JPS62155203A - Sterilizer composition for bran - Google Patents
Sterilizer composition for branInfo
- Publication number
- JPS62155203A JPS62155203A JP29388685A JP29388685A JPS62155203A JP S62155203 A JPS62155203 A JP S62155203A JP 29388685 A JP29388685 A JP 29388685A JP 29388685 A JP29388685 A JP 29388685A JP S62155203 A JPS62155203 A JP S62155203A
- Authority
- JP
- Japan
- Prior art keywords
- inorganic peroxide
- activator
- present
- cationic surfactant
- 10pts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は畜舎用殺菌剤組成物に関し、更に詳しくは畜舎
における“ふん”等の有機物の存在下においても優れた
殺菌効力を有する畜舎用殺菌剤組成物に関する。Detailed Description of the Invention [Field of Industrial Application] The present invention relates to a disinfectant composition for livestock housing, and more specifically to a disinfectant composition for livestock housing that has excellent disinfectant efficacy even in the presence of organic matter such as "feces" in livestock housing. The present invention relates to a drug composition.
殺菌活性を有する陽イオン性界面活性剤、例えばアルキ
ルジメチルベンジルアンモニウム塩、置換ベンザルコニ
ウム塩、ベンゼトニウム塩、ジアルキルジメチルアンモ
ニウム塩等は牛、馬、鶏などの畜舎に使用した場合、多
量の“ふん”が付着しているため、殺菌力が著しく低下
するという欠点があった。Cationic surfactants with bactericidal activity, such as alkyldimethylbenzylammonium salts, substituted benzalkonium salts, benzethonium salts, and dialkyldimethylammonium salts, can cause large amounts of feces when used in livestock housing such as cattle, horses, and chickens. ” had the disadvantage that the bactericidal power was significantly reduced.
そこで本発明者らは、このような欠点を解消し“ふん”
等由来の有機物存在下においても優れた殺菌効力を有す
る畜舎用殺菌剤組成物を得るべく鋭意研究を行った結果
、陽イオン性界面活性剤と無機過酸化物を併用すること
により、有機物存在下においても優れた殺菌力を発揮す
ることを見出し本発明を完成した。Therefore, the inventors of the present invention have solved these drawbacks and
As a result of intensive research to obtain a disinfectant composition for livestock barns that has excellent bactericidal efficacy even in the presence of organic matter derived from The present invention was completed by discovering that it also exhibits excellent sterilizing power.
即ち、本発明は陽イオン性界面活性剤及び無機過酸化物
を必須成分として含有することを特徴とする畜舎用殺菌
剤組成物を提供するものである。That is, the present invention provides a disinfectant composition for livestock housing, which is characterized by containing a cationic surfactant and an inorganic peroxide as essential components.
本発明に用いられる陽イオン性界面活性剤としては殺菌
活性を有するものであれば特に限定されず、例えばアル
キルジメチルベンジルアンモニウム塩、置換ベンザルコ
ニウム塩、ベンゼトニウム塩、ジアルキルジメチルアン
モニウム塩などのモノカチオン化合物のほか、Ｎ−アル
キル−Ｎ、Ｎ、Ｎ’、Ｎ”Ｎｌ−ペンタメチル−プロピ
レンアンモニウム塩などのポリカチオン化合物が挙げら
れる。The cationic surfactant used in the present invention is not particularly limited as long as it has bactericidal activity, and includes monocationic surfactants such as alkyldimethylbenzylammonium salts, substituted benzalkonium salts, benzethonium salts, and dialkyldimethylammonium salts. In addition to the compounds, examples thereof include polycationic compounds such as N-alkyl-N, N, N', N''Nl-pentamethyl-propylene ammonium salt.
無機過酸化物としては、過炭酸ナトリウム、過硼酸ナト
リウム、過酸化トリポリリン酸ナトリウム、過酸化ビロ
リン酸ナトリウム、過酸化ケイ酸ナトリウム等が挙げら
れる。Examples of the inorganic peroxide include sodium percarbonate, sodium perborate, sodium peroxide tripolyphosphate, sodium peroxide birophosphate, and sodium peroxide silicate.
