JPS6256088B2 - - Google Patents
Info
- Publication number
- JPS6256088B2 JPS6256088B2 JP58027367A JP2736783A JPS6256088B2 JP S6256088 B2 JPS6256088 B2 JP S6256088B2 JP 58027367 A JP58027367 A JP 58027367A JP 2736783 A JP2736783 A JP 2736783A JP S6256088 B2 JPS6256088 B2 JP S6256088B2
- Authority
- JP
- Japan
- Prior art keywords
- oxide
- weight
- mol
- cao
- loss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 14
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 11
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 claims description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 5
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 5
- 239000000696 magnetic material Substances 0.000 claims description 5
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 4
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 3
- 230000035699 permeability Effects 0.000 description 9
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 8
- 239000000292 calcium oxide Substances 0.000 description 8
- WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(iii) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910001935 vanadium oxide Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Soft Magnetic Materials (AREA)
- Compounds Of Iron (AREA)
- Magnetic Ceramics (AREA)
Description
本発明は、通信機用の変成器磁心として使用す
るのに適する高初透磁率と低損失特性を有する酸
化物磁性材料に関するものである。
近年、電子装置の小型化が進んでいるが、これ
に対して電子装置に使用される電子部品について
も小型化が要求されている。この要求に従つて本
発明者は、高透磁率かつ低損失インダクタンス素
子の開発に従事し、本発明をするに至つた。
本発明は、上記の事より、高透磁率と低損失な
特性を有する酸化物磁性材料を提供するものであ
る。
即ち、酸化第二鉄（Fe2O3）、酸化マンガン
（MnO）、酸化亜鉛（ZnO）を主成分とし、酸化
カルシウム（CaO）0.003〜0.1重量％、酸化ビス
マス（Bi2O3）0.003〜0.05重量％および酸化バナ
ジウム（V2O5）0.003〜0.1重量％を複合添加する
ことによつて、高透磁率かつ抵損失な酸化物磁性
材料を得るものである。
以下。図面により詳細に本発明を説明する。第
１図および第２図は酸化第二鉄（Fe2O3）52モル
％、酸化マンガン（MnO）26モル％、酸化亜鉛
（ZnO）22モル％から成る基本組成に、酸化カル
シウム（CaO）0.003〜0.1重量％、酸化ビスマス
（Bi2O3）0.003〜0.05重量％、酸化バナジウム
（V2O5）0.003〜0.05重量％を単独又は複合添加
し、混合、仮焼後1300℃で焼成した場合の初透磁
率μiacの特性曲線であり、第１図はCaOを
0.01wt％とし、曲線１〜曲線５はそれぞれV2O5
を０、0.003、0.01、0.05 0.1wt％添加したもので
あり、第２図はV2O5を0.01wt％とし、曲線６〜
曲線１０はそれぞれCaOを０、0.003、0.01、
0.05、0.1wt％添加したものである。又、第３図
は第１図の場合の損失係数のグラフであり、曲線
１１〜曲線１５はそれぞれV2O5を０、0.003、
0.01、0.05 0.1wt％添加したものであり、第４図
は第２図の場合の損失係数のグラフであり、曲線
１６〜曲線２０は、それぞれCaOを０、0.003、
0.01、0.05、0.1wt％添加したものである。図面
より、酸化カルシウム、酸化バナジウム単独の添
加ではμiacの向上が見られないが、酸化ビスマ
スとの複合添加により0.005〜0.03wt％の範囲で
μiacが著しく向上することが判かる。
また、CaO、Bi2O3複合添加により、CaO0.01
〜0.03wt％Bi2O30.005〜0.03wt％の範囲でμiac
をあまり低下させることなく、損失が著しく小さ
くなる。又、V2O5、Bi2O5複合添加により
V2O50.005〜0.05wt％、Bi2O30.005〜0.03wt％の
範囲でμicaの低下をあまり低下させることな
く、損失が小さくなる。
CaO、Bi2O3、V2O5複合添加により、CaO0.01
〜0.03wt％、Bi2O30.005〜0.03wt％、V2O50.005
〜0.05wt％の範囲でμiacをあまり低下させるこ
となく、損失を著しく小さくすることができる。
実施例
Fe2O352モル％、MnO26モル％、ZnO22モル％
から成る基本組成にCaOを0.01又は0.02重量％、
Bi2O3を0.01重量％、V2O5を0.01又は0.02重量％
複合添加し、ボールミルで20時間混合し、800℃
で２時間仮焼した後外径30φ内径18φ、高さ10mm
のリング状試料に成形し、1300℃で４時間1.0％
の酸素を含む窒素雰囲気中で焼成したフエライト
の10KHzでの透磁率（μiac）、磁気損失係数（tan
δ／μiac）を第１表に示す。
