JPS6226217Y2 - - Google Patents
Info
- Publication number
- JPS6226217Y2 JPS6226217Y2 JP1980038728U JP3872880U JPS6226217Y2 JP S6226217 Y2 JPS6226217 Y2 JP S6226217Y2 JP 1980038728 U JP1980038728 U JP 1980038728U JP 3872880 U JP3872880 U JP 3872880U JP S6226217 Y2 JPS6226217 Y2 JP S6226217Y2
- Authority
- JP
- Japan
- Prior art keywords
- heat
- water
- barrier layer
- sensitive recording
- label
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010410 layer Substances 0.000 claims description 57
- 230000004888 barrier function Effects 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 17
- 238000004040 coloring Methods 0.000 claims description 16
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 8
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 239000013053 water resistant agent Substances 0.000 claims description 6
- 229920003169 water-soluble polymer Polymers 0.000 claims description 5
- 239000002861 polymer material Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 description 21
- 238000004519 manufacturing process Methods 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- 238000001454 recorded image Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 description 2
- TXFPEBPIARQUIG-UHFFFAOYSA-N 4'-hydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1 TXFPEBPIARQUIG-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 229940015043 glyoxal Drugs 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- XBQRPFBBTWXIFI-UHFFFAOYSA-N 2-chloro-4-[2-(3-chloro-4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(Cl)=CC=1C(C)(C)C1=CC=C(O)C(Cl)=C1 XBQRPFBBTWXIFI-UHFFFAOYSA-N 0.000 description 1
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
- YMTYZTXUZLQUSF-UHFFFAOYSA-N 3,3'-Dimethylbisphenol A Chemical compound C1=C(O)C(C)=CC(C(C)(C)C=2C=C(C)C(O)=CC=2)=C1 YMTYZTXUZLQUSF-UHFFFAOYSA-N 0.000 description 1
- NSOYUYYTMRZCLE-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-methylphenyl)ethyl]-2-methylphenol Chemical compound C1=C(O)C(C)=CC(CCC=2C=C(C)C(O)=CC=2)=C1 NSOYUYYTMRZCLE-UHFFFAOYSA-N 0.000 description 1
- 229940073735 4-hydroxy acetophenone Drugs 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- IMHDGJOMLMDPJN-UHFFFAOYSA-N biphenyl-2,2'-diol Chemical group OC1=CC=CC=C1C1=CC=CC=C1O IMHDGJOMLMDPJN-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- OIDPCXKPHYRNKH-UHFFFAOYSA-J chrome alum Chemical compound [K]OS(=O)(=O)O[Cr]1OS(=O)(=O)O1 OIDPCXKPHYRNKH-UHFFFAOYSA-J 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Landscapes
- Heat Sensitive Colour Forming Recording (AREA)
- Adhesive Tapes (AREA)
Description
【考案の詳細な説明】
本考案は感熱記録方式により記録しうる剥離ラ
ベルすなわち感熱記録用剥離ラベルに関し、更に
詳しくは有機樹脂フイルムを長期間重ねておいて
も記録した画像が消失されることのない感熱記録
用剥離ラベルに関する。[Detailed description of the invention] The present invention relates to a release label that can be recorded using a heat-sensitive recording method, that is, a release label for heat-sensitive recording. Regarding a peelable label for heat-sensitive recording.
