JPS6238638B2 - - Google Patents

Info

Publication number
JPS6238638B2
JPS6238638B2 JP595083A JP595083A JPS6238638B2 JP S6238638 B2 JPS6238638 B2 JP S6238638B2 JP 595083 A JP595083 A JP 595083A JP 595083 A JP595083 A JP 595083A JP S6238638 B2 JPS6238638 B2 JP S6238638B2
Authority
JP
Japan
Prior art keywords
heat pipe
metal hydride
heat
hydrogen
hollow part
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP595083A
Other languages
Japanese (ja)
Other versions
JPS59131885A (en
Inventor
Ikuro Yonezu
Kenji Nasako
Naojiro Pponda
Takashi Sakai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Institute of Advanced Industrial Science and Technology AIST
Original Assignee
Agency of Industrial Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology
Priority to JP595083A priority Critical patent/JPS59131885A/en
Publication of JPS59131885A publication Critical patent/JPS59131885A/en
Publication of JPS6238638B2 publication Critical patent/JPS6238638B2/ja
Granted legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D15/00Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
    • F28D15/02Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
    • F28D15/04Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure
    • F28D15/046Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure characterised by the material or the construction of the capillary structure

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
  • Sorption Type Refrigeration Machines (AREA)

Description

【発明の詳細な説明】 この発明はスリーブ形(ドーナツ形)ヒートパ
イプの中央中空部に金属水素化物を充填してな
り、該ヒートパイプの外管と内管との間に形成さ
れた円筒形のウイツク部を、該ヒートパイプの軸
に平行な1以上の仕切り部材で仕切つて、特にヒ
ートパイプの軸方向の熱伝達能力に優れた金属水
素化物の容器に関する。
DETAILED DESCRIPTION OF THE INVENTION This invention is a sleeve-shaped (doughnut-shaped) heat pipe in which the central hollow part is filled with a metal hydride, and a cylindrical shape formed between an outer tube and an inner tube of the heat pipe. The present invention relates to a metal hydride container which has an excellent heat transfer ability, particularly in the axial direction of the heat pipe, by partitioning the wick part of the heat pipe with one or more partition members parallel to the axis of the heat pipe.

なおこの明細書において“ウイツク部”とは、
スリーブ形ヒートパイプの外管と内管との間に形
成され、ウイツクと作動液とが封入された円筒形
の空隙部を意味する。
In this specification, "wick part" means
A cylindrical cavity formed between the outer tube and the inner tube of a sleeve-shaped heat pipe and filled with a heat pipe and a working fluid.

金属水素化物は多量の水素を可逆的に吸収・放
出する性質を有することから水素貯蔵用材料とし
ての利用が注目され、また水素の吸収・放出時の
反応熱が大きいので蓄熱材料としての利用も注目
されている。そして金属水素化物を使用する水素
貯蔵装置や蓄熱装置では金属水素化物に効率よく
熱を吸収させること、また金属水素化物から発生
する熱を効率よく取り出すことが重要である。
Since metal hydrides have the property of reversibly absorbing and releasing large amounts of hydrogen, their use as hydrogen storage materials has attracted attention, and since they generate a large amount of reaction heat when absorbing and releasing hydrogen, they can also be used as heat storage materials. Attention has been paid. In hydrogen storage devices and heat storage devices that use metal hydrides, it is important to make the metal hydride absorb heat efficiently and to efficiently extract heat generated from the metal hydride.

しかし金属水素化物は、水素化・脱水素化を繰
り返すと微粉化し体積減少を起こすので熱交換機
能が低下すること、金属水素化物自体の熱伝導率
が小さいことから反応熱伝達の点不利なことなど
の問題点がある。
However, when metal hydrides are repeatedly hydrogenated and dehydrogenated, they become pulverized and their volume decreases, which reduces their heat exchange function, and the metal hydrides themselves have low thermal conductivity, which is disadvantageous in terms of reaction heat transfer. There are other problems.