本発明の殺菌剤組成物は、上記２成分を任意の割合に混
合して使用できるが、殺菌効果、経済性等を考慮すると
、陽イオン性界面活性剤１重量部に対し無機過酸化物０
６１〜１００重量部の範囲で使用することが好ましい。The bactericidal composition of the present invention can be used by mixing the above two components in any ratio, but considering the bactericidal effect, economical efficiency, etc.
It is preferable to use it in a range of 61 to 100 parts by weight.
上記の範囲を外れると本発明の顕著な効果である有機物
存在下での優れた殺菌力が得られない。より好ましくは
、陽イオン性界面活性剤１重量部に対し無機過酸化物０
．３〜５０重景部である。Outside the above range, the excellent bactericidal activity in the presence of organic matter, which is the remarkable effect of the present invention, cannot be obtained. More preferably, 0 parts by weight of inorganic peroxide per 1 part by weight of cationic surfactant.
．． It is a 3-50 heavy view part.
本発明の殺菌剤組成物は通常粉体、顆粒、錠剤等の固形
物として製剤され、使用に当たり、水に希釈し施用され
る。その時の濃度は対象物によっても異なるが、通常１
０〜１１０００ｐｐである。The fungicide composition of the present invention is usually formulated as a solid substance such as powder, granules, or tablets, and is diluted with water before application. The concentration at that time varies depending on the object, but it is usually 1
It is 0 to 11000 pp.
勿論、陽イオン性界面活性剤と無機過酸化物をそれぞれ
製剤し、使用に当たり、両者を水に希釈して施用するこ
とも本発明に含まれるものである。Of course, it is also within the scope of the present invention to prepare a cationic surfactant and an inorganic peroxide, respectively, and apply the two after diluting them with water.
また、上記２成分に加え、更に無機過酸化物の活性化剤
を併用すると一層優れた効果が得られる。従って、本発
明は第２発明として陽イオン性界面活性剤、無機過酸化
物および無機過酸化物の活性化剤を必須成分として含有
することを特徴とする畜舎用殺菌剤組成物を提供するも
のである。Further, in addition to the above two components, an even more excellent effect can be obtained by using an inorganic peroxide activator in combination. Therefore, as a second invention, the present invention provides a disinfectant composition for livestock housing, which is characterized by containing a cationic surfactant, an inorganic peroxide, and an activator for the inorganic peroxide as essential components. It is.
第３成分として用いられる無機過酸化物の活性化剤とし
ては、グルコースペンタアセテート、グルコーステトラ
アセテート、フラクトースペンタアセテート、シューク
ロースオクタアセテート、ソルビタンテトラアセテート
、ソルビトールヘキサアセテート、マンニットヘキサア
セテート、マンニタンテトラアセテート、キシリフトペ
ンタアセテート、キシリタントリアセテート、エリスリ
トールテトラアセテート等の多価アルコールの酢酸エス
テル類、テトラアセチルエチレンジアミン、テトラアセ
チルグリコルリルウリル等のＮ−アセチル化物が好まし
いが、無水フタール酸、無水コハク酸等の有機酸無水物
も使用することができる。Examples of the inorganic peroxide activator used as the third component include glucose pentaacetate, glucose tetraacetate, fructose pentaacetate, sucrose octaacetate, sorbitan tetraacetate, sorbitol hexaacetate, mannithexaacetate, and mannitanetetraacetate. Acetate esters of polyhydric alcohols such as acetate, xylift pentaacetate, xylitane triacetate, and erythritol tetraacetate, and N-acetylated products such as tetraacetylethylenediamine and tetraacetylglycolluril are preferred, but phthalic anhydride and succinic anhydride are preferred. Organic acid anhydrides such as the like can also be used.