従来より、剥離ラベルは、商品にその容量、価
格、品質等を表示するための商品ラベル、郵送物
に貼付する宛名表示ラベル等に広く用いられてい
る。これら剥離ラベルにプリンターによつて表示
記録するものがあるが、その記録方式としては押
印方式、タイプリボン方式等が実用化されてい
る。しかしながらこれら記録方式では騒音がある
こと、インクを補充したり、リボン交換が必要で
ある等の欠点を有することからこのようなことが
必要とされない感熱記録方式の採用が強く望まれ
ていた。しかしながら感熱記録方式を剥離ラベル
の記録に適用しようとすると前記利点がある反面
大きな欠点を有していた。すなわち、感熱記録材
料として記録画像が鮮明であり、保存カブリが少
ないという点で実用点には無色又は淡色のロイコ
染料とこれを熱時発色せしめる酸性物質との発色
成分系を用いたものが最も有利であるが、このタ
イプの感熱記録材料を採用した剥離ラベルは例え
ば商品ラベルに適用した場合に塩化ビニル樹脂フ
イルム、ポリプロピレンフイルム等でそのラベル
の上から包込んだりあるいはこれらフイルムで包
装した商品の上に剥離ラベルを貼着し、この商品
を重ね合わせて保管あるいは陳列したとき、わず
か半日程度で熱記録した画像が判読できないほど
消失してしまうという大きな欠点を有していたか
らである。 Conventionally, peelable labels have been widely used as product labels for indicating the capacity, price, quality, etc. of products, address display labels attached to mailed items, and the like. Some of these peelable labels are displayed and recorded using a printer, and the printing methods such as the stamping method and the type ribbon method have been put into practical use. However, these recording methods have drawbacks such as noise and the need to replenish ink and replace the ribbon, so there has been a strong desire to adopt a thermal recording method that does not require such things. However, when trying to apply the thermal recording method to recording on peelable labels, although it has the above-mentioned advantages, it also has major drawbacks. In other words, from a practical point of view, the most practical heat-sensitive recording material is one that uses a color-forming component system consisting of a colorless or light-colored leuco dye and an acidic substance that causes the color to develop when heated. Advantageously, a peelable label employing this type of heat-sensitive recording material can be applied to a product label, for example, by wrapping the label over the label with a vinyl chloride resin film, polypropylene film, etc., or by wrapping a product wrapped with such a film. This is because when a peelable label is attached to the top of the product and the products are stored or displayed one on top of the other, the thermally recorded image disappears to the point of being unreadable after only half a day.
このような有機樹脂フイルムあるいはシートと
重ねた場合記録画像が消失してしまうという現象
は郵送物の宛名ラベルの場合にも多く発生し、こ
のような理由から剥離紙への記録方式として感熱
方式の採用が阻まれていたものである。 This phenomenon of recorded images disappearing when stacked with organic resin films or sheets often occurs in the case of address labels for mailed items, and for this reason, thermal methods are not recommended as a recording method for release paper. Recruitment was being prevented.
本考案者は上記したような現象につき鋭意、検
討し、樹脂フイルムの表面に存在するかあるいは
フイルム内部から浸出する可塑剤が原因している
ことをつきとめた。すなわち、これら有機樹脂を
フイルム化するために可塑剤を添加するが、この
可塑剤が加熱により一旦形成された発色染料を分
解して消色してしまうというものである。そこで
本考案者らは樹脂フイルム中に含有される可塑剤
を直接感熱層と接触することを阻止する水溶性高
分子物質からなる障壁層を感熱発色層上に設ける
ことを提案した。ところが有機樹脂フイルム中の
可塑剤は感圧接着層および支持体を浸透して感熱
発色層に到達して、やはり記録画像を消失せしめ
ることがあることが判り、この裏面からの可塑剤
の浸透をも阻止せんとするのが、本考案の目的で
ある。 The inventor of the present invention has carefully studied the above-mentioned phenomenon and found that it is caused by a plasticizer present on the surface of the resin film or exuded from inside the film. That is, a plasticizer is added to form a film from these organic resins, but this plasticizer decomposes the coloring dye once formed by heating and erases the color. Therefore, the present inventors proposed that a barrier layer made of a water-soluble polymer substance be provided on the thermosensitive coloring layer to prevent the plasticizer contained in the resin film from coming into direct contact with the thermosensitive layer. However, it has been found that the plasticizer in the organic resin film can penetrate through the pressure-sensitive adhesive layer and the support and reach the thermosensitive coloring layer, causing the recorded image to disappear. The purpose of this invention is to prevent this.
