JPS6213379A - Ink jet recording method - Google Patents

Ink jet recording method

Info

Publication number
JPS6213379A
JPS6213379A JP15382485A JP15382485A JPS6213379A JP S6213379 A JPS6213379 A JP S6213379A JP 15382485 A JP15382485 A JP 15382485A JP 15382485 A JP15382485 A JP 15382485A JP S6213379 A JPS6213379 A JP S6213379A
Authority
JP
Japan
Prior art keywords
recording
ink
electrode
pulse width
resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15382485A
Other languages
Japanese (ja)
Inventor
Katsumi Suzuki
克己 鈴木
Sakae Tamura
栄 田村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP15382485A priority Critical patent/JPS6213379A/en
Publication of JPS6213379A publication Critical patent/JPS6213379A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0023Digital printing methods characterised by the inks used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/015Ink jet characterised by the jet generation process
    • B41J2/04Ink jet characterised by the jet generation process generating single droplets or particles on demand
    • B41J2/06Ink jet characterised by the jet generation process generating single droplets or particles on demand by electric or magnetic field
    • B41J2002/061Ejection by electric field of ink or of toner particles contained in ink

Landscapes

  • Duplication Or Marking (AREA)
  • Particle Formation And Scattering Control In Inkjet Printers (AREA)

Abstract

PURPOSE:To enable stable recording to be performed irrespective of resistance of a liquid ink, by a method wherein a pulse of voltage having negative polarity based on 0V as reference and a specified pulse width ratio is impressed on a counter electrode opposed to a recording electrode. CONSTITUTION:A pulse of voltage having negative polarity with based on 0V and a pulse width ratio of 2/5-3/5 is impressed on the counter electrode opposed to the recording electrode. The figure shows the pulse width of a pulse form DC potential impressed on a roller form back electrode 7 provided as the counter electrode. For example, where the resistance of the ink is as low as 10<6>-10<7>OMEGAcm, the ink 9 is selectively driven to fly when the pulse width ratio l/n is less than 3/5 (preferably, 1/20-1/2), and where the resistance of the ink is as high as 10<10>-10<11>OMEGAcm, the ink 9 is efficiently driven to fly when the pulse width ratio is more than 3/5 (preferably, 1/2-1). Namely, when the pulse width ratio l/n is 2/3-3/5 (optimally, 1/2), favorable ink jet recording through selective flying of the ink can be performed irrespective of the resistance of the ink.

Description

【発明の詳細な説明】 〔発明の技術分野〕 本発明はたとえば、!リンターあるいはファクシミリな
どに用いられる記録装置に関する。
[Detailed Description of the Invention] [Technical Field of the Invention] The present invention includes, for example! It relates to recording devices used in linters, facsimiles, etc.

〔発明の技術的背景とその問題点〕[Technical background of the invention and its problems]

この種の記録装置としては、従来より、現像、定着操作
の不要な普通紙記録方式としてインクジェット記録方式
のものが知られているが、高速記録性、簡易性を向上さ
せるため電子平面走査化が望まれている。
As for this type of recording device, the inkjet recording method is conventionally known as a plain paper recording method that does not require developing or fixing operations, but electronic flat scanning has been adopted to improve high-speed recording performance and simplicity. desired.

しかしながら、インクジェット記録方式の電子平面走査
化は主にマルチノズルにすることによって検討がなされ
ており、この場合、各記録ノズルのインク目ずまシによ
る信頼性の低下が問題となって実用化にいたっていない
のが現状である。
However, converting the inkjet recording system to electronic plane scanning has mainly been studied by using multiple nozzles, but in this case, the problem of reduced reliability due to ink smudges in each recording nozzle has prevented its practical use. The current situation is that this is not the case.

一方、ゼログラフィーに代表される電子写真方式では少
なくともドラム状の感光体と、その周囲部に配設された
帯電器、現像器、転写器、清浄器、除電器を必要とする
ため、小型化、低価格化に限界があるのが現状である。
On the other hand, electrophotographic methods such as xerography require at least a drum-shaped photoreceptor and a charger, developer, transfer device, purifier, and static eliminator arranged around it, making it more compact. Currently, there are limits to how low prices can be reduced.

