JPS6220318Y2 - - Google Patents
Info
- Publication number
- JPS6220318Y2 JPS6220318Y2 JP16173878U JP16173878U JPS6220318Y2 JP S6220318 Y2 JPS6220318 Y2 JP S6220318Y2 JP 16173878 U JP16173878 U JP 16173878U JP 16173878 U JP16173878 U JP 16173878U JP S6220318 Y2 JPS6220318 Y2 JP S6220318Y2
- Authority
- JP
- Japan
- Prior art keywords
- transfer
- layer
- transfer sheet
- parts
- printed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010410 layer Substances 0.000 claims description 70
- 239000002023 wood Substances 0.000 claims description 35
- 239000012790 adhesive layer Substances 0.000 claims description 18
- 239000000049 pigment Substances 0.000 claims description 15
- 239000010445 mica Substances 0.000 claims description 14
- 229910052618 mica group Inorganic materials 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 239000000203 mixture Substances 0.000 description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 239000011347 resin Substances 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000000243 solution Substances 0.000 description 10
- 229920000178 Acrylic resin Polymers 0.000 description 9
- 239000004925 Acrylic resin Substances 0.000 description 9
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 8
- 238000002845 discoloration Methods 0.000 description 8
- 238000007639 printing Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 6
- 229920006267 polyester film Polymers 0.000 description 6
- 229920002379 silicone rubber Polymers 0.000 description 6
- 239000004945 silicone rubber Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 241000238370 Sepia Species 0.000 description 5
- 238000007646 gravure printing Methods 0.000 description 5
- 238000007650 screen-printing Methods 0.000 description 5
- 239000004606 Fillers/Extenders Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000002932 luster Substances 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004709 Chlorinated polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Decoration By Transfer Pictures (AREA)
Description
【考案の詳細な説明】
本考案は木材の照りを呈し、且つ耐薬品性に優
れた転写層を被転写体上に形成しうる転写シート
に関するものである。[Detailed Description of the Invention] The present invention relates to a transfer sheet that can form a transfer layer on a transfer object that exhibits the luster of wood and has excellent chemical resistance.
従来、木目柄の転写シートは数多く存在し、プ
ラスチツク成形品に簡単に絵付する方法として利
用されて来ており、広範囲にわたつて多数の用途
に有効に活用されている。その殆んどは、被転写
基材の色を隠すために構成材料として不透明イン
キを使用しており且つ転写層の表面の艶消しがな
されるように構成されたもので、一見木材を思わ
せるように、工夫されてはいるが、実際の木材と
比較すると表現されている木目柄が表面的且つ平
面的である欠点を有する。それに比較して天然木
材の方は表面に幾分透明感があり、色、艶も表面
で反射されている光また表面よりやや奥で反射さ
れている光が、いりまじつて立体感を思わせ且つ
木目の模様にそつて艶も均一でなく独特な光沢即
ち、一般に「照り」と称されるものを持つている
ことが判る。 Conventionally, there have been a large number of wood grain pattern transfer sheets, which have been used as a simple method for painting plastic molded products, and are effectively used in a wide range of applications. Most of them use opaque ink as a constituent material to hide the color of the transferred substrate, and are structured so that the surface of the transfer layer is matte, so at first glance it looks like wood. Although this method has been devised, it has the disadvantage that the expressed wood grain pattern is superficial and flat when compared to actual wood. In comparison, natural wood has a somewhat transparent surface, and the color and luster of the light that is reflected on the surface, as well as the light that is reflected slightly deeper than the surface, gives it a sense of three-dimensionality. Moreover, it can be seen that the gloss is not uniform along the grain pattern, but has a unique luster, or what is generally called ``shin''.
また、この天然木材の「照り」を表現するため
に転写層中に金属粉末を混入した転写シートも考
えられるが、このものは耐薬品性に弱く、特に酸
性あるいはアルカリ性の物質により浸かされ著し
い変色を起こすために、その用途には数多くの制
限があつた。 In addition, a transfer sheet with metal powder mixed into the transfer layer to express the "shine" of this natural wood may be considered, but this sheet has poor chemical resistance, and is particularly susceptible to significant discoloration when immersed in acidic or alkaline substances. Because of this, there were many restrictions on its use.
