JPH0617289B2 - Fungicide composition for storage - Google Patents
Fungicide composition for storageInfo
- Publication number
- JPH0617289B2 JPH0617289B2 JP60293886A JP29388685A JPH0617289B2 JP H0617289 B2 JPH0617289 B2 JP H0617289B2 JP 60293886 A JP60293886 A JP 60293886A JP 29388685 A JP29388685 A JP 29388685A JP H0617289 B2 JPH0617289 B2 JP H0617289B2
- Authority
- JP
- Japan
- Prior art keywords
- inorganic peroxide
- activator
- present
- composition
- livestock
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は畜舎用殺菌剤組成物に関し、更に詳しくは畜舎
における“ふん”等の有機物の存在下においても優れた
殺菌効力を有する畜舎用殺菌剤組成物に関する。TECHNICAL FIELD The present invention relates to a bactericidal composition for livestock houses, and more particularly to a bactericidal composition for livestock houses which has an excellent bactericidal effect even in the presence of an organic substance such as “feces” in a livestock house. Agent composition.
〔従来技術およびその問題点〕 殺菌活性を有する陽イオン性界面活性剤、例えばアルキ
ルジメチルベンジルアンモニウム塩、置換ベンザルコニ
ウム塩、ベンゼトニウム塩、ジアルキルジメチルアンモ
ニウム塩等は牛、馬、鶏などの畜舎に使用した場合、多
量の“ふん”が付着しているため、殺菌力が著しく低下
するという欠点があった。[Prior art and its problems] Cationic surfactants having bactericidal activity, such as alkyldimethylbenzylammonium salts, substituted benzalkonium salts, benzethonium salts, dialkyldimethylammonium salts, etc., for cattle, horses, chickens, etc. When used, there was a drawback that the sterilizing power was remarkably reduced because a large amount of "dung" adhered.
そこで本発明者らは、このような欠点を解消し“ふん”
等由来の有機物存在下においても優れた殺菌効力を有す
る畜舎用殺菌剤組成物を得ずべく鋭意研究を行った結
果、陽イオン性界面活性剤と無機過酸化物及び無機過酸
化物の活性化剤を併用することにより、有機物存在下に
おいても優れた殺菌力を発揮することを見出し本発明を
完成した。Therefore, the inventors of the present invention have eliminated such drawbacks, and
As a result of earnestly conducting research to obtain a bactericidal composition for livestock that has excellent bactericidal effect even in the presence of organic substances derived from the like, the cationic surfactant and the inorganic peroxide and the activation of the inorganic peroxide The present invention has been completed by finding that the combined use of the agents exhibits excellent bactericidal activity even in the presence of organic substances.
即ち、本発明は陽イオン性界面活性剤、無機過酸化物及
び無機過酸化物の活性化剤を必須成分として含有し、無
機過酸化物と無機過酸化物の活性化剤の配合割合（重量
比）が10／１〜１／10であることを特徴とする畜舎用殺
菌剤組成物を提供するものである。That is, the present invention contains a cationic surfactant, an inorganic peroxide and an activator of an inorganic peroxide as essential components, and the compounding ratio of the inorganic peroxide and the activator of the inorganic peroxide (weight: The present invention provides a bactericide composition for livestock houses, characterized in that the ratio is 10/1 to 1/10.
本発明に用いられる陽イオン性界面活性剤としては殺菌
活性を有するものであれば特に限定されず、例えばアル
キルジメチルベンジルアンモニウム塩、置換ベンザルコ
ニウム塩、ベンゼトニウム塩、ジアルキルジメチルアン
モニウム塩などのモノカチオン化合物のほか、Ｎ−アル
キル−N,N,N′，Ｎ′，Ｎ′−ペンタメチル−プロピレ
ンアンモニウム塩などのポリカチオン化合物が挙げられ
る。The cationic surfactant used in the present invention is not particularly limited as long as it has bactericidal activity, and examples thereof include monocations such as alkyldimethylbenzylammonium salt, substituted benzalkonium salt, benzethonium salt and dialkyldimethylammonium salt. In addition to compounds, polycationic compounds such as N-alkyl-N, N, N ', N', N'-pentamethyl-propylene ammonium salts can be mentioned.