The present invention relates to an oxide magnetic material having high initial permeability and low loss characteristics suitable for use as a transformer core for communication equipment. 2. Description of the Related Art In recent years, electronic devices have become smaller, and electronic components used in electronic devices are also required to be smaller. In response to this demand, the present inventor engaged in the development of a high magnetic permeability and low loss inductance element, and came up with the present invention. In view of the above, the present invention provides an oxide magnetic material having high magnetic permeability and low loss characteristics. That is, the main components are ferric oxide (Fe 2 O 3 ), manganese oxide (MnO), and zinc oxide (ZnO), calcium oxide (CaO) 0.003-0.1% by weight, and bismuth oxide (Bi 2 O 3 ) 0.003-0.003% by weight. By adding 0.05% by weight and 0.003 to 0.1% by weight of vanadium oxide (V 2 O 5 ), an oxide magnetic material with high magnetic permeability and resistance loss is obtained. below. The present invention will be explained in detail with reference to the drawings. Figures 1 and 2 show a basic composition consisting of 52 mol% ferric oxide (Fe 2 O 3 ), 26 mol% manganese oxide (MnO), 22 mol% zinc oxide (ZnO), and calcium oxide (CaO). 0.003 to 0.1% by weight, bismuth oxide (Bi 2 O 3 ) 0.003 to 0.05% by weight, and vanadium oxide (V 2 O 5 ) 0.003 to 0.05% by weight were added singly or in combination, mixed, calcined, and then fired at 1300°C. Figure 1 shows the characteristic curve of the initial permeability μiac when CaO is
0.01wt%, and curves 1 to 5 are each V 2 O 5
0, 0.003, 0.01, 0.05 and 0.1wt%, and Figure 2 shows V 2 O 5 as 0.01wt% and curves 6 to 6.
Curve 10 has CaO of 0, 0.003, 0.01, and
0.05, 0.1wt% added. Moreover, FIG. 3 is a graph of the loss coefficient in the case of FIG. 1, and curves 11 to 15 indicate V 2 O 5 of 0, 0.003, and
0.01, 0.05 and 0.1wt% are added. FIG. 4 is a graph of the loss coefficient in the case of FIG.
0.01, 0.05, and 0.1wt% were added. From the drawing, it can be seen that the addition of calcium oxide or vanadium oxide alone does not improve μiac, but the combined addition with bismuth oxide significantly improves μiac in the range of 0.005 to 0.03 wt%. In addition, by adding CaO and Bi 2 O 3 together, CaO0.01
μiac in the range of ~0.03wt% Bi2O3 0.005 ~0.03wt%
The loss is significantly reduced without significantly reducing the In addition, by adding V 2 O 5 and Bi 2 O 5 together,
In the range of V 2 O 5 0.005 to 0.05 wt% and Bi 2 O 3 0.005 to 0.03 wt%, the loss becomes small without reducing the decrease in μica too much. CaO0.01 by combined addition of CaO, Bi 2 O 3 and V 2 O 5
~0.03wt%, Bi2O3 0.005 ~0.03wt%, V2O5 0.005
In the range of ~0.05wt%, the loss can be significantly reduced without significantly reducing μiac. Example Fe 2 O 3 52 mol%, MnO2 6 mol%, ZnO2 2 mol%
0.01 or 0.02% by weight of CaO in the basic composition consisting of
0.01% by weight of Bi 2 O 3 , 0.01 or 0.02% by weight of V 2 O 5
Add the composite, mix in a ball mill for 20 hours, and heat at 800℃.
After calcination for 2 hours, the outer diameter is 30φ, the inner diameter is 18φ, and the height is 10mm.
Formed into a ring-shaped sample and heated to 1.0% at 1300℃ for 4 hours.
Magnetic permeability (μiac) and magnetic loss coefficient (tan
δ/μiac) is shown in Table 1.
