JPS62201206A - Vulcanizing device - Google Patents

Vulcanizing device

Info

Publication number
JPS62201206A
JPS62201206A JP61043522A JP4352286A JPS62201206A JP S62201206 A JPS62201206 A JP S62201206A JP 61043522 A JP61043522 A JP 61043522A JP 4352286 A JP4352286 A JP 4352286A JP S62201206 A JPS62201206 A JP S62201206A
Authority
JP
Japan
Prior art keywords
bladder
discharge port
hot water
gas
tire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61043522A
Other languages
Japanese (ja)
Inventor
Itsuo Takahama
高浜 逸夫
Masao Hayashi
柾夫 林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Priority to JP61043522A priority Critical patent/JPS62201206A/en
Publication of JPS62201206A publication Critical patent/JPS62201206A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D30/00Producing pneumatic or solid tyres or parts thereof
    • B29D30/06Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
    • B29D30/0601Vulcanising tyres; Vulcanising presses for tyres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D30/00Producing pneumatic or solid tyres or parts thereof
    • B29D30/06Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
    • B29D30/0601Vulcanising tyres; Vulcanising presses for tyres
    • B29D30/0662Accessories, details or auxiliary operations
    • B29D2030/0666Heating by using fluids
    • B29D2030/0667Circulating the fluids, e.g. introducing and removing them into and from the moulds; devices therefor

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Tyre Moulding (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)

Abstract

PURPOSE:To make it possible to uniformly heat and vulcanize a green tire and consequently improve the quality of tire by a method wherein the discharging direction of high temperature liquid from a discharge port is directed upwards to the interior space of a bladder. CONSTITUTION:In the state that hot water 37 under high temperature and pressure is discharged from a discharge port 35 in a bladder 27 so as to circulate, the air or gas in the hot water 37 separated from the water and floats in the form of bubbles in such a manner as to stagnate at the upper portion 39a in the upper part of an interior space 39. Because the discharging direction of the discharge port 35 of a vulcanizing deice 21 is directed to the upper part of the interior space 39, bubble-shaped air or gas intending to stagnate is agitated by the hot water 37 so as to be uniformly distributed and prevented from stagnating. Consequently, the deterioration of the inner surface 27c of the bladder 27 at the early stage due to the high temperature oxygen in the air or gas is prevented from occurring. In addition, because the interior space 39 turns to have uniform temperature distribution by the hot water 37, which circulates from above to below along the inner surface 27c, a green tire contacting with the bladder 27 is heated and vulcanized under uniform temperature and consequently a vulcanized tire with excellent quality is obtained.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は加硫装置、詳しくは、タイヤ加硫時にブラダ内
に高温液体を吐出する吐出口の改良に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a vulcanizing device, and more particularly, to an improvement in a discharge port for discharging high temperature liquid into a bladder during tire vulcanization.

(従来の技術) 従来、加硫装置の吐出口としては、例えば、特開昭57
−185134号公報に係るものがある。
(Prior Art) Conventionally, as a discharge port of a vulcanizing device, for example,
There is one related to Publication No.-185134.

これはタイヤ内のブラダ内部にスチームおよびガス等の
気体を供給するものであり、上部および下部クランブリ
ングの間に上記クランプリングと若干の間隙を有する邪
魔板を設け、かつスチームの供給口より高い位置に別に
設けたガスの供給口から前記間隙を通じてガスを噴射す
るようにして、ガスとスチームとを別々の2つの供給口
から供給し、ガスとスチームの気体の比重差を利用して
加硫室内の上部と下部との温度差を均一にしたものであ
る。このようなスチームやガス等を加硫媒体として用い
るものは、乗用車のようにそれほど大きくないタイヤの
場合には差支えないが、ハスやトラック等の大型車用の
大きなタイヤにあってはその熱容量の違いによって、加
硫媒体として高温液体(温水)を用いる場合が多い。
This is to supply gas such as steam and gas to the inside of the bladder in the tire, and a baffle plate is provided between the upper and lower clamping rings with a slight gap from the clamping ring, and is higher than the steam supply port. Gas is injected through the gap from a gas supply port separately provided at a location, and gas and steam are supplied from two separate supply ports, and the difference in specific gravity between the gas and steam is utilized for vulcanization. This equalizes the temperature difference between the upper and lower parts of the room. Using steam, gas, etc. as a vulcanizing medium is fine for tires that are not very large, such as those for passenger cars, but for large tires for large vehicles such as lotuses and trucks, the heat capacity may be low. Depending on the difference, high temperature liquid (warm water) is often used as the vulcanization medium.

