JPS62179467A - Gel like aroma composition - Google Patents

Gel like aroma composition

Info

Publication number
JPS62179467A
JPS62179467A JP61021033A JP2103386A JPS62179467A JP S62179467 A JPS62179467 A JP S62179467A JP 61021033 A JP61021033 A JP 61021033A JP 2103386 A JP2103386 A JP 2103386A JP S62179467 A JPS62179467 A JP S62179467A
Authority
JP
Japan
Prior art keywords
gel
fragrance
gelling agent
sodium
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP61021033A
Other languages
Japanese (ja)
Other versions
JPH0580229B2 (en
Inventor
嘉明 森田
田中 光昭
幸一 山田
渡邊 洋二
義行 渡辺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lion Corp
Original Assignee
Lion Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lion Corp filed Critical Lion Corp
Priority to JP61021033A priority Critical patent/JPS62179467A/en
Publication of JPS62179467A publication Critical patent/JPS62179467A/en
Publication of JPH0580229B2 publication Critical patent/JPH0580229B2/ja
Granted legal-status Critical Current

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  • Cosmetics (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Fats And Perfumes (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 技術分野 本発明は、ゲル状芳香剤組成物に関する。[Detailed description of the invention] Technical field The present invention relates to gel fragrance compositions.

発明の背景 従来のゲル状芳香剤としては、揮発性テルペン系炭化水
素等の溶剤、ステアリン酸ナトリウム、オキシ脂肪酸、
ワックス等のゲル化剤、エタノール等のゲル化剤の可溶
化剤、増粘剤、香料、水等からなるものが知られている
。しかしながら、従来のゲル状芳香剤には、種々の欠点
がある。
Background of the Invention Conventional gel fragrances include solvents such as volatile terpene hydrocarbons, sodium stearate, oxyfatty acids,
Those comprising a gelling agent such as wax, a solubilizing agent for the gelling agent such as ethanol, a thickener, a fragrance, water, etc. are known. However, conventional gel fragrances have various drawbacks.

即ち、ゲル化剤としてステアリン酸ナトリウムを用いた
場合には、強固で安定なゲルができる反面溶解温度が8
0℃以上と高温を必要とするため製造時に香料が分解す
るという欠点がある。更に、ゲル化剤としてオキシ脂肪
酸、ワックスを用いた場合には、ゲル強度が充分でない
ため形態安定性に欠け、夏期の高温や長期保存によりゲ
ルの離漿、溶解等が生じるという欠点がある。
That is, when sodium stearate is used as a gelling agent, a strong and stable gel can be formed, but the melting temperature is 8.
Since it requires high temperatures of 0°C or higher, it has the disadvantage that the fragrance decomposes during production. Furthermore, when oxyfatty acid or wax is used as a gelling agent, the gel strength is insufficient, resulting in a lack of morphological stability, and there are drawbacks such as syneresis and dissolution of the gel due to high temperatures in summer or long-term storage.

本発明者は、従来のゲル状芳香剤の上記欠点を解消する
べく鋭意研究した結果、特に特定のゲル化剤と特定の可
溶化剤と特定の増粘剤とを組み合せて用いることにより
、ゲルが強固、安定で、且つ製造時の溶解温度が低くて
良いため香料の分解がなく、ゲルの離漿、溶解等も起こ
らないという侵れた特長を有するゲル状芳香剤組成物が
得られることを見出し、本発明を完成するに至った。
As a result of intensive research in order to solve the above-mentioned drawbacks of conventional gel fragrances, the present inventor has found that by using a combination of a specific gelling agent, a specific solubilizer, and a specific thickener, It is possible to obtain a gel-like fragrance composition which has the unique characteristics of being strong and stable, and requiring only a low melting temperature during production, so that the fragrance does not decompose, and gel syneresis and dissolution do not occur. They discovered this and completed the present invention.

発明の構成 本発明は、揮発性炭化水素、ゲル化剤、可溶化剤、増粘
剤、水及び香料を含むゲル状芳香剤組成物において、ゲ
ル化剤としてパルミチン酸ナトリウム、ミリスチン酸ナ
トリウム及びラウリン酸ナトリウムの少なくとも1種を
、可溶化剤として3−メチル−3−メトキシブタノール
、ヘキシレングリコール及びプロピレングリコールの少
なくとも1種を、増結剤としてエチルセルロース又は(
及び〉メチルセルロースをそれぞれ使用することを特徴
とするゲル状芳香剤組成物に係るものである。
Components of the Invention The present invention provides a gel fragrance composition comprising a volatile hydrocarbon, a gelling agent, a solubilizer, a thickener, water, and a fragrance, in which sodium palmitate, sodium myristate, and laurin are used as gelling agents. At least one of sodium acid, at least one of 3-methyl-3-methoxybutanol, hexylene glycol and propylene glycol as a solubilizer, and ethyl cellulose or (
The present invention relates to a gel fragrance composition characterized in that it uses methylcellulose and methylcellulose, respectively.