すなわち、本考案は支持体の裏面に水溶性高分
子物質からなる障壁層並びに感圧接着層を順次設
けてこれに剥離紙を貼付し、同支持体の表面には
無色又は淡色のロイコ染料と酸性物質とを発色成
分として含有する感熱発色層及び水溶性高分子物
質よりなる障壁層を順次設けたことを特徴とする
感熱記録用剥離ラベルよりなるものである。 That is, in the present invention, a barrier layer made of a water-soluble polymer material and a pressure-sensitive adhesive layer are sequentially provided on the back side of a support, and a release paper is attached to this, and a colorless or light-colored leuco dye is coated on the surface of the support. This peelable label for heat-sensitive recording is characterized in that a heat-sensitive color-forming layer containing an acidic substance as a color-forming component and a barrier layer made of a water-soluble polymer substance are sequentially provided.
本考案においては又、水溶性高分子物質に耐水
化剤を添加することもある。障壁層を形成する水
溶性高分子物質としては例えば、ポリビニルアル
コール、カルボキシメチルセルロース、メチルセ
ルロース、エチルセルロース、ヒドロキシメチル
セルロース、ヒドロキシエチルセルロース、ヒド
ロキシプロピルセルロース、ポリアクリルアミ
ド、デンプン、ゼラチン、カゼイン、ポリビニル
ピロリドン等が例示される。またこれらを耐水化
する耐水化剤としてはホルムアルデヒド、グリオ
キザール、クロム明ばん、メラミン、メラミン−
ホルムアルデヒド樹脂、ポリアミド樹脂、ポリア
ミド−エピクロルヒドリン樹脂等が挙げられる。
これら耐水化剤は水溶性高分子物質に対して20〜
100％の割合で添加されるのが好ましい。 In the present invention, a water-resistant agent may also be added to the water-soluble polymeric substance. Examples of water-soluble polymeric substances forming the barrier layer include polyvinyl alcohol, carboxymethylcellulose, methylcellulose, ethylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, polyacrylamide, starch, gelatin, casein, polyvinylpyrrolidone, and the like. . In addition, the water-resistant agents used to make these materials waterproof include formaldehyde, glyoxal, chrome alum, melamine, and melamine-
Examples include formaldehyde resin, polyamide resin, polyamide-epichlorohydrin resin, and the like.
These water resistant agents have a 20~
Preferably, it is added at a rate of 100%.
障壁層の厚さは、好ましくは１μ〜10μ程度が
よく、１μ以下だと均一膜厚の層が形成し難く
又、10μ以上だと感熱発色層への熱伝導が速やか
でなく、記録に多くの熱エネルギーを要する。 The thickness of the barrier layer is preferably about 1μ to 10μ; if it is less than 1μ, it will be difficult to form a layer with a uniform thickness, and if it is more than 10μ, the heat conduction to the thermosensitive coloring layer will not be quick enough, and recording will be difficult. of heat energy is required.
又、前記障壁層において、ポリスチレン樹脂等
の有機溶剤に可溶の高分子物質を用いた場合に
は、従来にくらべて多少記録画像の保存性は向上
できるものの、それでも一昼夜も有機樹脂フイル
ムと接触しておくと記録画像は消失し、判読不能
となつてしまう。本考案の如く障壁層に水溶性高
分子物質を用いることによつて始めて半永久的に
記録画像を消失することなく、鮮明に維持するこ
とができ、本考案の目的が達成されるものであ
る。そして耐水化剤を添加すれば、その機能は一
層安定して発揮せしめられる。 In addition, when a polymeric substance soluble in organic solvents such as polystyrene resin is used in the barrier layer, the storage stability of recorded images can be improved somewhat compared to conventional methods, but it still does not come into contact with the organic resin film all day and night. If left unattended, the recorded images will disappear and become unreadable. Only by using a water-soluble polymeric substance in the barrier layer as in the present invention can the recorded image be kept clear semi-permanently without disappearing, and the object of the present invention can be achieved. If a water-resistant agent is added, the function can be exhibited even more stably.
なお、本考案の障壁層中に、前記水溶性高分子
物質の機能を阻害しない程度で、従来の感熱発色
層中において用いられているヘツド走行向上剤を
添加して熱ヘツドの走行性を改良したり着色剤を
添加して種分けを容易にしてもよい。 In addition, a head running improver used in conventional heat-sensitive coloring layers is added to the barrier layer of the present invention to an extent that does not inhibit the function of the water-soluble polymeric substance to improve the running properties of the thermal head. Or a coloring agent may be added to facilitate classification.
