kawada
弘 川田
Shozo Okamura
省三 岡村
Akira Wakui
明 涌井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hodogaya Chemical Co Ltd
Original Assignee
Hodogaya Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hodogaya Chemical Co Ltd filed Critical Hodogaya Chemical Co Ltd
Priority to JP60198574A priority Critical patent/JPH0613445B2/en
Publication of JPS6259202A publication Critical patent/JPS6259202A/en
Publication of JPH0613445B2 publication Critical patent/JPH0613445B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Pretreatment Of Seeds And Plants (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE:The titled powdery coating agent, containing a specific compound having the properties of reaction with water to release oxygen, e.g. calcium peroxide or magnesium peroxide, EDDP, etc., and capable of improving the germination ratio and effectively growing paddy rice with a small amount of chemical. CONSTITUTION:A powdery coating agent containing calcium peroxide or magnesium peroxide and N-(2,6-dimethylphenyl)-N-(methoxyacetyl)alanine methyl ester (metalaxyl), having high antimicrobial activity against algal fungi and for preventing fungi of damping-off occurring in a seedling raising boxes, etc., and O-ethyl-S,S-diphenyl dithiophosphate (EDDP) and 4,5,6,7-tetrachlorophthalide (phthalide) useful for blast of paddy rice as active constituents. The mixing ratios based on the calcium peroxide, etc. are preferably as follows; 30-100ppm metalaxyl and 300-800ppm phthalide.

Description

【発明の詳細な説明】 本発明は、洪水土壌中直播用の水S種子の粉衣剤に関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a dusting agent for water S seeds for direct sowing in flooded soil.

近年わが国においては、水稲の新しい栽培方法種子を深
さ1〜1.51mの土壌中に播種するもので、苗を育て
る労力、時間を大幅に削減するばかりでなく、移植時に
おける機械的な植傷みもなく、分げつを促して1〜2割
の増収が期待される。
In recent years, a new cultivation method for paddy rice has been introduced in Japan, in which seeds are sown in soil at a depth of 1 to 1.51 m. This method not only greatly reduces the labor and time required to raise seedlings, but also eliminates mechanical planting during transplanting. There is no damage, and by encouraging tillering, it is expected that the yield will increase by 10-20%.

しかしながら、たんkc裸籾を湛水した状態で深さ1〜
1.5 clmの土壌中に播種しても、酸素不足となり
順調な発芽、生育を期待することはぐきない。
However, when tankkc bare paddy is submerged in water, the depth is 1~1.
Even if the seeds are sown in 1.5 clm of soil, there will be a lack of oxygen and it will not be possible to expect smooth germination and growth.

この問題点を克服する方法として、特公昭47−287
51号公報(水S種子発芽促進法)および持分1185
5−22045号公報(湛水土壌中直播方法)が挙げら
れる。すなわち、過酸化カルシウムが土壌中で水と反応
して徐々に酸素を放出する性質を利用してイネ種子の発
芽を助けるものである。
As a way to overcome this problem,
Publication No. 51 (Water S Seed Germination Promotion Method) and Equity 1185
No. 5-22045 (direct sowing method in flooded soil) is mentioned. That is, calcium peroxide aids in the germination of rice seeds by utilizing the property of reacting with water in the soil and gradually releasing oxygen.

しかしながら、こうした薬剤を粉衣処理した種子であっ
ても、強還元日または播棟後の低温といった環境不良の
条件下とおいては、出芽苗立ちの不良をきたすことがあ
る。
However, even with seeds coated with such chemicals, under poor environmental conditions such as strong reduction days or low temperatures after sowing, poor seedling emergence may occur.

この問題の解決方法の一つとして、過酸化カルシウムに
、3−ヒドロ中シー5−メチルイソキサゾール(商標名
「タチガレン」)を混合して種子粉衣することKより効
果を期待することができるとされている〔小川正巳等 
農業および園芸4B、1297〜1300(1973)
)。しかし、必ずしも、すべての環境不良水田で満足す
べき効果が得られるものではない。
One way to solve this problem is to mix calcium peroxide with 5-methylisoxazole in 3-hydrochloride (trade name: Tachigaren) and coat the seeds with the mixture, which is expected to be more effective. It is said that it is possible [Masami Ogawa et al.
Agriculture and Horticulture 4B, 1297-1300 (1973)
). However, satisfactory effects cannot necessarily be obtained in all environmentally poor paddy fields.

