JPS62176771A - Polishing tape - Google Patents

Polishing tape

Info

Publication number
JPS62176771A
JPS62176771A JP1859486A JP1859486A JPS62176771A JP S62176771 A JPS62176771 A JP S62176771A JP 1859486 A JP1859486 A JP 1859486A JP 1859486 A JP1859486 A JP 1859486A JP S62176771 A JPS62176771 A JP S62176771A
Authority
JP
Japan
Prior art keywords
polishing
vinyl
tape
abrasive
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1859486A
Other languages
Japanese (ja)
Inventor
Nobutaka Yamaguchi
信隆 山口
Eiichi Tadokoro
田所 栄一
Masaaki Fujiyama
正昭 藤山
Masahiro Uchiumi
正広 内海
Akira Kasuga
明 春日
Masami Suzuki
正美 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujifilm Holdings Corp
Original Assignee
Fuji Photo Film Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Photo Film Co Ltd filed Critical Fuji Photo Film Co Ltd
Priority to JP1859486A priority Critical patent/JPS62176771A/en
Publication of JPS62176771A publication Critical patent/JPS62176771A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To improve the surface performance of a coated film by forming said coated film containing the polishing agent made of chromium oxide and the bonding agent made of vinyl chloride-vinyl active-vinyl alcohol onto a nonmagnetic supporting body, thus permitting the sufficient polishing without damaging the tape sliding surface of a magnetic head. CONSTITUTION:A polishing tape is constituted of a nonmagnetic supporting body 1 and a coated layer 2 formed onto the supporting body 1. Said coated layer 2 contains a polishing agent 3 and a bonding agent, and said polishing agent 3 consists of the polishing particles made of chromium oxide having a Mohs' hardness of 8.5 or so, and the bonding agent is made of vinyl chloride- vinyl acetate-vinyl alcohol. Therefore, the tape sliding surface of a magnetic head 4 can be smoothly polished without damaging the tape sliding surface by the polishing agent 3 having a proper hardness. Further, since only vinyl chloride-vinyl acetate-vinyl alcohol as three component copolymer having the superior dispersion performance is used as bonding agent, said polishing agent can be uniformly dispersed into the coating liquid, and the surface performance of the coated film can be improved.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は磁気記録再生装置の磁気ヘッドの精密研磨に用
いる研磨テープに関するものであり、とくにビデオ用あ
るいは高級オーディオ用の磁気ヘッドの平滑仕上に用い
る研磨テープに関するものである。
Detailed Description of the Invention (Field of Industrial Application) The present invention relates to an abrasive tape used for precision polishing of magnetic heads of magnetic recording and reproducing devices, and is particularly suitable for smoothing magnetic heads for video or high-end audio. This invention relates to the polishing tape used.

(従来技術) ビデオ用あるいは高級オーディオ用の磁気ヘッド等はテ
ープ摺動面の平滑性がとくに要求されるため、一般に磁
気ヘッドを製作する際粗削りの後研磨テープを用いてテ
ープ摺動面を平滑に仕上げている。このような研磨テー
プは可撓性を有する非磁性支持体に微細な研磨粒子等を
塗着したものであり、磁気ヘッドのテープ摺動面の曲面
形状になじんでこの面を精密に研磨仕上することができ
る。
(Prior art) Magnetic heads for video or high-end audio require particularly smooth tape sliding surfaces, so when manufacturing magnetic heads, a polishing tape is generally used to smooth the tape sliding surface after rough cutting. It is being completed. This kind of abrasive tape is made by coating fine abrasive particles on a flexible non-magnetic support, and adapts to the curved shape of the tape sliding surface of the magnetic head to precisely polish this surface. be able to.