本考案は天然木材の呈する「照り」を呈し、且
つ、耐薬品性に富む転写層をプラスチツク成形品
等の表面に形成すべく研究の結果、基体シートと
透明剥離層と木目柄の印刷絵柄層と接着剤層より
なる転写シートの印刷絵柄層を酸化チタンが表面
コートされたマイカ超薄片を含有するインキの印
刷被膜により構成することにより、天然木肌面の
呈する光沢、所謂照りを有し、且つ変色が起らな
い耐薬品性に富む転写層を被転写体上に形成しう
る転写シートを構成しうることを見い出し、完成
したものである。 This invention was developed as a result of research to form a transfer layer on the surface of plastic molded products that exhibits the "shine" of natural wood and is highly chemical resistant. By constructing the printed pattern layer of the transfer sheet consisting of the adhesive layer and the adhesive layer with a printed film of ink containing ultra-thin mica flakes whose surface is coated with titanium oxide, it has the luster, so-called shine, of a natural wood surface. In addition, it was discovered and completed that it is possible to construct a transfer sheet that can form a transfer layer that does not cause discoloration and is highly resistant to chemicals on a transfer target.
即ち、本考案の要旨は基体シートの片面に透明
剥離層を設け、該透明剥離層上に木目柄の印刷絵
層を設け、更に印刷絵柄層を設けた透明剥離層面
に接着剤層を設けてなる転写シートにおいて、前
記印刷絵柄層中に酸化チタンが表面コートされた
マイカ超薄片が分散せしめられていることを特徴
とする転写シートである。 That is, the gist of the present invention is to provide a transparent release layer on one side of a base sheet, provide a printed picture layer with a wood grain pattern on the transparent release layer, and further provide an adhesive layer on the surface of the transparent release layer on which the printed picture layer is provided. This transfer sheet is characterized in that ultrathin mica flakes whose surface is coated with titanium oxide are dispersed in the printed pattern layer.
以下、本考案につき、図面を参照しながら詳細
に説明する。 Hereinafter, the present invention will be explained in detail with reference to the drawings.
第１図は本考案の第１実施態様の転写シートの
模式的断面図を示し、１は基体シート、２は透明
剥離層、３は酸化チタンが表面コートされたマイ
カ超薄片が混入されたインキを用いてなる木目柄
の印刷絵柄層、４は木目柄の印刷絵柄層中の酸化
チタンが表面コートされたマイカ超薄片、５は接
着剤層である。 FIG. 1 shows a schematic cross-sectional view of a transfer sheet according to the first embodiment of the present invention, in which 1 is a base sheet, 2 is a transparent release layer, and 3 is an ultrathin piece of mica whose surface is coated with titanium oxide. A printed picture layer with a wood grain pattern is formed using ink, 4 is an ultra-thin piece of mica whose surface is coated with titanium oxide in the printed picture layer with a wood grain pattern, and 5 is an adhesive layer.
第２図は第１図示の転写シートの基体シート１
の透明剥離層２を設けるべき側に凸模様層６を設
けた本考案の第２実施態様の転写シートの模式的
断面図である。 Figure 2 shows the base sheet 1 of the transfer sheet shown in Figure 1.
FIG. 2 is a schematic cross-sectional view of a transfer sheet according to a second embodiment of the present invention, in which a convex pattern layer 6 is provided on the side where a transparent peeling layer 2 is to be provided.
第３図は第２図示の転写シートの接着剤層５中
に着色顔料７が分散せしめられている本考案の第
３実施態様の転写シートの模式的断面図である。 FIG. 3 is a schematic cross-sectional view of a transfer sheet according to a third embodiment of the present invention, in which colored pigments 7 are dispersed in the adhesive layer 5 of the transfer sheet shown in FIG.
第４図は第２図示の転写シートの接着剤層５中
に着色顔料７及び酸化チタンが表面コートされた
マイカ超薄片４を分散せしめられている本考案の
第４実施態様の転写シートの模式的断面図であ
る。 FIG. 4 shows a transfer sheet according to a fourth embodiment of the present invention, in which colored pigments 7 and ultrathin mica flakes 4 whose surface is coated with titanium oxide are dispersed in the adhesive layer 5 of the transfer sheet shown in FIG. It is a schematic cross-sectional view.
第５図は第１図に示した転写シートを被転写体
８に接着剤層５により接着し、基体シート１を透
明剥離層２から剥離してなる転写製品の模式的断
面図である。 FIG. 5 is a schematic cross-sectional view of a transfer product obtained by adhering the transfer sheet shown in FIG.
第６図は第２図に示した転写シートを被転写体
８に接着剤層５により接着し、基体シート１を透
明剥離層２から剥離してなる転写製品の模式的断
面図である。 FIG. 6 is a schematic cross-sectional view of a transfer product obtained by adhering the transfer sheet shown in FIG. 2 to a transfer target 8 with an adhesive layer 5 and peeling the base sheet 1 from the transparent release layer 2.
