JPS62190315A - Method and device for spraying slurry-like fuel - Google Patents

Method and device for spraying slurry-like fuel

Info

Publication number
JPS62190315A
JPS62190315A JP630786A JP630786A JPS62190315A JP S62190315 A JPS62190315 A JP S62190315A JP 630786 A JP630786 A JP 630786A JP 630786 A JP630786 A JP 630786A JP S62190315 A JPS62190315 A JP S62190315A
Authority
JP
Japan
Prior art keywords
target
mixing chamber
cws
passage
fuel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP630786A
Other languages
Japanese (ja)
Other versions
JPH0151731B2 (en
Inventor
Shizuo Kataoka
静夫 片岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takuma Co Ltd
Original Assignee
Takuma Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takuma Co Ltd filed Critical Takuma Co Ltd
Priority to JP630786A priority Critical patent/JPS62190315A/en
Publication of JPS62190315A publication Critical patent/JPS62190315A/en
Publication of JPH0151731B2 publication Critical patent/JPH0151731B2/ja
Granted legal-status Critical Current

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Abstract

PURPOSE:To reduce an amount of gas for spray working and to improve combustion efficiency, by a method wherein coal and water slurry (CWS) is fed through a conduction passage with a pressure, a fission atomization, wherein CWS is injected at a throttle part to a target for collision, and atomization, wherein an eddy flow is collided with a groove formed in the outer periphery of the target, take place. CONSTITUTION:Coal and water slurry (CWS) is fed with a pressure through a conduction passage 11 to a single hole 13 of a throttle part, the CWS is throttled at the throttle part to form a high speed single liquid column, which is injected in a mixing chamber 15. The liquid column is collided with a target 18 positioned facing the single hole and is fission-atomized for primary atomization. An eddy flow is exerted on the CWS within the mixing chamber 15 by means of atomized gas fed through a flow passage 14 communicated with a gas conduction passage 12 for atomization. The eddy flow is collided with a groove, formed in the outer periphery of the target, when it flows through the mixing chamber, and is agitated for promotion of atomization. The CWS is sprayed through a spray nozzle 16 into a furnace 19 in a state to be sufficiently atomized. This constitution enables improvement in combustion efficiency of the CWS without needing quantities of gas for spray working.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は石炭、水、スラリー(以下、CWSという)に
代表されるスラリー状燃料を微粒化させて燃焼させるた
めのIIIIjf方法とその装置に関するものである。
[Detailed Description of the Invention] Industrial Application Field The present invention relates to a IIIjf method and apparatus for atomizing and combusting a slurry fuel such as coal, water, and slurry (hereinafter referred to as CWS). be.

従来の技術 CWSはポンプ等によりボイラのバーナへ加圧供給され
液体燃料同様に、噴霧作動用気体として蒸気や空気によ
り微粒化して燃焼させることができる。
Conventional technology CWS is pressurized and supplied to the burner of a boiler by a pump or the like, and like liquid fuel, it can be atomized with steam or air and combusted as a spray operating gas.

しかしなから、CWSは多重の微粉化された石炭を含み
水を溶媒とし・て、数種類の添加剤を加えて製造されて
いるため、粘度が高いこと、ノズルにつまりやすいこと
、微粉化された石炭粒子が水の表面張力の影響をうけ微
粒化しにくいこと及びCWSを加熱する場合に適正な温
度域をはずれるとかえって凝集して粘度が上がるなとア
トマイザ−開発上の考慮すべき特性を持っている。
However, since CWS is manufactured by containing multiple layers of pulverized coal, using water as a solvent, and adding several types of additives, it has a high viscosity, is easily clogged in the nozzle, and has a high viscosity. Coal particles are affected by the surface tension of water and are difficult to atomize, and when CWS is heated outside of the appropriate temperature range, it will aggregate and increase viscosity, which are characteristics that should be taken into consideration when developing an atomizer. There is.

CWSのアトマイザ−については、未だ開発途上にある
が、その構造で大別すると、外部混合型と内部混合型と
の2つのタイプがある。そして、内部混合型は外部混合
型に比して微粒化状態が良好であると、一般に言われて
いる。
CWS atomizers are still under development, but they can be roughly divided into two types: an external mixing type and an internal mixing type. It is generally said that the internal mixing type has a better atomization state than the external mixing type.