従来、このようなテープとしては例えば、酸化亜鉛(Z
n O)等からなる研磨剤と塩化ビニル−酢酸ビニル共
重合体等からなるバインダとポリイソシアネート等の硬
化剤を混練した塗液を支持体上にmWしたクリーニング
テープが知られている〈特開昭53−102017号)
Conventionally, such tapes include, for example, zinc oxide (Z
A cleaning tape is known in which a coating liquid prepared by kneading an abrasive such as nO), a binder such as a vinyl chloride-vinyl acetate copolymer, and a curing agent such as polyisocyanate is coated on a support in mW (Unexamined Japanese Patent Publication No. (Sho 53-102017)
.

しかしながら上記テープは主に磁気ヘッドに付着した叶
埃等を除去することを目的とづるものであってその目的
からして研磨剤もモース硬度4.5程度の酸化亜鉛等を
使用しているため、研磨剤の硬度が小さ過ぎて磁気ヘッ
ド研磨用のテープとしては不十分であった。
However, the tape mentioned above is mainly intended to remove dust etc. attached to the magnetic head, and for that purpose, the abrasive used is zinc oxide, etc., which has a Mohs hardness of about 4.5. However, the hardness of the abrasive was too low to be used as a magnetic head polishing tape.

また、上記塗液は、バインダが塩化ビニル−酢酸ビニル
共重合体等からなるため研磨剤の分散性に欠けるうえ、
研磨層の硬度を補填する意味で硬化剤を用いているため
混練後塗着するまでの時間の良さによって塗液の硬化の
程度が異なるという問題があり、これにより支持体上塗
膜の表面性が劣りかつその程度のバラツキも大きいとい
う問題があった。塗膜の表面性が良好でない場合にはヘ
ッド表面に多数の傷が形成され、高感度、高S/N比が
要求されるビデオ用あるいは高級オーディオ用の磁気ヘ
ッドとして十分な特性を得ることが困難となる。
In addition, since the binder of the above coating liquid is made of vinyl chloride-vinyl acetate copolymer, etc., it lacks the dispersibility of the abrasive, and
Since a curing agent is used to compensate for the hardness of the polishing layer, there is a problem in that the degree of curing of the coating solution varies depending on the time from kneading to coating. There was a problem that the quality was inferior and the degree of variation was large. If the surface properties of the coating film are not good, many scratches will be formed on the head surface, making it difficult to obtain sufficient characteristics as a magnetic head for video or high-end audio applications that require high sensitivity and high S/N ratio. It becomes difficult.

(発明の目的) 本発明は上記問題を解決するためになされたものであり
、磁気ヘッドを傷つけることなく十分に研磨でき、これ
により高特性の磁気ヘッドを製作し得る研磨テープを提
供することを目的とするものである。
(Objective of the Invention) The present invention has been made to solve the above problems, and an object of the present invention is to provide a polishing tape that can sufficiently polish a magnetic head without damaging it, thereby making it possible to manufacture a magnetic head with high characteristics. This is the purpose.

(fe明の構成) 本発明の研磨テープは、酸化クロムからなる研磨剤、塩
化ビニル−酢酸ビニル−ビニルアルコールのみからなる
結合剤(バインダ)を含む塗膜を非磁性支持体上に形成
したことを特徴とづるものである。
(Structure of Fe Akira) The abrasive tape of the present invention has a coating film containing an abrasive agent made of chromium oxide and a binder made only of vinyl chloride-vinyl acetate-vinyl alcohol formed on a non-magnetic support. It is characterized by

なお、上記研磨テープとは、いわゆるテープ形状のもの
のほか、ディスク形状あるいはシート形状のものも広く
含むものとする。
Note that the above-mentioned polishing tape broadly includes not only so-called tape-shaped polishing tapes but also disc-shaped or sheet-shaped polishing tapes.