そこで、上記ノズル方式の不都合点のない平面走査形の
インクジェット方式として、第2図乃至第5図に示すよ
うなスリットノエット方式のものが提案されている。す
なわち、図中1aは下側記録ヘッドAを構成する絶縁性
の基板で、この基板la上にはたとえば8本あるいは1
6本で・セターニングされた複数本の個別電極2a・・
・、2b・・・が設けられている。前記個別電極2a・
・・、2b・・・は所定のギヤラグd3を介して1対1
で対向し、そのギャッfd3間には例えばアモルファス
セレン(以後a−8e )または、アモルファスシリコ
ン(以後、a−8iと記す)などの光導電性膜3が着膜
されている。また、前記個別電極2b・・・には第1の
共通電極4が電気的に接続されている。
Therefore, as a planar scanning inkjet system that does not have the disadvantages of the nozzle system, a slit noette system as shown in FIGS. 2 to 5 has been proposed. That is, in the figure, 1a is an insulating substrate constituting the lower recording head A, and on this substrate la there are, for example, 8 or 1 recording head.
Multiple settered individual electrodes 2a with 6 pieces...
. , 2b . . . are provided. The individual electrode 2a.
..., 2b... are one-to-one via a predetermined gear lug d3.
A photoconductive film 3 of, for example, amorphous selenium (hereinafter referred to as a-8e) or amorphous silicon (hereinafter referred to as a-8i) is deposited between the gaps fd3. Further, a first common electrode 4 is electrically connected to the individual electrodes 2b.

また、上記構成の下側記録ヘッド部Aと微少間隔d2を
存して基板lb上に第2の共通電極5を有する上側記録
ヘッド部Bが設けられている。これら、下側および上側
記録ヘッド部A1Bからなる記録ヘッドHの先端にはス
リット状の開口部6が形成されていboまた、前記記録
ヘッドHと微少間隔d、を存してローラ状の対向電極7
が設けられ、前記記録ヘッドHと対向電極7との間には
普通紙等の被記録体8が介在される構成となっている。
Further, an upper recording head section B having a second common electrode 5 is provided on the substrate 1b with a slight distance d2 from the lower recording head section A having the above structure. A slit-shaped opening 6 is formed at the tip of the recording head H consisting of the lower and upper recording head portions A1B, and a roller-shaped counter electrode is formed at a slight distance d from the recording head H. 7
is provided, and a recording medium 8 such as plain paper is interposed between the recording head H and the counter electrode 7.

また、ノ0はインク収納容器で、このインク収納容器1
0からインク9が、上記記録ヘッドHの先端開口部6へ
供給されるようになっている。
Also, No. 0 is an ink storage container, and this ink storage container 1
Ink 9 is supplied from 0 to the tip opening 6 of the recording head H.

また、上記光導電性膜3の上方にはレンズアレイ11や
光源12および原稿台13が配設され、原稿台13が矢
印の方向へ移動するにつれて、原稿の光像がレンズアレ
イ11を通って光導電性膜3へ照射される構成になって
いる。
Further, above the photoconductive film 3, a lens array 11, a light source 12, and a document table 13 are arranged, and as the document table 13 moves in the direction of the arrow, the optical image of the document passes through the lens array 11. The photoconductive film 3 is irradiated with light.

次に、このスリットソエット方式の記録方式の記録原理
を説明する。
Next, the recording principle of this slit soet recording method will be explained.

原稿台13および被記録体8はスイッチONによシ同期
して動作し、光汀12が点灯し、原稿の光像はファイバ
ーレンズアレイ11を通して光導電体膜3上に照射され
る。
The original platen 13 and the recording medium 8 operate in synchronization with the switch ON, the light beam 12 lights up, and the optical image of the original is irradiated onto the photoconductor film 3 through the fiber lens array 11.

下側共通電極4には例えばeの直流電流が、又、上側共
通電極5には■の直流電圧が接続されていて、光が照射
された部分の記録電極2a・・・には記録ヘッドHの先
端にeの電位が、暗部に対しては■の電位が出力される
For example, a direct current (e) is connected to the lower common electrode 4, a direct current voltage (3) is connected to the upper common electrode 5, and the recording electrodes 2a, which are irradiated with light, are connected to the recording head H A potential e is output to the tip of the image, and a potential ■ is output to the dark area.