本発明者らは、本問題解決のため鉛量検討を行った結果
、特定の化合物による特異の作用を見い出し、本発明を
完成させた。すなわち本発明は過酸化カルシウムまたは
過酸化マグネシウム、ヘ一(2,6−ジメチルフェニル
)−N−(メトキシアセチル)アラニンメチルエステル
(以下メタラ中シルという)、0−エチル−5,s−ジ
フェニルジチオホスフェート(以下EDDPという)お
よび4.5,6.7−テトラクロルフタリド(以下フサ
ライドという)を含有する湛水土壌中直播用の水稲種子
粉衣剤である。
The present inventors investigated the amount of lead in order to solve this problem, and as a result, discovered a unique effect of a specific compound, and completed the present invention. That is, the present invention provides calcium peroxide or magnesium peroxide, he-(2,6-dimethylphenyl)-N-(methoxyacetyl)alanine methyl ester (hereinafter referred to as metalla-syl), 0-ethyl-5,s-diphenyldithio This is a rice seed dressing for direct sowing in flooded soil containing phosphate (hereinafter referred to as EDDP) and 4,5,6,7-tetrachlorophthalide (hereinafter referred to as futhalide).

メタラキシルは藻菌類に対して高い抗菌力を有し、水稲
の育苗箱等で生ずるムレ菌防止用尾タチガレン剤と混合
してf史用されており、EDDPおよびフサライドは水
稲の主にいもち病に対して使用されるものである。また
、これらを単独で用いた場合においては、若干の出芽向
上がみられるものの、実用的な効果とはいえない。しか
しながら、上記3剤を混合することによって顕著な出芽
率の向上が認められると同時に、これらを単独で使用す
る場合に比較して、薬景をおよそ半分に減少することも
できる。
Metalaxyl has high antibacterial activity against algal fungi and has been used in combination with a powdery mildew agent to prevent the fungus that grows in paddy rice seedling boxes, while EDDP and fusaride are mainly used for rice blast disease. It is used for Furthermore, when these are used alone, although a slight improvement in germination is observed, this cannot be said to be a practical effect. However, by mixing the above-mentioned three agents, a remarkable improvement in the germination rate is observed, and at the same time, the medicinal appearance can be reduced by about half compared to when these are used alone.

本発明を実施するにあたっては、粉衣剤として過酸化カ
ルシウム等にメタラキシル、EDDPおよびフサライド
をあらかじめ混合してから粉衣する方法、粉衣前に種子
を旧記5薬剤の混合希釈ケン濁液に浸漬した後、過酸化
カルシウム等に粉衣する方法、あるいは、過酸化カルシ
ウム等を粉衣する時に使用する水の代りに@記6薬剤を
混合希釈したケン濁液をr更用する等の方法が利用でき
る。
In carrying out the present invention, there is a method in which metalaxyl, EDDP, and fusaride are mixed in advance with calcium peroxide, etc. as a dressing agent, and then the seeds are immersed in a diluted suspension of a mixture of the five chemicals listed above before dressing. After that, there are methods such as coating the calcium peroxide, etc., or replacing the water used when coating the calcium peroxide with a diluted sulfur solution mixed with the chemical described in 6. Available.

さらに、必要に応じて、過酸化カルシウム等の効果の減
少を防止する作用が認められている既知の薬剤との併用
、あるいは目的に応じて生育促進作用を有する植物生育
調節剤と混合して使用することもできる。
Furthermore, if necessary, it can be used in combination with known drugs that have been shown to prevent the effects of calcium peroxide from decreasing, or in combination with plant growth regulators that have a growth-promoting effect depending on the purpose. You can also.