本発明の畜舎用殺菌剤組成物は、上記三成分を任意の割
合に混合して使用できるが、貯蔵安定性、殺菌効果、経
済性等を考慮すると、陽イオン性界面活性剤１重量部に
対し、無機過酸化物０．１〜ｌＯ重量部、活性化剤０．
１〜１０重量部の範囲で使用することが好ましい。更に
、無機過酸化物と活性化剤の配合割合（重量比）は１０
０／１〜１／１００が好ましく、より好ましくは１０／
１〜１／１０である。The disinfectant composition for livestock barns of the present invention can be used by mixing the above three components in any proportion, but considering storage stability, bactericidal effect, economical efficiency, etc., 1 part by weight of the cationic surfactant should be used. On the other hand, 0.1 to 10 parts by weight of inorganic peroxide and 0.0 parts by weight of activator.
It is preferable to use it in a range of 1 to 10 parts by weight. Furthermore, the blending ratio (weight ratio) of inorganic peroxide and activator is 10
Preferably 0/1 to 1/100, more preferably 10/1
It is 1 to 1/10.
本発明の畜舎用殺菌剤組成物が“ふん”等の有機物の存
在下においても優れた殺菌効力を有するかの機作につい
ては必ずしも明確ではないが、無機過酸化物と無機過酸
化物の活性化剤から生じる有機過酸と陽イオン性界面活
性剤との共役効果により細菌などの細胞膜に不可逆的な
変性を起こさせることによると思われる。The mechanism by which the disinfectant composition for livestock barns of the present invention has excellent bactericidal efficacy even in the presence of organic matter such as "feces" is not necessarily clear, but the activity of inorganic peroxide and inorganic peroxide is This is thought to be due to irreversible denaturation of cell membranes of bacteria and the like due to the conjugate effect of the organic peracid generated from the cationic surfactant and the cationic surfactant.
次に実施例を挙げて本発明を説明するが、本発明はこれ
らの実施例に限定されるものではない。Next, the present invention will be explained with reference to Examples, but the present invention is not limited to these Examples.
実施例１
アルキル（炭素数１２）ジメチルベンジルアンモニウム
クロライドに過炭酸ナトリウム（ＰＣ）とグルコースペ
ンタアセテート（ＧＰＡ）の一定重量配合混合物を加え
、各種濃度の試験液を調製した。この検液に鶏糞５％を
分散させ、その後あらかじめ液体培地で培養した大腸菌
を５分間接触させ、その後集菌し新しい培地に植えつぎ
２４時間放置後大腸菌の生育状態を下記の基準で評価し
た。結果を表１に示す。Example 1 A constant weight mixture of sodium percarbonate (PC) and glucose pentaacetate (GPA) was added to alkyl (carbon number 12) dimethylbenzylammonium chloride to prepare test solutions of various concentrations. 5% chicken manure was dispersed in this test solution, and then E. coli cultured in a liquid medium was brought into contact for 5 minutes.The bacteria were then collected, planted in a new medium, and left for 24 hours.The growth state of E. coli was evaluated using the following criteria. The results are shown in Table 1.
評 価
表 １
実施例２
ジアルキル（炭素数１０）ジメチルアンモニウムクロラ
イドに過炭酸ナトリウム（ＰＣ）とテトラアセチルエチ
レンジアミン（ＴＡｔ！ＤＡ）の一定重量配合混合物を
加え、各種濃度の試験液を調製した。この検液に鶏糞５
％を分散させ、その後あらかじめ液体培地で培養した大
腸菌を５分間接触させ、その後集菌し新しい培地に植え
つぎ２４時間放放置後腸菌の生育状態を実施例１と同様
の基準で評価した。結果を表２に示す。−表 ２Evaluation Table 1 Example 2 A constant weight mixture of sodium percarbonate (PC) and tetraacetylethylenediamine (TAt!DA) was added to dialkyl (10 carbon atoms) dimethylammonium chloride to prepare test solutions of various concentrations. This test solution contains 5 chicken feces.