先にこの発明の発明者らは、これらの問題点を
改善するとともに金属水素化物容器自体への顕熱
ロスを減少させた、スリーブ形ヒートパイプの中
央中空部に金属水素化物を充填してなる金属水素
化物容器を開示した(特開昭58−47988号公報お
よび特開昭58−47989号公報参照)。これらの金属
水素化物容器のスリーブ形ヒートパイプの管内の
熱伝達は作動液の蒸発・凝縮のサイクルを繰返し
てなされるが、その過程には、該ヒートパイプの
軸に対して垂直の方向へのウイツクを通しての作
動液の移動の過程が含まれる。そしてこれらの金
属水素化物容器のウイツク部は該ヒートパイプの
外管と内管との間に形成された仕切りのない円筒
形の密閉されたひとつの空隙で形成されているの
で、ヒートパイプの軸の垂直方向への作動液の移
動速度は十分とはいえず、作動液移動の斑が原因
で起る部分的なドライアウト現象が予測される。
従つてこの方向の熱伝達能力は満足すべきもので
はない。
Previously, the inventors of this invention have solved these problems and reduced the sensible heat loss to the metal hydride container itself by filling the central hollow part of a sleeve-shaped heat pipe with metal hydride. A metal hydride container has been disclosed (see JP-A-58-47988 and JP-A-58-47989). Heat transfer in the sleeve-shaped heat pipes of these metal hydride containers is achieved through repeated cycles of evaporation and condensation of the working fluid, but this process involves a change in the direction perpendicular to the axis of the heat pipe. This includes the process of moving hydraulic fluid through the wick. The opening part of these metal hydride containers is formed by a single sealed cylindrical gap with no partitions formed between the outer tube and the inner tube of the heat pipe, so that the axis of the heat pipe The movement speed of the hydraulic fluid in the vertical direction is not sufficient, and it is predicted that a partial dryout phenomenon will occur due to uneven movement of the hydraulic fluid.
Therefore, the heat transfer ability in this direction is not satisfactory.

この発明は上記のスリーブ形ヒートパイプのウ
イツク部を改良して、該ヒートパイプの軸方向の
熱伝達能力を向上させた発明であり、 スリーブ形ヒートパイプの中央中空部に金属水
素化物を充填し、その中央中空部の両端中央開口
を閉鎖部材で閉鎖し、その閉鎖部材には開閉弁を
有する水素出入導管を、水素は通過しうるが金属
水素化物を通過しえない区画体を介して、ヒート
パイプ中央中空部に通じるよう設置してなる金属
水素化物容器であつて、 該ヒートパイプの外管と内管との間に形成され
た円筒形のウイツク部を、該ヒートパイプの軸に
平行な1以上の仕切り部材で仕切つてなることを
特徴とする金属水素化物容器を提供するものであ
る。
This invention is an invention in which the heat transfer capacity of the heat pipe in the axial direction is improved by improving the heat pipe part of the sleeve-shaped heat pipe, and the central hollow part of the sleeve-shaped heat pipe is filled with metal hydride. , the central opening at both ends of the central hollow part is closed with a closing member, and a hydrogen inlet/outlet conduit having an on-off valve is connected to the closing member, through a partition body through which hydrogen can pass but not the metal hydride, A metal hydride container installed to communicate with a central hollow part of a heat pipe, wherein a cylindrical wick part formed between an outer pipe and an inner pipe of the heat pipe is arranged parallel to the axis of the heat pipe. The present invention provides a metal hydride container characterized in that it is partitioned by one or more partition members.

この発明の容器は、ウイツク部がヒートパイプ
の軸方向に平行な仕切り板で仕切られているがそ
の仕切り板の数に制限はなく、適宜選択される。
このような仕切り板を設けることによつてヒート
パイプの軸方向に対して垂直方向への作動液の移
動行程が小さくなるためこの方向へのウイツクを
通しての作動液の作動速度は余り問題にならず、
また部分的なドライアウト現象もほとんど起らな
くなる。従つて作動液とその蒸気の移動は該ヒー
トパイプの軸と平行な方向に十分なされるため、
この方向の熱伝達に優れている。その結果この発
明の容器は、後述のような熱交換器を、その水素
出入導管の設置されていない側の一端に設置した
蓄熱装置用として好適なものである。
In the container of the present invention, the wick portion is partitioned by partition plates parallel to the axial direction of the heat pipe, but the number of partition plates is not limited and can be selected as appropriate.
By providing such a partition plate, the moving distance of the working fluid in the direction perpendicular to the axial direction of the heat pipe becomes smaller, so the working speed of the working fluid through the wick in this direction is not so much of a problem. ,
In addition, the local dry-out phenomenon hardly occurs. Therefore, the working fluid and its vapor are sufficiently moved in the direction parallel to the axis of the heat pipe.
Excellent heat transfer in this direction. As a result, the container of the present invention is suitable for use in a heat storage device in which a heat exchanger as described below is installed at one end of the container where the hydrogen inlet/output conduit is not installed.

次にこの発明を図面によつて説明する。 Next, this invention will be explained with reference to the drawings.

