JPS62254894A - Active oxygen water - Google Patents
Active oxygen waterInfo
- Publication number
- JPS62254894A JPS62254894A JP9989386A JP9989386A JPS62254894A JP S62254894 A JPS62254894 A JP S62254894A JP 9989386 A JP9989386 A JP 9989386A JP 9989386 A JP9989386 A JP 9989386A JP S62254894 A JPS62254894 A JP S62254894A
- Authority
- JP
- Japan
- Prior art keywords
- active oxygen
- water
- air
- oxygen
- disinfection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 32
- 239000001301 oxygen Substances 0.000 title claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 9
- 238000004140 cleaning Methods 0.000 abstract description 5
- 235000013305 food Nutrition 0.000 abstract description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052753 mercury Inorganic materials 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 13
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 230000000249 desinfective effect Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 1
- QRSFFHRCBYCWBS-UHFFFAOYSA-N [O].[O] Chemical compound [O].[O] QRSFFHRCBYCWBS-UHFFFAOYSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/08—Cleaning containers, e.g. tanks
- B08B9/20—Cleaning containers, e.g. tanks by using apparatus into or on to which containers, e.g. bottles, jars, cans are brought
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
Description
〔産業上の利用分野〕
本発明は、食品等の製造機器、医療用機器又はこれらの
付属品、構成部品等を噴射的に洗浄しかつ完全に消毒す
るために極めて有用な活性酸素水に関する。
〔従来の技術〕
食品製造機器、医療用機器等に付着した汚れを除去する
には、通常、ａ、洗剤とブラシを使用するす、高圧水を
噴射する Ｃ１高圧空気を噴射する ｄ、水蒸気を噴射
する等各種の方法がある。このうち、１の方法は最も普
遍的で、取扱者の手指等を含めて、広範囲の対象を洗条
しうるものであるが、汚れを除去したのち残存する洗剤
を除去するため多量の水が必要であシ、しかも必ずしも
完全な消毒が確保されないのが実状であった。また、ｂ
の方法は、秒速１００ｍにも達する高速かつ高圧の水を
洗条する対象に向けて噴射衝突させるものであるから、
例えば人手によシたわし等を用いて強くこするようなも
のであるが、この場合でも完全な消毒が保障されなかっ
た。さらにＣの方法は通常気吹（キプキ）といわれてい
る方法で対象に付着している汚れを概略除去しうる程度
のもので消毒の点では寧ろ不完全であった。また、ｄの
方法は対象に付着する比較的頑固な汚れも除去可能であ
って、はぼ完全な殺菌消毒も確保される方法であるが、
高圧水蒸気を製造するために大損りなボイラー等の設備
を太し、さらに、作業者に係る安全対策に十分な配慮が
必要である吟の問題点を内包するものであった。
〔発明が解決しようとする間跣点〕
本発明は叙上の実状に鑑みてなされたもので、列記した
如き従来法における洗浄汽消毒の不完全性、作業上の危
険性その他諸々の問題点を解決すぺ〈検討を重ねている
過程において、残留毒性のない噴射性の油性酸素水を使
用することに着意し、種々実験を行った結果、本発明に
到達したものである。
通常オゾン水の製造には、（１）コロナ放電による方法
、（ｉｉ）１８５０オーゲストロングの波長の紫外線を
照射する水銀ランプを使用する方法等があシ、かくして
発生したオゾンを水に接触・溶解せしめて得られる。
例えば、上記（１１）法では。
（ｏ） ＋ ０□ □ ０３
活性酸素 酸素 オゾン
となるものであるが、中間生成体となる活性酸素[Industrial Field of Application] The present invention relates to active oxygen water that is extremely useful for spray cleaning and complete disinfection of food manufacturing equipment, medical equipment, and their accessories and components. [Prior art] To remove stains from food manufacturing equipment, medical equipment, etc., the following methods are usually used: a. Using detergent and a brush. C. Spraying high-pressure water. C. Spraying high-pressure air. d. Spraying water vapor. There are various methods such as spraying. Among these methods, method 1 is the most universal and can wash a wide range of objects, including the hands and fingers of the handler, but it requires a large amount of water to remove the remaining detergent after removing dirt. The reality is that complete disinfection is not always possible. Also, b
This method involves jetting and colliding high-speed, high-pressure water that can reach up to 100 m/s toward the object to be washed.