% was dispersed, and then E. coli cultured in a liquid medium in advance was brought into contact with the cells for 5 minutes.The bacteria were then collected, planted in a new medium, and left for 24 hours.The growth state of the coli bacteria was evaluated using the same criteria as in Example 1. The results are shown in Table 2. -Table 2
Claims (1)
として含有することを特徴とする畜舎用殺菌剤組成物。 ２ 陽イオン性界面活性剤、無機過酸化物及び無機過酸
化物の活性化剤を必須成分として含有することを特徴と
する畜舎用殺菌剤組成物。 ３ 無機過酸化物の活性化剤が多価アルコールの酢酸エ
ステルである特許請求の範囲第２項記載の畜舎用殺菌剤
組成物。[Scope of Claims] 1. A disinfectant composition for livestock housing, characterized by containing a cationic surfactant and an inorganic peroxide as essential components. 2. A disinfectant composition for livestock housing, which contains a cationic surfactant, an inorganic peroxide, and an activator for the inorganic peroxide as essential components. 3. The disinfectant composition for livestock barns according to claim 2, wherein the activator of the inorganic peroxide is an acetate ester of a polyhydric alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60293886A JPH0617289B2 (en) | 1985-12-27 | 1985-12-27 | Fungicide composition for storage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60293886A JPH0617289B2 (en) | 1985-12-27 | 1985-12-27 | Fungicide composition for storage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62155203A true JPS62155203A (en) | 1987-07-10 |
| JPH0617289B2 JPH0617289B2 (en) | 1994-03-09 |
Family
ID=17800423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60293886A Expired - Lifetime JPH0617289B2 (en) | 1985-12-27 | 1985-12-27 | Fungicide composition for storage |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0617289B2 (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2685202A1 (en) * | 1991-12-24 | 1993-06-25 | Sederma Sa | Novel method of pharmaceutical and cosmetic treatment for the regulation of seborrhoea, acne and the cutaneous flora |
| WO1994024869A1 (en) * | 1993-04-28 | 1994-11-10 | Kao Corporation | Germicidal composition |
| WO2003028429A2 (en) | 2001-10-01 | 2003-04-10 | Sandia Corporation | Enhanced formulations for neutralization of chemical, biological and industrial toxants |
| US6723890B2 (en) | 1998-06-30 | 2004-04-20 | Sandia Corporation | Concentrated formulations and methods for neutralizing chemical and biological toxants |
| WO2004089089A1 (en) | 2003-04-02 | 2004-10-21 | Kao Corporation | Composition for bactericide production and process for producing organic peracid |
| US7282470B2 (en) | 2002-07-19 | 2007-10-16 | Sandia Corporation | Decontamination formulation with sorbent additive |
| US7390432B2 (en) | 1998-06-30 | 2008-06-24 | Sandia Corporation | Enhanced formulations for neutralization of chemical, biological and industrial toxants |
| US8846107B2 (en) | 2010-12-29 | 2014-09-30 | Ecolab Usa Inc. | In situ generation of peroxycarboxylic acids at alkaline pH, and methods of use thereof |
| US8858895B2 (en) | 2010-12-29 | 2014-10-14 | Ecolab Usa Inc. | Continuous on-line adjustable disinfectant/sanitizer/bleach generator |
| US8889900B2 (en) | 2010-12-29 | 2014-11-18 | Ecolab Usa Inc. | Sugar ester peracid on site generator and formulator |
| US9845290B2 (en) | 2014-12-18 | 2017-12-19 | Ecolab Usa Inc. | Methods for forming peroxyformic acid and uses thereof |
| US9902627B2 (en) | 2011-12-20 | 2018-02-27 | Ecolab Usa Inc. | Stable percarboxylic acid compositions and uses thereof |
| US9926214B2 (en) | 2012-03-30 | 2018-03-27 | Ecolab Usa Inc. | Use of peracetic acid/hydrogen peroxide and peroxide-reducing agents for treatment of drilling fluids, frac fluids, flowback water and disposal water |