本発明における揮発性炭化水素としては主留分の沸点範
囲が130〜280℃のテルペン系炭化水素を用いるの
が好ましい。沸点範囲がこの範囲外となると香料及び媒
体の蒸散mが一定化しないことがあるので好ましくない
。特に好ましいものとしては、例えばα−ピネン、β−
ピネン、d−リモネン、これらの混合物、又はこれらの
いずれかを主成分とするテレピン油、オレンジ油等の天
然精油等を挙げることができ、これらの少なくとも1種
を用いる。揮発性テルペン系炭化水素は、ぞれ自体芳香
を有すると共に、香料成分のキャリアーとしての働きを
するものである。また、揮発性炭化水素として、上記テ
ルペン系炭化水素にイソパラフィン系炭化水素を併用す
ることができる。
As the volatile hydrocarbon in the present invention, it is preferable to use a terpene hydrocarbon whose main fraction has a boiling point range of 130 to 280°C. If the boiling point range is outside this range, the transpiration m of the perfume and the medium may not be constant, which is not preferable. Particularly preferable examples include α-pinene, β-pinene, and β-pinene.
Examples include pinene, d-limonene, mixtures thereof, and natural essential oils such as turpentine oil and orange oil containing any of these as main components, and at least one of these is used. Volatile terpene-based hydrocarbons each have an aroma and function as a carrier for fragrance components. Further, as the volatile hydrocarbon, an isoparaffin hydrocarbon can be used in combination with the above terpene hydrocarbon.

併用し得るイソパラフィン系炭化水素としては、蒸散性
の点から主留分の沸点範囲が100〜250℃のものが
好ましい。
The isoparaffinic hydrocarbon that can be used in combination is preferably one whose main fraction has a boiling point range of 100 to 250°C from the viewpoint of transpiration.

揮発性炭化水素の使用量は、常法に従い広い範囲から選
択され得るが、組成物中通常的50重金%以上程度、好
ましくは約60〜90重量%である。テルペン系炭化水
素にイソパラフィン系炭化水素を併用する場合の併用割
合は、特に限定されず、香調により適宜設定される。
The amount of volatile hydrocarbon to be used can be selected from a wide range according to conventional methods, but it is usually about 50% by weight or more, preferably about 60 to 90% by weight in the composition. The ratio of the isoparaffin hydrocarbons used in combination with the terpene hydrocarbons is not particularly limited, and is appropriately set depending on the aroma.

本発明においては、ゲル化剤としてバルミチン酸ナトリ
ウム、ミリスチン酸ナトリウム及びラウリン酸ナトリウ
ムの少なくとも1種を用いることを必須とする。
In the present invention, it is essential to use at least one of sodium valmitate, sodium myristate, and sodium laurate as a gelling agent.

従来、上記脂肪酸ナトリウムはゲル化作用があることは
知られていたが、ゲル強度が充分でない等の種々の難点
のためこの種の芳香剤組成物のゲル化剤としては実用化
されるに至っていなかった、。
Conventionally, it has been known that the above-mentioned sodium fatty acids have a gelling effect, but due to various drawbacks such as insufficient gel strength, they have not been put to practical use as gelling agents for this type of fragrance composition. It wasn't.

而して、本発明者は、本発明特定の可溶化剤及び増粘剤
を組み合せて使用することにより、上記脂肪酸ナトリウ
ムの使用を実用化することに成功し、しかも従来のゲル
化剤の欠点をすべて解消できたものである。
Therefore, the present inventor has successfully put the use of the above-mentioned fatty acid sodium to practical use by using the specific solubilizer and thickener of the present invention in combination, and also overcomes the drawbacks of conventional gelling agents. We were able to resolve all of these issues.

即ち、本発明においては、ゲル化剤、可溶化剤、増粘剤
として、それぞれ特定のものを用いることにより、強固
、安定なゲルが得られ、溶解温度が80℃未満であるの
で製造時の香料の分解等も起らず、又ゲルの離漿、溶解
等もないという優れたゲル状芳香剤組成物が得られる。
That is, in the present invention, by using specific gelling agents, solubilizing agents, and thickening agents, a strong and stable gel can be obtained, and since the melting temperature is less than 80°C, An excellent gel-like fragrance composition is obtained in which the fragrance does not decompose, and the gel does not undergo syneresis or dissolution.

上記特定のゲル化剤の使用量は、特に限定されないが、
組成物中通常的4〜8重量%程度とするのが好ましい。
The amount of the specific gelling agent used is not particularly limited, but
It is preferable that the amount is usually about 4 to 8% by weight in the composition.

