JPH0131387B2 - - Google Patents
Info
- Publication number
- JPH0131387B2 JPH0131387B2 JP59033854A JP3385484A JPH0131387B2 JP H0131387 B2 JPH0131387 B2 JP H0131387B2 JP 59033854 A JP59033854 A JP 59033854A JP 3385484 A JP3385484 A JP 3385484A JP H0131387 B2 JPH0131387 B2 JP H0131387B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- fragrance
- gel
- water
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003205 fragrance Substances 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 29
- 229930195733 hydrocarbon Natural products 0.000 claims description 24
- CVYDEWKUJFCYJO-UHFFFAOYSA-M sodium;docosanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O CVYDEWKUJFCYJO-UHFFFAOYSA-M 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- -1 terpene hydrocarbons Chemical class 0.000 claims description 12
- 235000007586 terpenes Nutrition 0.000 claims description 12
- 150000002334 glycols Chemical class 0.000 claims description 8
- 235000019441 ethanol Nutrition 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 7
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 6
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 6
- 239000003349 gelling agent Substances 0.000 description 6
- 235000001510 limonene Nutrition 0.000 description 4
- 229940087305 limonene Drugs 0.000 description 4
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 3
- 235000021357 Behenic acid Nutrition 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 229940116226 behenic acid Drugs 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 229940051250 hexylene glycol Drugs 0.000 description 3
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 2
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- MOYAFQVGZZPNRA-UHFFFAOYSA-N Terpinolene Chemical compound CC(C)=C1CCC(C)=CC1 MOYAFQVGZZPNRA-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 2
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 2
- 229930006722 beta-pinene Natural products 0.000 description 2
- BQOFWKZOCNGFEC-UHFFFAOYSA-N carene Chemical compound C1C(C)=CCC2C(C)(C)C12 BQOFWKZOCNGFEC-UHFFFAOYSA-N 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 2
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 2
- XOKSLPVRUOBDEW-UHFFFAOYSA-N pinane Chemical compound CC1CCC2C(C)(C)C1C2 XOKSLPVRUOBDEW-UHFFFAOYSA-N 0.000 description 2
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 2
- 229940045870 sodium palmitate Drugs 0.000 description 2
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- YKFLAYDHMOASIY-UHFFFAOYSA-N γ-terpinene Chemical compound CC(C)C1=CCC(C)=CC1 YKFLAYDHMOASIY-UHFFFAOYSA-N 0.000 description 2
- GQVMHMFBVWSSPF-SOYUKNQTSA-N (4E,6E)-2,6-dimethylocta-2,4,6-triene Chemical compound C\C=C(/C)\C=C\C=C(C)C GQVMHMFBVWSSPF-SOYUKNQTSA-N 0.000 description 1
- 150000000133 (4R)-limonene derivatives Chemical class 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- FAMJUFMHYAFYNU-UHFFFAOYSA-N 1-methyl-4-(propan-2-yl)cyclohex-1-ene Chemical compound CC(C)C1CCC(C)=CC1 FAMJUFMHYAFYNU-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 235000003901 Crambe Nutrition 0.000 description 1
- 241000220246 Crambe <angiosperm> Species 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- 241001310492 Pectis angustifolia Species 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 239000002386 air freshener Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- VYBREYKSZAROCT-UHFFFAOYSA-N alpha-myrcene Natural products CC(=C)CCCC(=C)C=C VYBREYKSZAROCT-UHFFFAOYSA-N 0.000 description 1
- 125000003447 alpha-pinene group Chemical group 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229930006737 car-3-ene Natural products 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- GQVMHMFBVWSSPF-UHFFFAOYSA-N cis-alloocimene Natural products CC=C(C)C=CC=C(C)C GQVMHMFBVWSSPF-UHFFFAOYSA-N 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 150000002628 limonene derivativess Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000007823 ocimene derivatives Chemical class 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 229930004008 p-menthane Natural products 0.000 description 1
- 229930006728 pinane Natural products 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- MRQYKJNZWPCFNB-UHFFFAOYSA-M sodium;icosanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCC([O-])=O MRQYKJNZWPCFNB-UHFFFAOYSA-M 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- XJPBRODHZKDRCB-UHFFFAOYSA-N trans-alpha-ocimene Natural products CC(=C)CCC=C(C)C=C XJPBRODHZKDRCB-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- IHPKGUQCSIINRJ-UHFFFAOYSA-N β-ocimene Natural products CC(C)=CCC=C(C)C=C IHPKGUQCSIINRJ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Description
【発明の詳細な説明】 本発明はゲル状芳香剤組成物に関する。[Detailed description of the invention] The present invention relates to gel fragrance compositions.