また、感熱発色層は従来の如く、紙、合成樹脂
シート、金属蒸着紙等より成る支持体上に形成さ
れるが、該層を構成するロイコ染料、酸性物質及
び結合剤は従来より公知のものが用いられ、その
一例を下記に示す。 Furthermore, the heat-sensitive coloring layer is conventionally formed on a support made of paper, synthetic resin sheet, metallized paper, etc., but the leuco dye, acidic substance, and binder constituting the layer are conventionally known ones. is used, an example of which is shown below.
１ ロイコ染料
クリスタルバイオレツトラクトン、３−イン
ドリノ−３−ｐ−ジメチルアミノフエニル−６
−ジメチルアミノフタリド、３−ジエチルアミ
ノ−７−クロロフルオラン、３−ジエチルアミ
ノ−７−シクロヘキシルアミノフルオラン、３
−ジエチルアミノ−５−メチル−７−ｔ−プチ
ルフルオラン、３−ジエチアミノ−６−メチル
−７−アニリノフルオラン、３−ジエチルアミ
ノ−６−メチル−７−ｐ−ブチルアニリノフル
オラン。1 Leuco dye Crystal violet lactone, 3-indolino-3-p-dimethylaminophenyl-6
-dimethylaminophthalide, 3-diethylamino-7-chlorofluorane, 3-diethylamino-7-cyclohexylaminofluorane, 3
-diethylamino-5-methyl-7-t-butylfluorane, 3-diethylamino-6-methyl-7-anilinofluorane, 3-diethylamino-6-methyl-7-p-butylanilinofluorane.
２ 酸性物質
２，２−ビス（４−オキシフエニル）プロパ
ン（別名ビスフエノールＡ）、４−フエニルフ
エノール、４−ヒドロキシアセトフエノン、
２，2′−ジヒドロキシジフエニル、２，2′−メ
チレンビス（４−クロルフエノール）、２，
2′−メチレンビス（４−メチル−６−ｔ−ブチ
ルフエノール）、４，4′イソプロピリデンジフ
エノール、４，4′−イソプロピリデンビス（２
−クロルフエノール）、４，4′−イソプロピリ
デンビス（２−メチルフエノール）、４，4′−
エチレンビス（２−メチルフエノール）、４，
4′−チオビス（６−ｔ−ブチル−３−メチルフ
エノール）。2 Acidic substances 2,2-bis(4-oxyphenyl)propane (also known as bisphenol A), 4-phenylphenol, 4-hydroxyacetophenone,
2,2'-dihydroxydiphenyl, 2,2'-methylenebis(4-chlorophenol), 2,
2'-methylenebis(4-methyl-6-t-butylphenol), 4,4'isopropylidenediphenol, 4,4'-isopropylidenebis(2
-chlorophenol), 4,4'-isopropylidene bis(2-methylphenol), 4,4'-
Ethylene bis(2-methylphenol), 4,
4'-thiobis(6-t-butyl-3-methylphenol).
３ 結合剤
ポリビニルアルコール、メトキシセルロー
ス、ヒドロキシエチルセルロース、カルボキシ
メチルセルロース、ポリビニルピロリドン、ポ
リアクリルアミド、ポリアクリル酸、デンプ
ン、ゼラチン、ポリスチレン、塩化ビニル−酢
酸ビニル共重合体、ポリブチルメタクリレート
などの水溶性あるいは水性エマルジヨン。3 Binder Water-soluble or water-based emulsion such as polyvinyl alcohol, methoxycellulose, hydroxyethylcellulose, carboxymethylcellulose, polyvinylpyrrolidone, polyacrylamide, polyacrylic acid, starch, gelatin, polystyrene, vinyl chloride-vinyl acetate copolymer, polybutyl methacrylate, etc. .
また更に、感熱発色層中に感熱記録材料の分野
で公知の添加剤を添加することもできる。 Furthermore, additives known in the field of heat-sensitive recording materials may also be added to the heat-sensitive coloring layer.