(発明の効果) 本発明の研磨テープによれば、研磨剤としてモース硬度
が8.5である適度に硬い酸化クロムを用いているから
、磁気ヘッドのテープ摺動面を傷っけることなく確実に
かつ十分に研磨することができる。また、バインダとし
て分散性のよい三元系共重合体である塩化ビニル−酢酸
ビニル−ビニルアルコールのみを使用しているから研磨
剤を塗液中に均一に分散させることができ、塗膜の表面
性を向上させることができる。さらに、分散性がよいた
めω1磨材が塗膜中に均一に存在しバインダーと研磨材
の結合力が大で塗膜強度が強くなり、従来のような研磨
材が凝集し塗膜強度が弱いものと異なり硬化剤を使用し
なくてもよいから塗液混練俊の経過時間により塗液の粘
度が大ぎく異なることはないため塗布しやすくそのため
、塗膜表面の表面性のバラツキの発生を防止することが
できる。
(Effects of the Invention) According to the abrasive tape of the present invention, since moderately hard chromium oxide with a Mohs hardness of 8.5 is used as the abrasive, the tape sliding surface of the magnetic head can be reliably protected from damage. It can be polished quickly and thoroughly. In addition, since only vinyl chloride-vinyl acetate-vinyl alcohol, which is a ternary copolymer with good dispersibility, is used as a binder, the abrasive can be uniformly dispersed in the coating liquid, and the surface of the coating film is can improve sex. Furthermore, due to its good dispersibility, the ω1 abrasive exists uniformly in the coating film, and the binding force between the binder and the abrasive is large, increasing the strength of the coating, whereas conventional abrasives aggregate and reduce the strength of the coating. Unlike conventional coatings, there is no need to use a hardening agent, so the viscosity of the coating solution does not vary greatly depending on the elapsed time of mixing the coating solution, making it easier to apply and preventing variations in the surface properties of the coating film surface. can do.

(実 施 態 様) 以下、本発明の実IM態様について詳細に説明する。(Implementation mode) Hereinafter, the actual IM aspect of the present invention will be explained in detail.

本発明の実施態様による研磨テープは図示するように非
磁性支持体1と、この支持体1上に形成された塗布層2
から構成されている。塗布層2は、研磨剤3.結合剤(
バインダ)を含むものである。
As shown in the figure, the polishing tape according to the embodiment of the present invention includes a non-magnetic support 1 and a coating layer 2 formed on the support 1.
It consists of The coating layer 2 is coated with an abrasive 3. Binding agent (
binder).

また、この研磨剤3はモース硬度8.5の酸化クロムの
研磨粒子からなり、上記結合剤は塩化ビニル−酢酸ビニ
ル−ビニルアルコールからなる。
Further, this abrasive 3 is made of abrasive particles of chromium oxide having a Mohs hardness of 8.5, and the binder is made of vinyl chloride-vinyl acetate-vinyl alcohol.

上述した適度に硬い研磨剤3により、磁気ヘッド4のテ
ープ摺動面を傷つけることなく平滑に研削することがで
きる。なJ3、この研磨粒子の粒子径は10μTrL〜
0.01μm程度であればよいが、最終仕上用として用
いる場合には1μm−0,1μm程度とするのが好まし
い。
By using the moderately hard abrasive 3 described above, it is possible to grind the tape sliding surface of the magnetic head 4 smoothly without damaging it. J3, the particle size of this abrasive particle is 10μTrL ~
It may be about 0.01 μm, but when used for final finishing, it is preferably about 1 μm-0.1 μm.

このような研磨剤としては、例えばr N D −80
1゜N O−802,N O−803(日本電工)J:
rG5.G7(日本化学工業)」がある。
As such an abrasive, for example, r N D -80
1゜NO-802, NO-803 (Nippon Denko) J:
rG5. G7 (Nihon Kagaku Kogyo)".

この研磨剤3を分散させる塩化ビニル−酢酸ビニル−ビ
ニルアルコールは塩化ビニル酢酸ビニルに第3成分とし
てのビニルアルコールを結合させた3元系共重合体であ
り、第3成分としてのビニルアルコールを結合させるこ
とにより研磨剤3を分散させるかが大きくなり、従来研
磨剤3が部分的に凝集することにより生じていた磁気ヘ
ッドのft1ll!!iむらの発生を防止することがで
きる。
The vinyl chloride-vinyl acetate-vinyl alcohol in which this polishing agent 3 is dispersed is a ternary copolymer in which vinyl chloride and vinyl acetate are combined with vinyl alcohol as a third component. By doing so, the degree of dispersion of the abrasive 3 becomes larger, and the ft1ll! of the magnetic head, which conventionally occurs due to partial agglomeration of the abrasive 3, increases. ! It is possible to prevent the occurrence of i-uniformity.