第1図はこの発明の金属水素化物容器の一実施
例の縦断面図で第2図はそのA―B断面図であ
る。1及び2はそれぞれ、スリーブ形ヒートパイ
プの外管と内管を示し、3はウイツク部10内に
配置されたウイツクを示す。そしてこのスリーブ
形ヒートパイプの両端開口は閉鎖板4a,4bで
閉鎖され、閉鎖板4aには開閉弁7を有する水素
出入導管8が取付けられ、更にこの水素出入導管
8の閉鎖板4aへの取付け部からヒートパイプ中
央中空部5に、水素は通過しうるが金属水素化物
は通過し得ない例えば焼結合金のごとき多孔性導
管9が同軸に延出され、該中央中空部5に金属水
素化物6が充填されている。この金属水素化物容
器は多孔性導管9によつて金属水素化物の系外へ
の飛散が防止されると共に水素の出入が迅速に行
われる。なおこの導管9がこの実施例のように対
向する閉鎖板4bまで延出されず中央中空部の途
中まで突出したもの、また円筒状以外の形態のも
のでもよい。第2図においてウイツク部10はス
リーブ形ヒートパイプの中心軸に平行な仕切り板
11a,11bによつて仕切られて2つに分割さ
れている。このようにふたつに分割されているの
で、スリーブ形ヒートパイプの中心軸に平行な方
向への、作動液とその蒸気の移動が十分に行われ
この方向への熱伝達に優れている。
FIG. 1 is a longitudinal cross-sectional view of an embodiment of the metal hydride container of the present invention, and FIG. 2 is a cross-sectional view thereof taken along the line AB. Reference numerals 1 and 2 respectively indicate an outer tube and an inner tube of the sleeve-shaped heat pipe, and 3 indicates a wick disposed within the wick portion 10. The openings at both ends of this sleeve-shaped heat pipe are closed by closing plates 4a and 4b, and a hydrogen inlet/output conduit 8 having an on-off valve 7 is attached to the closing plate 4a, and furthermore, the hydrogen inlet/outlet conduit 8 is attached to the closing plate 4a. A porous conduit 9, for example made of sintered alloy, through which hydrogen can pass but not metal hydrides, extends coaxially from the central hollow part 5 of the heat pipe to the central hollow part 5 of the heat pipe. 6 is filled. In this metal hydride container, the porous conduit 9 prevents the metal hydride from scattering out of the system, and allows hydrogen to enter and exit quickly. Note that the conduit 9 may not extend to the opposing closing plate 4b as in this embodiment, but may protrude halfway into the central hollow, or may have a shape other than a cylinder. In FIG. 2, the heat pipe 10 is partitioned into two parts by partition plates 11a and 11b parallel to the central axis of the sleeve-shaped heat pipe. Since it is divided into two parts in this way, the working fluid and its vapor can sufficiently move in the direction parallel to the central axis of the sleeve-shaped heat pipe, and heat transfer in this direction is excellent.

次いで第1図と第2図に示した金属水素化物容
器を用いた蓄熱装置の縦断面図を第3図に示し
た。すなわち前記の金属水素化物容器に熱交換器
21を接設した蓄熱装置であり、この熱交換器2
1には熱媒22が充填され、また熱媒22の出入
導管23a,23bを有する。そして金属水素化
物容器自体は断熱材20で覆われている。この蓄
熱装置は次のようにして熱交換を行う。
Next, FIG. 3 shows a longitudinal sectional view of a heat storage device using the metal hydride container shown in FIGS. 1 and 2. That is, it is a heat storage device in which a heat exchanger 21 is connected to the metal hydride container, and this heat exchanger 2
1 is filled with a heat medium 22 and has conduits 23a and 23b for the heat medium 22 in and out. The metal hydride container itself is then covered with a heat insulating material 20. This heat storage device performs heat exchange as follows.