| US10031081B2 (en) | 2013-03-05 | 2018-07-24 | Ecolab Usa Inc. | Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring |
| US10165774B2 (en) | 2013-03-05 | 2019-01-01 | Ecolab Usa Inc. | Defoamer useful in a peracid composition with anionic surfactants |
| US10433547B2 (en) | 2014-12-18 | 2019-10-08 | Ecolab Usa Inc. | Generation of peroxyformic acid through polyhydric alcohol formate |
| US10893674B2 (en) | 2013-03-05 | 2021-01-19 | Ecolab Usa Inc. | Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids |
| US11040902B2 (en) | 2014-12-18 | 2021-06-22 | Ecolab Usa Inc. | Use of percarboxylic acids for scale prevention in treatment systems |
| US11260040B2 (en) | 2018-06-15 | 2022-03-01 | Ecolab Usa Inc. | On site generated performic acid compositions for teat treatment |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59176252A (en) * | 1983-03-15 | 1984-10-05 | インテロックス・ケミカルズ・リミテッド | Peroxide compound and manufacture |
-
1985
- 1985-12-27 JP JP60293886A patent/JPH0617289B2/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59176252A (en) * | 1983-03-15 | 1984-10-05 | インテロックス・ケミカルズ・リミテッド | Peroxide compound and manufacture |
Cited By (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2685202A1 (en) * | 1991-12-24 | 1993-06-25 | Sederma Sa | Novel method of pharmaceutical and cosmetic treatment for the regulation of seborrhoea, acne and the cutaneous flora |
| WO1994024869A1 (en) * | 1993-04-28 | 1994-11-10 | Kao Corporation | Germicidal composition |
| US6723890B2 (en) | 1998-06-30 | 2004-04-20 | Sandia Corporation | Concentrated formulations and methods for neutralizing chemical and biological toxants |
| US7390432B2 (en) | 1998-06-30 | 2008-06-24 | Sandia Corporation | Enhanced formulations for neutralization of chemical, biological and industrial toxants |
| WO2003028429A2 (en) | 2001-10-01 | 2003-04-10 | Sandia Corporation | Enhanced formulations for neutralization of chemical, biological and industrial toxants |
| WO2003028429A3 (en) * | 2001-10-01 | 2003-12-18 | Sandia Corp | Enhanced formulations for neutralization of chemical, biological and industrial toxants |
| AU2002341750B2 (en) * | 2001-10-01 | 2007-10-11 | Sandia Corporation | Enhanced formulations for neutralization of chemical, biological and industrial toxants |
| US7282470B2 (en) | 2002-07-19 | 2007-10-16 | Sandia Corporation | Decontamination formulation with sorbent additive |
| WO2004089089A1 (en) | 2003-04-02 | 2004-10-21 | Kao Corporation | Composition for bactericide production and process for producing organic peracid |
| EP1618786A4 (en) * | 2003-04-02 | 2006-05-24 | Kao Corp | Composition for bactericide production and process for producing organic peracid |
| US8933263B2 (en) | 2010-12-29 | 2015-01-13 | Ecolab Usa Inc. | Water temperature as a means of controlling kinetics of onsite generated peracids |
| US11678664B2 (en) | 2010-12-29 | 2023-06-20 | Ecolab Usa Inc. | Water temperature as a means of controlling kinetics of onsite generated peracids |
| US8877254B2 (en) | 2010-12-29 | 2014-11-04 | Ecolab Usa Inc. | In situ generation of peroxycarboxylic acids at alkaline pH, and methods of use thereof |
| US8889900B2 (en) | 2010-12-29 | 2014-11-18 | Ecolab Usa Inc. | Sugar ester peracid on site generator and formulator |
| US10201156B2 (en) | 2010-12-29 | 2019-02-12 | Ecolab Usa Inc. | Continuous on-line adjustable disinfectant/sanitizer/bleach generator |
| US9192909B2 (en) | 2010-12-29 | 2015-11-24 | Ecolab USA, Inc. | Sugar ester peracid on site generator and formulator |
| US9365509B2 (en) | 2010-12-29 | 2016-06-14 | Ecolab Usa Inc. | Continuous on-line adjustable disinfectant/sanitizer/bleach generator |