更に詳細には、本発明はゲル化剤としてベヘニ
ン酸ソーダを含有するゲル状芳香剤組成物、更に
詳細にはベヘニン酸ソーダゲル化剤の他に揮発性
テルペン炭化水素及び/又はイソパラフイン系炭
化水素を溶剤として含有するゲル状芳香剤組成物
に関する。 More particularly, the present invention provides a gelled fragrance composition containing sodium behenate as a gelling agent, and more particularly, a volatile terpene hydrocarbon and/or isoparaffinic hydrocarbon in addition to the sodium behenate gelling agent. It relates to a gel fragrance composition containing as a solvent.
従来、ゲル状芳香剤組成物中で溶剤として使用
されている。揮発性テルペン炭化水素及び/又は
イソパラフイン系炭化水素溶剤のゲル化にはステ
アリン酸ソーダが使用されていた(例えば特公昭
57−16818号、同57−50502号及び特開昭55−
75493号)。しかし、ゲル化剤としてステアリン酸
ソーダを使用すると、得られるゲル状芳香剤製品
は周辺の水と作用して溶解するという欠点があつ
た。例えば、ステアリン酸ソーダを含有するゲル
状芳香剤を水中に投入するとゲル表面が白濁し、
そのままの状態で長時間放置すると分離して溶解
してしまつた。この原因は芳香剤成分であるテス
アリン酸ソーダが水溶性であるため、外部からの
水の添加によつて徐々に溶解することによる。 Traditionally, it is used as a solvent in gel fragrance compositions. Sodium stearate was used for gelation of volatile terpene hydrocarbons and/or isoparaffinic hydrocarbon solvents (e.g.
No. 57-16818, No. 57-50502 and JP-A-55-
No. 75493). However, the use of sodium stearate as a gelling agent has the disadvantage that the resulting gelled fragrance product interacts with surrounding water and dissolves. For example, when a gel fragrance containing sodium stearate is poured into water, the gel surface becomes cloudy;
If left as is for a long time, it would separate and dissolve. This is because sodium tesalate, which is a fragrance component, is water-soluble, so it gradually dissolves when water is added from the outside.
かかる欠点を克服すべく、本発明者は鋭意研究
を重ねた結果、ゲル化剤としてのベヘニン酸ソー
ダを使用すれば、上記欠点が解消することを発明
した。 In order to overcome these drawbacks, the inventors of the present invention have conducted extensive research and have discovered that the above drawbacks can be overcome by using sodium behenate as a gelling agent.
本発明によれば、ベヘニン酸ソーダ2〜15重量
%、揮発性テルペン炭化水素及び/又はイソパラ
フイン系炭化水素40重量%以上、グリコール類及
び/又はグリコールモノエーテル類及び/又はエ
チルアルコール1〜30重量%、水0.3〜10重量%、
並びに香科0.1〜40重量%を含有することを特徴
とするゲル状芳香剤組成物が提供される。 According to the present invention, 2 to 15% by weight of sodium behenate, 40% or more by weight of volatile terpene hydrocarbons and/or isoparaffinic hydrocarbons, 1 to 30% of glycols and/or glycol monoethers and/or ethyl alcohol. wt%, water 0.3-10 wt%,
Also provided is a gel-like fragrance composition characterized by containing 0.1 to 40% by weight of Aromaceae.