このように加硫媒体として高温液体を用いる加硫装置と
しては従来、例えば、第6図に示すようなものがある。
As a vulcanizing apparatus that uses a high-temperature liquid as a vulcanizing medium, there is a conventional vulcanizing apparatus as shown in FIG. 6, for example.

この従来の加硫装置1は力l硫金型3内の生タイヤ5の
内側に収納されるブラダ7と、ブラダ7の上端部7aお
よび下端部7bをそれぞれ保持する一対のブラダリング
9を備えている。
This conventional vulcanizing device 1 includes a bladder 7 that is housed inside a green tire 5 in a curing mold 3, and a pair of bladder rings 9 that respectively hold an upper end 7a and a lower end 7b of the bladder 7. There is.

高温高圧の液体(温水)11は加硫袋W1の中心部から
上下一対のブラダリング9によって形成された一つの断
面円形の吐出口13を通ってブラダ7内に吐出され、環
状のブラダ2内空間15を循環してブラダリング9の吐
出口13とほぼ反対側に設けられた排出口(図には示さ
れていない)から排出される。
High-temperature, high-pressure liquid (hot water) 11 is discharged from the center of the vulcanization bag W1 into the bladder 7 through one discharge port 13 with a circular cross section formed by a pair of upper and lower bladder rings 9, and is discharged into the bladder 7 into the annular inner space of the bladder 2. 15 and is discharged from an outlet (not shown) provided on the side substantially opposite to the outlet 13 of the bladder ring 9.

(発明が解決しようとする問題点) しかしながら、高温高圧の温水11がブラダ7内の空間
15に吐出する際に温水11中のエアーまたはガスが泡
状になり、また、温水から分離してエアーまたはガスは
浮上がってブラダ7の内部空間15の上部15aに溜ま
り易い。このため、ブラダ7の内部空間15の上部15
aと下部15bとの温度差が生じ、この部分に接触した
生タイヤ5の上部サイドウオール17および下部サイド
ウオール18とに加硫度に差を生ずるという問題点があ
る。また、エアーおよびガスには酸素を含有しており、
これら酸素が分離して、高温高圧下でブラダ7の内面7
cに接触し、ブラダ7の内面7cの劣化を早めてブラダ
7の寿命を低下させるという問題点もある。
(Problems to be Solved by the Invention) However, when the high-temperature, high-pressure hot water 11 is discharged into the space 15 in the bladder 7, the air or gas in the hot water 11 becomes bubble-like, and the air or gas is separated from the hot water. Alternatively, the gas tends to float up and accumulate in the upper part 15a of the internal space 15 of the bladder 7. For this reason, the upper part 15 of the internal space 15 of the bladder 7
There is a problem in that a temperature difference occurs between a and the lower part 15b, resulting in a difference in the degree of vulcanization between the upper sidewall 17 and the lower sidewall 18 of the green tire 5 that are in contact with this part. In addition, air and gas contain oxygen,
These oxygens are separated, and the inner surface 7 of the bladder 7 is heated under high temperature and high pressure.
There is also the problem that the inner surface 7c of the bladder 7 accelerates deterioration and shortens the lifespan of the bladder 7.