上記信号出力の原理は第4図に示す等価回路で説明され
る。すなわち、光導電体膜3の光照射時の抵抗をρ  
暗時の抵抗をρI)arい上側共ph ゝ 通電極5と記録電極2a・・・の間のインク9の抵抗ρ
1NKとすると、 ρph < p INy〈ρDark の関係がなりたつようにインク抵抗ρINKが調整され
ているため、光照射時にはρINKが支配的となシ、電
源15によシeの電位が記録電極2a・・・の先端に出
力され、暗時にはρ  が支配的とark なり、電源14によ勺■の電位が出力される。
The principle of the above signal output is explained using the equivalent circuit shown in FIG. That is, the resistance of the photoconductor film 3 when irradiated with light is ρ
The resistance in the dark is ρI) ar, both on the upper side ph The resistance ρ of the ink 9 between the communication electrode 5 and the recording electrode 2a...
1NK, the ink resistance ρINK is adjusted so that the relationship ρph <pINy<ρDark holds true, so ρINK is dominant during light irradiation, and the electric potential of the source e is applied to the recording electrodes 2a and 2a by the power supply 15. .

次にローラ状背面電極7には0Vに対してe側にパルス
状の電圧が印加され、前述した記録電極2a・・・先端
に■の電位が出力されたとき、インクメニカス9aに■
の電荷が注入されインク9が背面電極7側へ飛翔して被
記録体8上に原稿画像に対応して選択的な記録が出来る
原理となっている。
Next, a pulsed voltage is applied to the e side of 0 V to the roller-shaped back electrode 7, and when a potential of ■ is output to the tip of the recording electrode 2a, the ink menicus 9a is
This is the principle in which the ink 9 is injected and flies toward the back electrode 7, and selective recording can be performed on the recording medium 8 in accordance with the original image.

本発明者らの検討の結果、下記に示すゾロ七ヌ設定条件
であれば充分良好なインク飛翔による記録が可能である
ことが判明している。すなわち、 下側共通電極4の印加電圧 e50 V−el kV上
側共通電極5の印加電圧 O〜■1 kVローラ状状面
面電極7印加電圧 0−02.OkV周  波  数 
         10〜10kHzギヤ、 7’  
dt loam〜500μm、d、 10μm〜300
1Jrnギャッfd3の値は光導電体膜3の比抵抗によ
っても異なるが例えば光導電体膜3がa−5t膜である
場合は20 μm 〜80 μmXa−8s 、 a−
3eTeである場合は5μm〜50μ情である。
As a result of studies by the present inventors, it has been found that sufficiently good recording by ink flying is possible under the following setting conditions. That is, the voltage applied to the lower common electrode 4 e50 V-el kV The voltage applied to the upper common electrode 5 O~■1 kV The voltage applied to the roller-shaped surface electrode 7 0-02. OkV frequency
10~10kHz gear, 7'
dt loam~500μm, d, 10μm~300
The value of 1Jrn gap fd3 varies depending on the specific resistance of the photoconductor film 3, but for example, when the photoconductor film 3 is an a-5t film, the value is 20 μm to 80 μmXa-8s, a-
In the case of 3eTe, the thickness is 5 μm to 50 μm.

光導電体膜3が例えばa−8i膜である場合ρDark
はio9〜1012Qyn、ρ、5゜誂105〜108
Ω口となるから、インク抵抗=ρ1NKFi、lO6〜
1010Ω口に選ばなければならない。
When the photoconductor film 3 is, for example, an a-8i film, ρDark
is io9~1012Qyn, ρ, 5゜゜105~108
Since it is a Ω port, ink resistance = ρ1NKFi, lO6~
Must be selected as 1010Ω.

光導電体膜3上に照射される光像の内、明部は50 L
ux〜500 Luxである。
Of the light image irradiated onto the photoconductor film 3, the bright area is 50 L.
It is ux ~ 500 Lux.

