JPS6213611B2 - - Google Patents

Info

Publication number
JPS6213611B2
JPS6213611B2 JP55116572A JP11657280A JPS6213611B2 JP S6213611 B2 JPS6213611 B2 JP S6213611B2 JP 55116572 A JP55116572 A JP 55116572A JP 11657280 A JP11657280 A JP 11657280A JP S6213611 B2 JPS6213611 B2 JP S6213611B2
Authority
JP
Japan
Prior art keywords
dye
laser beam
beam shape
confirmation tool
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP55116572A
Other languages
Japanese (ja)
Other versions
JPS5740618A (en
Inventor
Makoto Honda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dai Nippon Printing Co Ltd
Original Assignee
Dai Nippon Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai Nippon Printing Co Ltd filed Critical Dai Nippon Printing Co Ltd
Priority to JP11657280A priority Critical patent/JPS5740618A/en
Publication of JPS5740618A publication Critical patent/JPS5740618A/en
Publication of JPS6213611B2 publication Critical patent/JPS6213611B2/ja
Granted legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J1/00Photometry, e.g. photographic exposure meter
    • G01J1/48Photometry, e.g. photographic exposure meter using chemical effects

Description

【発明の詳細な説明】 本発明は、レーザー光線の利用に際して、その
ビーム形状を確認するための手段に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to means for confirming the shape of a laser beam when using it.

近年、レーザー光線の利用が、材料の物性の研
究や精密加工、さらには外科手術など種々の分野
で、盛んに試みられている。いずれの場合も、レ
ーザービームの形状を精密にコントロールしなけ
ればならず、その前提として、ビーム形状を正確
に知ることが必要である。
In recent years, the use of laser beams has been actively attempted in various fields such as research on the physical properties of materials, precision processing, and even surgery. In either case, the shape of the laser beam must be precisely controlled, and as a precondition for this, it is necessary to accurately know the beam shape.

この目的で従来とられてきた手段は、プラスチ
ツク材料の小片にレーザー光を照射して、そこに
生じる焼け痕ないしくぼみの輪郭でビーム形状を
知るというものである。この焼け痕は、プラスチ
ツクの溶融や熱分解によるものなので、溶融が照
射を受けた領域に隣接する部分に及んで輪郭が崩
れたりして、十分正確にビーム形状を反映すると
は限らないという欠点がある。プラスチツクの熱
分解に伴う臭気や煙の発生も不快であるし、レー
ザー光の波長に適合するプラスチツク材料を選定
使用しなければならないといつたわずらわしさも
ある。
The conventional method for this purpose is to irradiate a small piece of plastic material with laser light and determine the shape of the beam by looking at the outline of the burn marks or depressions that occur there. These burn marks are caused by melting or thermal decomposition of the plastic, so they have the disadvantage that they do not necessarily reflect the beam shape accurately enough, as the melting extends to areas adjacent to the irradiated area, causing the contour to collapse. be. The odor and smoke generated by the thermal decomposition of plastics are unpleasant, and it is also troublesome to select and use plastic materials that are compatible with the wavelength of the laser beam.

本発明の目的は、上記の問題を一挙に解決し、
照射されたレーザービームの形状を正確に示すこ
とができ、臭気や煙の発生がなく、かつどのよう
なレーザー光波長をもカバーできるレーザービー
ム形状確認用具を提供することにある。
The purpose of the present invention is to solve the above problems at once,
To provide a laser beam shape confirmation tool that can accurately indicate the shape of an irradiated laser beam, does not generate odor or smoke, and can cover any wavelength of laser light.

この目的を達成するため本発明で採用したの
は、染料と無機質物との組み合わせである。すな
わち、本発明のレーザービーム形状確認用具は、
レーザー光の照射により分解脱色する染料を無機
質物担体に担持させた基本的構成を有する。そし
て、この構成から直ちに理解されるように、レー
ザー光による染料の分解―脱色を利用してビーム
形状を知るものである。
To achieve this objective, the present invention employs a combination of a dye and an inorganic substance. That is, the laser beam shape confirmation tool of the present invention is
It has a basic structure in which an inorganic material carrier carries a dye that decomposes and decolorizes when irradiated with laser light. As is immediately understood from this configuration, the beam shape is determined by utilizing the decomposition and decolorization of dye by laser light.