第７図は第３図に示した転写シートを被転写体
８に接着剤層５により接着し、基体シート１を透
明剥離層２から剥離してなる転写製品の模式的断
面図である。 FIG. 7 is a schematic cross-sectional view of a transfer product obtained by adhering the transfer sheet shown in FIG. 3 to an object 8 to be transferred using an adhesive layer 5, and peeling the base sheet 1 from the transparent release layer 2.
第８図は第４図に示した転写シートを被転写体
８に接着剤層５により接着し、基体シート１を透
明剥離層２から剥離してなる転写製品の模式的断
面図である。 FIG. 8 is a schematic cross-sectional view of a transfer product obtained by adhering the transfer sheet shown in FIG. 4 to a transfer target 8 with an adhesive layer 5 and peeling the base sheet 1 from the transparent release layer 2.
第１図に示す転写シートはポリエステルフイル
ムの如きプラスチツクフイルム、セロハンの如き
再生セルロースのフイルム、紙、金属箔などを目
的に応じて選択した基体シート１にアクリル系樹
脂、ゴム系樹脂、ビニル系樹脂、各種のハードレ
ジン、ポリアミド樹脂などの如き皮膜が透明とな
り剥離が良好な樹脂系のインキ組成物、或いはそ
れらに必要に応じてシリコン等の離型剤を添加し
てなる樹脂系のインキ組成物をグラビア印刷法、
シルクスクリーン印刷法などの印刷法により透明
剥離層２を形成し、透明剥離層２上に透明剥離層
２との接着性がよい樹脂バインダーを溶剤に溶か
したベヒクル中に着色顔料添加剤などと共に酸化
チタンがコーテイングされたマイカ超薄片を分散
させてなるインキ組成物を用いてグラビア印刷
法、スクリーン印刷法などによつて層中に酸化チ
タンがコーテイングされたマイカ超薄片４が分散
せしめられている木目柄の印刷絵柄層３を形成
し、次いでその上にアクリル系樹脂、ABS樹
脂、各種のハードレジン、塩素化ポリエチレン、
塩素化ポリプロピレンなどの樹脂系のインキ組成
物を例えばグラビア印刷法、スクリーン印刷法な
どの印刷法によつて塗工して接着剤層８を形成す
ることによつて製造することができる。 The transfer sheet shown in FIG. 1 is made of a base sheet 1 made of plastic film such as polyester film, regenerated cellulose film such as cellophane, paper, metal foil, etc. depending on the purpose, and acrylic resin, rubber resin, vinyl resin. , various hard resins, polyamide resins, and other resin-based ink compositions with transparent films and good peeling, or resin-based ink compositions made by adding a release agent such as silicone to these as necessary. The gravure printing method,
A transparent release layer 2 is formed by a printing method such as a silk screen printing method, and a resin binder with good adhesion to the transparent release layer 2 is oxidized on the transparent release layer 2 together with coloring pigment additives etc. in a vehicle containing a solvent. Using an ink composition in which ultrathin mica flakes coated with titanium are dispersed, ultrathin mica flakes 4 coated with titanium oxide are dispersed in a layer by gravure printing, screen printing, or the like. A printed pattern layer 3 with a wood grain pattern is formed, and then acrylic resin, ABS resin, various hard resins, chlorinated polyethylene,
The adhesive layer 8 can be manufactured by applying a resin-based ink composition such as chlorinated polypropylene by a printing method such as a gravure printing method or a screen printing method.
而して、上記の本考案に係る転写シートにおい
て基体シート１の透明剥離層２を設けるべき側の
面をマツト状にして、転写層の表面の艶消しがな
されるように構成しても良い。 Therefore, in the transfer sheet according to the present invention, the surface of the base sheet 1 on the side where the transparent release layer 2 is to be provided may be made matte, so that the surface of the transfer layer is matted. .
次に上記の本考案に係る転写シートにおいて透
明剥離層を染料を混入した樹脂を用いて構成して
も良い。 Next, in the transfer sheet according to the present invention described above, the transparent release layer may be constructed using a resin mixed with a dye.