しかしながら、本発明者らの検討によると、インク抵抗
=ρINKが10〜10’Ω錦と低いとき、第5図に示
すように、本来、光がON 、 OFF l、ているB
領域以外の光が全面照射しているA領域に対応した記録
電極2a・・・端にグラスの信号がリークしてしまいイ
ンク9が飛翔していわゆるカブリが発生するという不具
合点が生じた。
However, according to the studies of the present inventors, when the ink resistance = ρINK is as low as 10 to 10'Ω, as shown in FIG.
A problem occurred in that the signal of the glass leaked to the edge of the recording electrode 2a corresponding to the A area, which was entirely irradiated with light from other areas, causing the ink 9 to fly and causing so-called fog.

10m また、インク抵抗が10〜10   と高い場合には、
記録電極2&・・・端よりインクメニスカス9aへ電荷
の注入が小さくなシ、インク9が飛翔しにくくなるとい
う不具合点も生じた。
10m Also, if the ink resistance is as high as 10 to 10,
There also occurred a problem that the injection of charge from the ends of the recording electrodes 2 to the ink meniscus 9a was small, making it difficult for the ink 9 to fly.

〔発明の目的〕[Purpose of the invention]

本発明は上記事情に着目してなされたもので、その目的
とするところは、液状インクの抵抗の高低に影響を受け
ることなく、安定した記録が可能なイン、クジエツト記
録方法を提供しようとするものである。
The present invention has been made in view of the above circumstances, and its purpose is to provide an in/out printing method that allows stable recording without being affected by the level of resistance of liquid ink. It is something.

〔発明の概要〕[Summary of the invention]

本発明は上記目的を達成するため、記録電極に対向する
対向電極に対し0Vを基準として一極性のパルス電圧t
−パルス幅比215乃至315で印加することにより記
録電極に対して電気信号をリークさせることなく、マた
、インクメニカスに対し良好に電荷を注入できるように
したものである。
In order to achieve the above object, the present invention applies a unipolar pulse voltage t to a counter electrode facing a recording electrode with reference to 0V.
- By applying the pulse width at a pulse width ratio of 215 to 315, electric charges can be injected into the ink menicus without leaking electrical signals to the recording electrodes.

〔発明の実施例〕[Embodiments of the invention]

以下、本発明を第1図に示す一実施例を参照して説明す
る。
The present invention will be explained below with reference to an embodiment shown in FIG.

第1図は対向電極としてのローラ状背面電極7に印加す
る・やルス状の直流電位のノゼルス幅を示す。
FIG. 1 shows the nozzle width of a slightly lasing direct current potential applied to the roller-shaped back electrode 7 as a counter electrode.

本発明者らの検討の結果、例えば、インク抵抗が10〜
10Ω備と低い場合には、パルス幅比J/nは315よ
シ小さい方が(よシ好適には1/20〜1/2)、イン
ク9は選択的に飛翔し、又インク抵抗が10〜10 Ω
備と大きい場合には、・ソルス幅比ノ/nは215より
大きい方が(より好適には1/2〜1)インク9が効率
よく飛翔することが判明した。
As a result of the inventors' studies, for example, the ink resistance is 10 to
If the pulse width ratio J/n is as low as 10 Ω, the smaller the pulse width ratio J/n is than 315 (preferably 1/20 to 1/2), the ink 9 will be selectively ejected, and the ink resistance will be 10 Ω. ~10Ω
It has been found that the ink 9 flies more efficiently when the Solus width ratio is larger than 215 (more preferably 1/2 to 1).

すなわち、パルス幅比νnは215〜315(最適には
1/2)の時インクの抵抗の高低のいかんにか刀りわら
ず選択的インク飛翔による良好なスリットジェット方式
の記録が可能であることを発見した。
In other words, when the pulse width ratio νn is 215 to 315 (optimally 1/2), good slit jet recording is possible due to selective ink flight regardless of the level of ink resistance. discovered.

このことは、パルス周波数にも依存するが周波数が10
0〜1 kHzの範囲では上記傾向がいっそう強く、本
発明のパルス幅の効果があることが判明した。
This depends on the pulse frequency, but if the frequency is 10
It was found that the above tendency was even stronger in the range of 0 to 1 kHz, indicating that the pulse width of the present invention was effective.