本発明においては、従来、ゲル化剤として使用
されていたステアリン酸ソーダの代わりにベヘニ
ン酸ソーダを芳香剤成分の全重量に対して2〜15
重量%使用する。ベヘニン酸ソーダはステアリン
酸ソーダよりも炭素数が4多く、炭素鎖が長いた
めに疎水性が強い。従つて、ゲル化剤としてベヘ
ニン酸ソーダを使用して製造したゲル状芳香剤組
成物は、水中に投入しても、完全に水を弾き、ま
た長時間水中に投入しても全く変化は生じない。
しかし、ベヘニン酸の量が2重量%により少ない
と、ゲルの強度(固さ)が不十分であり、また15
重量%より多いとゲルが生成しにくくなり、残量
が多くなるので好ましくない。 In the present invention, sodium behenate is used in place of sodium stearate, which has been conventionally used as a gelling agent, in an amount of 2 to 15% based on the total weight of the fragrance component.
Use % by weight. Sodium behenate has 4 more carbon atoms than sodium stearate and has a longer carbon chain, making it highly hydrophobic. Therefore, a gel-like fragrance composition manufactured using sodium behenate as a gelling agent completely repels water even when placed in water, and does not change at all even when placed in water for a long time. do not have.
However, when the amount of behenic acid is less than 2% by weight, the strength (hardness) of the gel is insufficient, and
If the amount exceeds % by weight, it becomes difficult to form a gel and the amount remaining becomes large, which is not preferable.
本発明において使用するベヘニン酸ソーダは純
度が40%以上のものが好ましく、特に純度60%以
上が好ましい。不純物としてパルミチン酸ソー
ダ、ステアリン酸ソーダ、オレイン酸ソーダ、ア
ラキン酸ソーダ等の脂肪酸ソーダ及び水を含有し
ていてもよい。例えば、ステアリン酸ソーダ又は
パルミチン酸ソーダを不純物として含有するベヘ
ニン酸ソーダを使用すると、その組成比により、
水中における溶解速度の異なるゲル状芳香剤組成
物を製造することができる。しかし、いずれの場
合においても、ベヘニン酸の純度は40%以上が好
ましい。ベヘニン酸の純度が40%より少いと、所
望の耐久性ゲル状芳香剤組成物は得られない場合
がある。このようなベヘニン酸ソーダとしては、
ナタネ油、クランベ油、魚油等又は天然油脂中に
存在するエルカ酸等を水素添加、ケン化分解及び
精製して得られたベヘニン酸ソーダが使用でき
る。 The sodium behenate used in the present invention preferably has a purity of 40% or more, particularly preferably 60% or more. It may contain fatty acid sodas such as sodium palmitate, sodium stearate, sodium oleate, and sodium arachinate, and water as impurities. For example, when using sodium behenate containing sodium stearate or sodium palmitate as an impurity, depending on the composition ratio,
Gel fragrance compositions with different dissolution rates in water can be produced. However, in any case, the purity of behenic acid is preferably 40% or more. If the purity of behenic acid is less than 40%, the desired durable gel fragrance composition may not be obtained. As such sodium behenate,
Sodium behenate obtained by hydrogenating, saponifying and decomposing and refining erucic acid, etc. present in rapeseed oil, crambe oil, fish oil, etc. or natural fats and oils can be used.