無機過酸化物としては、過炭酸ナトリウム、過硼酸ナト
リウム、過酸化トリポリリン酸ナトリウム、過酸化ピロ
リン酸ナトリウム、過酸化ケイ酸ナトリウム等が挙げら
れる。Examples of the inorganic peroxide include sodium percarbonate, sodium perborate, sodium peroxytripolyphosphate, sodium peroxypyrophosphate, sodium peroxysilicate and the like.
本発明の殺菌剤組成物は、上記２成分を任意の割合に混
合して使用できるが、殺菌効果、経済性等を考慮する
と、陽イオン性界面活性剤１重量部に対し無機過酸化物
0.1〜100重量部の範囲で使用することが好ましい。The disinfectant composition of the present invention can be used by mixing the above-mentioned two components in an arbitrary ratio. However, considering the disinfection effect, economy, etc., the inorganic peroxide is added to 1 part by weight of the cationic surfactant.
It is preferably used in the range of 0.1 to 100 parts by weight.
上記の範囲を外れると本発明の顕著な効果である有機物
存在下での優れた殺菌力が得られない。より好ましく
は、陽イオン性界面活性剤１重量部に対し無機過酸化物
0.3〜50重量部である。When the amount is out of the above range, the excellent bactericidal activity in the presence of an organic substance, which is the remarkable effect of the present invention, cannot be obtained. More preferably, the inorganic peroxide is added to 1 part by weight of the cationic surfactant.
0.3 to 50 parts by weight.
本発明の殺菌剤組成物は通常粉体、顆粒、錠剤等の固形
物として製剤され、使用に当たり、水に希釈し施用され
る。その時の濃度は対象物によっても異なるが、通常10
〜1000ppmである。The bactericidal composition of the present invention is usually formulated as a solid substance such as powder, granules and tablets, and is diluted with water before use. The concentration at that time varies depending on the object, but is usually 10
~ 1000ppm.
勿論、陽イオン性界面活性剤と無機過酸化物をそれぞれ
製剤し、使用に当たり、両者を水に希釈して施用するこ
とも本発明に含まれるものである。Needless to say, it is also included in the present invention that the cationic surfactant and the inorganic peroxide are each formulated, and both are diluted with water before use.
本発明では、上記２成分に加え、更に無機過酸化物の活
性化剤を必須成分として併用することにより優れた効果
を発現するものである。In the present invention, an excellent effect is exhibited by using an activator of an inorganic peroxide as an essential component in addition to the above two components.
第３成分として用いられる無機過酸化物の活性化剤とし
ては、グルコースペンタアセテート、グルコーステトラ
アセテート、フラクトースペンタアセテート、シューク
ロースオクタアセテート、ソルビタンテトラアセテー
ト、ソルビトールヘキサアセテート、マンニットヘキサ
アセテート、マンニタンテトラアセテート、キシリット
ペンタアセテート、キシリタントリアセテート、エリス
リトールテトラアセテート等の多価アルコールの酢酸エ
ステル類、テトラアセチルエチレンジアミン、テトラア
セチルグリコルリルウリル等のＮ−アセチル化物が好ま
しいが、無水フタール酸、無水コハク酸等の有機酸無水
物も使用することができる。Examples of the inorganic peroxide activator used as the third component include glucose pentaacetate, glucose tetraacetate, fructose pentaacetate, sucrose octaacetate, sorbitan tetraacetate, sorbitol hexaacetate, mannitol hexaacetate, and mannitan tetraacetate. Acetates of polyhydric alcohols such as acetate, xylit pentaacetate, xylitane triacetate, and erythritol tetraacetate, and N-acetylated products such as tetraacetylethylenediamine and tetraacetylglycoluriluril are preferable, but phthalic anhydride and succinic anhydride are preferable. Organic acid anhydrides such as can also be used.
本発明の畜舎用殺菌剤組成物は、上記三成分を任意の割
合に混合して使用できるが、貯蔵安定性、殺菌効果、経
済性等を考慮すると、陽イオン性界面活性剤１重量部に
対し、無機過酸化物0.1〜10重量部、活性化剤0.1〜10重
量部の範囲で使用することが好ましい。更に、無機過酸
化物と活性化剤の配合割合（重量比）は10／１〜１／10
であることが必要であり、好ましくは７／３〜３／７で
ある。The sterilizing composition for livestock sheds of the present invention can be used by mixing the above three components in arbitrary ratios, but in consideration of storage stability, sterilizing effect, economy, etc., 1 part by weight of the cationic surfactant is added. On the other hand, it is preferable to use 0.1 to 10 parts by weight of the inorganic peroxide and 0.1 to 10 parts by weight of the activator. Furthermore, the mixing ratio (weight ratio) of the inorganic peroxide and the activator is 10/1 to 1/10.