支持体の裏面に設けられる剥離紙並びにこれを
支持体に接着する感圧接着層は従来の剥離ラベル
に用いられているものならいずれも使用できる
が、例えば剥離紙としては、紙等の台紙上にシリ
コーン樹脂等の剥離層を設けたもの、感圧接着層
は、SBR系ラテツクスを用いることにより形成す
ることができる。 The release paper provided on the back side of the support and the pressure-sensitive adhesive layer that adheres it to the support can be any of those used in conventional release labels. A release layer made of silicone resin or the like and a pressure-sensitive adhesive layer can be formed by using SBR latex.
以上の材料を用いて形成する本考案の感熱記録
用剥離ラベルの構成は第１図の如くである。すな
わち、第１図において１は支持体であり、その裏
面には台紙５上に剥離層４を設けてなる剥離紙３
を感圧接着層２並びに水溶性高分子物質とさらに
必要に応じて耐水化剤を添加してなる障壁層１０
を介して貼付されている。支持体１の表面には前
述の無色又は淡色のロイコ染料、酸性物質、結合
剤更には添加剤を有する感熱発色層６が形成さ
れ、次いで該感熱発色層６上に前記水溶性高分子
物質更に所望により耐水化剤ヘツド走行向上剤含
有の障壁層７が形成されている。図中９は剥離部
分を一括して示したものである。 The structure of the heat-sensitive recording release label of the present invention formed using the above-mentioned materials is as shown in FIG. That is, in FIG. 1, 1 is a support, and on the back side there is a release paper 3 formed by providing a release layer 4 on a mount 5.
a pressure-sensitive adhesive layer 2 and a barrier layer 10 formed by adding a water-soluble polymeric substance and a water-resistant agent if necessary.
It is pasted through. On the surface of the support 1, a thermosensitive coloring layer 6 containing the aforementioned colorless or light-colored leuco dye, an acidic substance, a binder, and further additives is formed, and then on the thermosensitive coloring layer 6, the water-soluble polymeric substance is further added. If desired, a barrier layer 7 containing a water resistance agent and a head running improving agent is formed. Reference numeral 9 in the figure collectively indicates the peeled portions.
第２図は、本考案感熱記録用剥離ラベルの実施
態様の一例の斜視図であつて、芯管８を芯として
ロール状に巻いたものであり、使用し易いよう
に、剥離紙３の上に剥離部分９を適宜の大きさに
分離して貼付してあるものである。 FIG. 2 is a perspective view of an embodiment of the release label for heat-sensitive recording of the present invention, which is wound into a roll with a core tube 8 as the core. The peelable portion 9 is separated into appropriate sizes and attached.
本考案を更に製造例、比較例により具体的に説
明する。 The present invention will be further specifically explained with reference to manufacturing examples and comparative examples.
製造例 １
下記成分をそれぞれボールミルを用いて24時間
粉砕分散して分散液ＡおよびＢを調整したのち、
分散液ＡおよびＢをさらに混合して感熱発色層形
成液を調製した。Production Example 1 Dispersions A and B were prepared by grinding and dispersing the following components for 24 hours using a ball mill, and then
Dispersions A and B were further mixed to prepare a thermosensitive coloring layer forming liquid.
クリスタルバイオレツトラクトン 1.5重量部
ポリビニルアルコール（20％水溶液）
5.0 〃
水 43.5 〃
〔分散液 Ｂ〕
ビスフエノールＡ 6.0重量部
炭酸カルシウム 3.0 〃
ステアリン酸アミド 1.0 〃
ポリビニルアルコール（20％水溶液）
10.0 〃
水 30.0 〃
さらに、ポリビニルアルコール5.0重量部と水
95.0重量部とを混合して障壁層形成液Ｃを調製し
た。
Crystal Violet Lactone 1.5 parts by weight Polyvinyl alcohol (20% aqueous solution)
5.0 〃 Water 43.5 〃 [Dispersion B] Bisphenol A 6.0 parts by weight Calcium carbonate 3.0 〃 Stearic acid amide 1.0 〃 Polyvinyl alcohol (20% aqueous solution)
10.0 〃 Water 30.0 〃 In addition, 5.0 parts by weight of polyvinyl alcohol and water
Barrier layer forming liquid C was prepared by mixing 95.0 parts by weight.