本発明では組成物中に揮発性テルペン系炭化水
素及び/又はイソパラフイン系炭化水素を溶剤と
して40重量%以上用いるが、テルペン系炭化水素
としては揮発性を有するものであればいかなるも
のを用いても良い。好ましい揮発性テルペン系炭
化水素としてはたとえばα−ピネン、β−ピネ
ン、リモネン、ジペンテン、p−シメン、3−カ
レン、γ−テルピネン、ミルセン、オシメン、ア
ロオシメン、p−メンタン、ピナン、ターピノー
レン、1−p−メンテン並びにリモネンダイマ
ー、ジペンテンダイマー又はその水添物、または
これらの混合物、またはこれらの混合物を主成分
とするもの、たとえば天然精油、たとえばα−ピ
ネン、β−ピネンを主成分とするテレビン油、d
−リモネンを主成分とするオレンジ油、及びレモ
ン油等を挙げることができる。 In the present invention, 40% by weight or more of a volatile terpene hydrocarbon and/or isoparaffin hydrocarbon is used as a solvent in the composition, but any volatile terpene hydrocarbon can be used. Also good. Preferred volatile terpene hydrocarbons include, for example, α-pinene, β-pinene, limonene, dipentene, p-cymene, 3-carene, γ-terpinene, myrcene, ocimene, alloocimene, p-menthane, pinane, terpinolene, 1- p-menthene, limonene dimer, dipentene dimer or hydrogenated products thereof, mixtures thereof, or mixtures thereof, such as natural essential oils such as turpentine oil whose main component is α-pinene or β-pinene; d
- Orange oil and lemon oil, which have limonene as a main component, can be mentioned.
特にd−リモネンはその香気からシトラス系調
合香料の重要な成分であり、シトラス系芳香剤の
溶剤としては特に優れている。特にこれらのテル
ペン系炭化水素を溶剤に用いると天然の風味をだ
すのに良く、また芳香剤の匂いが最後まで変わり
にくいという特徴がある。これらの天然のテルペ
ン系炭化水素中には少量のアルコール類、ケトン
類、アルデヒド類等の含酸素化合物が含まれてい
るがゲル形成には影響がないので含酸素化合物の
混入はさしつかえない。 In particular, d-limonene is an important component of citrus-based fragrances because of its aroma, and is particularly excellent as a solvent for citrus-based fragrances. In particular, when these terpene hydrocarbons are used as a solvent, they are good for bringing out a natural flavor, and the aroma of the aromatic agent does not change easily until the end. These natural terpene hydrocarbons contain small amounts of oxygen-containing compounds such as alcohols, ketones, aldehydes, etc., but since they do not affect gel formation, mixing of oxygen-containing compounds is not a problem.
イソパラフイン系炭化水素については、それ自
身毒性が無く、臭気が非常に少なく、適度の揮発
性を有し、安価であるので溶剤としては、非常に
好ましい。イソパラフイン系炭化水素のうち、示
性式がC8H18〜C18H38、更に好ましくは、C10H22
〜C16H34のものが本発明に特に好適である。イ
ソパラフイン系炭化水素と揮発性テルペン系炭化
水素を混合して用いることもできる。かような混
合揮発性炭化水素を用いた場合も本発明のゲル状
芳香剤組成物に含まれるものである。40%より少
いと、ベヘニン酸ソーダが溶解しにくくなり、好
ましくない。 Isoparaffinic hydrocarbons are highly preferred as solvents because they are nontoxic, have very little odor, have appropriate volatility, and are inexpensive. Among isoparaffinic hydrocarbons, those having a characteristic formula of C 8 H 18 to C 18 H 38 , more preferably C 10 H 22
-C16H34 are particularly suitable for the present invention. It is also possible to use a mixture of isoparaffinic hydrocarbons and volatile terpene hydrocarbons. The use of such mixed volatile hydrocarbons is also included in the gel fragrance composition of the present invention. If it is less than 40%, sodium behenate becomes difficult to dissolve, which is not preferable.
グリコール類及び/又はグリコールモノエーテ
ル類及び/又はエチルアルコールは1〜30重量%
にて混入する。好ましいグリコール類としては、
たとえばヘキシレングリコール、ジプロピレング
リコール、ジエチレングリコール、1,6−ヘキ
サンジオール、1,5−ペンタンジオール、2,
2−ジメチル−1,3−プロパンジオール、また
はこれらの混合物を挙げることができるが、これ
らに限定されるものではない。 Glycols and/or glycol monoethers and/or ethyl alcohol from 1 to 30% by weight
Contaminated with Preferred glycols include:
For example, hexylene glycol, dipropylene glycol, diethylene glycol, 1,6-hexanediol, 1,5-pentanediol, 2,
Examples include, but are not limited to, 2-dimethyl-1,3-propanediol and mixtures thereof.