そこで、内部混合型の代表的な例を第5図、第6図で説
明する。
Therefore, typical examples of the internal mixing type will be explained with reference to FIGS. 5 and 6.

図において、1はスラリー状燃料通路、2は霧化用気体
通路、3は燃料導出口、4は流路、5は混合室、6は噴
射ノズル、7はアトマイザ−であり、スラリー状燃料通
路1から圧送されたスラリー状燃料は燃料導出口3から
噴出して霧化用気体通路2からの露化用気体と合流し、
混合室5で混合されて噴射ノズル6から微粒化されて噴
出し、燃焼室内で燃焼を行うものである。この内部混合
型においては、構造が複雑なわりには未だ充分な微粒化
が達成されているとはいえない。
In the figure, 1 is a slurry fuel passage, 2 is an atomizing gas passage, 3 is a fuel outlet, 4 is a flow passage, 5 is a mixing chamber, 6 is an injection nozzle, and 7 is an atomizer. The slurry fuel pumped from 1 is jetted out from the fuel outlet 3 and merges with the exposing gas from the atomizing gas passage 2.
The mixture is mixed in a mixing chamber 5, atomized and ejected from an injection nozzle 6, and combusted in a combustion chamber. In this internal mixing type, although the structure is complex, it cannot be said that sufficient atomization has been achieved yet.

このため 1)CWSの微粒化状態が悪く燃焼効率が低いこと°2
)微粒化特性を改善するために使用する噴霧作動用気体
の消費量が多いこと 3)つまりやすいこと の問題点を持っている。
For this reason, 1) The atomization state of CWS is poor and the combustion efficiency is low.
) There are problems in that the consumption amount of the atomizing gas used to improve the atomization characteristics is large; and (3) it is easy to clog.

更に、CWSを加熱することが提案されているが、粘度
の低下を目的とした場合が多く充分な効果を上げるに致
っていない。
Furthermore, although it has been proposed to heat CWS, the purpose is often to lower the viscosity, and it has not been able to achieve a sufficient effect.

発明が解決しようとする問題点 本発明は、CWSの噴霧における上述の如き問題、即ち
CWSの微粒化状態が悪く燃焼効率が低いために燃料コ
ストが上昇すること、微粒化特性を改善するために使用
する噴霧作動用気体を多量に必要とするので噴霧化する
ためのコストが上昇すること、及びノズル構造が複雑化
すると共に微粒化された石炭粒子による閉塞を生じ易い
こと等の問題を解決せんとするものであり、これによっ
て、CWSの燃焼を安定した連続運転を可能とし、CW
Sの燃焼効率を高め、CWSの中小型ボイラ等への商業
的普及を計るものである。
Problems to be Solved by the Invention The present invention solves the above-mentioned problems in CWS atomization, namely, the increase in fuel cost due to poor atomization state of CWS and low combustion efficiency, and to improve the atomization characteristics. This method solves problems such as the need for a large amount of atomizing gas, which increases the cost of atomization, and the complexity of the nozzle structure, which tends to cause blockages due to atomized coal particles. This enables stable continuous operation of CWS combustion, and
The aim is to improve the combustion efficiency of S and to promote commercial use of CWS in small and medium-sized boilers.

問題点を解決するための手段 本発明は、CWSの噴射口を単穴口として閉塞を防止し
、CWSの昇圧力に要した動力の一部を混合室内のター
ゲットに向けて噴射し、衝突させて分裂微粒化の作用に
有効に利用することにより、ここで既にCWSは分裂微
粒化するので、その後に供給される噴霧作動用気体の供
給は少なくてすみ、混合室内部に挿入されたターゲット
の外周の形状による攪イ1、衝突作用により微粒化を更
に推進させることによって上述の問題を解決するもので
ある。
Means for Solving the Problems The present invention uses a single-hole CWS injection port to prevent clogging, and injects a portion of the power required to increase the pressure of the CWS toward a target in the mixing chamber, causing the target to collide. By effectively utilizing the action of splitting and atomization, the CWS is already split and atomized, so the subsequent supply of spray operating gas is less necessary, and the outer periphery of the target inserted into the mixing chamber is reduced. The above-mentioned problem is solved by further promoting atomization by the agitation 1 and collision effect due to the shape of the particle.