次に第２図に示す転写シートの製造方法は上記
した第１図示の転写シートの製造方法と同様であ
るが、この場合には基体シート１に凸模様層６を
形成した点を異にするものである。この場合、凸
模様層６は基体シート１との接着性が良く且つ透
明剥離層２との剥離が可能であることが必要であ
り、例えばポリエステル樹脂、セルロース系樹
脂、ウレタン系樹脂などを使用しそれらに体質顔
料を添加し更に必要に応じてシリコン等の揆水
剤、揮発剤を添加したインキ組成物を用いて印刷
形成したものを使用することができる。 Next, the method for manufacturing the transfer sheet shown in FIG. 2 is the same as the method for manufacturing the transfer sheet shown in FIG. It is something. In this case, the convex pattern layer 6 needs to have good adhesion to the base sheet 1 and be removable from the transparent release layer 2. For example, polyester resin, cellulose resin, urethane resin, etc. are used. It is possible to use those formed by printing using an ink composition to which an extender pigment is added and, if necessary, a water repellent such as silicone and a volatile agent are added.
次に第３図に示す転写シートの製造方法は上記
した第２図示の転写シートの製造方法と同様であ
るが、この場合には接着剤層５をアクリル系樹
脂、ABS樹脂、各種のハードレジン、塩素化ポ
リエチレン、塩素化ポリプロピレンなどの樹脂中
に着色顔料を分散させたインキ組成物を例えばグ
ラビア印刷法、スクリーン印刷法などの印刷法に
よつて塗工して形成した点を異にするものであ
る。 Next, the method of manufacturing the transfer sheet shown in FIG. 3 is the same as the method of manufacturing the transfer sheet shown in FIG. , which differs in that it is formed by applying an ink composition in which a colored pigment is dispersed in a resin such as chlorinated polyethylene or chlorinated polypropylene by a printing method such as gravure printing or screen printing. It is.
次に第４図に示す転写シートの製造方法は上記
した第２図示の転写シートの製造方法と同様であ
るが、この場合には接着剤層５をアクリル系樹
脂、ABS樹脂、各種のハードレジン、塩素化ポ
リエチレン、塩素化ポリプロピレンなどの樹脂中
に顔料及び酸化チタンが表面コートされたマイカ
超薄片を分散させたインキ組成物を例えばグラビ
ア印刷法、スクリーン印刷法などの印刷法によつ
て塗工して形成した点を異にするものである。 Next, the method for manufacturing the transfer sheet shown in FIG. 4 is the same as the method for manufacturing the transfer sheet shown in FIG. An ink composition in which ultrathin mica flakes whose surface is coated with pigment and titanium oxide is dispersed in a resin such as chlorinated polyethylene or chlorinated polypropylene is applied by a printing method such as gravure printing or screen printing. The difference is that it was formed by engineering.
つぎに、本考案の具体的実施例を説明する。 Next, specific embodiments of the present invention will be described.
実施例 １
厚み25μのポリエステルフイルム（東レ社製）
の片面に下記組成の剥離層形成用インキ：
アクリル系樹脂 30部
メチルエチルケトン 35部
トルエン 35部
を版深60μのグラビアベタ版で全面均一にコート
した。次いで下記組成の印刷インキ：
アクリル系樹脂 25部
セピア顔料 10部
酸化チタンを表面コート
したマイカ超薄片 10部
メチルエチルケトン 25部
トルエン 30部
を使用し網点グラビア版にて木目柄を印刷した。
次いで該印刷面に下記組成の接着剤層形成用イン
キ：
アクリル系樹脂 30部
メチルエチルケトン 35部
トルエン 35部
を版深60μのグラビアベタ版で全面均一にコート
して本考案の転写シートＡを得た。Example 1 25μ thick polyester film (manufactured by Toray Industries)
The entire surface was uniformly coated with a release layer forming ink having the following composition: 30 parts of acrylic resin, 35 parts of methyl ethyl ketone, and 35 parts of toluene using a gravure solid plate with a plate depth of 60 μm. Next, a wood grain pattern was printed using a halftone gravure plate using a printing ink having the following composition: 25 parts of acrylic resin, 10 parts of sepia pigment, 10 parts of mica ultrathin flakes whose surface was coated with titanium oxide, 25 parts of methyl ethyl ketone, and 30 parts of toluene.
Next, the printed surface was uniformly coated with an adhesive layer forming ink having the following composition: 30 parts of acrylic resin, 35 parts of methyl ethyl ketone, and 35 parts of toluene using a gravure solid plate with a plate depth of 60 μm to obtain a transfer sheet A of the present invention. .