過酸化カルシウム等とメタラキシル、EDDPおよびフ
サライドの混合比率は、過酸化カルシラム製剤(たとえ
ば、有効酸素8%を含有する粉衣用製剤、たとえば商標
名、カルパー粉剤)もしくは過酸化マグネシウム製剤(
たとえば、有効酸素8%及び固結剤として焼石コラを含
有する粉衣用製剤、以下Mf02剤という)に対し、メ
タラキシルは20〜200 ppm、 EDDP 、 
フt?4 Mハトもに100〜1000 ppmである
。望ましくはメタラキシル50〜100 ppm、 B
DDP 、 7f?イドはともに300〜s o o 
ppmである。カルパー粉剤等の10アールあたりのす
用量は約5〜4欣であり、カルバ−粉剤等に対するメタ
ラキシルの添加量は1f以下であって、BDDP、フサ
ライドの添加量にあっても10f以下ときわめて少量で
よい。
The mixing ratio of calcium peroxide, etc., metalaxyl, EDDP and fusaride is based on calcium peroxide preparations (for example, powder dressing preparations containing 8% effective oxygen, such as brand name Calper powder) or magnesium peroxide preparations (
For example, for a dressing preparation containing 8% effective oxygen and calcined kola as a caking agent (hereinafter referred to as Mf02 agent), metalaxyl is 20 to 200 ppm, EDDP,
Fut? 100-1000 ppm for 4M pigeons. Preferably metalaxyl 50-100 ppm, B
DDP, 7f? Both IDs are 300~s o o
It is ppm. The amount of metalaxyl added to Culver powder, etc. per 10 ares is about 5 to 4 ml, and the amount of metalaxyl added to Culver powder, etc. is less than 1 f, and even the amount of BDDP and fusaride added is extremely small, less than 10 f. That's fine.

末剤が良好な生育に寄与する理由は現在のところ不明で
あるが、発芽から苗立に至る過程で、カルバ−粉剤等の
分解を促進する、生成するP&素を収奪するとか、生育
抑制作用を有する物質を生産する等、出芽、苗立に好ま
しくない影響を与える微生物の生育を阻止する、もしく
はこうした環境不良条件下で生育した脆弱な苗に対する
病原菌の侵入を阻止するのではないか、と考えられる。
The reason why the powder contributes to good growth is currently unknown, but it may promote the decomposition of the carver powder, etc. during the process from germination to seedling establishment, take away the generated P& elements, or have a growth inhibiting effect. It is thought that it may inhibit the growth of microorganisms that have an unfavorable effect on germination and seedling establishment, such as by producing substances with Conceivable.

以下に本発明の有用性を試験例を示して説明する。The usefulness of the present invention will be explained below by showing test examples.

試験例1 有機物添加土狼における試験乾粉重量と等i
tのカルパー粉剤およびMP、2剤のそれぞれに、メク
ラキシル0.5%水溶液とEDDP。
Test Example 1 Test dry powder weight and etc. in organic matter added soil
0.5% mecraxyl aqueous solution and EDDP for each of the Calper powder and MP of t.

フサライド混合水利剤(商標名ヒノラプサイド水和剤、
EDDP15%、フサライド20%含有)を適it混合
し、水稲種子(品種 コシヒカリ)に常法によって粉衣
した。この種子20粒をデンプン0.2%を含む代かき
した水田上の深さ18mに播種した。播種後、3−の湛
水とし、20℃遮光下のバイオトロン内に誼き経時的に
出芽数を調査した。試験は4反復で実施し、その結果を
平均値で第1表、第2表に示す。
Fusaride mixed hydrating agent (trade name Hinorapside hydrating agent,
(containing 15% EDDP and 20% fusaride) was mixed in an appropriate amount and coated on paddy rice seeds (variety Koshihikari) using a conventional method. Twenty of these seeds were sown at a depth of 18 m on paddy fields containing 0.2% starch. After sowing, the seedlings were submerged in water for 30 minutes and placed in a biotron at 20° C. in the dark, and the number of sprouts was examined over time. The test was conducted four times, and the results are shown in Tables 1 and 2 as average values.

第1表 カルパー粉剤に混合 第2表 Mr、2剤に混合 試験例2 圃場における試験 水稲種子(品種 ササニシキ)にメタラキシル0.5%
液剤もしくはメタフキシル0,5ノラプサイド水和剤(
EDDP15%,フサライド20%含有)を混和したも
のの処定量を常法により乾粉と同重量のカルバ−粉剤を
粉衣する時に便う水に希釈して混合させた。4月24日
に落水した水田の土壌表層下約1国の部分に、上記によ
って粉衣した種子を10アールあたり、乾粉4kg相当
量(50粒/m )を播種した後、水深3cI11に湛
水した。
Table 1 Mixed with Calper powder Table 2 Mixed with Mr, 2 agents Test example 2 Test in the field 0.5% metalaxyl in paddy rice seeds (variety Sasanishiki)
Liquid formulation or Metafuxil 0,5 Norapside hydrating agent (
A predetermined amount of the mixture (containing 15% EDDP and 20% fusaride) was diluted and mixed with the same weight of carba powder as the dry powder in the water used when dressing. Seeds coated as described above were sown in an amount equivalent to 4 kg of dry powder (50 grains/m2) per 10 ares in about 1 country below the surface of the soil of a paddy field that had flooded on April 24th, and then submerged in water at a depth of 3 cI11. did.