そのため、CWSの導通路である第1通路とその外側に
噴霧作動用気体の導通路である第2通路とを備えた供給
導体の先端に、アトマイザー本体を着脱自在に連結し、
該アトマイザー本体内に、外周が溝状のターゲットと混
合室と前記第1通路に連通ずる絞り部の単穴口の流路と
前記第2通路に連通して混合室内に旋回流を与える複数
の流路と微粒化された燃料を噴霧するための複数の穴口
を有する噴霧ノズルとを設け、前記ターゲットは、前記
絞り部との間隔が調節可能でかつ噴霧ノズルに着脱自在
に螺挿されるようにする。
Therefore, the atomizer main body is removably connected to the tip of a supply conductor that has a first passage that is a conduction path for the CWS and a second passage that is a conduction path for the atomizing gas on the outside thereof.
The atomizer main body includes a target having a groove-shaped outer periphery, a mixing chamber, a single-hole flow path of a constriction portion communicating with the first passage, and a plurality of flows communicating with the second passage to provide a swirling flow in the mixing chamber. and a spray nozzle having a plurality of holes for spraying atomized fuel, and the target has an adjustable distance from the constriction part and is detachably screwed into the spray nozzle. .

作用 CWSはCWS導通路に圧送され絞り部によって、混合
室の軸方向にそって混合室中心部に設けられたターゲッ
トに向って1本の液柱状で噴射され、ターゲットに衝突
させられることにより分裂微粒化させられる、次いで混
合室周壁からの噴霧作動用気体の混合室内壁に正接する
方向への導入によって、混合室内に渦巻状の混合流が形
成され、更に、混合室内に挿入された前記ターゲツ゛ト
の外周の溝による攪拌作用により微粒化が促進されて噴
霧ノズルから噴霧される。
The working CWS is forced into the CWS conduit and is injected by the throttle part in the form of a single liquid column toward a target provided in the center of the mixing chamber along the axial direction of the mixing chamber, and is split by colliding with the target. By introducing the atomizing gas from the peripheral wall of the mixing chamber in a direction tangential to the wall of the mixing chamber, a swirling mixed flow is formed in the mixing chamber, and the target inserted into the mixing chamber is Atomization is promoted by the stirring action of the grooves on the outer periphery of the atomizer and the atomizer is sprayed from the atomizer nozzle.

実施例 本発明の実施例を第1図乃至第4図に基づいて説明する
Embodiment An embodiment of the present invention will be explained based on FIGS. 1 to 4.

第4図は本発明に係るCWSO噴露方法及びその装置に
適用されるCWSの供給系統を示すものであり、CWS
タンクAと、ポンプ等のCWS圧送装置Bと、ストレー
ナCと、流量計りと、CWSを噴霧するアトマイザ−E
等からなるものである。
FIG. 4 shows a CWS supply system applied to the CWSO blowing method and device according to the present invention.
Tank A, CWS pressure feeding device B such as a pump, strainer C, flow meter, and atomizer E that sprays CWS.
etc.

第1図及び第2は本発明の実施例に係るアトマイザ−を
示すものである。
1 and 2 show an atomizer according to an embodiment of the present invention.

このアトマイザ−は、供給導体10の中心部に設けられ
前記流量計り側からのCWSが圧送されるCWSの導通
路11と該通路11の外側に設けられ図示しない圧縮機
からの圧縮気体が圧送される霧化用気体導通路12とか
らなる供給導体10と、混合室15と、前記通路11と
混合室15を連通ずる絞り部の単穴口13と9通路12
と混合室15を連通する流路14A及び14と、混合室
15の中心にあり単穴口13の対面に設けられたターゲ
ット18と。
This atomizer includes a CWS conduction path 11 provided at the center of the supply conductor 10 to which the CWS from the flow meter side is pumped, and a CWS conduction path 11 provided outside the path 11 to which compressed gas from a compressor (not shown) is pumped. a supply conductor 10 consisting of an atomizing gas passage 12; a mixing chamber 15; a single hole opening 13 of a constriction portion that communicates the passage 11 and the mixing chamber 15;
and the flow paths 14A and 14 that communicate with the mixing chamber 15, and the target 18 provided at the center of the mixing chamber 15 and facing the single hole opening 13.