For example, the disinfectant may be rubbed forcefully by hand using a scrubbing brush, but even in this case, complete disinfection was not guaranteed. Furthermore, method C was a method commonly called kipuki, which was only capable of removing most of the dirt adhering to the object, and was rather incomplete in terms of disinfection. In addition, method d is a method that can remove relatively stubborn dirt adhering to the object and also ensures complete sterilization.
In order to produce high-pressure steam, equipment such as a boiler, which was a major loss, was required to be thickened, and furthermore, there were problems in that it required sufficient consideration for safety measures for workers. [Disadvantages to be Solved by the Invention] The present invention has been made in view of the above-mentioned actual situation, and the present invention has been made in view of the above-mentioned actual situation, and it solves the incompleteness of cleaning steam disinfection, the operational danger, and other problems in the conventional method as listed above. In the course of repeated studies to solve the problem, we came to the conclusion of using a propellant oil-based oxygen water with no residual toxicity, and as a result of various experiments, we arrived at the present invention. Normally, ozone water is produced by (1) a method using corona discharge, (ii) a method using a mercury lamp that irradiates ultraviolet light with a wavelength of 1850 Aug. Obtained by dissolving. For example, in the method (11) above. (o) + 0□ □ 03 Active oxygen Oxygen Active oxygen that becomes ozone, but is an intermediate product
〔０〕
はオゾンｏ３よシ一層不安定であることがら、これが酸
化力及び殺菌力において一層強力であると推定できる。
本発明者は、紫外線灯（ＧＭ管）等によシ発生する活性
酸素を水に溶解してオゾン水として貯えたものよシ、製
造直後の溶液を対象物に叩き付けるようにして使用する
場合の方が上記の酸化力及び殺菌力に係る効果が遥かに
優れていることに着目し、これが実用を期待して穐々実
験を重ねた結果活性酸素を含有する空気又は酸素をエジ
ェクタで吸引して、高速で噴射りと混和してなる活性酸
素水が著しく好適であることを発見し、特にこの混和に
際し活性酸素の一部が気泡として存在する態様のものが
格別に好ましいことを知得したものである。
また、かかる条件で得られる活性酸素水は、対象物を活
性酸素を含む空気中又は酸素中に置く場合と比較しても
遥かに強力な酸化作用及び殺菌作用を有することも確認
できた。
本発明に係る活性酸素水の作用効果は、高速で宇宙空間
を飛しようするスペースシャトルが該空間に存在する活
性酸素分子と衝突することによシ想像以上にその外殻に
強い腐蝕を受けている事実とも符合するものである。
以下実施例に基づいて本発明を説明する。
〔実施例〕
Ａ、噴射ノズルを通って毎分１０Ｊ加圧噴射させる洗浄
機をつくシ、前記ノズルの手前にインジェクタを設け、
該インジェクタから活性酸素を含む空気を前記噴射水に
吸収させた。
Ｂ、前記活性酸素は、消５！電力１５ワットの水銀灯（
１８５０，２５３７及び３６０ｏオーゲストロングのＵ
Ｖを発生させるＧＭ管）によシ発生させた。
Ｃ・ 上記Ａ、Ｂの組合わせによＱ、噴射速度毎秒約１
００ｍで活性酸素濃度０．１〜０．１６ ｐｐｍの活性
酸素水が得られ、これを消費者から返却された牛乳瓶内
面の洗浄及び消毒に適用した結果、適用前１本につき１
１０． ＯＯＯケの大腸菌（Ｅ、Ｃｏ１１）が検出され
ていたものが適用後は不検出となシ、洗浄及び消毒が極
めて効果的に行われた。[0]
Since ozone is more unstable than ozone O3, it can be assumed that it is more powerful in terms of oxidizing and disinfecting power. The present inventor has proposed that, in addition to the active oxygen generated by ultraviolet lamps (GM tubes) being dissolved in water and stored as ozone water, the solution immediately after production is used by striking the object. Focusing on the fact that the above-mentioned oxidizing power and sterilizing power are far superior, we conducted extensive experiments with the hope that this method would be put to practical use.As a result, we found that air or oxygen containing active oxygen was sucked in with an ejector. , discovered that active oxygen water obtained by spraying and mixing at high speed is extremely suitable, and that it is particularly preferable that active oxygen water is mixed in such a way that some of the active oxygen exists as bubbles. It is. It was also confirmed that the active oxygen water obtained under these conditions has much stronger oxidizing and bactericidal effects than when the object is placed in air or oxygen containing active oxygen. The effect of the active oxygen water according to the present invention is that the outer shell of the space shuttle, which is flying at high speed through space, collides with the active oxygen molecules existing in the space, resulting in stronger corrosion than expected. This is consistent with the fact that The present invention will be explained below based on Examples. [Example] A. A washer is installed that sprays 10 J per minute under pressure through an injection nozzle, an injector is installed in front of the nozzle,
Air containing active oxygen was absorbed into the injected water from the injector. B. The active oxygen is extinguished 5! 15 watt mercury lamp (
1850, 2537 and 360o august strong U
It was generated by a GM tube that generates V. C. Due to the combination of A and B above, Q, the injection speed is approximately 1 per second.