この範囲内では、ゲル強度が充分で、残渣も殆んどない
Within this range, the gel strength is sufficient and there is almost no residue.

本発明においては、可溶化剤として3−メチル−3−メ
トキシブタノール、ヘキシレングリコール及びプロピレ
ングリコールの少なくとも1種を用いることを必須とす
る。使用量は、特に限定されないが、組成物中通常的3
〜10重量%程度とするのが好ましい。この範囲内では
、ゲル化剤が充分に溶解する。
In the present invention, it is essential to use at least one of 3-methyl-3-methoxybutanol, hexylene glycol, and propylene glycol as a solubilizer. The amount used is not particularly limited, but the amount is usually 3% in the composition.
The content is preferably about 10% by weight. Within this range, the gelling agent is sufficiently dissolved.

本発明においては、増粘剤としてエチルセルロース及び
メチルセルロースのいずれか又は両方を用いることを必
須とする。これらは、ゲルに適度な弾力性を付与し、ゲ
ル強度を向上させ、離漿を防止する作用を有する。使用
量は、特に限定されないが、組成物中通常約0.1〜5
市吊%程度、好ましくは約0.2〜1重句%程度である
。この範囲内では、ゲル強度が充分で、混合時の粘度が
適度なため作業性が良い。
In the present invention, it is essential to use either or both of ethyl cellulose and methyl cellulose as a thickener. These have the effect of imparting appropriate elasticity to the gel, improving gel strength, and preventing syneresis. The amount used is not particularly limited, but it is usually about 0.1 to 5% in the composition.
The amount is approximately 0.2% to 1%, preferably approximately 0.2% to 1%. Within this range, the gel strength is sufficient and the viscosity during mixing is appropriate, resulting in good workability.

本発明においては上記各成分と共に水及び香料を配合す
る。水は、ゲル化剤を溶解する作用をなす。また、香料
としては揮発性炭化水素に可溶であれば如何なる香料を
も使用できる。これらの使用Rは、常法に従えば良く、
水は組成物中通常約0.5〜4重量%程度配合される。
In the present invention, water and perfume are blended with each of the above components. Water serves to dissolve the gelling agent. Moreover, any fragrance can be used as long as it is soluble in volatile hydrocarbons. These R can be used according to the usual method,
Water is usually added in an amount of about 0.5 to 4% by weight in the composition.

香料の使用量はその種類及び目的とする製品に応じて広
い範囲から選択できるが、通常組成物巾約0.5〜25
重伍%程度の範囲である。
The amount of fragrance to be used can be selected from a wide range depending on the type and the intended product, but it is usually about 0.5 to 25% of the composition width.
It is in the range of about 5%.

本発明組成物は、香料以外の上記各成分に、更に必要に
応じて酸化防止剤、着色剤等を添加混合し、80℃未満
好ましくは70〜78℃程度で均一に溶解後、香料を添
加混合し、次いで冷却固化(成形)することにより容易
に製造できる。
The composition of the present invention is prepared by adding and mixing an antioxidant, a coloring agent, etc. as necessary to each of the above components other than the fragrance, and after uniformly dissolving the mixture at a temperature below 80°C, preferably around 70 to 78°C, the fragrance is added. It can be easily manufactured by mixing and then cooling and solidifying (molding).

発明の効果 本発明により、下記の如き顕茗な効果が奏される。Effect of the invention The present invention provides the following remarkable effects.

(1)得られたゲルは、強固で、且つ適度の弾力性を有
しており、経時的にも安定である。
(1) The obtained gel is strong and has appropriate elasticity, and is stable over time.

(2)製造時、ゲル化剤の溶解温度が80℃未満と低い
ため香料が分解せず、従って香調に優れる。
(2) During production, the dissolution temperature of the gelling agent is as low as less than 80°C, so the fragrance does not decompose, and therefore the fragrance is excellent.

(3)ゲルは熱安定性に優れ、離漿、溶解等が殆んど起
らない。
(3) The gel has excellent thermal stability, and syneresis and dissolution hardly occur.

(4)香料等が均一に蒸散し、ゲルの収縮も均一である
(4) The fragrance etc. evaporate uniformly, and the gel shrinks uniformly.

実施例及び比較例 以下、実施例及び比較例を挙げて、本発明を更に具体的
に説明する。
EXAMPLES AND COMPARATIVE EXAMPLES The present invention will now be described in more detail with reference to Examples and Comparative Examples.

実施例1〜8及び比較例1〜10 下記第1表及び第2表に示す実施例及び比較例のゲル状
芳香剤組成物をg!4製した。
Examples 1 to 8 and Comparative Examples 1 to 10 The gel fragrance compositions of the Examples and Comparative Examples shown in Tables 1 and 2 below were prepared by g! 4 were made.