〔実施例の1〕 抵抗100mのインクを用いて以下に示すゾロセス設定
条件で第5図に示すのと同じB領域のみでの光のON 
、 OFFを行いA領域は全面照射で、インクの選択的
飛翔実験を行った。
[Example 1] Using ink with a resistance of 100 m, turn on the light only in the B region, which is the same as shown in Figure 5, under the Zorothe setting conditions shown below.
, OFF, and area A was irradiated over the entire surface to conduct a selective ink flight experiment.

下側共通電極4の印加電圧 −250v上側共通電極5
の印加電圧 +250Vロ一ラ状背面電極7の印加電圧
 −5oov周波数        1 kHz ギヤy f  dt  150μ、dz  IQQμm
、ds 40μm光導電体膜3はシランがスのグロー放
電分解法によるa−8I B /’D10Ωα、ρ、、
−10Ω口光導電体膜面光導電体膜面上度100 Lu
xでノJ?ルヌ幅比をl/nを0〜1で変化させた。
Applied voltage of lower common electrode 4 -250v Upper common electrode 5
Applied voltage +250V Applied voltage of roller-shaped back electrode 7 -5oov Frequency 1 kHz Gear y f dt 150μ, dz IQQμm
, ds 40 μm photoconductor film 3 is a-8I B /'D10Ωα, ρ, , which is obtained by glow discharge decomposition of silane gas.
-10Ω photoconductor film surface photoconductor film surface height 100 Lu
No J in x? The l/n width ratio was varied from 0 to 1.

〔実施例の2〕 インク抵抗を10 0口とした以外は〔実施例の1〕と
まったく同様のノロ七ヌ条件でパルス幅比をノ/nを0
〜1で変化させた。
[Example 2] The pulse width ratio was set to 0/n under the same conditions as [Example 1] except that the ink resistance was set to 100.
It was varied by ~1.

〔実施例の1〕および〔実施例の2〕のそれぞれ低抵抗
および高抵抗のインクを用いて〔実施例の1〕で示した
プr+ に7条件で74’ルス幅比1/2に設定し、第
2図の構成のスリ、トジェット方式の記録装置を用いて
画出し実験を行ったところ、低抵抗インクについては一
部カブリがあったものの実用上問題のない複写画像が得
られた。又高抵抗インクについては、全体的に濃度が若
干薄れていたが、まずまずの複写画像が得られた。
Using the low-resistance and high-resistance inks of [Example 1] and [Example 2], the pull r+ shown in [Example 1] was set to 74' pulse width ratio 1/2 under 7 conditions. However, when we conducted an image reproduction experiment using a pick-and-jet recording device with the configuration shown in Figure 2, we were able to obtain copied images with no practical problems, although there was some fogging with the low-resistance ink. Ta. Regarding the high-resistance ink, although the overall density was slightly faded, a passable copy image was obtained.

〔発明の効果〕〔Effect of the invention〕

本発明は以上説明したように、記録電極に対向する対向
電極に対し、Ovを基準として一極性のパルス電圧を・
母ルス幅比215乃至315で印加したから、液状イン
クの抵抗の高低に影響を受けることなく安定して記録で
きるという効果を襲するものである。
As explained above, the present invention applies a unipolar pulse voltage to the counter electrode facing the recording electrode with Ov as a reference.
Since the ink was applied at a master pulse width ratio of 215 to 315, it is possible to stably record without being affected by the resistance level of the liquid ink.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例である対向電極に印加するノ
々ルス電圧を示すグラフ図、第2図乃至第5図は従来例
を示すもので、第2図は記録装置を示す概略的構成図、
第3図は電極を示す平面図、第4図は電気回路図、第5
図はインクの飛翔状態を示す説明図である。 H・・・記録ヘッド、21L・・・・・・記録電極、7
・・・対向電極、8・・・被記録体。
Fig. 1 is a graph showing the Nords voltage applied to the counter electrode according to an embodiment of the present invention, Figs. 2 to 5 show conventional examples, and Fig. 2 is a schematic diagram showing a recording device. configuration diagram,
Figure 3 is a plan view showing the electrode, Figure 4 is an electric circuit diagram, Figure 5
The figure is an explanatory diagram showing the flying state of ink. H... Recording head, 21L... Recording electrode, 7
. . . Counter electrode, 8 . . . Recorded object.