(問題点を解決するための手段) そこで前述の問題点を解決するため、本発明に係る加硫
装置は、加硫金型内の生タイヤの内側に収納されるブラ
ダと、このブラダの上端部および下端部をそれぞれ保持
する一対のブラダリングと、を備え、前記一対のブラダ
リングの間に形成された吐出口からブラダ内に高温液体
を吐出して前記生タイヤを加硫する加硫装置において、
前記吐出口の高温液体吐出方向を前記ブラダの内部空間
上方に向けるようにした構成としている。
(Means for Solving the Problems) Therefore, in order to solve the above-mentioned problems, the vulcanizing device according to the present invention includes a bladder that is housed inside a green tire in a vulcanization mold, and an upper end of this bladder. A vulcanizing device that vulcanizes the green tire by discharging a high-temperature liquid into the bladder from a discharge port formed between the pair of bladder rings, the vulcanizing device comprising: a pair of bladder rings holding a lower end portion and a lower end portion,
The high-temperature liquid discharge direction of the discharge port is directed upward into the internal space of the bladder.

(作用) 本発明の加硫装置の吐出口は高温液体吐出方向なブラダ
の内部空間の上方に向けるようになされているので、吐
出口から吐出した高温流体はブラダの内部空間の上方に
向かい、ブラダの内面に沿って生タイヤの上部サイドウ
オールからトレンドおよび下部サイドウオールの順に循
環して排出口から排出されるので、内部空間の上方にエ
アーまたはガスが泡状に溜っていても、これらは吐出す
る高温液体に混入攪拌されて均一に分布し、ついには排
出される。したがって、内部空間の上部と下部に温度差
が生ずることがなく、またブラダの上部内面の劣化が早
まることもない。
(Function) Since the discharge port of the vulcanizing device of the present invention is directed upward into the internal space of the bladder in the high temperature liquid discharge direction, the high temperature fluid discharged from the discharge port is directed upward into the internal space of the bladder. It circulates along the inner surface of the bladder, from the upper sidewall of the green tire to the trend and lower sidewalls, and is discharged from the exhaust port, so even if air or gas accumulates in the form of bubbles above the internal space, it will be removed. It is mixed into the discharged high-temperature liquid, stirred, distributed uniformly, and finally discharged. Therefore, a temperature difference does not occur between the upper and lower parts of the internal space, and the inner surface of the upper part of the bladder does not deteriorate prematurely.

(実施例) 以下、本発明の実施例を図面に基づいて説明する。(Example) Embodiments of the present invention will be described below based on the drawings.

