JPS62192472A - Ink paint and adhesive having mildewproofing and antimicrobial activity and preventing forgery - Google Patents

Abstract

PURPOSE:To discriminate a forged note and to carry out the mildproofing of articles, by mixing water paint or printing ink with fine powder of radioactive marble, limestone, common mica, etc., and coating articles such as paper with the paint or printing them by using the ink. CONSTITUTION:Crushed powders of radioactive marble, limestone, actinolite, common mica, uranium minerals, monarite or magnetite are immersed or dispersed in water, or dispersed in an adhesive. The resulting liquid is applied to paper, plastic films, foods and rubber goods, or the surfaces of metals or concrete are coated or printed with said liquid. In this way, the bactericidal treatment and the mildewproofing of paper money, wallpaper, packaging films, rubber goods, bread, eggs, feathers, cloth, etc., can be carried out, and a forged note can be discriminated.

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention detects counterfeit banknotes and applies them to foods such as anti-mold wallpaper, sterilizing rubber molded products, sanitary paper and plastic containers, stamped bread, koniyaki, etc., industrial freezer paints, and other products. Radiation marble, limestone, as printing ink and adhesive
The aim is to develop a printing ink, quantity, and adhesive containing a mixture of dianthine, dolomite, moiseite, magnetite monazite, uranite, and rhea jadeite powder.

Many of the common and well-known banknotes are counterfeit banknotes, and it can be seen that many of them are printed on paper, photosensitive dyes, or printing ink with magnetic properties, but the counterfeiting techniques are very clever. Furthermore, there was a need for a method that would enable rapid observation. In addition, since banknotes come in contact with many patients, they are susceptible to staining and need to be sterilized. Also, rubber products,
By coating the surface of the container, it becomes sterilizing, and there was a demand for the development of a method to prevent the disease and mold.

In addition, there was a demand for prevention of mold formation in bread, biscuits, and sweets. In addition, mold always grows on indoor walls during the rainy season, and similar mold grows on duvets, sweatshirts, and woven fabrics, and a method to improve this problem has been desired. Furthermore, improvements have been required in the preservation of konjac and the freshness and preservation of eggs and other foods.

In many of these fire prevention crimes, halides, sulfides, peroxides, and organic fungicides were used in printing ink paints, but many of these are harmful, and there is a need to develop innocent fungicides. Ta.

In addition, there was a risk of contracting the disease Hakusei from shared futon pillows, mats, geta, slipper sachets, contact surfaces such as pachinko handles, door handles, escalators, chairs, etc. In addition, there was a demand for surface treatments that had medicinal properties for headaches, such as pillows, as well as antibacterial properties.

For this reason, the present invention incorporates fine powders of radiating marble, limestone, dioxite, dolomite, moiseite, and magnetite into water-soluble paints and printing inks, and disperses them into adhesives. When making adhesive paint, by applying and printing it, it generates gamma rays and beta rays due to its radiation effect, so counterfeiting can be detected using a Geiger meter, making it easy to identify unbalanced banknotes. Not only can it be done, but also the radiation can
Since the banknote surface is sterilized, hygiene is improved. In addition, when painting the surface of bread, sweets, fruits, etc., it prevents mold from entering and acts as a mold preventive agent, and when stored for more than 3 days, it inhibits the formation of colored mold for 20 days. When mixed with radiation marble and lime powder in bread, it is useful as a calcium nutrient for children's growth, and when added to milk or juice, it is useful as a preservative.

In addition, rubber products such as rubber gloves, finger caps, rubber clothing, and rubber shoes have mold on their surfaces, age due to temperature, and
Since they are worn together, they need to have sterilizing properties, and for this reason, a countermeasure that is harmless and has a long-lasting sterilizing effect is needed.