【表】
以上、詳記した如く、本発明によれば、高透磁
率であり低損失である酸化物磁性材料を得ること
ができるものであり、工業的に非常に有意義なも
のである。[Table] As detailed above, according to the present invention, it is possible to obtain an oxide magnetic material having high magnetic permeability and low loss, and it is industrially very significant.
第１図〜第４図はFe2O352モル％、MnO26モル
％、ZnO22モル％を主成分とし、CaO、Bi2O3、
V2O5を単独又は複合添加した場合のグラフであ
り、第１図はCaOを0.01wt％一定とした初透磁率
のグラフであり、第２図はV2O5を0.01wt％一定
とした初透磁率のグラフであり、第３図は第１図
の場合の損失係数のグラフであり、第４図は第２
図の場合の損失係数のグラフである。
In Figures 1 to 4, the main components are 52 mol% Fe 2 O 3 , 26 mol% MnO, and 2 mol% ZnO, and CaO, Bi 2 O 3 ,
These are graphs when V 2 O 5 is added alone or in combination. Figure 1 is a graph of initial permeability with CaO constant at 0.01wt%, and Figure 2 is a graph when V 2 O 5 is constant at 0.01wt%. Fig. 3 is a graph of the loss coefficient in the case of Fig. 1, and Fig. 4 is a graph of the initial permeability in the case of Fig. 2.
It is a graph of a loss coefficient in the case of a figure.
Claims (1)
ンガン（MnO）22〜39モル％、酸化亜鉛
（ZnO）８〜25モル％を主成分とし、酸化カルシ
ウム（CaO）0.003〜0.1重量％、酸化ビスマス
（Bi2O3）0.003〜0.05重量％、酸化バナジウム
（V2O5）0.003〜0.1重量％を副成分として同時に
含むことを特徴とする酸化物磁性材料。1 The main components are 50 to 56 mol% of ferric oxide (Fe 2 O 3 ), 22 to 39 mol% of manganese oxide (MnO), 8 to 25 mol% of zinc oxide (ZnO), and 0.003 to 0.003 of calcium oxide (CaO). An oxide magnetic material characterized in that it simultaneously contains 0.1% by weight, bismuth oxide (Bi 2 O 3 ) 0.003 to 0.05% by weight, and vanadium oxide (V 2 O 5 ) 0.003 to 0.1% by weight as subcomponents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58027367A JPS59156920A (en) | 1983-02-21 | 1983-02-21 | Magnetic oxide material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58027367A JPS59156920A (en) | 1983-02-21 | 1983-02-21 | Magnetic oxide material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59156920A JPS59156920A (en) | 1984-09-06 |
| JPS6256088B2 true JPS6256088B2 (en) | 1987-11-24 |
Family
ID=12219072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58027367A Granted JPS59156920A (en) | 1983-02-21 | 1983-02-21 | Magnetic oxide material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59156920A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05330906A (en) * | 1991-03-07 | 1993-12-14 | Hitachi Ferrite Ltd | Mn-zn-based ferrite |
| JP2907253B2 (en) * | 1993-03-05 | 1999-06-21 | 日立金属 株式会社 | High permeability Mn-Zn ferrite |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5149079A (en) * | 1974-10-25 | 1976-04-27 | Nippon Mining Co | ZAIRYOSHIKENSOCHI |
| JPS56160330A (en) * | 1980-05-13 | 1981-12-10 | Tohoku Metal Ind Ltd | Magnetic oxide material |
| JPS6253446A (en) * | 1985-08-30 | 1987-03-09 | 日産テクシス株式会社 | Apparatus for driving weft yarn engaging body of weft yarn storage apparatus |
-
1983
- 1983-02-21 JP JP58027367A patent/JPS59156920A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5149079A (en) * | 1974-10-25 | 1976-04-27 | Nippon Mining Co | ZAIRYOSHIKENSOCHI |
| JPS56160330A (en) * | 1980-05-13 | 1981-12-10 | Tohoku Metal Ind Ltd | Magnetic oxide material |
| JPS6253446A (en) * | 1985-08-30 | 1987-03-09 | 日産テクシス株式会社 | Apparatus for driving weft yarn engaging body of weft yarn storage apparatus |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59156920A (en) | 1984-09-06 |
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