Claims (3)

【特許請求の範囲】[Claims] (1)先端部に開口部を有した記録ヘッドと、この記録
ヘッドの先端開口部に設けられた記録電極と、この記録
電極に対向され被記録体を支持する対向電極と、前記記
録電極に液状インクを供給するインク供給部とを具備し
、前記記録電極に出力される電気信号に対応して前記液
状インクを被記録体に飛翔させて記録する方法において
、前記対向電極に対し、0Vを基準として正負いずれか
一極性のパルス電圧を印加することを特徴とするインク
ジェット記録方法。
(1) A recording head having an opening at its tip, a recording electrode provided at the opening at the tip of the recording head, a counter electrode that faces the recording electrode and supports a recording object, and a recording electrode that supports the recording object. and an ink supply section that supplies liquid ink, and in the method of recording by causing the liquid ink to fly onto a recording medium in response to an electric signal output to the recording electrode, 0V is applied to the counter electrode. An inkjet recording method characterized by applying a pulse voltage of either positive or negative polarity as a reference.
(2)パルス電圧はパルス幅比2/5乃至3/5である
ことを特徴とするインクジェット記録方法。
(2) An inkjet recording method characterized in that the pulse voltage has a pulse width ratio of 2/5 to 3/5.
(3)パルス電圧の周波数は100Hz以上であること
を特徴とする特許請求の範囲第1項記載のインクジェッ
ト記録方法。
(3) The inkjet recording method according to claim 1, wherein the frequency of the pulse voltage is 100 Hz or more.
JP15382485A 1985-07-12 1985-07-12 Ink jet recording method Pending JPS6213379A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15382485A JPS6213379A (en) 1985-07-12 1985-07-12 Ink jet recording method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15382485A JPS6213379A (en) 1985-07-12 1985-07-12 Ink jet recording method

Publications (1)

Publication Number Publication Date
JPS6213379A true JPS6213379A (en) 1987-01-22

Family

ID=15570891

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15382485A Pending JPS6213379A (en) 1985-07-12 1985-07-12 Ink jet recording method

Country Status (1)

Country Link
JP (1) JPS6213379A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02178054A (en) * 1988-12-29 1990-07-11 Ricoh Co Ltd Recording device
EP0893261A2 (en) 1997-07-22 1999-01-27 Nec Corporation Inkjet recording apparatus and control method for the same
US5874176A (en) * 1994-05-20 1999-02-23 Ube Industries, Ltd. Resin composite containing polyamide matrix and polyolefine grains dispersed therein
US6075091A (en) * 1995-07-13 2000-06-13 Mitsui Chemicals Inc. Composition of polyamide and acid or anhydride-grafted ethylene/C6-C20 α-olefin copolymer
US6305691B1 (en) 1995-04-10 2001-10-23 Nippon Pillar Packing Co., Ltd. Shaft sealing apparatus
KR20180066207A (en) 2015-12-01 2018-06-18 미쓰이 가가쿠 가부시키가이샤 Highly dynamic polyamide resin composition

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02178054A (en) * 1988-12-29 1990-07-11 Ricoh Co Ltd Recording device
US5874176A (en) * 1994-05-20 1999-02-23 Ube Industries, Ltd. Resin composite containing polyamide matrix and polyolefine grains dispersed therein
US6305691B1 (en) 1995-04-10 2001-10-23 Nippon Pillar Packing Co., Ltd. Shaft sealing apparatus
US6075091A (en) * 1995-07-13 2000-06-13 Mitsui Chemicals Inc. Composition of polyamide and acid or anhydride-grafted ethylene/C6-C20 α-olefin copolymer
EP0893261A2 (en) 1997-07-22 1999-01-27 Nec Corporation Inkjet recording apparatus and control method for the same
US6190004B1 (en) 1997-07-22 2001-02-20 Nec Corporation Inkjet recording apparatus
KR20180066207A (en) 2015-12-01 2018-06-18 미쓰이 가가쿠 가부시키가이샤 Highly dynamic polyamide resin composition
KR20190028817A (en) 2015-12-01 2019-03-19 미쓰이 가가쿠 가부시키가이샤 Polyamide resin composition with high fluidity

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