上記転写シートＡをABS樹脂板に密着させ、
表面温度200℃のシリコーンゴムローラーにて圧
6.5Kg／cm2、走行スピード15mm／秒の条件で転写
した。得られた木目柄の転写層は従来の転写層に
比較して透明感があり且つ奥行きが深く立体感に
富んだもので本当の木材を思わせるものであつ
た。又、転写層を10％塩酸水溶液及び10％水酸化
ナトリウム水溶液に２昼夜浸漬したにもかかわら
ず、一切変色はみられなかつた。 Place the above transfer sheet A closely on the ABS resin plate,
Press with a silicone rubber roller with a surface temperature of 200℃.
Transfer was carried out under conditions of 6.5 kg/cm 2 and a running speed of 15 mm/sec. The resulting wood grain pattern transfer layer was more transparent, deeper and more three-dimensional than conventional transfer layers, and was reminiscent of real wood. Further, even though the transfer layer was immersed in a 10% aqueous hydrochloric acid solution and a 10% aqueous sodium hydroxide solution for two days and nights, no discoloration was observed.
実施例 ２
厚み25μのポリエステルフイルム（東レ社製）
の片面にポリエステル樹脂と体質顔料を含むイン
キで凸模様を印刷し、以後実施例１と同様にして
印刷面に剥離層形成用インキを全面コートし、次
いで木目柄を印刷し、次いで接着剤層形成用イン
キを全面コートして本考案の転写シートＢを得
た。Example 2 25μ thick polyester film (manufactured by Toray Industries)
A convex pattern is printed on one side with an ink containing a polyester resin and an extender pigment, and then the entire printed surface is coated with a release layer forming ink in the same manner as in Example 1. Then, a wood grain pattern is printed, and then an adhesive layer is applied. Transfer sheet B of the present invention was obtained by coating the entire surface with forming ink.
上記転写シートＢをABS樹脂板に密着させ、
表面温度200℃のシリコーンゴムローラーにて圧
6.5Kg／cm2、走行スピード15mm／秒の条件で転写
した。得られた木目柄の転写層は従来の転写層に
比較して透明感があり且つ奥行きが深く立体感に
富んだもので本当の木材を思わせるものであつ
た。又、転写層を10％塩酸水溶液及び10％水酸化
ナトリウム水溶液に２昼夜浸漬したにもかかわら
ず、一切変色はみられなかつた。 Place the above transfer sheet B on the ABS resin plate,
Press with a silicone rubber roller with a surface temperature of 200℃.
Transfer was carried out under conditions of 6.5 kg/cm 2 and a running speed of 15 mm/sec. The resulting wood grain pattern transfer layer was more transparent, deeper and more three-dimensional than conventional transfer layers, and was reminiscent of real wood. Further, even though the transfer layer was immersed in a 10% aqueous hydrochloric acid solution and a 10% aqueous sodium hydroxide solution for two days and nights, no discoloration was observed.
実施例 ３
厚み25μのポリエステルフイルム（東レ社製）
の片面に実施例１と同様にして剥離層形成用イン
キを全面コートし、次いで木目柄を印刷した。次
いで該印刷面に下記組成の接着剤層形成用イン
キ：
アクリル系樹脂 30部
セピア顔料 20部
メチルエチルケトン 25部
トルエン 25部
を版深60μのグラビアベタ版で全面均一にコート
して本考案の転写シートＣを得た。Example 3 25μ thick polyester film (manufactured by Toray Industries)
The entire surface of one side was coated with release layer forming ink in the same manner as in Example 1, and then a wood grain pattern was printed. Next, the printed surface was uniformly coated with an adhesive layer forming ink having the following composition: 30 parts of acrylic resin, 20 parts of sepia pigment, 25 parts of methyl ethyl ketone, and 25 parts of toluene using a gravure solid plate with a plate depth of 60 μm to form the transfer sheet of the present invention. I got a C.
上記転写シートＣをABS樹脂板に密着させ、
表面温度200℃のシリコーンゴムローラーにて圧
6.5Kg／cm2、走行スピード15mm／秒の条件で転写
した。得られた木目柄の転写層は従来の転写層に
比較して透明感があり且つ奥行きが深く立体感に
富んだもので本当の木材を思わせるものであつ
た。又、転写層を10％塩酸水溶液及び10％水酸化
ナトリウム水溶液に２昼夜浸漬したにもかかわら
ず、一切変色はみられなかつた。 Place the above transfer sheet C closely on the ABS resin plate,
Press with a silicone rubber roller with a surface temperature of 200℃.