グリコールモノエーテル類としてはグリコール
類のモノメチルエーテル、モノエチルエーテル、
3−メチル−3−メトキシブタノールまたはこれ
らの混合物が好ましいが、必ずしもかようなエー
テル類に限定されるものではない。グリコール
類、グリコールモノエーテル類またはこれらの混
合物を用いる場合、1重量%未満になるとベヘニ
ン酸ソーダが溶解しにくくなるので好ましくな
い。またグリコール類は揮発分が揮発した後、残
留成分として残るため30重量%を越ると、残留分
が多くなり好ましくない。エチルアルコールを単
独で用いる場合、1重量%未満では前述と同様に
ベヘニン酸ソーダが溶解しにくくなり一方30重量
%を越えると、生成ゲルの揮発速度が早くなりす
ぎて芳香剤として適さなくなる。エチルアルコー
ルとグリコール類及び/又はグリコールモノエー
テル類との混合物を使用することもできる。この
場合には混合物が1〜30重量%の範囲となるよう
に用いる。 Glycol monoethers include glycol monomethyl ether, monoethyl ether,
3-Methyl-3-methoxybutanol or a mixture thereof is preferred, but is not necessarily limited to such ethers. When using glycols, glycol monoethers, or a mixture thereof, if the amount is less than 1% by weight, it is not preferable because sodium behenate becomes difficult to dissolve. In addition, glycols remain as residual components after the volatile components have evaporated, so if it exceeds 30% by weight, the residual components will increase, which is not preferable. If ethyl alcohol is used alone, if it is less than 1% by weight, sodium behenate will be difficult to dissolve as described above, while if it exceeds 30% by weight, the resulting gel will volatilize too quickly, making it unsuitable as a fragrance. It is also possible to use mixtures of ethyl alcohol and glycols and/or glycol monoethers. In this case, the amount of the mixture is in the range of 1 to 30% by weight.
水は0.3〜10重量%の範囲で含有される。0.3重
量%未満ではベヘニン酸ソーダが溶解しなくな
り、10重量%を越ると各成分が分離し易くなる。
また水については、ベヘニン酸ソーダに含まれる
水分量も重要であり、最終的なゲル状芳香剤組成
物中に0.3〜10重量%の範囲で含まれていること
を意味する。 Water is contained in a range of 0.3 to 10% by weight. If it is less than 0.3% by weight, sodium behenate will not dissolve, and if it exceeds 10% by weight, each component will be likely to separate.
Regarding water, the amount of water contained in sodium behenate is also important, meaning that it is contained in the final gel fragrance composition in a range of 0.3 to 10% by weight.
本発明のゲル状芳香剤組成物においては、香料
は揮発性テルペン系炭化水素及び/又はイソパラ
フイン系炭化水素に可溶であればいかなる香料を
用いることもできる。香料は0.1〜40重量%の範
囲で用いる。0.1重量%未満では適度の芳香が得
られなくなり、一方40重量%を越えて用いてもさ
ほどの効果があがらない。 In the gel fragrance composition of the present invention, any fragrance can be used as long as it is soluble in volatile terpene hydrocarbons and/or isoparaffinic hydrocarbons. The fragrance is used in a range of 0.1 to 40% by weight. If it is less than 0.1% by weight, it will not be possible to obtain a suitable fragrance, while if it is used in excess of 40% by weight, it will not be very effective.
なお、本発明のゲル状芳香剤組成物にににおい
ては、必要に応じて他の添加剤、例えば酸化防止
剤(例えばBHT等)や増粘安定剤としての脂肪
酸金属塩(例えばステアリン酸アルミニウム、ス
テアリン酸マグネシウム等)及びその他の添加剤
を適宜使用できる。 In addition, in the gel-like fragrance composition of the present invention, other additives such as antioxidants (such as BHT) and fatty acid metal salts as thickening stabilizers (such as aluminum stearate, etc.) may be added as necessary. magnesium stearate, etc.) and other additives can be used as appropriate.