担体とする無機質物は、レーザー光線の照射に
よる熱の発生に耐えて形状を維持できるものであ
る限り、その種類に制限はない。ただし、担体と
しての役割をはたすためには、多孔質に形成すべ
きであり、吸着やイオン交換により染料を保持で
きることが望ましい。例をあげれば、アルミナ、
シリカ、ケイ酸カルシウム、リン酸ジルコニウ
ム、またはゼオライト、モンモリロナイト等の粘
土類であり、1種に限らず2種以上併用できる。
The type of inorganic material used as a carrier is not limited as long as it can withstand the generation of heat due to laser beam irradiation and maintain its shape. However, in order to fulfill the role of a carrier, it should be formed porous, and it is desirable that the dye can be retained by adsorption or ion exchange. For example, alumina,
These are clays such as silica, calcium silicate, zirconium phosphate, zeolite, and montmorillonite, and not only one type but two or more types can be used in combination.

染料は、酸性染料、塩基性染料、反応性染料、
分散染料など多種類のものが使用でき、レーザー
光の照射を受けて速やかに分解―脱色するものが
好ましい。多くの染料は広いスペクトル範囲のレ
ーザー光線で分解され脱色するが、特定の波長領
域の光線にとくに感じやすいものもあるから、そ
れらを2種以上組み合わせることにより、ある程
度まで波長領域の確認まで行なえる。
Dyes include acid dyes, basic dyes, reactive dyes,
Many types of dyes, such as disperse dyes, can be used, and those that quickly decompose and decolorize when irradiated with laser light are preferred. Many dyes are decomposed and decolorized by laser light over a wide spectral range, but some dyes are particularly sensitive to light in a specific wavelength range, so by combining two or more of them, it is possible to confirm wavelength ranges to a certain extent.

担体の形状にも制約はなく、用途に応じて、シ
ート状、ペレツトないしタブレツト状、短冊状な
ど任意にえらぶことができる。
There are no restrictions on the shape of the carrier, and it can be arbitrarily selected depending on the purpose, such as a sheet, pellet or tablet, or strip.

染料の担持の手法にもバラエテイがあり、粉末
状の担体物質に、たとえば水溶液からの吸着また
はイオン交換により染料を担持させてから、この
粉末を所望の形状に成形してもよいし、あらかじ
め担体物質で成形体を用意しておいてから、これ
に染料を吸着またはイオン交換により担持させて
もよい。成形体の製造は、プレス法、焼結法また
は両者の併用によることができるし、必要ならば
適宜のバインダーを利用することもできる。
There are various methods for supporting dyes; it is possible to support dyes on a powdered carrier material, for example by adsorption from an aqueous solution or by ion exchange, and then mold this powder into a desired shape. A molded body may be prepared from the material and then the dye may be supported thereon by adsorption or ion exchange. The molded body can be produced by a pressing method, a sintering method, or a combination of both, and if necessary, an appropriate binder can be used.

あるいはまた、染料の粉末と担体物質の粉末と
を機械的に混合してプレスしたり、湿式で混合し
てスラリーを抄造したりする手法もとれる。担持
とは、担体成形体中に染料が保持されている限
り、上記のような単なる混合状態にある場合をも
包含する。
Alternatively, a method may be used in which the dye powder and the carrier material powder are mechanically mixed and pressed, or wet-mixed to form a slurry. Supporting includes the case where the dye is in a mere mixed state as described above, as long as the dye is retained in the carrier molded body.

担持させる染料の量、換言すれば担体物質中に
おける濃度には、別段の制限はない。吸着やイオ
ン交換による場合は、その容量によつて上限が決
定されるが、実用上はそれより少なくて足りる。
担体物質と接触させる染料溶液の濃度および量に
よつて担持量がコントロールできるから、多少の
実験によつて、それぞれの用途に応じた最適濃度
を見出すとよい。
There are no particular limitations on the amount of dye supported, or in other words the concentration in the carrier material. In the case of adsorption or ion exchange, the upper limit is determined by the capacity, but in practice, less is sufficient.
Since the amount of dye supported can be controlled by the concentration and amount of the dye solution brought into contact with the carrier material, the optimum concentration for each application can be found through some experimentation.