Transfer was carried out under conditions of 6.5 kg/cm 2 and a running speed of 15 mm/sec. The resulting wood grain pattern transfer layer was more transparent, deeper and more three-dimensional than conventional transfer layers, and was reminiscent of real wood. Further, even though the transfer layer was immersed in a 10% aqueous hydrochloric acid solution and a 10% aqueous sodium hydroxide solution for two days and nights, no discoloration was observed.
実施例 ４
厚み25μのポリエステルフイルム（東レ社製）
の片面にポリエステル樹脂と体質顔料を含むイン
キで凸模様を印刷し、以後実施例３と同様にして
印刷面に剥離層形成用インキを全面コートし、次
いで木目柄を印刷し、次いで接着剤層形成用イン
キを全面コートして本考案の転写シートＤを得
た。Example 4 25μ thick polyester film (manufactured by Toray Industries)
A convex pattern is printed on one side with an ink containing a polyester resin and an extender pigment, and then the entire printed surface is coated with a release layer forming ink in the same manner as in Example 3. Then, a wood grain pattern is printed, and then an adhesive layer is applied. The entire surface was coated with a forming ink to obtain a transfer sheet D of the present invention.
上記転写シートＤをABS樹脂板に密着させ、
表面温度200℃のシリコーンゴムローラーにて圧
6.5Kg／cm2、走行スピード15mm／秒の条件で転写
した。得られた木目柄の転写層は従来の転写層に
比較して透明感があり且つ奥行きが深く立体感に
富んだもので本当の木材を思わせるものであつ
た。又、転写層を10％塩酸水溶液及び10％水酸化
ナトリウム水溶液に２昼夜浸漬したにもかかわら
ず、一切変色はみられなかつた。 The above transfer sheet D is brought into close contact with the ABS resin plate,
Press with a silicone rubber roller with a surface temperature of 200℃.
Transfer was carried out under conditions of 6.5 kg/cm 2 and a running speed of 15 mm/sec. The resulting wood grain pattern transfer layer was more transparent, deeper and more three-dimensional than conventional transfer layers, and was reminiscent of real wood. Further, even though the transfer layer was immersed in a 10% aqueous hydrochloric acid solution and a 10% aqueous sodium hydroxide solution for two days and nights, no discoloration was observed.
実施例 ５
厚み25μのポリエステルフイルム（東レ社製）
の片面にポリエステル樹脂と体質顔料を含むイン
キで凸模様を印刷し、以後実施例１と同様にして
印刷面に剥離層形成用インキを全面コートし、次
いで木目柄を印刷した。次いで該印刷面に下記組
成の接着剤層形成用インキ：
アクリル系樹脂 25部
セピア顔料 20部
酸化チタンを表面コート
したマイカ超薄片 10部
メチルエチルケトン 25部
トルエン 20部
を版深60μのグラビアベタ版で全面均一にコート
して本考案の転写シートＥを得た。Example 5 25μ thick polyester film (manufactured by Toray Industries)
A convex pattern was printed on one side of the board using an ink containing a polyester resin and an extender pigment, and then the entire printed surface was coated with a release layer forming ink in the same manner as in Example 1, and then a wood grain pattern was printed. Next, ink for forming an adhesive layer with the following composition on the printed surface: 25 parts of acrylic resin, 20 parts of sepia pigment, 10 parts of ultra-thin mica flakes whose surface is coated with titanium oxide, 25 parts of methyl ethyl ketone, and 20 parts of toluene are applied to a gravure solid plate with a plate depth of 60μ. The entire surface was coated uniformly to obtain a transfer sheet E of the present invention.
上記転写シートＥをABS樹脂板に密着させ、
表面温度200℃のシリコーンゴムローラーにて圧
6.5Kg／cm2、走行スピード15mm／秒の条件で転写
した。得られた木目柄の転写層は従来の転写層に
比較して透明感があり且つ奥行きが深く立体感に
富んだもので本当の木材を思わせるものであつ
た。又、転写層を10％塩酸水溶液及び10％水酸化
ナトリウム水溶液に２昼夜浸漬したにもかかわら
ず、一切変化はみられなかつた。 Place the above transfer sheet E on the ABS resin plate,
Press with a silicone rubber roller with a surface temperature of 200℃.
Transfer was carried out under conditions of 6.5 kg/cm 2 and a running speed of 15 mm/sec. The resulting wood grain pattern transfer layer was more transparent, deeper and more three-dimensional than conventional transfer layers, and was reminiscent of real wood. Further, even though the transfer layer was immersed in a 10% hydrochloric acid aqueous solution and a 10% sodium hydroxide aqueous solution for two days and nights, no change was observed.