本発明のゲル状芳香剤組成物の製造にあたつて
は、ベヘニン酸ソーダ、揮発性テルペン炭化水素
及び/又はイソパフイン系炭化水素、グリコール
類及び/又はグリコールモノエーテル類及び/又
はエチルアルコール、水並びに必要に応じては所
望の添加剤を温度70℃〜90℃にて、ベヘニン酸ソ
ーダが完全に溶解するまで加熱撹拌する。次い
で、放置して温度60℃〜70℃まで冷却した後に、
所望の香料を添加し、十分に撹拌してから放冷す
ると固い安定なゲル状の芳香剤が得られる。 In producing the gel fragrance composition of the present invention, sodium behenate, volatile terpene hydrocarbons and/or isopafine hydrocarbons, glycols and/or glycol monoethers and/or ethyl alcohol, water, Further, if necessary, desired additives are heated and stirred at a temperature of 70°C to 90°C until the sodium behenate is completely dissolved. Then, after being left to cool down to a temperature of 60°C to 70°C,
When the desired fragrance is added, sufficiently stirred, and then allowed to cool, a hard and stable gel-like fragrance is obtained.
このようにして製造した本発明によるゲル状芳
香剤組成物は、水分の多い場所、例えば浴室、台
所、洗面所等に放置して、水がかかつても全く溶
解や白濁が生ぜず、持続して芳香を放ちながら、
数カ月間かかつて揮発する。 The gel-like fragrance composition according to the present invention produced in this manner does not dissolve or become cloudy at all even if it is left in a place with a lot of moisture, such as a bathroom, kitchen, washroom, etc., and persists without dissolving or becoming cloudy. While emitting a fragrance,
It evaporates for several months.
以下、実施例を用いて本発明を更に詳細に説明
するが、本発明はこれら実施例に記載の範囲に限
定されない。 EXAMPLES Hereinafter, the present invention will be explained in more detail using Examples, but the present invention is not limited to the scope described in these Examples.
実施例 1
以下の重量割合の各成分を使用して、本発明に
よるゲル状芳香剤組成物を製造した。Example 1 A gel fragrance composition according to the present invention was prepared using each component in the following weight proportions.
成 分 (g)
1 ベヘニン酸ソーダ(純度80%) 6.0
2 ヘキシレングリコール 5.0
3 水 1.0
4 BHT(酸化防止剤) 0.3
5 リモネン 82.7
6 香料(レモン系調合香料) 5.0
100.0
上記成分1.2.3.4.5を200ml三角フラスコに入れ、
70〜80℃でベヘニン酸ソーダが完全に溶解するま
で加熱撹拌したのち、65℃まで冷却し、6.香料を
加えてよくかきまぜて放冷すると、固い安定なゲ
ル状芳香剤が得られた。この芳香剤を浴室内に放
置し、その減少量及び状態を観察したところ、温
水、シヤワー等がその芳香剤にかかつても全く白
濁、溶解などがなく、少しずつ減少し、約2カ月
で約90%が揮発した。またその間レモンの香りが
持続していた。Ingredients (g) 1 Sodium behenate (purity 80%) 6.0 2 Hexylene glycol 5.0 3 Water 1.0 4 BHT (antioxidant) 0.3 5 Limonene 82.7 6 Fragrance (lemon-based blended fragrance) 5.0 100.0 Above ingredients 1.2.3.4. Put 5 into a 200ml Erlenmeyer flask,
After heating and stirring at 70 to 80°C until the sodium behenate was completely dissolved, the mixture was cooled to 65°C, 6. After adding the fragrance, stirring well and allowing to cool, a hard and stable gel-like fragrance was obtained. When we left this air freshener in the bathroom and observed the amount and condition of the reduction, we found that when hot water, showers, etc. 90% evaporated. Also, the lemon scent persisted during that time.