この塩化ビニル−酢酸ビニル−ビニルアルコールとして
は、例えば「エスレックA(積木化学)」: rMPR
−TA (8信化学〉に「ビニライトVAGH(UCC
)J ; rビンカビニル100OG(電気化学工業)
」がある。
As this vinyl chloride-vinyl acetate-vinyl alcohol, for example, "S-LEC A (Building Wood Chemical)": rMPR
-TA (8 Shin Chemical) “Vinilight VAGH (UCC)
) J ; r Vincavinyl 100OG (Denki Kagaku Kogyo)
” is there.

なお、塩化ビニル、酢酸ビニルおよびビニルアルコール
各成分の共重合比は研磨剤3を十分に分散させることが
でき、かつ塗布層2が十分な可撓性を有するような比率
とすべきであり、このような観点から塩化ビニルを50
〜98重け%、酢酸ビニルを0.5〜40重徂%、ビニ
ルアルコールを1〜20重M%とし、さらに好ましくは
塩化ビニルを85〜95重量%、酢酸ビニルを1〜5m
ff1%、ビニルアルコールを3〜9重量%とする。な
お、平均重合度は200〜700程度であればよいが、
350〜SOO程度とすればより好ましい。
Note that the copolymerization ratio of vinyl chloride, vinyl acetate, and vinyl alcohol components should be such that the abrasive 3 can be sufficiently dispersed and the coating layer 2 has sufficient flexibility. From this perspective, vinyl chloride
-98% by weight, vinyl acetate 0.5-40% by weight, vinyl alcohol 1-20% by weight, more preferably vinyl chloride 85-95% by weight, vinyl acetate 1-5m
ff1% and vinyl alcohol 3 to 9% by weight. Note that the average degree of polymerization may be about 200 to 700, but
It is more preferable to set it to about 350 to SOO.

また、添加剤として分散剤、潤滑剤、フィラーを加える
こともできる。
Moreover, a dispersant, a lubricant, and a filler can also be added as additives.

さらに、前述した非磁性支持体1としては、ポリエチレ
ンテレフタレート(PET)、ポリエチレン−2,6−
ナフタレート等のポリエステル類。
Furthermore, as the non-magnetic support 1 mentioned above, polyethylene terephthalate (PET), polyethylene-2,6-
Polyesters such as naphthalate.

ポリエチレン、ポリプロピレン等のポリオレフィン類、
セルロース・ダイアセテート、セルロース・1〜リアセ
テート、セルロースアセテート・ブチレート、セルロー
スアセテ−ドブOビオネート等のセルロース誘導体等が
用いられる。
Polyolefins such as polyethylene and polypropylene,
Cellulose derivatives such as cellulose diacetate, cellulose 1-lyacetate, cellulose acetate butyrate, and cellulose acetate bionate are used.

なお、塗布層2の厚みは、磁気ヘッド4の形状、材質に
もよるが、この厚みがあまり大きいと、磁気ヘッドと研
磨テープの接触が悪くなるので、50μm以下が好まし
い。
The thickness of the coating layer 2 depends on the shape and material of the magnetic head 4, but if the thickness is too large, the contact between the magnetic head and the polishing tape will be poor, so it is preferably 50 μm or less.

つぎに実施例を挙げてさらに詳細に説明する。Next, a more detailed explanation will be given with reference to examples.