実施例 ６
基体シートとして厚さ25μの艶消しポリエステ
ルシート（東レ社製）を用い、他の条件は実施例
１ないし５と同様にして本考案の転写シートＦ，
Ｇ，Ｈ，Ｉ及びＪを得た。Example 6 A matte polyester sheet (manufactured by Toray Industries, Inc.) with a thickness of 25 μm was used as the base sheet, and other conditions were the same as in Examples 1 to 5, so that the transfer sheet F of the present invention,
G, H, I and J were obtained.
上記転写シートＦ，Ｇ，Ｈ，Ｉ及びＪをABS
樹脂板に密着させ、表面温度200℃のシリコーン
ゴムローラーにて圧6.5Kg／cm2、走行スピード15
mm／秒の条件で転写した。得られた木目柄の転写
層は従来の転写層に比較して透明感があり且つ奥
行きが深く立体感に富んだもので本当の木材を思
わせるものであつた。又、転写層を10％塩酸水溶
液及び10％水酸化ナトリウム水溶液に２昼夜浸漬
したにもかかわらず、一切変色はみられなかつ
た。 The above transfer sheets F, G, H, I and J are ABS
Place it in close contact with the resin plate and use a silicone rubber roller with a surface temperature of 200℃ at a pressure of 6.5Kg/cm 2 and a running speed of 15.
Transfer was performed at mm/sec. The resulting wood grain pattern transfer layer was more transparent, deeper and more three-dimensional than conventional transfer layers, and was reminiscent of real wood. Further, even though the transfer layer was immersed in a 10% aqueous hydrochloric acid solution and a 10% aqueous sodium hydroxide solution for two days and nights, no discoloration was observed.
比較例
実施例１と同様にしてただし印刷インキ、接着
剤形成用インキを下記組成のものを使用して転写
シートを得た。Comparative Example A transfer sheet was obtained in the same manner as in Example 1, except that printing ink and adhesive forming ink having the following compositions were used.
（印刷インキの組成）
アクリル系樹脂 25部
セピア顔料 10部
アルミニウム微粉末 10部
メチルエチルケトン 25部
トルエン 30部
（接着剤形成用インキの組成）
アクリル系樹脂 30部
セピア顔料 10部
アルミニウム微粉末 10部
メチルエチルケトン 25部
トルエン 25部
得られた転写シートを実施例１と同じ条件にて
ABS樹脂板に転写した。得られた転写製品を10
％塩酸水溶液及び10％水酸化ナトリウム水溶液に
浸漬するとわずか一昼夜にて著しい変色を起し、
木目の柄が消えるほどであつた。(Composition of printing ink) Acrylic resin 25 parts Sepia pigment 10 parts Fine aluminum powder 10 parts Methyl ethyl ketone 25 parts Toluene 30 parts (Composition of adhesive forming ink) Acrylic resin 30 parts Sepia pigment 10 parts Fine aluminum powder 10 parts Methyl ethyl ketone 25 parts Toluene 25 parts The obtained transfer sheet was subjected to the same conditions as Example 1.
Transferred to ABS resin plate. 10 of the resulting transfer products
When immersed in 10% hydrochloric acid aqueous solution and 10% sodium hydroxide aqueous solution, significant discoloration occurs in just one day and night.
It was so hot that the grain pattern disappeared.
以上詳記した通り、本考案に係る転写シートに
よれば、透明剥離層、及び木目柄の印刷絵柄層の
透明バインダー部分を通して層内に入り込んだ光
がマイカ超薄片に当り、そこで反射され、再び透
明剥離層及び木目柄の印刷絵柄層の透明バインダ
ー部分を通過し、表面で反射するものや、表面よ
りやや奥から出てくるものや更にそれより奥から
出てくるものなど種々の反射光が入り交じつて反
射してくる結果深みのある照りを呈する転写層を
被転写体上に形成することができる。又、本考案
に係る転写シートによれば、酸、アルカリの作用
により変色のおこらない耐薬品性に富む転写層を
被転写体上に形成することができる。 As detailed above, according to the transfer sheet of the present invention, light that has entered the layer through the transparent release layer and the transparent binder portion of the wood grain printed pattern layer hits the ultra-thin mica flakes and is reflected there. A variety of reflected light passes through the transparent release layer and the transparent binder part of the wood grain print pattern layer again, and is reflected on the surface, and light that comes out from a little deeper than the surface, and light that comes out from even deeper than that. As a result of the mixture of reflections, a transfer layer exhibiting a deep shine can be formed on the transfer target. Further, according to the transfer sheet of the present invention, it is possible to form a transfer layer on the object to be transferred, which is highly resistant to chemicals and does not discolor due to the action of acids or alkalis.