Active oxygen water with an active oxygen concentration of 0.1 to 0.16 ppm was obtained at 00m, and as a result of applying this to cleaning and disinfecting the inner surfaces of milk bottles returned by consumers, it was found that 1 per bottle before application.
10. OOOke of Escherichia coli (E, Co11) was detected, but it was not detected after application, and cleaning and disinfection were extremely effective.
Claims (1)
を含有する該空気又は酸素をエジエクタで吸引し、高速
で噴射する水に混和して、該活性酸素を該水に溶解せし
めてなることを特徴とする活性酸素水。Air or oxygen containing active oxygen generated by lighting an ultraviolet lamp in air or oxygen is sucked in by an ejector, mixed with water that is sprayed at high speed, and the active oxygen is dissolved in the water. Active oxygen water featuring
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9989386A JPH0238278B2 (en) | 1986-04-30 | 1986-04-30 | KATSUSEISANSOSUI |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9989386A JPH0238278B2 (en) | 1986-04-30 | 1986-04-30 | KATSUSEISANSOSUI |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62254894A true JPS62254894A (en) | 1987-11-06 |
| JPH0238278B2 JPH0238278B2 (en) | 1990-08-29 |
Family
ID=14259453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9989386A Expired - Lifetime JPH0238278B2 (en) | 1986-04-30 | 1986-04-30 | KATSUSEISANSOSUI |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0238278B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02501990A (en) * | 1987-10-23 | 1990-07-05 | テクノバイオ株式会社 | A method for introducing and combining gases into water, equipment for carrying out the method, and water produced by the method |
| WO1991000247A1 (en) * | 1989-06-26 | 1991-01-10 | Mitsubishi Denki Kabushiki Kaisha | Fluid treater and method of stopping the same |
| JPH05200391A (en) * | 1992-01-22 | 1993-08-10 | Nishihara Environ Sanit Res Corp | Method and device for high degree treatment of organic matter |
| WO1997029859A1 (en) * | 1996-02-14 | 1997-08-21 | Henkel-Ecolab Gmbh & Co. Ohg | Method of cleaning drink bottles |
| WO1998000245A1 (en) * | 1996-07-01 | 1998-01-08 | Henkel-Ecolab Gmbh & Co. Ohg | Process for machine cleaning reusable packagings soiled with tenacious stains |
-
1986
- 1986-04-30 JP JP9989386A patent/JPH0238278B2/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02501990A (en) * | 1987-10-23 | 1990-07-05 | テクノバイオ株式会社 | A method for introducing and combining gases into water, equipment for carrying out the method, and water produced by the method |
| WO1991000247A1 (en) * | 1989-06-26 | 1991-01-10 | Mitsubishi Denki Kabushiki Kaisha | Fluid treater and method of stopping the same |
| EP0431190A1 (en) * | 1989-06-26 | 1991-06-12 | Mitsubishi Denki Kabushiki Kaisha | Fluid treater and method of stopping the same |
| JPH05200391A (en) * | 1992-01-22 | 1993-08-10 | Nishihara Environ Sanit Res Corp | Method and device for high degree treatment of organic matter |
| WO1997029859A1 (en) * | 1996-02-14 | 1997-08-21 | Henkel-Ecolab Gmbh & Co. Ohg | Method of cleaning drink bottles |
| WO1998000245A1 (en) * | 1996-07-01 | 1998-01-08 | Henkel-Ecolab Gmbh & Co. Ohg | Process for machine cleaning reusable packagings soiled with tenacious stains |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0238278B2 (en) | 1990-08-29 |
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