実  施  例 厚さ12μmのポリエチレンテレフタレート([〕ET
)支持体上に下記の塗布組成の5μmの厚さで塗布して
研磨テープ1を作った。なa3、以下の説明において部
はすべて重Δ部(固形分重量)を示す。
Example Polyethylene terephthalate ([]ET
) A polishing tape 1 was prepared by coating the following coating composition on a support to a thickness of 5 μm. In the following description, all parts indicate weight Δ parts (solid content weight).

塗  布  組  成 ・Cr203(粒状、サイズ0.5μm径)・・・・・
・300部 ・塩化ビニル−酢酸ビニル−ビニルアルコール共重合体
く共重合比91:  3:  6.重合度420)・・
・60部 ・シリコーン油           ・・・・・・0
.3部・メチルエチルケトン       ・・・・・
・150部・酢酸n−ブチル         ・・・
・・・300部比  較  例  1 次に、上記実施例に対する比較例として上記実施例と略
同様の支持体上に下記の塗布組成の混合液を塗布して研
磨テープ2を作った。なお、本比較例は特開昭53−1
02017号に開示されたサンプル〜α24と同様のも
のである。
Coating composition: Cr203 (granular, size 0.5μm diameter)...
- 300 parts - Vinyl chloride-vinyl acetate-vinyl alcohol copolymer, copolymerization ratio 91:3:6. Degree of polymerization 420)...
・60 parts ・Silicone oil ・・・・・・0
.. Part 3: Methyl ethyl ketone...
・150 parts・n-butyl acetate...
...300 copies Comparison Example 1 Next, as a comparative example to the above example, a polishing tape 2 was prepared by coating a liquid mixture having the following coating composition on a support substantially similar to that of the above example. This comparative example is based on Japanese Patent Application Laid-Open No. 53-1
This sample is similar to sample α24 disclosed in No. 02017.

塗  布  組  成 −ZnO・・・・・・ 300部 (サイズ120μ亀径、モース硬度4.5)・塩化ビニ
ル−酢酸ビニル共重合体 ・・・・・・34.7部(共
重合比87:13.重合度350)・ポリエステルポリ
オール     ・・・・・・ 21部(アジピンM1
モルとジエチレングリ コール1モルとトリメチロールプロ パン0.06モルの反応生成物粘度 (75℃) 1000CP 、比重1.180I−1価
609M価〈2) ・大豆レシチン          ・・・・・・2.
4部・シリコーン油(ジメチル・ポリシロキサン)・・
・・・・0.1部 ・ポリイソシアネート       ・・・・・・ 1
8部(3モルの2.4−トリレンジイワシ アネート化合物と1モルのトリメチ ロールプロパンの反応生成物の75W[%酢酸エチル溶
液) ・メチルエチルケトン       ・・・・・・/1
00部やトルエン              ・・・
・・・ 400部比  較  例  2 さらに、実施例における研磨剤であるCrz03をα−
8in(粒状、サイズ0.5μ■径、モース硬度9.5
)に変え、他は実施例と同様の方法で研磨テープ3を作
った。
Coating composition - ZnO 300 parts (size 120μ diameter, Mohs hardness 4.5) Vinyl chloride-vinyl acetate copolymer 34.7 parts (copolymerization ratio 87 :13.Polymerization degree 350)・Polyester polyol 21 parts (Adipine M1
The reaction product of 1 mole of diethylene glycol and 0.06 mole of trimethylolpropane has a viscosity (75°C) of 1000CP, a specific gravity of 1.180I - a monovalent value of 609M (2) - Soybean lecithin...2.
4 parts: Silicone oil (dimethyl polysiloxane)...
...0.1 part polyisocyanate ...1
8 parts (75W [% ethyl acetate solution of the reaction product of 3 moles of 2.4-tolylene diisocyanate compound and 1 mole of trimethylolpropane] ・Methyl ethyl ketone ....../1
00 parts or toluene...
... 400 copies Comparison Example 2 Furthermore, Crz03, which is the abrasive in the example, was
8in (granular, size 0.5μ diameter, Mohs hardness 9.5
), and other than that, polishing tape 3 was made in the same manner as in the example.