For this reason, the present invention proposes a durable, non-toxic, inexpensive, germicidal, radiating marble, limestone,
Adhesives are made by mixing crushed rock powders of sunstone, dolomite, moiseite, and magnetite with adhesives, and paints with radiation properties are made by mixing the same magnet powders in printing ink. When mixed into a radiation paint to make a radiation paint, it exhibits bactericidal properties due to the radiation effect, and is always reducible, which can be applied and printed on packaging materials to be used for packaging food, pharmaceuticals, and industrial materials. It is possible to maintain freshness for a long period of time, which has many benefits.

In addition, when this radiating stone powder is applied as wallpaper or curtains with medicinal ingredients, it is combined with the action of tea ingredients such as catechol, tannins, caffene, vitamin C, chlorophyll, minerals, etc., and radiating marble. Due to the radiation-reducing properties of limestone powder, limestone, dolomite, dolomite, etc., durable wallpaper lasting more than 5 years is made, and curtains are made with extremely high deodorizing ability and hydrogen sulfide. It absorbs and decomposes sulfurous acid, ammonia gas, and nitrous acid gas well, and is particularly useful as a wall surface treatment for hospitals such as those for sick patients.It is also hygienic because mold does not form due to its radiation action. In general, water-soluble polyvinyl acetal and polymethylcellulose phacrylate, as well as non-hydrogen vinyl acetate resin, polyethine vinyl acetate resin, ethyl cellulose lacquer polyester resin, polyacid, and other resins are used. Cheap resins include ureathracin, quetruaerin,
Resins are also used. However, as food additives, in addition to sierrac resin, succinic acid ester, fumaric acid resin, hydrous carbon-based materials such as ethyl cellulose and polyacrylic acid powder, gum arabic and the like are used.

2. To increase freshness retention, sulfuric acid or ferrous chloride, vitamin C, organic acids, reducing metal powders, sulfites, thiolates, hydrosulfides, sulfides, etc. are appropriately added to this radiating jadeite powder. In addition, when kneading into plastic film or dispersing paint as a mixture into plastic sol, by applying it to the surface of the packaging material, it maintains its deoxidizing properties for a longer period of time, and is often used for freshness-preserving packaging. It is used as a deodorizer and eliminates the occurrence of odor. Generally known deodorants containing a mixture of ferrous salt and vitamin C do not disperse gas and react when they come into contact with other malodorous gases, but in this product, malodorous gases are directly decomposed by radiation reducing gas. The effect is doubled, the garlic odor is removed, and the need for hydrogen peroxide, which is used to sterilize paper cartons of milk, etc., is sterilized by this radiation action, which solves the problem of carcinogenicity. Become,
In addition, since the ion exchangeability of the radiating powder coating increases when applied, it is often used as an anti-static and anti-mold agent, and has many uses as a coating for electrical parts.

When coated with paint for the inner walls of shoes or clothing, it has many properties such as preventing athlete's foot, deodorizing body odor, preventing static electricity, and preventing mold.

This radiation marble, limestone, agiostone, dolomite,
The component that dissolves in water of moiseite and magnetite is Ca5
0mg/ml Au0.1mg/mlSi20m
g/ml Ag0.04mg/mlMg20mg
/ml Rh0.591mg/mlB0.5mg
/ml Os-mg/mlBa0.5mg/ml
Pt0.009mg/mlSe0.5mg/ml
Ru0.015mg/mlZn0.5mg/ml
Le0.023mg/mlNb0.005mg/
ml Pd0.020mg/ml Al0.5mg/ml
Fe0.5-0.01mg/mlGe0.17m
g/ml M0.001mg/ml or less Se0.00
6mg/ml Lh0.001mg/ml or less D2o0
．． 001mg/ml Ra is less than 0.001mg/ml and contains a lot of white metal, as well as germanium, galen, and rare metals.

The pH value is 7.4 to 7.8, and the analysis results of this marble and limestone are as follows.