まず蓄熱時には、熱エネルギーを熱媒22から
金属水素化物容器に伝達することによつて、スリ
ーブ形ヒートパイプを通じて同容器中の金属水素
化物16を加熱し、発生した水素ガスは多孔性導
管19によつて過され開放された開閉弁17を
通過し水素出入導管18によつて水素ボンベなど
(図示せず)に導かれて貯蔵される。一方、放熱
時には、水素ボンベなどから水素ガスが開放され
た開閉弁17を通過し水素出入導管を通じさらに
多孔性導管19を通過して金属水素化物に接触さ
せて反応させ発生した熱をスリーブ形ヒートパイ
プを通じて熱交換器21に伝達し、熱媒22を加
熱し、その熱を利用する。この金属水素化物容器
のウイツク部は前記第2図に示したようにふたつ
に分割されているのでスリーブ形ヒートパイプの
軸方向への作動液とその蒸気の移動が十分に行わ
れ、この蓄熱装置は優れた熱交換能力を有する。
First, during heat storage, thermal energy is transferred from the heating medium 22 to the metal hydride container to heat the metal hydride 16 in the container through the sleeve-shaped heat pipe, and the generated hydrogen gas is transferred to the porous conduit 19. The hydrogen then passes through the opened on-off valve 17 and is led to a hydrogen cylinder or the like (not shown) through the hydrogen in/out conduit 18 and stored. On the other hand, during heat dissipation, hydrogen gas from a hydrogen cylinder or the like passes through the open on-off valve 17, passes through the hydrogen inlet/output conduit, and further passes through the porous conduit 19, contacts the metal hydride, reacts, and generates heat. The heat is transmitted to the heat exchanger 21 through the pipe, heats the heat medium 22, and utilizes the heat. Since the wick part of the metal hydride container is divided into two parts as shown in FIG. has excellent heat exchange ability.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はこの発明の金属水素化物容器の一実施
例の縦断面、第2図は第1図のA―Bにおける断
面図、第3図はこの発明の一実施例の金属水素化
物容器を用いる蓄熱装置の縦断面図である。 1,11…外管、2,12…内管、3,13…
ウイツク、4a,4b,14a,14b…閉鎖
板、5,15…スリーブ形ヒートパイプの中央中
空部、6,16…金属水素化物、7,17…開閉
弁、8,18…水素出入導管、9,19…管状区
画体、20…断熱材、21…熱交換器、22…熱
媒、および23a,23b…熱媒出入導管、1
0,30…ウイツク部、および11a,11b…
仕切り板。
FIG. 1 is a longitudinal section of an embodiment of a metal hydride container of the present invention, FIG. 2 is a sectional view taken along line AB in FIG. 1, and FIG. It is a longitudinal cross-sectional view of the heat storage device used. 1, 11...outer tube, 2,12...inner tube, 3,13...
4a, 4b, 14a, 14b... Closing plate, 5, 15... Central hollow part of sleeve-shaped heat pipe, 6, 16... Metal hydride, 7, 17... Opening/closing valve, 8, 18... Hydrogen inlet/outlet conduit, 9 , 19... Tubular compartment body, 20... Heat insulating material, 21... Heat exchanger, 22... Heat medium, and 23a, 23b... Heat medium inlet/output conduit, 1
0, 30...wick part, and 11a, 11b...
Partition board.

Claims (1)

【特許請求の範囲】 1 スリーブ形ヒートパイプの中央中空部に金属
水素化物を充填し、その中央中空部の両端中央開
口を閉鎖部材で閉鎖し、その閉鎖部材には開閉弁
を有する水素出入導管を、水素は通過しうるが金
属水素化物を通過しえない区画体を介して、ヒー
トパイプ中央中空部に通じるよう設置してなる金
属水素化物容器であつて、 該ヒートパイプの外管と内管との間に形成され
た円筒形のウイツク部を、該ヒートパイプの軸に
平行な1以上の仕切り部材で仕切つてなることを
特徴とする金属水素化物の容器。
[Scope of Claims] 1. A central hollow part of a sleeve-shaped heat pipe is filled with a metal hydride, and central openings at both ends of the central hollow part are closed with closing members, and the closing member includes a hydrogen inlet/outlet conduit having an on-off valve. A metal hydride container installed to communicate with the central hollow part of the heat pipe through a partition that allows hydrogen to pass through but not the metal hydride, the outer tube and the inner tube of the heat pipe being connected to each other. 1. A metal hydride container, characterized in that a cylindrical wick portion formed between the heat pipe and the heat pipe is partitioned by one or more partition members parallel to the axis of the heat pipe.
JP595083A 1983-01-19 1983-01-19 Container made of metal hydride Granted JPS59131885A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP595083A JPS59131885A (en) 1983-01-19 1983-01-19 Container made of metal hydride

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP595083A JPS59131885A (en) 1983-01-19 1983-01-19 Container made of metal hydride

Publications (2)

Publication Number Publication Date
JPS59131885A JPS59131885A (en) 1984-07-28
JPS6238638B2 true JPS6238638B2 (en) 1987-08-19

Family

ID=11625169

Family Applications (1)

Application Number Title Priority Date Filing Date
JP595083A Granted JPS59131885A (en) 1983-01-19 1983-01-19 Container made of metal hydride

Country Status (1)

Country Link
JP (1) JPS59131885A (en)

Also Published As

Publication number Publication date
JPS59131885A (en) 1984-07-28

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