混合通路を火炉19に開口する噴霧ノズル16とからな
るアトマイザー本体20とて主として構成されている。
The atomizer main body 20 mainly includes a spray nozzle 16 that opens a mixing passage into a furnace 19 .

そして、前記絞り部の単穴口13及び流路14Aを備え
た部材21とその前方に位置する流路14及び混合室1
5の一部を備えた部材22と更にその前方に位置する混
合室15の残部と噴震ノズル16及びターゲット18を
備えた部材23とからなる前記アトマイザー本体20は
、カバー24を前記供給導体10に螺着することによっ
て、供給導体10に対して着脱自在に構成されている。
A member 21 having the single hole opening 13 of the constriction part and the flow path 14A, the flow path 14 located in front of the member 21, and the mixing chamber 1
The atomizer main body 20 includes a member 22 including a part of the mixing chamber 15 , a member 23 including the remainder of the mixing chamber 15 located in front of the member 22 , a jet nozzle 16 , and a target 18 . By screwing it into the supply conductor 10, it is configured to be detachable from the supply conductor 10.

そして、前記流路14は、混合室15周壁からの噴霧作
動用気体を混合室内壁に正接する方向へ導入することに
よって、混合室内に渦巻状の混合流を形成させるような
方向に複数個設けられている。
A plurality of the flow passages 14 are provided in a direction such that a spiral mixed flow is formed in the mixing chamber by introducing the spray operating gas from the peripheral wall of the mixing chamber 15 in a direction tangential to the wall of the mixing chamber. It is being

またターゲット18は、部材23に形成したターゲット
取付ねじ孔17に螺挿することによって絞り部との間隔
が調節可能であるように噴霧ノズルに着脱自在になされ
ており、このターゲット18は、第2図に示すように部
材23の中心部に配置され、その外周に噴霧ノズル16
が等間隔で複数個設けられている。
Further, the target 18 is detachably attached to the spray nozzle so that the distance from the constriction part can be adjusted by screwing into a target mounting screw hole 17 formed in the member 23. As shown in the figure, a spray nozzle 16 is arranged at the center of the member 23, and a spray nozzle 16 is arranged on the outer periphery of the member 23.
are provided at equal intervals.

更にターゲット18は、第3図a、b、cに示すように
、頭部18Aと前記ターゲット取付ねじ孔17に螺挿さ
れる取付ねじ部18Bと混合室内挿入部18Cとからな
り、混合室内挿入部18Cの外周には溝が形成されてお
り、この溝は、取付ねじ部18Bの複数の線(C)等で
形成されている。
Furthermore, as shown in FIGS. 3a, b, and c, the target 18 consists of a head 18A, a mounting screw part 18B screwed into the target mounting screw hole 17, and a mixing chamber insertion part 18C. A groove is formed on the outer periphery of 18C, and this groove is formed by a plurality of lines (C) of the mounting screw portion 18B.

CWSタンクA内のCWSは、ポンプ等のCWS圧送装
置BによってストレーナC2流量計りを経てCWSを噴
霧するアトマイザ−Eに送られ、微粒化されて火炉19
に噴霧され燃焼に供される。
The CWS in the CWS tank A is sent by a CWS pressure feeding device B such as a pump to an atomizer E that sprays CWS via a strainer C2 flow meter, and is atomized and sent to a furnace 19.
It is sprayed on and used for combustion.

前記流量計りを経たCWSは、導通路11から絞り部の
単穴口13に圧送され、この絞り部によって絞られて高
速な1本の液柱として混合室15に噴射され、単穴口の
対面にあるターゲット18に衝突し、衝突による作用で
分裂微粒化されて1次霧化される。
The CWS that has passed through the flowmeter is fed under pressure from the conduction path 11 to the single-hole port 13 of the constriction section, is throttled by the constriction section, and is injected into the mixing chamber 15 as a single high-speed liquid column, which is located on the opposite side of the single-hole port. The particles collide with the target 18, and are split and atomized by the action of the collision, resulting in primary atomization.