第1〜第5図は本発明に係る加硫装置の一実施例を示す
図である。加硫装置21は、加硫金型23内の生タイヤ
25の内側に収納されて弾性ゴムからなる環状のブラダ
27と、このブラダ27の上端部27aおよび下端部2
7bをそれぞれ保持する上下一対のブラダリング30お
よび31とを備えている。上ブラダリング30の下側に
は上ブラダリング30のほぼ全周に渡って下方に突出し
た上突出部30aが設けられ、下ブラダリング31の上
側には下ブラダリング31のほぼ全周にわたって上方に
突出し、上突出部30aから離隔し間隙33を形成して
下突出部31aが設けられている。一対の上下ブラダリ
ング30および31間にほぼ全周に渡って形成された間
隙33は同時に吐出口35をも形成し、この吐出口35
からブラダ27内に高温高圧の温水(高温液体)37を
吐出して生タイヤ25を加熱加硫する。吐出口35は、
前述の上突出部30aと下突出部31aとによって、温
水37の吐出方向をブラダ27の内部空間39の上方に
向けるようにし、かつ放射外方にいくにしたがって開口
断面積が絞られるように形成されている。排出口40は
第3図に示すように、上下ブラダリング30と31との
間の吐出口35の円周方向の一部に一対の邪魔板42に
より放射方向に向くよう画成され、かつその部分に対応
する下突出部31aの一部を第5図に示すように間隙3
3側面より深く削り取って断面長方形に形成されている
。排出口40は下プラグリング31の中心部の排出通路
44に連通している。
1 to 5 are diagrams showing an embodiment of the vulcanization apparatus according to the present invention. The vulcanizing device 21 includes an annular bladder 27 which is housed inside the green tire 25 in a vulcanizing mold 23 and is made of elastic rubber, and an upper end 27a and a lower end 2 of the bladder 27.
It is provided with a pair of upper and lower bladder rings 30 and 31 that respectively hold the bladder rings 7b. An upper protrusion 30a is provided on the lower side of the upper bladder ring 30 and protrudes downward over almost the entire circumference of the upper bladder ring 30, and an upper protrusion 30a that protrudes upward over almost the entire circumference of the lower bladder ring 31 is provided on the upper side of the lower bladder ring 31. A lower protrusion 31a is provided spaced apart from the protrusion 30a to form a gap 33. A gap 33 formed over almost the entire circumference between the pair of upper and lower bladder rings 30 and 31 also forms a discharge port 35, and this discharge port 35
The green tire 25 is heated and vulcanized by discharging high-temperature, high-pressure hot water (high-temperature liquid) 37 into the bladder 27. The discharge port 35 is
The above-mentioned upper protruding part 30a and lower protruding part 31a are formed so that the hot water 37 is directed upward in the internal space 39 of the bladder 27, and the opening cross-sectional area is narrowed as it goes radially outward. has been done. As shown in FIG. 3, the discharge port 40 is defined by a pair of baffle plates 42 in a part of the circumferential direction of the discharge port 35 between the upper and lower bladder rings 30 and 31, and faces in the radial direction. As shown in FIG.
It is formed into a rectangular cross section by cutting deeper than the three sides. The discharge port 40 communicates with a discharge passage 44 in the center of the lower plug ring 31.

次に作用について説明する。Next, the effect will be explained.

本発明の加硫装置21を用いて生タイヤ25を加硫する
際、高温高圧の温水37は吐出口35からブラダ27内
に吐出され循環する。この際、温水37中の工アーまた
はガスが泡状になり温水から分離して浮上がり、ブラダ
27内の内部空間39上方の上部39aに滞溜しようと
する。しかしながら、第1図に示すように、本発明の加
硫装置21の吐出口35は高温液体(温水)37の吐出
方向がブラダ27の内部空間39上方に向けるように形
成されているので、内部空間39の上部39aに滞溜し
ようとする泡状のエアーまたはガスは、吐出する温水3
7により均一に分布するよう攪拌され、エアーまたはガ
スが上部39aに滞溜するのを防止する。このため、エ
アーまたはガス中の高温の酸素によってブラダ27の内
面27cが早期に劣化することはなく、ブラダ27の寿
命を大幅に増加できる。
When the green tire 25 is vulcanized using the vulcanizing device 21 of the present invention, high-temperature, high-pressure hot water 37 is discharged from the discharge port 35 into the bladder 27 and circulated. At this time, air or gas in the hot water 37 becomes bubble-like, separates from the hot water, floats, and tends to accumulate in the upper part 39a above the internal space 39 in the bladder 27. However, as shown in FIG. 1, the discharge port 35 of the vulcanizing device 21 of the present invention is formed such that the discharge direction of the high temperature liquid (warm water) 37 is directed upward to the internal space 39 of the bladder 27. Bubbly air or gas that tends to accumulate in the upper part 39a of the space 39 is removed from the hot water 3 to be discharged.
7 to uniformly distribute the air or gas, thereby preventing air or gas from accumulating in the upper part 39a. Therefore, the inner surface 27c of the bladder 27 does not deteriorate early due to high-temperature oxygen in the air or gas, and the life of the bladder 27 can be significantly extended.