次に、上記で得た各芳香剤組成物について、ゲル強度、
離漿及び香調を調べた。試験法は下記の通りである。
Next, for each fragrance composition obtained above, gel strength,
Syneresis and aroma were investigated. The test method is as follows.

0ゲル強度<(7)・・・レオメータ−により、N08
9アダプター(直径1Qmmの円柱)を用いて測定した
0 gel strength<(7)...N08 by rheometer
Measurement was performed using a 9 adapter (cylinder with a diameter of 1 Qmm).

0離漿(g)・・・40℃で3力月保存後、ゲル100
g当りの離漿ωを測定した。
0 syneresis (g)...Gel 100 after storage at 40℃ for 3 months
The syneresis ω per g was measured.

0香調・・・下記評価基準により判定した。0 fragrance tone: Determined according to the following evaluation criteria.

◎・・・非常に優れている、 ○・・・優れている、 Δ・・・あまり良くない、 ×・・・悪い。◎・・・Excellent ○...Excellent Δ...not very good, ×...Bad.

試験結果を第3表及び第4表に示す。The test results are shown in Tables 3 and 4.

上記第3表及び第4表から、本願特定のゲル化剤、可溶
化剤及び増粘剤を組み合せて用いることにより初めて、
ゲル強度が高く、離漿が殆んどなく、香調が非常に優れ
るゲル状芳香剤組成物が得られることが明らかである。
From Tables 3 and 4 above, it is clear that by using a combination of the gelling agent, solubilizer, and thickener specified in the present application,
It is clear that a gel-like fragrance composition with high gel strength, almost no syneresis, and excellent fragrance tone can be obtained.

(以 上)(that's all)

Claims (1)

【特許請求の範囲】[Claims] (1)揮発性炭化水素、ゲル化剤、可溶化剤、増粘剤、
水及び香料を含むゲル状芳香剤組成物において、ゲル化
剤としてパルミチン酸ナトリウム、ミリスチン酸ナトリ
ウム及びラウリン酸ナトリウムの少なくとも1種を、可
溶化剤として3−メチル−3−メトキシブタノール、ヘ
キシレングリコール及びプロピレングリコールの少なく
とも1種を、増粘剤としてエチルセルロース又は(及び
)メチルセルロースをそれぞれ使用することを特徴とす
るゲル状芳香剤組成物。
(1) Volatile hydrocarbon, gelling agent, solubilizer, thickener,
In a gel fragrance composition containing water and fragrance, at least one of sodium palmitate, sodium myristate, and sodium laurate is used as a gelling agent, and 3-methyl-3-methoxybutanol and hexylene glycol are used as solubilizers. and propylene glycol, and ethyl cellulose and/or methyl cellulose as a thickener, respectively.
JP61021033A 1986-01-31 1986-01-31 Gel like aroma composition Granted JPS62179467A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61021033A JPS62179467A (en) 1986-01-31 1986-01-31 Gel like aroma composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61021033A JPS62179467A (en) 1986-01-31 1986-01-31 Gel like aroma composition

Publications (2)

Publication Number Publication Date
JPS62179467A true JPS62179467A (en) 1987-08-06
JPH0580229B2 JPH0580229B2 (en) 1993-11-08

Family

ID=12043657

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61021033A Granted JPS62179467A (en) 1986-01-31 1986-01-31 Gel like aroma composition

Country Status (1)

Country Link
JP (1) JPS62179467A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06207162A (en) * 1992-09-16 1994-07-26 S T Chem Co Ltd Evaporation inhibitor
WO1999017717A3 (en) * 1997-10-08 1999-06-24 Johnson & Son Inc S C Liquid compositions containing ethylcellulose and terpenoid compounds
JP2009001501A (en) * 2007-06-19 2009-01-08 Dainippon Jochugiku Co Ltd Insect pest repellent for human body
JP2017160327A (en) * 2016-03-09 2017-09-14 信越化学工業株式会社 Volatile composition

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06207162A (en) * 1992-09-16 1994-07-26 S T Chem Co Ltd Evaporation inhibitor
WO1999017717A3 (en) * 1997-10-08 1999-06-24 Johnson & Son Inc S C Liquid compositions containing ethylcellulose and terpenoid compounds
JP2009001501A (en) * 2007-06-19 2009-01-08 Dainippon Jochugiku Co Ltd Insect pest repellent for human body
JP2017160327A (en) * 2016-03-09 2017-09-14 信越化学工業株式会社 Volatile composition

Also Published As

Publication number Publication date
JPH0580229B2 (en) 1993-11-08

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