It is necessary to be, and it is preferably 7/3 to 3/7.
本発明の畜舎用殺菌剤組成物が“ふん”等の有機物の存
在下においても優れた殺菌効力を有するかの機作につい
ては必ずしも明確ではないが、無機過酸化物と無機過酸
化物の活性化剤から生じる有機過酸と陽イオン性界面活
性剤との共役効果により細菌などの細胞膜に不可逆的な
変性を起こさせることによると思われる。The mechanism of whether the disinfectant composition for livestock shed of the present invention has excellent sterilizing effect even in the presence of organic matter such as "feces" is not necessarily clear, but the activity of inorganic peroxide and inorganic peroxide It is thought that this is due to the irreversible denaturation of the cell membrane of bacteria due to the coupling effect of the organic peracid generated from the agent and the cationic surfactant.
次に実施例を挙げて本発明を説明するが、本発明はこれ
らの実施例に限定されるものではない。Next, the present invention will be described with reference to examples, but the present invention is not limited to these examples.
実施例１ アルキル（炭素数12！ジメチルベンジルアンモニウムク
ロライドに過炭酸ナトリウム（PC）とグルコースペンタ
アセテート（GPA）の一定重量配合混合物を加え、各種
濃度の試験液を調製した。この検液に鶏糞５％を分散さ
せ、その後あらかじめ液体培地で培養した大腸菌を５分
間接触させ、その後集菌し新しい培地に植えつぎ24時間
放置後大腸菌の生育状態を下記の基準で評価した。結果
を表１に示す。Example 1 Alkyl (C12! Dimethylbenzylammonium chloride) was mixed with a fixed weight mixture of sodium percarbonate (PC) and glucose pentaacetate (GPA) to prepare test solutions of various concentrations. %, Followed by contacting Escherichia coli cultivated in a liquid medium in advance for 5 minutes, collecting the cells, planting them in a new medium, and leaving them for 24 hours, and then evaluating the growth state of Escherichia coli according to the following criteria. .
評 価 実施例２ ジアルキル（炭素数10）ジメチルアンモニウムクロライ
ドに過炭酸ナトリウム（PC）とテトラアセチルエチレン
ジアミン（TAEDA）の一定重量配合混合物を加え、各種
濃度の試験液を調製した。この検液に鶏糞５％を分散さ
せ、その後あらかじめ液体培地で培養した大腸菌を５分
間接触させ、その後集菌し新しい培地に植えつぎ24時間
放置後大腸菌の生育状態を実施例１と同様の基準で評価
した。結果を表２に示す。Rating Example 2 Dialkyl (10 carbon atoms) dimethylammonium chloride was mixed with a fixed weight mixture of sodium percarbonate (PC) and tetraacetylethylenediamine (TAEDA) to prepare test solutions of various concentrations. 5% of chicken feces was dispersed in this test solution, and then Escherichia coli cultivated in a liquid medium was contacted for 5 minutes, then the cells were collected, planted in a new medium, and allowed to stand for 24 hours. It was evaluated by. The results are shown in Table 2.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 岩崎 徹治 和歌山県和歌山市雑賀崎1247 (72)発明者 日置 祐一 和歌山県和歌山市西浜1450 (56)参考文献 特開 昭59−176252（ＪＰ，Ａ) ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Tetsuji Iwasaki 1247 Saikazaki, Wakayama City, Wakayama Prefecture (72) Inventor Yuichi Hioki 1450 Nishihama, Wakayama City, Wakayama Prefecture (56) Reference JP-A-59-176252 (JP, A)
Claims (2)
無機過酸化物及び無機過酸化物の活性化剤を必須成分と
して含有し、無機過酸化物と無機過酸化物の活性化剤の
配合割合（重量比）が10／１〜１／10であることを特徴
とする畜舎用殺菌剤組成物。1. A cationic surfactant having bactericidal activity,
Contains an inorganic peroxide and an activator of an inorganic peroxide as essential components, and the compounding ratio (weight ratio) of the inorganic peroxide and the activator of an inorganic peroxide is 10/1 to 1/10 A bactericide composition for livestock houses, which is characterized in that:
の酢酸エステルである特許請求の範囲第１項記載の畜舎
用殺菌剤組成物。2. The disinfectant composition for livestock shelter according to claim 1, wherein the activator of the inorganic peroxide is an acetic acid ester of a polyhydric alcohol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60293886A JPH0617289B2 (en) | 1985-12-27 | 1985-12-27 | Fungicide composition for storage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60293886A JPH0617289B2 (en) | 1985-12-27 | 1985-12-27 | Fungicide composition for storage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62155203A JPS62155203A (en) | 1987-07-10 |