次いでCWSは、霧化用気体導通路12に連通した流路
14から供給される霧化気体により混合室内で渦巻流を
与えられる。この渦巻流は混合室を通過する際にターゲ
ラ)1Bの外周に形成されている溝に当たり激しく攪拌
されてより微粒化が促進され、微粒化が充分に行われた
状態で噴霧ノズル16から火炉19内へ噴霧される。
Next, the CWS is given a swirling flow in the mixing chamber by the atomizing gas supplied from the flow path 14 communicating with the atomizing gas conduit 12 . When this swirling flow passes through the mixing chamber, it hits the grooves formed on the outer periphery of the targera (1B) and is violently stirred, further promoting atomization. sprayed inwards.

発明の効果 本発明によれば、CWSは、ターゲットへの衝突による
分裂微粒化とターゲットの外周に形成されている溝に渦
巻流が当たることによる微粒化によって、その微粒化は
充分に行われる。したがって、噴霧作動用気体の供給は
従来の微粒化方法及びその装置に比較して非常に少なく
てすむので燃焼効率の高いものが得られる。
Effects of the Invention According to the present invention, the CWS is sufficiently atomized by splitting and atomizing by collision with the target and atomizing by the swirling flow hitting the grooves formed on the outer periphery of the target. Therefore, the supply of the atomizing gas is much smaller than in conventional atomization methods and devices, resulting in high combustion efficiency.

またCWSは、絞り部によって絞られて高速な1本の液
柱として混合室に噴射されるので、その単穴口はつまる
ことがない。
In addition, since the CWS is squeezed by the constrictor and injected into the mixing chamber as a single high-speed liquid column, the single-hole port will not become clogged.

更にターゲットは螺挿されているので、CWSの供給量
やスラリーの状態に応じて絞り部との間隔を調節するこ
とができる。
Further, since the target is screwed in, the distance between the target and the throttle part can be adjusted depending on the amount of CWS supplied and the state of the slurry.

更にまた、アトマイザー本体は供給導体に着脱自在に連
結されており、ターゲットは前述のように螺挿されてい
るので、アトマイサー内部の清掃及び取り替え等が簡単
にできる。
Furthermore, since the atomizer main body is detachably connected to the supply conductor, and the target is screwed in as described above, the inside of the atomizer can be easily cleaned and replaced.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明に係るアトマイザ−の断面図、第2図は
その正面図、第3図は各種のターゲットの側面図、第4
図はCWSの供給系統図、第5図は従来例のアトマイザ
−の断面図、第6図は更に他の従来例のアトマイザ−の
断面図を示す。
Fig. 1 is a sectional view of an atomizer according to the present invention, Fig. 2 is a front view thereof, Fig. 3 is a side view of various targets, and Fig. 4 is a sectional view of an atomizer according to the present invention.
The figure shows a supply system diagram of the CWS, FIG. 5 shows a sectional view of a conventional atomizer, and FIG. 6 shows a sectional view of another conventional atomizer.

Claims (4)