前記により調製した感熱発色層形成液を上質紙
（約50ｇ／m2）の表面に塗布、乾燥して、付着量
が５ｇ／m2（固型分）の感熱発色層を形成せしめ
て、さらにこの感熱発色層の上に上記Ｃ液を塗
布、乾燥して付着量が２ｇ／m2（固型分）とした
障壁層を形成せしめた。ついで、上質紙の裏面に
もＣ液を塗布、乾燥して付着量が2.5ｇ／m2（固
型分）とした障壁層を形成し、これに上質紙（約
50ｇ／m2）上にシリコーン樹脂を塗工した剥離台
紙をSBR系ラテツクス感圧接着剤によつて貼合せ
て感熱記録用剥離ラベルを得た。 The thermosensitive coloring layer forming liquid prepared above was applied to the surface of high-quality paper (approximately 50 g/m 2 ) and dried to form a thermosensitive coloring layer with an adhesion amount of 5 g/m 2 (solid content). The above-mentioned liquid C was applied onto this thermosensitive coloring layer and dried to form a barrier layer having an adhesion amount of 2 g/m 2 (solid content). Next, liquid C was applied to the back side of the high-quality paper and dried to form a barrier layer with an adhesion amount of 2.5 g/m 2 (solid content).
(50 g/m 2 ) was laminated with a release mount coated with silicone resin using an SBR latex pressure-sensitive adhesive to obtain a release label for heat-sensitive recording.
この感熱記録用剥離ラベルを熱傾斜試験機（東
洋精機製）で印字して（条件：150℃、１秒、２
Kg／cm2）、塩ビラツプフイルム（信越ポリマー
製）に貼付し、上層も塩ビラツプフイルムで覆
い、印字濃度の低下を測定したところ、スタート
時の濃度1.15のものが24時間後でも11.5であり、
まつたく濃度変化がなかつた。 This heat-sensitive recording peel label was printed using a thermal gradient tester (manufactured by Toyo Seiki) (conditions: 150°C, 1 second, 2
Kg/cm 2 ), was attached to a vinyl chloride wrap film (manufactured by Shin-Etsu Polymer), the upper layer was also covered with a vinyl chloride wrap film, and the decrease in print density was measured.The density at the start was 1.15, but it was still 11.5 after 24 hours. and
There was no noticeable change in concentration.
比較例 １
Ｃ液を用いない他は製造例１と全く同じ操作で
感熱記録用剥離ラベルを得て、これをもつて同一
試験をしたところ、スタート時の濃度が1.16のも
のが24時間後0.34となり、画像判読が不可能な濃
度となつた。Comparative Example 1 A heat-sensitive recording peel label was obtained in the same manner as in Production Example 1, except that Liquid C was not used, and the same test was carried out using this label.The concentration at the start was 1.16, but after 24 hours it was 0.34. This resulted in a density that made it impossible to read the image.
比較例 ２
上質紙の裏面にＣ液を用いない他は製造例１と
全く同じ操作で感熱記録用剥離シートを得、同一
試験を行なつたところ、スタート時の濃度が1.16
のものが24時間後0.67となり、画像判読が困難と
なつた。Comparative Example 2 A release sheet for heat-sensitive recording was obtained in exactly the same manner as in Production Example 1, except that liquid C was not used on the back side of the high-quality paper, and the same test was conducted, and the starting density was 1.16.
The value became 0.67 after 24 hours, making it difficult to interpret the image.
製造例 ２
下記成分をそれぞれボールミルを用いて24時間
粉砕分散して分散液ＤおよびＥを調製したのち、
分散液ＤおよびＥをさらに混合して感熱発色層形
成液を調製した。Production Example 2 Dispersions D and E were prepared by pulverizing and dispersing the following components using a ball mill for 24 hours, and then
Dispersions D and E were further mixed to prepare a thermosensitive coloring layer forming liquid.