Cao40~48% Ce2o30.001%Mgo1
~3% P2o50.001%Sio21~3%
As2o50.001%Feio31~2% Mno
The average value is 20.01%, and since it is a natural stone, there are some composition errors depending on the place of origin and behavior, and the carbonate ionto period is 25 to 4.
It contains 0%, and moiseite and magnetite also elute metal ions by carbonate ions. This radiation stone powder used as a paint is made by crushing the stone mined from the mine shaft with a manganese clay grinder, placing it in a trommel, separating the particles while washing with water, and crushing it with a crusher. Use after processing into 400 meters or 700 meters.

This radioactivity is 1.2 to 1.7 times the natural radioactivity, and generates weak radiation that has no effect on the human body, including gamma rays, beta rays, and alpha rays.

When adding ferrous chloride to these radiating jadeite powders to maintain freshness, 2Fecl2+2Caco3→2Fe
co3■Cacl2→2Co2+Feo2+2Cacl
3 and becomes Fe2O3 by deoxidation. Also 2Fe+2
Nacl+C+2H2o+2Caco3+2Fecl2
■→2Fe2O3+Co2+2Nacl+2H2+Fe
Since it becomes 2O2+2Cael2, it becomes deacidifying. This generated gas is released.

As described above, the printing ink made according to the present invention has radiation properties, antifungal effects, and bactericidal properties, so it is not only useful for identifying banknotes due to its long durability, but also extremely hygienic. When this radiating stone powder is mixed and dispersed in paint, it is used as an antistatic agent and as an anion generating material, and when applied to cloth, it is used as an anti-mold agent and has extremely long durability. Also, when applied to wrapping paper or plastic processed products, it has a deodorizing effect and has been developed for various uses to preserve freshness, making it an industrially useful invention.

The implementation of this invention will be explained as follows using the drawings.

FIG. 1 is a front view of a banknote, and FIG. 2 is a side view taken along the line A-B. Outer frame pattern on the printed surface of the paper (P),
The whole number 2 is printed on one copy with printing ink (1), the numbers are similarly printed with radiation stone-containing printing ink (2), and the various types are printed with ink (3). (4) (4') is a portrait of a person with a sketch.

In Figure 3, a pattern is printed on wallpaper (5) using printing ink (6), and paint (7) is applied. Apply adhesive glue (8) to the back of this wallpaper (5) and press separate paper (9) to create a scroll (
d). FIG. 4 is a diagonal side view of the electric wire (10), and a paint is applied to the surface film (13) of the coating (11) on the surface of the steel wire/glass wire (2) for radiation properties. FIG. 5 shows a steel pipe (14), the surface (14') and inner wall (15) of which are coated with a water-resistant resin film. When the radiating stone powder is applied to this inner wall (15) to a thickness of 0.1 to 0.8 grains, the iron surface does not become the rust of Fero3, but becomes a tetra-iron oxide surface of Feofe2O3, forming a black color and improving corrosion resistance. becomes.

Furthermore, Fig. 6 shows the curtain membrane (16) (16'), on which a large number of fittings 17 (17') are fitted, which are fitted onto the rail (18) and opened and closed by an automatic sweater. . This radiation stone mixed with paint is applied to each curtain (16
) (16') is coated to form a coating (19) (19')
) and acts as a fungicide.

FIG. 7 is a front view of a woman's garment, in which the radiating paint containing gemstone powder is applied to the upper and lower surfaces (23, 23') of the upper garment (20) and lower garment (21).

When applying this radiating stone powder-containing paint to the surface, spraying it with a spray that has an anti-mold effect and is effective for one year will not only further activate it, but also have an anti-electrostatic effect and protect the skin. It has the effect of preventing fogging. It also deodorizes bad odors, and extends the washing time as the odor is deodorized. FIG. 8 is a side view of the cigarette (a). (25) of this cigarette (a) is rice paper, and a radiating powder paint is sprayed onto the rice paper to form a coating (25'), and the tobacco (27) is processed into a cylinder and rolled up. Then, one side is welded as a filter (26) and joined with rice paper. This filter (2
6) The acetate fiber bundle is made of radiating jadeite powder (
It consists of a lighter (28) in which the paint of 26') is sprayed and granules of active filler or a mixture of zeolite, radiating jadeite powder and ferrous chloride organic acid are placed therein.