【特許請求の範囲】[Claims] (1)固体及び液体の混合物からなるスラリー状燃料を
スラリー状燃料導通路に圧送して絞り部によって、混合
室の軸方向にそって混合室中心部に設けられたターゲッ
トに向って1本の液柱状で噴射し、ターゲットに衝突さ
せてスラリー状燃料を分裂微粒化させ、次いで混合室周
壁からの噴霧作動用気体の混合室内壁に正接する方向へ
の導入によって、混合室内に渦巻状の混合流を形成させ
、更に、混合室内に挿入された前記ターゲットの外周の
溝による攪拌作用により微粒化を促進させてから噴霧さ
せることを特徴とするスラリー状燃料の噴霧方法。
(1) Slurry fuel consisting of a mixture of solid and liquid is pumped into a slurry fuel conduit, and a constriction section directs the slurry fuel into a single stream along the axial direction of the mixing chamber toward a target provided at the center of the mixing chamber. The slurry fuel is injected in the form of a liquid column and collides with a target to split and atomize the slurry fuel, and then the spray operating gas is introduced from the mixing chamber peripheral wall in a direction tangential to the mixing chamber wall, creating a spiral mixture inside the mixing chamber. A method of spraying slurry-like fuel, which comprises forming a flow and further promoting atomization by a stirring action by a groove on the outer periphery of the target inserted into a mixing chamber before spraying.
(2)スラリー状燃料の導通路である第1通路とその外
側に噴霧作動用気体の導通路である第2通路とを備えた
供給導体の先端に、アトマイザー本体を着脱自在に連結
し、該アトマイザー本体内に、外周が溝状のターゲット
と混合室と前記第1通路に連通する絞り部の単穴口の流
路と前記第2通路に連通して混合室内に旋回流を与える
複数の流路と微粒化された燃料を噴霧するための複数の
穴口を有する噴霧ノズルとを設け、前記ターゲットは、
前記絞り部との間隔が調節可能でかつ噴霧ノズルに着脱
自在に螺挿されていることを特徴とするスラリー状燃料
の噴霧装置。
(2) The atomizer body is removably connected to the tip of the supply conductor, which has a first passage that is a passage for slurry fuel and a second passage that is a passage for atomizing gas outside the supply conductor. The atomizer body includes a target having a groove-shaped outer periphery, a mixing chamber, a flow path having a single hole in a constriction portion that communicates with the first passage, and a plurality of flow passages that communicate with the second passage and provide a swirling flow within the mixing chamber. and a spray nozzle having a plurality of holes for spraying atomized fuel, the target comprising:
A spraying device for slurry fuel, characterized in that the distance between the throttle portion and the throttle portion is adjustable, and the spray nozzle is detachably screwed into the spray nozzle.
(3)ターゲットの外周に形成した溝がターゲットの軸
線方向の溝から成ることを特徴とする特許請求の範囲第
2項記載のスラリー状燃料の噴霧装置。
(3) The slurry fuel spraying device according to claim 2, wherein the grooves formed on the outer periphery of the target are grooves extending in the axial direction of the target.
(4)ターゲットの外周に形成した溝がターゲットの半
径方向の溝から成ることを特徴とする特許請求の範囲第
2項記載のスラリー状燃料の噴霧装置。
(4) The slurry fuel spraying device according to claim 2, wherein the grooves formed on the outer periphery of the target are grooves in the radial direction of the target.
JP630786A 1986-01-17 1986-01-17 Method and device for spraying slurry-like fuel Granted JPS62190315A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP630786A JPS62190315A (en) 1986-01-17 1986-01-17 Method and device for spraying slurry-like fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP630786A JPS62190315A (en) 1986-01-17 1986-01-17 Method and device for spraying slurry-like fuel

Publications (2)

Publication Number Publication Date
JPS62190315A true JPS62190315A (en) 1987-08-20
JPH0151731B2 JPH0151731B2 (en) 1989-11-06

Family

ID=11634714

Family Applications (1)

Application Number Title Priority Date Filing Date
JP630786A Granted JPS62190315A (en) 1986-01-17 1986-01-17 Method and device for spraying slurry-like fuel

Country Status (1)

Country Link
JP (1) JPS62190315A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100408916C (en) * 2005-08-16 2008-08-06 江苏双良锅炉有限公司 Frequency conversion and automatically controlled dual-purpose boiler with built-in precombustion chamber using coal water slurry or oil as fuel
CN108151013A (en) * 2017-12-08 2018-06-12 亿利洁能科技(颍上)有限公司 A kind of briquette boiler atomizing combustion method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100408916C (en) * 2005-08-16 2008-08-06 江苏双良锅炉有限公司 Frequency conversion and automatically controlled dual-purpose boiler with built-in precombustion chamber using coal water slurry or oil as fuel
CN108151013A (en) * 2017-12-08 2018-06-12 亿利洁能科技(颍上)有限公司 A kind of briquette boiler atomizing combustion method

Also Published As

Publication number Publication date
JPH0151731B2 (en) 1989-11-06

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