３−ジエチル−６−メチル−７−アニリノフル
オラン 1.5重量部
ポリビニルアルコール（20％水溶液）
5.0 〃
水 43.5 〃
〔分散液 Ｅ〕
ビスフエノールＡ 6.0重量部
ステアリン酸アミド 1.0 〃
ポリビニルアルコール（20％水溶液）
10.0 〃
水 33.0 〃
さらに下記組成をもつて障壁層形成液Ｆを調製
した。
3-diethyl-6-methyl-7-anilinofluorane 1.5 parts by weight Polyvinyl alcohol (20% aqueous solution)
5.0 〃 Water 43.5 〃 [Dispersion E] Bisphenol A 6.0 parts by weight Stearic acid amide 1.0 〃 Polyvinyl alcohol (20% aqueous solution)
10.0 〃 Water 33.0 〃 Furthermore, barrier layer forming liquid F was prepared with the following composition.
酸化デンプン（20％溶液） 25.0重量部
グリオキザール（40％溶液） 11.4 〃
塩化アンモン 1.1 〃
水 62.5 〃
上記によつて調製した感熱発色層形成液並びに
障壁層形成液Ｆをもつて製造例１と同様にして感
熱記録用剥離ラベルを得た。これを製造例１の場
合と同様に試験をしたところ、スタート時の濃度
が1.25のものが24時間後でも1.25であり、全く濃
度変化がなかつた。また、耐水試験で水中に５分
間浸漬後脱脂綿で５往復こすつた後でも感熱層の
剥離はなく濃度変化もなかつた。
Oxidized starch (20% solution) 25.0 parts by weight Glyoxal (40% solution) 11.4 〃 Ammonium chloride 1.1 〃 Water 62.5 〃 Same as in Production Example 1 using the thermosensitive color forming layer forming liquid and barrier layer forming liquid F prepared as above. A peelable label for heat-sensitive recording was obtained. When this was tested in the same manner as in Production Example 1, the starting concentration of 1.25 remained 1.25 even after 24 hours, and there was no change in concentration at all. Further, in a water resistance test, the heat-sensitive layer did not peel off and there was no change in density even after immersing it in water for 5 minutes and rubbing it back and forth with absorbent cotton 5 times.
比較例 ３
上質紙の裏面にＣ液を用いない他は製造例２と
全く同じ操作で感熱記録用剥離ラベルを得、同一
試験を行なつたところ、スタート時の濃度が1.25
のものが24時間後0.87となり、画像判読が困難と
なつた。Comparative Example 3 A peelable label for heat-sensitive recording was obtained in exactly the same manner as in Production Example 2, except that liquid C was not used on the back side of the high-quality paper, and the same test was conducted, and the starting density was 1.25.
The value became 0.87 after 24 hours, making it difficult to interpret the image.
比較例 ４ 下記組成をもつた障壁層形成液Ｇを調製した。Comparative example 4 Barrier layer forming liquid G having the following composition was prepared.
［障壁層形成液 Ｇ］
ポリスチレン（分子量約２万） ５重量部
ベンゼン 95重量部
上記によつて調製した障壁層形成液Ｇを製造例
１におけるＣ液の代りに使用した以外は製造例１
と同様にして、比較用の感熱記録用剥離ラベルを
作製した。[Barrier layer forming liquid G] Polystyrene (molecular weight approximately 20,000) 5 parts by weight Benzene 95 parts by weight Production example 1 except that the barrier layer forming liquid G prepared above was used instead of liquid C in production example 1.
In the same manner as above, a comparative release label for heat-sensitive recording was produced.
この感熱記録用剥離ラベルを製造例１の場合と
同様に評価試験をしたところ、試験前の画像濃度
1.13のものが、試験後は0.54に低下した。 When this heat-sensitive recording peel label was subjected to an evaluation test in the same manner as in Production Example 1, the image density before the test was
The value of 1.13 decreased to 0.54 after the test.
比較例 ５
前記障壁層形成液Ｇを、製造例１における上質
紙の裏面に塗布したＣ液の代わりに使用した以外
は製造例１と同様にして、比較用の感熱記録用剥
離ラベルを作製した。Comparative Example 5 A comparative heat-sensitive recording release label was produced in the same manner as in Production Example 1, except that the barrier layer forming liquid G was used instead of Liquid C applied to the back side of the high-quality paper in Production Example 1. .