| US9505715B2 (en) | 2010-12-29 | 2016-11-29 | Ecolab Usa Inc. | Sugar ester peracid on site generator and formulator |
| US9763442B2 (en) | 2010-12-29 | 2017-09-19 | Ecolab Usa Inc. | In situ generation of peroxycarboxylic acids at alkaline pH, and methods of use thereof |
| US8858895B2 (en) | 2010-12-29 | 2014-10-14 | Ecolab Usa Inc. | Continuous on-line adjustable disinfectant/sanitizer/bleach generator |
| US9861101B2 (en) | 2010-12-29 | 2018-01-09 | Ecolab Usa Inc. | Continuous on-line adjustable disinfectant/sanitizer/bleach generator |
| US9883672B2 (en) | 2010-12-29 | 2018-02-06 | Ecolab Usa Inc. | Sugar ester peracid on site generator and formulator |
| US10244751B2 (en) | 2010-12-29 | 2019-04-02 | Ecolab Usa Inc. | Water temperature as a means of controlling kinetics of onsite generated peracids |
| US11330818B2 (en) | 2010-12-29 | 2022-05-17 | Ecolab Usa Inc. | Water temperature as a means of controlling kinetics of onsite generated peracids |
| US10010075B2 (en) | 2010-12-29 | 2018-07-03 | Ecolab Usa Inc. | Water temperature as a means of controlling kinetics of onsite generated peracids |
| US11311011B2 (en) | 2010-12-29 | 2022-04-26 | Ecolab Usa Inc. | Continuous on-line adjustable disinfectant/sanitizer/bleach generator |
| US8846107B2 (en) | 2010-12-29 | 2014-09-30 | Ecolab Usa Inc. | In situ generation of peroxycarboxylic acids at alkaline pH, and methods of use thereof |
| US10477862B2 (en) | 2010-12-29 | 2019-11-19 | Ecolab Usa Inc. | In situ generation of peroxycarboxylic acids at alkaline pH, and methods of use thereof |
| US9902627B2 (en) | 2011-12-20 | 2018-02-27 | Ecolab Usa Inc. | Stable percarboxylic acid compositions and uses thereof |
| US10023484B2 (en) | 2012-03-30 | 2018-07-17 | Ecolab Usa Inc. | Use of peracetic acid/hydrogen peroxide and peroxide-reducing agents for treatment of drilling fluids, frac fluids, flowback water and disposal water |
| US9926214B2 (en) | 2012-03-30 | 2018-03-27 | Ecolab Usa Inc. | Use of peracetic acid/hydrogen peroxide and peroxide-reducing agents for treatment of drilling fluids, frac fluids, flowback water and disposal water |
| US10017403B2 (en) | 2012-03-30 | 2018-07-10 | Ecolab Usa Inc. | Use of peracetic acid/hydrogen peroxide and peroxide-reducing enzymes for treatment of drilling fluids, frac fluids, flowback water and disposal water |
| US11939241B2 (en) | 2012-10-05 | 2024-03-26 | Ecolab Usa Inc. | Stable percarboxylic acid compositions and uses thereof |
| US11180385B2 (en) | 2012-10-05 | 2021-11-23 | Ecolab USA, Inc. | Stable percarboxylic acid compositions and uses thereof |
| US11026421B2 (en) | 2013-03-05 | 2021-06-08 | Ecolab Usa Inc. | Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids |
| US10165774B2 (en) | 2013-03-05 | 2019-01-01 | Ecolab Usa Inc. | Defoamer useful in a peracid composition with anionic surfactants |
| US10031081B2 (en) | 2013-03-05 | 2018-07-24 | Ecolab Usa Inc. | Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring |
| US11206826B2 (en) | 2013-03-05 | 2021-12-28 | Ecolab Usa Inc. | Defoamer useful in a peracid composition with anionic surfactants |
| US10893674B2 (en) | 2013-03-05 | 2021-01-19 | Ecolab Usa Inc. | Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids |
| US11040902B2 (en) | 2014-12-18 | 2021-06-22 | Ecolab Usa Inc. | Use of percarboxylic acids for scale prevention in treatment systems |
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Also Published As
| Publication number | Publication date |
|---|---|
| JPH0617289B2 (en) | 1994-03-09 |
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