播種後1ケ月目に、健全菌数および1.5葉期以上の菌
数を調査した。試験は1条1区1mとし、10反復で実
施した。この間の平均地温(15m)は11〜20℃で
あった。その結果の平均値を第3表に示す。
One month after sowing, the number of healthy bacteria and the number of bacteria at the 1.5 leaf stage or above were investigated. The test was conducted with 1 row, 1 section, 1 m, and 10 repetitions. The average ground temperature (15 m) during this period was 11 to 20°C. The average values of the results are shown in Table 3.

第3表 試験例5  [!11場における試験 水81棟子(品種 キタアケ)にメクラキシル065%
液剤、もしくはメクラキシル0.5%液剤とヒノラブサ
イド水和剤(EDDP15%,フサライド20%含有)
を混合したものの処定Mを常法により乾粉と同重量のM
rO□剤を粉衣する時に使う水に希釈して混合せしめた
。5月17日に落水した水田の土壌表層下約1cmの部
分に上記によって粉衣した種子を10アールあたり、乾
粉B kg相当量(100粒/m)を播種したり、水深
3cmに湛水した。播種5遅間目に、健全菌数および′
5葉期以上の菌数を調査した。試験は1条1区1mとじ
10反復で実施した。この間の平均地温は8〜24℃で
あった。その結果の平均値を第4表に示す。
Table 3 Test Example 5 [! Meclaxil 065% in test water 81 mung roe (variety Kitaake) in field 11
Liquid formulation or Mecraxil 0.5% liquid formulation and Hinolabside hydrating agent (contains EDDP 15%, Fusaride 20%)
The same weight of M as the dry powder was prepared using a conventional method.
The rO□ agent was diluted and mixed with the water used for dressing. Seeds coated as described above were sown in an amount equivalent to dry powder B kg (100 grains/m) per 10 ares about 1 cm below the soil surface of a paddy field that had been flooded on May 17th, and submerged in water to a depth of 3 cm. . At the 5th late sowing, the number of healthy bacteria and '
The number of bacteria at the 5-leaf stage and above was investigated. The test was conducted with 1 row, 1 section, 1 m binding, and 10 repetitions. The average soil temperature during this period was 8 to 24°C. The average values of the results are shown in Table 4.

第4表 ■無処理   −56,64i 上記試験例に明らかなように、メタラΦシル、BDDP
およびフサライドを混合してカルバ−粉剤等に添加粉衣
した種子では、いずれも有意な出芽数、苗立数の増加が
認められる。すなわち、人工的に富栄養にした土壌条件
下においても、圃場条件下においてもカルパー粉剤等の
効果の減少を防ぎ、苗立率を向上させることを示した。
Table 4 ■ No treatment -56,64i As is clear from the above test example, metallized Φsil, BDDP
A significant increase in the number of germination and the number of seedlings established was observed in both cases of seeds coated with a mixture of fusaride and carver powder. In other words, it was shown that the effect of Culper powder etc. is prevented from decreasing and the seedling establishment rate is improved both under artificially enriched soil conditions and under field conditions.

以下に実施例を示す。Examples are shown below.

実施例1 カルバ−粉剤          97.7重電部メタ
ラキシル0.5%液剤     2.0重量部ヒノラプ
サイド水和剤(EDDP15%。
Example 1 Carba powder 97.7 parts metalaxyl 0.5% liquid 2.0 parts by weight Hinorapside wettable powder (EDDP 15%).

フサライド20%含有)0.3重量部 以上を十分混合したものの、乾粉重量と同量を水稲種子
に水を用いて粉衣した。
Although 0.3 parts by weight or more (containing 20% fusaride) was thoroughly mixed, rice seeds were coated with water in an amount equal to the weight of the dry powder.

実施例2 MfO,剤(有効酸素8%含有)    95.0重量
部メタラキシル0.5%液剤      2.olff
i部ヒノラプサイド粉剤(BDDP2%。
Example 2 MfO, agent (containing 8% effective oxygen) 95.0 parts by weight Metalaxyl 0.5% liquid agent 2. olff
Part i: Hinolapside powder (BDDP 2%).