この感熱記録用剥離ラベルを製造例１の場合と
同様に評価試験をしたところ、試験前の画像濃度
1.15のものが、試験後は0.86に低下した。 When this heat-sensitive recording peel label was subjected to an evaluation test in the same manner as in Production Example 1, the image density before the test was
The value of 1.15 decreased to 0.86 after the test.
第１図は本考案の感熱記録用剥離ラベルの層構
成を示す説明図、第２図は本考案の感熱記録用剥
離ラベルの一実施形態である。
１……支持体、２……感圧接着層、３……剥離
紙、４……剥離層、５……台紙、６……感熱発色
層、７……障壁層、８……芯管、９……剥離部
分、１０……障壁層。
FIG. 1 is an explanatory diagram showing the layer structure of the heat-sensitive recording release label of the present invention, and FIG. 2 is an embodiment of the heat-sensitive recording release label of the present invention. DESCRIPTION OF SYMBOLS 1... Support, 2... Pressure sensitive adhesive layer, 3... Release paper, 4... Release layer, 5... Mounting paper, 6... Thermosensitive coloring layer, 7... Barrier layer, 8... Core tube, 9...Peeling part, 10...Barrier layer.
Claims (1)
壁層並びに感圧接着層を順次設けてこれに剥離
紙を貼付し、同支持体の表面には無色又は淡色
のロイコ染料と酸性物質とを発色成分として含
有する感熱発色層及び水溶性高分子物質よりな
る障壁層を順次設けたことを特徴とする感熱記
録用剥離ラベル。 ２ 水溶性高分子物質に耐水化剤を添加した実用
新案登録請求の範囲第１項記載の感熱記録用剥
離ラベル。[Claims for Utility Model Registration] 1. A barrier layer made of a water-soluble polymer material and a pressure-sensitive adhesive layer are sequentially provided on the back side of a support, and a release paper is attached to this, and the surface of the support is colorless or light-colored. 1. A peelable label for heat-sensitive recording, characterized in that a heat-sensitive coloring layer containing a leuco dye and an acidic substance as color-forming components and a barrier layer made of a water-soluble polymer substance are sequentially provided. 2. A peelable label for heat-sensitive recording according to claim 1, which comprises a water-soluble polymeric substance and a water-resistant agent added thereto.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1980038728U JPS6226217Y2 (en) | 1980-03-26 | 1980-03-26 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1980038728U JPS6226217Y2 (en) | 1980-03-26 | 1980-03-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56140461U JPS56140461U (en) | 1981-10-23 |
| JPS6226217Y2 true JPS6226217Y2 (en) | 1987-07-04 |
Family
ID=29717218
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1980038728U Expired JPS6226217Y2 (en) | 1980-03-26 | 1980-03-26 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6226217Y2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58160173U (en) * | 1982-04-19 | 1983-10-25 | 大阪シーリング印刷株式会社 | label |
| JPS58203092A (en) * | 1982-05-24 | 1983-11-26 | Ricoh Co Ltd | Heat-sensitive recording sheet |
| JPS6141594A (en) * | 1984-08-03 | 1986-02-27 | Oji Paper Co Ltd | Thermal recording material for label |
| JP2511300B2 (en) * | 1988-12-12 | 1996-06-26 | 株式会社巴川製紙所 | Thermal recording label paper |
| JPH0688457B2 (en) * | 1990-11-05 | 1994-11-09 | 株式会社リコー | Thermal recording material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4851644A (en) * | 1971-10-28 | 1973-07-20 | ||
| JPS5361346A (en) * | 1976-11-15 | 1978-06-01 | Ricoh Co Ltd | Heat sensitive paper |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5389334U (en) * | 1976-12-22 | 1978-07-21 |
-
1980
- 1980-03-26 JP JP1980038728U patent/JPS6226217Y2/ja not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4851644A (en) * | 1971-10-28 | 1973-07-20 | ||
| JPS5361346A (en) * | 1976-11-15 | 1978-06-01 | Ricoh Co Ltd | Heat sensitive paper |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56140461U (en) | 1981-10-23 |
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