本発明のレーザービーム形状確認用具の使用法
は、従来のものと異なるところはない。
The method of using the laser beam shape confirmation tool of the present invention is no different from conventional tools.

レーザー光線が当つた部分の染料は速やかに分
解され脱色するから、非照射部とは明瞭な境界で
区画されたコントラストの強い二つの領域に分け
られ、ビーム形状の確認が容易である。担体はレ
ーザーのエネルギーを受けて温度が上昇するが、
多孔質の無機質物は熱伝導率が低いから、照射部
の熱が伝わることによりその周辺の染料までが分
解される高い温度に至る心配はない。従つて、レ
ーザー光の照射で生じた輪郭が二次的な理由で崩
れることはなく、ビーム形状にきわめて忠実な脱
色領域が維持される。
The dye in the area hit by the laser beam quickly decomposes and decolorizes, so it is divided into two areas with strong contrast separated by a clear boundary from the non-irradiated area, making it easy to confirm the beam shape. The temperature of the carrier increases as it receives laser energy, but
Since porous inorganic materials have low thermal conductivity, there is no need to worry about the heat from the irradiated area reaching a high temperature that would decompose the dye in the surrounding area. Therefore, the contour created by laser beam irradiation does not collapse due to secondary reasons, and a bleached area that is extremely faithful to the beam shape is maintained.

分解する染料は、担体マトリクス中の濃度が低
いこともあつて、ごく少量であるから、分解生成
物による臭気や煙の発生は、実質上ゼロというこ
とができる。
Since the dye that decomposes is in a very small amount, partly because its concentration in the carrier matrix is low, the generation of odor and smoke due to decomposition products can be said to be virtually zero.

実施例 1 多孔質ケイ酸カルシウム粉末100gをカチオン
染料(日本化薬製「カヤクリルブルーGSL」)の
5%水溶液1000ml中に投入して吸着させ、過し
て液を除いてからエタノールで洗浄し、再び過
した。
Example 1 100 g of porous calcium silicate powder was adsorbed into 1000 ml of a 5% aqueous solution of cationic dye (Kayacryl Blue GSL manufactured by Nippon Kayaku), filtered to remove the liquid, and washed with ethanol. , passed again.

ほとんど湿り気を感じなくなるまで乾燥したと
ころで、10Kg/cm2の圧力でプレス成形し、直径40
mm、厚さ3mmのペレツトを製造した。このペレツ
トは、取扱いに十分耐える強度をもつていた。
After drying until almost no moisture is felt, it is press-formed at a pressure of 10 kg/cm 2 and has a diameter of 40 mm.
Pellets with a thickness of 3 mm and a thickness of 3 mm were produced. The pellets had sufficient strength to withstand handling.

これに、出力0.6Wのアルゴンレーザー光線を
10秒間照射したところ、照射部はほぼ完全に脱色
して白色に近くなり、非照射部は濃いブルーのま
まであつてコントラストは強く、ビーム形状が明
瞭に確認できた。
To this, an argon laser beam with an output of 0.6W is applied.
When irradiated for 10 seconds, the irradiated area was almost completely bleached and became nearly white, while the non-irradiated area remained deep blue with strong contrast and the beam shape could be clearly seen.

実施例 2 多孔質ガラス粉末に対して、例1と同様にして
同じカチオン染料を吸着させたものを用意し、そ
の1部(重量)にケイ酸カルシウム3部を混合し
て、同様にペレツト化した。
Example 2 A porous glass powder was prepared in which the same cationic dye was adsorbed in the same manner as in Example 1, and 1 part (by weight) of the same was mixed with 3 parts of calcium silicate and pelletized in the same manner. did.