フサライド1.5%含有)      40重量部以上
を十分混合したものの、乾粉重量と同量を水稲種子に水
を用いて粉衣した。
Although 40 parts by weight or more of fusaride (containing 1.5%) were thoroughly mixed, the same amount as the weight of the dry powder was coated on paddy rice seeds using water.

実施例5 乾粉重量に等しい量のカルパー粉剤を、カルパー粉剤の
3%に相当するメクラキシル0.5%液剤。
Example 5 An amount of Calper powder equal to the dry powder weight was mixed with Mecraxil 0.5% solution, which corresponds to 3% of the Calper powder.

および0.2%に相当するヒノラブサイド水和剤(ED
DP15%、フサライド20%含有)を混合希釈した水
を用いて粉衣した。
and Hino Rabside Hydrating Agent (ED) equivalent to 0.2%
It was coated with water mixed and diluted with DP (containing 15% DP and 20% fusaride).

保土谷化学工業株式会社Hodogaya Chemical Industry Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] 過酸化カルシウムまたは過酸化マグネシウム、N−(2
,6−ジメチルフェニル)−N−(メトキシアセチル)
アラニンメチルエステル、o−エチル−s,s−ジフェ
ニルジチオホスフェートおよび4,5,6,7−テトラ
クロルフタリドを含有する湛水土壌中直播用の水稲種子
粉衣剤。
Calcium peroxide or magnesium peroxide, N-(2
,6-dimethylphenyl)-N-(methoxyacetyl)
A rice seed dressing for direct sowing in flooded soil containing alanine methyl ester, o-ethyl-s,s-diphenyldithiophosphate and 4,5,6,7-tetrachlorophthalide.
JP60198574A 1985-09-10 1985-09-10 Paddy seed dressing agent Expired - Lifetime JPH0613445B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60198574A JPH0613445B2 (en) 1985-09-10 1985-09-10 Paddy seed dressing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60198574A JPH0613445B2 (en) 1985-09-10 1985-09-10 Paddy seed dressing agent

Publications (2)

Publication Number Publication Date
JPS6259202A true JPS6259202A (en) 1987-03-14
JPH0613445B2 JPH0613445B2 (en) 1994-02-23

Family

ID=16393439

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60198574A Expired - Lifetime JPH0613445B2 (en) 1985-09-10 1985-09-10 Paddy seed dressing agent

Country Status (1)

Country Link
JP (1) JPH0613445B2 (en)

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CN1050030C (en) * 1991-12-16 2000-03-08 海保株式会社 Antimicrobial agent and method for sustaning freshness of food
WO2006005764A3 (en) * 2004-07-14 2006-04-13 Solvay Use of inorganic peroxides for oxygenation of soil in order to prevent diseases caused by anaerobic agents in plants
JP2013133285A (en) * 2011-12-26 2013-07-08 Sds Biotech Corp Composition for reducing phytotoxicity of herbicide
CN116602313A (en) * 2023-07-20 2023-08-18 南京农业大学三亚研究院 Wheat stain-resistant seed coating agent and application method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105660719A (en) * 2016-01-11 2016-06-15 中国水稻研究所 Oxygen-evolving seed coating agent for promoting direct seeding rice seed germination and seedling development and coating method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50148533A (en) * 1974-05-23 1975-11-28
JPS527437A (en) * 1975-07-04 1977-01-20 Nippon Petrochem Co Ltd Solvent for noxious organism controlling agents
JPS5454811A (en) * 1978-09-04 1979-05-01 Yoshiaki Nakamura Special rice seed
JPS5692851A (en) * 1979-12-04 1981-07-27 Basf Ag Nnsubstitutedd22methylnaphthylamide and bactericide containing it

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50148533A (en) * 1974-05-23 1975-11-28
JPS527437A (en) * 1975-07-04 1977-01-20 Nippon Petrochem Co Ltd Solvent for noxious organism controlling agents
JPS5454811A (en) * 1978-09-04 1979-05-01 Yoshiaki Nakamura Special rice seed
JPS5692851A (en) * 1979-12-04 1981-07-27 Basf Ag Nnsubstitutedd22methylnaphthylamide and bactericide containing it

Cited By (5)

* Cited by examiner, † Cited by third party
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