比  較  例  3 ざらに、実施例における研磨剤であるCrz03をS!
Oz(粒状、サイズ0.5μ辺径、モース硬度7)に変
え、他は実施例と同様の方法で研署テープ4を作った。
Comparison Example 3 Roughly, Crz03, the abrasive in the example, was mixed with S!
A research station tape 4 was made in the same manner as in the example except that the material was granular, side diameter 0.5 μm, Mohs hardness 7.

以上の実施例と比較例の各研磨テープについてヘッド研
削時間と研削後にJ3けるヘッド表面の傷の状態を調べ
た。その結果を下表に示す。
For each of the abrasive tapes of the above Examples and Comparative Examples, the head grinding time and the state of scratches on the head surface after grinding were investigated. The results are shown in the table below.

上表において、ヘッド研削時間はフェライトヘッド1μ
mを研削するのに必要な時間である。またヘッド表面の
傷は研削後の磁気ヘッドのギヤツブ面を顕微鏡で見て確
認された長さ0.5酎当りの幅2μm以上の傷の本数で
ある。
In the table above, the head grinding time is 1μ for the ferrite head.
This is the time required to grind m. Furthermore, the number of scratches on the head surface is the number of scratches with a width of 2 μm or more per 0.5 mm length, which was confirmed by looking at the gear surface of the magnetic head after grinding using a microscope.

上表から明らかなように、本実施例によりヘッド研削時
間を極めて短縮することができるとともに、磁気ヘッド
表面の大ぎなすり傷の発生を防止することができる。
As is clear from the above table, according to this embodiment, the head grinding time can be extremely shortened, and the occurrence of large scratches on the surface of the magnetic head can be prevented.

【図面の簡単な説明】[Brief explanation of drawings]

図面を磁気ヘッドの研磨時にJ3ける、本発明の一実施
態様による研磨テープの拡大断面図である。 1・・・非磁性支持体(PET) 2・・・塗  布  層 3・・・研  磨  剤 4・・・磁気ヘッド
FIG. 3 is an enlarged cross-sectional view of a polishing tape according to an embodiment of the present invention, taken at J3 during polishing of a magnetic head. 1... Non-magnetic support (PET) 2... Coating layer 3... Polishing agent 4... Magnetic head

Claims (1)

【特許請求の範囲】 研磨材、結合剤を含む研磨塗膜を可撓性を有する非磁性
支持体上に塗着してなる研磨テープにおいて、 前記研磨材が酸化クロムからなり、前記結合剤が塩化ビ
ニル−酢酸ビニル−ビニルアルコールのみからなるもの
であることを特徴とする研磨テープ。
[Scope of Claims] An abrasive tape comprising an abrasive coating film containing an abrasive material and a binder applied onto a flexible non-magnetic support, wherein the abrasive material is made of chromium oxide, and the binder is made of chromium oxide. An abrasive tape comprising only vinyl chloride, vinyl acetate, and vinyl alcohol.
JP1859486A 1986-01-30 1986-01-30 Polishing tape Pending JPS62176771A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1859486A JPS62176771A (en) 1986-01-30 1986-01-30 Polishing tape

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1859486A JPS62176771A (en) 1986-01-30 1986-01-30 Polishing tape

Publications (1)

Publication Number Publication Date
JPS62176771A true JPS62176771A (en) 1987-08-03

Family

ID=11975963

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1859486A Pending JPS62176771A (en) 1986-01-30 1986-01-30 Polishing tape

Country Status (1)

Country Link
JP (1) JPS62176771A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007263851A (en) * 2006-03-29 2007-10-11 Koden Electronics Co Ltd Direction detection device, inspection method of the direction detection device, adjustment method of the direction detection device, and control method of the direction detection device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007263851A (en) * 2006-03-29 2007-10-11 Koden Electronics Co Ltd Direction detection device, inspection method of the direction detection device, adjustment method of the direction detection device, and control method of the direction detection device

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