実施例 2
(g)
1 ベヘニン酸ソーダ(純度65%) 7.0
2 ジエチレングリコールモノエチルエーテル
6.0
3 BHT(酸化防止剤) 0.1
4 水 1.5
5 イソパラフイン系炭化水素溶剤(商品名
「IPソルベント1620」出光石油化学(株)製)78.4
6 香料(ジヤスミン系調合香料) 7
100.0
実施例1と同様の方法で本発明のゲル状芳香剤
組成物を製造し、同様の方法で試験したところ、
約2カ月間ジヤスミンの香りを持続し、2カ月後
には約90%が揮発した。Example 2 (g) 1 Sodium behenate (purity 65%) 7.0 2 Diethylene glycol monoethyl ether
6.0 3 BHT (antioxidant) 0.1 4 Water 1.5 5 Isoparaffinic hydrocarbon solvent (trade name "IP Solvent 1620" manufactured by Idemitsu Petrochemical Co., Ltd.) 78.4 6 Fragrance (diasmine-based mixed fragrance) 7 100.0 Example 1 and A gel fragrance composition of the present invention was produced in a similar manner and tested in a similar manner.
The diasmine scent lasted for about two months, and about 90% of it had evaporated after two months.
実施例 3
(g)
1 ナタネ油水素添加脂肪酸ソーダ(純度42%)
6.0
2 ヘキシレングリコール 5.0
3 BHT 0.3
4 水 1.2
5 リモネン 80.5
6 香料(ライム系調合香料) 7.0
100.0
実施例1と同様の方法で本発明のゲル状芳香剤
組成物を製造し、同様の方法で試験した。約2カ
月間で約90%が揮発し、その間ライムの香りが持
続していた。Example 3 (g) 1 Rapeseed oil hydrogenated fatty acid soda (purity 42%)
6.0 2 Hexylene glycol 5.0 3 BHT 0.3 4 Water 1.2 5 Limonene 80.5 6 Fragrance (lime-based mixed fragrance) 7.0 100.0 The gel-like fragrance composition of the present invention was produced in the same manner as in Example 1, and Tested. Approximately 90% of the liquid evaporated over a period of about two months, during which time the lime scent persisted.
Claims (1)
ペン炭化水素及び/又はイソパラフイン系炭化水
素40重量%以上、グリコール類及び/又はグリコ
ールモノエーテル類及び/又はエチルアルコール
1〜30重量%、水0.3〜10重量%、並びに香料0.1
〜40重量%を含有することを特徴とするゲル状芳
香剤組成物。1 Sodium behenate 2-15% by weight, volatile terpene hydrocarbons and/or isoparaffinic hydrocarbons 40% by weight or more, glycols and/or glycol monoethers and/or ethyl alcohol 1-30% by weight, water 0.3 ~10% by weight, as well as 0.1% fragrance
A gel fragrance composition characterized in that it contains ~40% by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59033854A JPS60179064A (en) | 1984-02-24 | 1984-02-24 | Gel like aromatic composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP59033854A JPS60179064A (en) | 1984-02-24 | 1984-02-24 | Gel like aromatic composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60179064A JPS60179064A (en) | 1985-09-12 |
JPH0131387B2 true JPH0131387B2 (en) | 1989-06-26 |
Family
ID=12398090
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59033854A Granted JPS60179064A (en) | 1984-02-24 | 1984-02-24 | Gel like aromatic composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60179064A (en) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62166855U (en) * | 1986-04-11 | 1987-10-23 | ||
US4983578A (en) * | 1989-04-18 | 1991-01-08 | The Drackett Company | Air freshener composition and device |
FR2894811B1 (en) † | 2005-12-21 | 2008-02-22 | Oreal | COSMETIC COMPOSITION WITH VOLUMER EFFECT |
US20070196301A1 (en) | 2005-12-21 | 2007-08-23 | L'oreal | Cosmetic composition with a volumizing effect |
JP5570856B2 (en) * | 2010-03-19 | 2014-08-13 | 日本メナード化粧品株式会社 | Air freshener composition |
JP6703922B2 (en) * | 2016-09-30 | 2020-06-03 | エステー株式会社 | Aroma composition |
-
1984
- 1984-02-24 JP JP59033854A patent/JPS60179064A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS60179064A (en) | 1985-09-12 |
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