このペレツトに対するアルゴンレーザー光線の
照射の結果も、例1と同様に満足すべきものであ
つた。
The results of irradiation of this pellet with argon laser beam were also satisfactory as in Example 1.

実施例 3 Na型モンモリロナイトを担体物質として用い
例1と同じカチオン染料を水溶液にしてイオン交
換することにより担持させた。
Example 3 Using Na-type montmorillonite as a carrier material, the same cationic dye as in Example 1 was made into an aqueous solution and supported by ion exchange.

このパルプを抄造して、厚さ0.1mmのシートを
得た。
This pulp was made into a sheet to obtain a sheet with a thickness of 0.1 mm.

0.6Wのアルゴンレーザー光線を60秒間照射し
て、そのピーム形状をシート上に明瞭に読みとる
ことができた。
By irradiating the sheet with a 0.6W argon laser beam for 60 seconds, the beam shape could be clearly read on the sheet.

Claims (1)

【特許請求の範囲】 1 レーザー光の照射により分解脱色する染料を
無機質物担体に担持させてなるレーザービーム形
状確認用具。 2 無機質物担体がアルミナ、シリカ、ケイ酸カ
ルシウム、リン酸ジルコニウムまたはゼオライ
ト、モンモリロナイト等の粘土類であり、染料が
酸性染料、塩基性染料、反応性染料、または分散
染料である特許請求の範囲第1項のレーザービー
ム形状確認用具。 3 無機質物担体がイオン交換性の物質であつて
染料がそれとイオン交換可能なイオン性染料であ
る特許請求の範囲第1項のレーザービーム形状確
認用具。 4 担体の形状が、シート状、ペレツト状、タブ
レツト状、または短冊状である特許請求の範囲第
1項のレーザービーム形状確認用具。 5 染料を吸着またはイオン交換により担持した
無機質物粉末を成形して得た特許請求の範囲第1
項のレーザービーム形状確認用具。 6 無機質物粉末の成形体に吸着またはイオン交
換により染料を担持させて得た特許請求の範囲第
1項のレーザービーム形状確認用具。
[Scope of Claims] 1. A laser beam shape confirmation tool comprising an inorganic material carrier supporting a dye that decomposes and decolorizes when irradiated with laser light. 2 The inorganic material carrier is clay such as alumina, silica, calcium silicate, zirconium phosphate, zeolite, montmorillonite, etc., and the dye is an acid dye, a basic dye, a reactive dye, or a disperse dye. Laser beam shape confirmation tool in Section 1. 3. The laser beam shape confirmation tool according to claim 1, wherein the inorganic substance carrier is an ion-exchangeable substance and the dye is an ionic dye with which ions can be exchanged. 4. The laser beam shape confirmation tool according to claim 1, wherein the carrier has a shape of a sheet, pellet, tablet, or strip. 5. Claim 1 obtained by molding an inorganic powder that supports a dye by adsorption or ion exchange.
Laser beam shape confirmation tool. 6. The laser beam shape confirmation tool according to claim 1, which is obtained by supporting a dye on a molded body of inorganic powder by adsorption or ion exchange.
JP11657280A 1980-08-25 1980-08-25 Laser beam configuration confirming device Granted JPS5740618A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11657280A JPS5740618A (en) 1980-08-25 1980-08-25 Laser beam configuration confirming device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11657280A JPS5740618A (en) 1980-08-25 1980-08-25 Laser beam configuration confirming device

Publications (2)

Publication Number Publication Date
JPS5740618A JPS5740618A (en) 1982-03-06
JPS6213611B2 true JPS6213611B2 (en) 1987-03-27

Family

ID=14690423

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11657280A Granted JPS5740618A (en) 1980-08-25 1980-08-25 Laser beam configuration confirming device

Country Status (1)

Country Link
JP (1) JPS5740618A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008014884A (en) * 2006-07-10 2008-01-24 Osaka Prefecture Univ Temperature history display material composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008014884A (en) * 2006-07-10 2008-01-24 Osaka Prefecture Univ Temperature history display material composition

Also Published As

Publication number Publication date
JPS5740618A (en) 1982-03-06

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