In this way, the radiating jadeite powder has the effect of reducing nicotinic acid, reducing the risk of lung cancer in residents who are not smokers, and by adding this filter, residual nicotine was reduced to 48% of that without a filter. 25%. Also, when iron salts are present relative to nicotine, the reduction is not less, to 20%.

Figure 1 shows the feathers, and the surface of the feathers (29) is coated with a mixture of 400 mt of radiating jadeite powder mixed with glue and a preservative, which is washed with water or sprayed with water to form a dry coating (29'). When it is placed in the duvet (30) shown in Fig. 10, the growth of mold on the feathers is suppressed and the feathers become odorless.
By spraying or applying this radiating gemstone powder paint (31), mold can be suppressed and deodorization can be carried out.

Moreover, this odorless and anti-mold effect is effective for more than one year.

Figure 11 shows a costume paper (32), the surface or inner surface of which is coated with a paint mixed with this radiating jadeite powder, and antifungal agents such as salicylic acid, gotylated salicylate, and naphthalene. The dispersed powder is applied and dried to form coatings (33) (33'). This range is between 10 and 300 microns.

The mold-proofing and deodorizing properties of this costume paper (32) have lasted for over a year, and insect-repellent properties are also added by adding salt as an insect repellent.

The first construction drawing shows a side view of the toothpaste tube (34).The inside of this tube (34) contains powdered toothpaste and paste (400 to 700 tons of radish powder). 35) is included.

A cap (34') is attached to the top of this tube (34).
The surface of the tube is printed with printing ink containing radiant powder to make it sterilized.

When using this toothpaste, it not only has the same abrasive properties as known calcium carbonate powder, but also has bactericidal properties, which improves the defects caused by cocoon worms.

Examples of formulations of this printing ink and paint are shown below.

Example (1) Printing ink for banknotes Polyester resin 100g Dye 15g Radiation marble, limestone or dolomite, Yokishi powder 400-700 Methunyu 10g Solvent 1
50g Example (2) Printing ink for banknotes Polyacryloethryl resin or polyurethane resin 100g Dye 20g Example (3) Printed figure ink 20g Elac Dyes, pigments 20g Alcohol 230g Cellulose ether 5g or the same ester 0.1g Stabilizer Radiation Marble , limestone, heliostone, dolomite, moiseite, magnetite ore 20g Example (4) Wall paint fiber ether 10g vinyl acetate resin or guilaral 10g alcohol 20
0g Goldenrod 20g Radiation Jadeite Powder 25g Fluorescent Dye 1g Example (5) Wall Dye Aqueous Vinyl Chloride Vinyl Acetate Co-emulsified Resin 100g Water 300g Tea Extract 5g Pigment Dye 13g Radiation Jadeite Powder 25g Antioxidant Surfactant Emulsifier 1 :2:52g Example (6) Paint for electric wires Polyester resin or polyamide resin 30g Solvent 200g Dye 13g Radiation gemite powder 20g Stabilizer 3g Example (7) Light steel pipe polyester resin or polyvinyl resin, polyamide resin 30g Solvent 300g Radiation 50 g of radiating stone powder 3 g of pigment Example (8) Polyvinyl acetal vinyl acetate resin for curtains 30 g of polyvinyl resin 250 g of solvent 38 g of radiation stone powder 0.1 g of stabilizer 2 g of fluorescent paint Example (9) Paint for clothing Low-polymerized polyethylene vinyl acetate 50 g of resin, polyvinyl resin, polyurethane resin, polybutyral resin 300 g of solvent 25 g of radiating jadeite powder 1 g of fluorescent paint 5 g of stabilizer emulsifier 3 g of others Example (10) Cigarette paint 10 g of methyl fiber bundle 150 g of water 30 g of radiating jadeite powder Agent■ Acrylic acid or 1g Polyvinyl alcohol, gum arabic 1g Powder 1g Example (11) Tobacco paint (for filters) Sodium alginate 20g Water 300g Fluorescent dye 0.1g Radiation jadeite powder 28g Ferrous sulfate 5g Glycerin 1g Example (12) Feather coating sodium alginate or methyl fiber bundle, C.I. M. C.C. M. 315g water 150g radiating jadeite powder 20g preservative 5g Example (13) Futon paint alcohol 200g Vinyl acetate or low ethylene emulsion resin 20g fluorescent dye 0.1 radiating jadeite powder 20g Example (14) Costume paint polybutylene resin 10g Alcohol 20g Naphthalene 5g Alphapinene 3g Radiation jadeite powder 10g Example (15) Toothpaste paint Glycerin 10g Glycerin ether 1g Menthol fragrance 5g Particle thickener 20g Water 130g Radiation jadeite powder 50g Sweetener 0.1g Sodium tungstate 0.02g Example (16) Egg paint Sodium alginate or gelatin casein, water glass 10g Water 100g Radiation jadeite powder 20g Example (17) Egg mount paint Casein gelatin, alginate 10g Water 200g Radiation jadeite powder 10g Example (1) and Examples (11) is masticated with a masticating roll, then extruded and poured into a container.