| JPH0617289B2 true JPH0617289B2 (en) | 1994-03-09 |
Family
ID=17800423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60293886A Expired - Lifetime JPH0617289B2 (en) | 1985-12-27 | 1985-12-27 | Fungicide composition for storage |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0617289B2 (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2685202B1 (en) * | 1991-12-24 | 1995-03-24 | Sederma Sa | NOVEL PHARMACEUTICAL AND COSMETIC TREATMENT METHOD FOR THE REGULATION OF SEBORRHEA, ACNE AND SKIN FLORA. |
| JP3281445B2 (en) * | 1993-04-28 | 2002-05-13 | 花王株式会社 | Fungicide composition |
| US7282470B2 (en) | 2002-07-19 | 2007-10-16 | Sandia Corporation | Decontamination formulation with sorbent additive |
| US7390432B2 (en) | 1998-06-30 | 2008-06-24 | Sandia Corporation | Enhanced formulations for neutralization of chemical, biological and industrial toxants |
| US6723890B2 (en) | 1998-06-30 | 2004-04-20 | Sandia Corporation | Concentrated formulations and methods for neutralizing chemical and biological toxants |
| WO2003028429A2 (en) * | 2001-10-01 | 2003-04-10 | Sandia Corporation | Enhanced formulations for neutralization of chemical, biological and industrial toxants |
| US7919122B2 (en) * | 2003-04-02 | 2011-04-05 | Kao Corporation | Composition for production of a sterilizer and a process for producing organic peracid |
| US8846107B2 (en) | 2010-12-29 | 2014-09-30 | Ecolab Usa Inc. | In situ generation of peroxycarboxylic acids at alkaline pH, and methods of use thereof |
| US8889900B2 (en) | 2010-12-29 | 2014-11-18 | Ecolab Usa Inc. | Sugar ester peracid on site generator and formulator |
| US8729296B2 (en) | 2010-12-29 | 2014-05-20 | Ecolab Usa Inc. | Generation of peroxycarboxylic acids at alkaline pH, and their use as textile bleaching and antimicrobial agents |
| US9321664B2 (en) | 2011-12-20 | 2016-04-26 | Ecolab Usa Inc. | Stable percarboxylic acid compositions and uses thereof |
| MX360142B (en) | 2012-03-30 | 2018-10-24 | Ecolab Usa Inc | Use of peracetic acid/hydrogen peroxide and peroxide-reducing agents for treatment of drilling fluids, frac fluids, flowback water and disposal water. |
| US20140256811A1 (en) | 2013-03-05 | 2014-09-11 | Ecolab Usa Inc. | Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids |
| US8822719B1 (en) | 2013-03-05 | 2014-09-02 | Ecolab Usa Inc. | Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring |
| US10165774B2 (en) | 2013-03-05 | 2019-01-01 | Ecolab Usa Inc. | Defoamer useful in a peracid composition with anionic surfactants |
| US11040902B2 (en) | 2014-12-18 | 2021-06-22 | Ecolab Usa Inc. | Use of percarboxylic acids for scale prevention in treatment systems |
| CN117142998A (en) | 2014-12-18 | 2023-12-01 | 艺康美国股份有限公司 | Production of peroxyformic acid by polyol formates |
| WO2016100700A1 (en) | 2014-12-18 | 2016-06-23 | Ecolab Usa Inc. | Methods for forming peroxyformic acid and uses thereof |
| CA3103876C (en) | 2018-06-15 | 2024-02-27 | Ecolab Usa Inc. | On site generated performic acid compositions for teat treatment |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8307037D0 (en) * | 1983-03-15 | 1983-04-20 | Interox Chemicals Ltd | Peroxygen compounds |
-
1985
- 1985-12-27 JP JP60293886A patent/JPH0617289B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62155203A (en) | 1987-07-10 |
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Legal Events
| Date | Code | Title | Description |
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| R250 | Receipt of annual fees |
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