第１図は本考案の第１実施態様の模式的断面
図、第２図は本考案の第２実施態様の模式的断面
図、第３図は本考案の第３実施態様の模式的断面
図、第４図は本考案の第４実施態様の模式的断面
図、第５図は第１図示の転写シートを用いてなる
転写製品の模式的断面図、第６図は第２図示の転
写シートを用いてなる転写製品の模式的断面図、
第７図は第３図示の転写シートを用いてなる転写
製品の模式的断面図、第８図は第４図示の転写シ
ートを用いてなる転写製品の模式的断面図であ
る。
１……基体シート、２……透明剥離層、３……
木目柄の印刷絵柄層、４……マイカ超薄片、５…
…接着剤層。
Fig. 1 is a schematic cross-sectional view of the first embodiment of the present invention, Fig. 2 is a schematic cross-sectional view of the second embodiment of the present invention, and Fig. 3 is a schematic cross-sectional view of the third embodiment of the present invention. , FIG. 4 is a schematic sectional view of the fourth embodiment of the present invention, FIG. 5 is a schematic sectional view of a transfer product using the transfer sheet shown in the first drawing, and FIG. A schematic cross-sectional view of a transfer product made using
FIG. 7 is a schematic sectional view of a transfer product using the transfer sheet shown in FIG. 3, and FIG. 8 is a schematic sectional view of a transfer product using the transfer sheet shown in FIG. 4. 1...Base sheet, 2...Transparent release layer, 3...
Printed pattern layer with wood grain pattern, 4... Ultra-thin mica flakes, 5...
...adhesive layer.
Claims (1)
該透明剥離層２上に木目柄の印刷絵柄層３を設
け、更に木目柄の印刷絵柄層３を設けた透明剥
離層２面に接着剤層５を設けてなる転写シート
において、前記木目柄の印刷絵柄層３中に酸化
チタンが表面コートされたマイカ超薄片４が分
散せしめられていることを特徴とする転写シー
ト。 (2) 前記基体シート１の透明剥離層２を設けるべ
き側に凸模様層６が設けられていることを特徴
とする実用新案登録請求の範囲第１項記載の転
写シート。 (3) 前記基体シート１が艶消しされていることを
特徴とする実用新案登録請求の範囲第１項又は
第２項記載の転写シート。 (4) 前記接着剤層５中に着色顔料７及び／又は前
記マイカ超薄片４が分散せしめられていること
を特徴とする実用新案登録請求の範囲第１項、
第２項又は第３項記載の転写シート。[Claims for Utility Model Registration] (1) A transparent release layer 2 is provided on one side of the base sheet 1,
A transfer sheet comprising a printed pattern layer 3 with a wood grain pattern on the transparent release layer 2, and an adhesive layer 5 on the surface of the transparent release layer 2 on which the printed pattern layer 3 with a wood grain pattern is provided. A transfer sheet characterized in that ultra-thin mica flakes 4 whose surface is coated with titanium oxide are dispersed in a printed pattern layer 3. (2) The transfer sheet according to claim 1, wherein a convex pattern layer 6 is provided on the side of the base sheet 1 where the transparent release layer 2 is to be provided. (3) The transfer sheet according to claim 1 or 2, wherein the base sheet 1 is matte. (4) Utility model registration claim 1, characterized in that the colored pigment 7 and/or the mica ultra-thin flakes 4 are dispersed in the adhesive layer 5;
The transfer sheet according to item 2 or 3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16173878U JPS6220318Y2 (en) | 1978-11-24 | 1978-11-24 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16173878U JPS6220318Y2 (en) | 1978-11-24 | 1978-11-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5578461U JPS5578461U (en) | 1980-05-30 |
| JPS6220318Y2 true JPS6220318Y2 (en) | 1987-05-23 |
Family
ID=29156766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16173878U Expired JPS6220318Y2 (en) | 1978-11-24 | 1978-11-24 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6220318Y2 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56155788A (en) * | 1980-05-02 | 1981-12-02 | Sangou Toki Kk | Transfer paper for performing precious-metal-colored painting |
-
1978
- 1978-11-24 JP JP16173878U patent/JPS6220318Y2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5578461U (en) | 1980-05-30 |
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