Other examples from example (2) to example (19) are, for example, example (9)
Example (16) Example (4) is diluted with solvent and sprayed.
Otherwise, mix it in a stirring medium and seal it in a container to make a paint.

Figure 13 shows a chicken egg and an egg mount. Egg (38)
The surfaces of (38a) and (38b) show the coatings (38'), (38'a), and (38'b) that were sprayed with the paint of Example (16) and dried, and these eggs (18), (38a, and 38b) were sprayed and dried. Mount (
37), and the surface of the mount (37) is coated with the paint film (37') of Example (17). In such cases, if the product is left at room temperature for 7 days, the
It can be stored for up to 26 days at a storage temperature of 25°C and maintains its freshness.

As mentioned above, the feature of this invention is that radiating marble, limestone, dolomite, agiostone powder, moiseite, and magnetite powder are ground into 100 to 700 mesh particles and mixed and dispersed in printing ink or paint liquid. Due to its radiation action, it acts as a reducing agent and generates anions, which not only has antifungal, antiseptic, and deodorizing effects, but also has hygienic properties due to its bactericidal properties.
It has a durability of more than one year and becomes effective, and when mixed into printing ink like banknotes, the radiation effect makes it easy to sort and identify banknotes and helps identify counterfeit books and prints. Furthermore, when this paint is applied to wrapping paper, it not only serves to preserve freshness, but also prevents the growth of mold, making it an industrially useful invention.

[Brief explanation of drawings]

Figure 1 is a front view of the banknote, Figure 2 is a side view cut along A-B,
Figure 3 is a diagonal front view of the wallpaper, Figure 4 is a diagonal side view of the electric wire, Figure 5 is a diagonal side view of the steel pipe, and Figure 6 is a front view of the curtain.
Figure 8 is a front view of clothing. Figure 8 is a diagonal side view of a cigarette. Figure 9 is a front view of feathers. Figure 10 is a front view of a duvet. Figure 11 is a front view of a paper bag containing clothes. The figure is a side view of the kneaded toothpaste tube, and Figure 13 is a side view of the chicken egg and mount.

Claims (1)

[Claims] As described in the following text, crushed stone powder of radiation marble, limestone, agiostone, dolomite, uranite, moiseite, and magnetite is immersed and dispersed in water, or the same magnetic powder is mixed and dispersed in an adhesive. It can be applied to outer rubber molded objects such as paper, plastic film, and food products, or coated and printed on metal and concrete surfaces.It has sterilizing and mold-proofing properties for banknote paper, wallpaper, packaging films, rubber products, bread eggs, feathers, and cloth. Printing ink paints and adhesives that feature the ability to prevent counterfeiting.