また、温水37はブラダ27の内面27Cに沿って上方
から下方に循環し、ブラダ27内向部空間39の上部3
9aから下部39bまで均一な温度分布となるので、ブ
ラダ27に接する生タイヤは、上部から下部まで均一な
温度で加熱加硫され、優れた品質の加硫タイヤができる
In addition, the hot water 37 circulates from above to below along the inner surface 27C of the bladder 27, and the hot water 37 circulates from above to below the inner surface 27C of the bladder 27.
Since the temperature distribution is uniform from 9a to the lower part 39b, the raw tire in contact with the bladder 27 is heated and vulcanized at a uniform temperature from the upper part to the lower part, and a vulcanized tire of excellent quality can be obtained.

また、ブラダ27内の温水37は、内部空間39の上部
39aから下部39bまで循環しながら、かつ、円周方
向に攪拌、循環を繰返して流れ、ブラダ27内は均一な
温度分布となる。このため温水37の熱エネルギーは有
効に加熱加硫に使用され、生タイヤ25の加硫時間が短
縮されてタイヤの生産効率が増大する。
Further, the hot water 37 in the bladder 27 flows while circulating from the upper part 39a to the lower part 39b of the internal space 39 and repeats stirring and circulation in the circumferential direction, so that the inside of the bladder 27 has a uniform temperature distribution. Therefore, the thermal energy of the hot water 37 is effectively used for heating and vulcanization, shortening the vulcanization time of the green tire 25 and increasing tire production efficiency.

(効果) 以上説明したように、本発明によれば、ブラダ内の内部
空間の上下が均一な温度分布となり生タイヤの均一な加
熱加硫ができ、タイヤの品質が向上できる。また、ブラ
ダ内の上部がエアーまたはガス中の酸素により早期劣化
するのを防止できる。
(Effects) As described above, according to the present invention, the temperature distribution is uniform in the upper and lower portions of the internal space within the bladder, allowing uniform heating and vulcanization of the green tire, and improving the quality of the tire. Further, it is possible to prevent early deterioration of the upper part inside the bladder due to oxygen in air or gas.

ブラダ内の温水が攪拌、循環されて均一な温度でタイヤ
の加硫ができるので、加硫時間の短縮ができ、タイヤの
生産効率が向上できる。
The hot water in the bladder is stirred and circulated, allowing the tire to be vulcanized at a uniform temperature, reducing vulcanization time and improving tire production efficiency.

【図面の簡単な説明】[Brief explanation of drawings]

第1〜5図は本発明に係る加硫装置の一実施例を示す図
であり、第1図はその半断面図、第2図はその吐出口3
5および排出口40をともに示す全体断面図、第3図は
その吐出口35と排出口40との円周方向の関係を示す
第2図におけるm−m矢視図、第4図はその排出口40
の上ブラダリング30を省略した斜視図、第5図はその
排出口40の開口断面を示す拡大断面図である。第6図
は従来の加硫装置を示す半断面図である。 21・・・・・・加硫装置、 23・・・・・・加硫金型、 25・・・・・・生タイヤ、 27・・・・・・ブラダ、 27a・・・・・・上端部、 27b・・・・・・下端部、 27C・・・・・・内面、 30・・・・・・上ブラダリング、 31・・・・・・下ブラダリング、 33・・・・・・間隙、 35・・・・・・吐出口、 37・・・・・・高温液体、 39・・・・・・内部空間、 39a・・・・・・上部、 39b・・・・・・下部、 40・・・・・・排出口、 42・・・・・・邪魔板、 44・・・・・・排出通路。
1 to 5 are diagrams showing one embodiment of the vulcanizing device according to the present invention, FIG. 1 is a half sectional view thereof, and FIG. 2 is a discharge port 3 thereof.
3 is an overall cross-sectional view showing both the discharge port 35 and the discharge port 40, FIG. 3 is a mm-m arrow directional view in FIG. Exit 40
FIG. 5 is a perspective view with the upper bladder ring 30 omitted, and FIG. 5 is an enlarged sectional view showing the opening cross section of the discharge port 40. FIG. 6 is a half-sectional view showing a conventional vulcanizing device. 21... Vulcanization device, 23... Vulcanization mold, 25... Green tire, 27... Bladder, 27a... Upper end 27b...Lower end part, 27C...Inner surface, 30...Upper bladder ring, 31...Lower bladder ring, 33...Gap, 35... Discharge port, 37... High temperature liquid, 39... Internal space, 39a... Upper part, 39b... Lower part, 40. ...Discharge port, 42...Baffle plate, 44...Discharge passage.

Claims (1)

【特許請求の範囲】[Claims] 加硫金型内の生タイヤの内側に収納されるブラダと、こ
のブラダの上端部および下端部をそれぞれ保持する一対
のブラダリングと、を備え、前記一対のブラダリングの
間に形成された吐出口からブラダ内に高温液体を吐出し
て前記生タイヤを加硫する加硫装置において、前記吐出
口の高温液体吐出方向を前記ブラダの内部空間上方に向
けるようにしたことを特徴とする加硫装置。
A bladder that is housed inside a green tire in a vulcanization mold, and a pair of bladder rings that hold the upper and lower ends of the bladder, respectively, and a discharge port formed between the pair of bladder rings. A vulcanizing device that vulcanizes the green tire by discharging high-temperature liquid into a bladder, characterized in that the high-temperature liquid discharge direction of the discharge port is directed upward into an internal space of the bladder.
JP61043522A 1986-02-28 1986-02-28 Vulcanizing device Pending JPS62201206A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61043522A JPS62201206A (en) 1986-02-28 1986-02-28 Vulcanizing device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61043522A JPS62201206A (en) 1986-02-28 1986-02-28 Vulcanizing device

Publications (1)

Publication Number Publication Date
JPS62201206A true JPS62201206A (en) 1987-09-04

Family

ID=12666078

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61043522A Pending JPS62201206A (en) 1986-02-28 1986-02-28 Vulcanizing device

Country Status (1)

Country Link
JP (1) JPS62201206A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5020982A (en) * 1987-12-29 1991-06-04 Sumitomo Rubber Industries Limited Apparatus for vulcanizing elastomer product
EP0488636A2 (en) * 1990-11-30 1992-06-03 Sumitomo Rubber Industries Limited Method for vulcanising tyre and apparatus used therefor
US5133914A (en) * 1987-12-29 1992-07-28 Sumitomo Rubber Industries Limited Method for vulcanizing elastomer product
CN103128890A (en) * 2011-12-05 2013-06-05 中国化工橡胶桂林有限公司 Large-diameter rim engineering machinery tire vulcanization clamp device
JP2016030422A (en) * 2014-07-30 2016-03-07 横浜ゴム株式会社 Pneumatic tire vulcanizer

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5020982A (en) * 1987-12-29 1991-06-04 Sumitomo Rubber Industries Limited Apparatus for vulcanizing elastomer product
US5133914A (en) * 1987-12-29 1992-07-28 Sumitomo Rubber Industries Limited Method for vulcanizing elastomer product
EP0488636A2 (en) * 1990-11-30 1992-06-03 Sumitomo Rubber Industries Limited Method for vulcanising tyre and apparatus used therefor
US5378425A (en) * 1990-11-30 1995-01-03 Sumitomo Rubber Industries, Ltd. Method for vulcanizing tire and apparatus therefor
CN103128890A (en) * 2011-12-05 2013-06-05 中国化工橡胶桂林有限公司 Large-diameter rim engineering machinery tire vulcanization clamp device
CN103128890B (en) * 2011-12-05 2016-06-29 中国化工橡胶桂林有限公司 Large-diameter rim off-the-road tyre sulfuration clamping device
JP2016030422A (en) * 2014-07-30 2016-03-07 横浜ゴム株式会社 Pneumatic tire vulcanizer

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