JPS62109836A - Production of preexpanded polystyrene based resin particle - Google Patents

Production of preexpanded polystyrene based resin particle

Info

Publication number
JPS62109836A
JPS62109836A JP21399486A JP21399486A JPS62109836A JP S62109836 A JPS62109836 A JP S62109836A JP 21399486 A JP21399486 A JP 21399486A JP 21399486 A JP21399486 A JP 21399486A JP S62109836 A JPS62109836 A JP S62109836A
Authority
JP
Japan
Prior art keywords
particles
treating agent
duct
preexpanded
resin particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP21399486A
Other languages
Japanese (ja)
Other versions
JPS636584B2 (en
Inventor
Masaaki Yokoyama
正明 横山
Kunikazu Nagasaki
長崎 邦和
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical BASF Co Ltd
Original Assignee
Mitsubishi Chemical BASF Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP5626879A external-priority patent/JPS55148134A/en
Application filed by Mitsubishi Chemical BASF Co Ltd filed Critical Mitsubishi Chemical BASF Co Ltd
Priority to JP21399486A priority Critical patent/JPS62109836A/en
Publication of JPS62109836A publication Critical patent/JPS62109836A/en
Publication of JPS636584B2 publication Critical patent/JPS636584B2/ja
Granted legal-status Critical Current

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  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

PURPOSE:To produce preexpanded particles, uniformly coated with a very small amount of a treating agent and hardly causing bridging, by atomizing a treating agent with a pressurized air for feeding preexpanded particles through a duct to a silo and bringing the atomized treating agent into contact with the preexpanded particles. CONSTITUTION:Resin particles are fed from a raw material hopper 1 to a preexpanding machine 3 by a screw feeder 2 and preexpanded particles are fed through an outlet 5 of a preexpanding tank 4 and hopper 6, passed through a pneumatic feeding duct 7 and pneumatically fed to an aging silo 8 while suspensed with a pressurized gas supplied from a particle feeding blower 9. In the stage, a spray nozzle 22 is placed in the interior of the pneumatic feeding duct 7 to atomize the treating agent emerging from the spray nozzle 22 with the pressurizing gas from the particle feeding blower 9 to coat the preexpanded particles with the treating agent in the flow of the atomized treating agent.

Description

【発明の詳細な説明】 本発明は処理剤をコーティングしたポリスチレン系樹脂
予備発泡粒子の製造方法に関1−るもので、特に、徴h
tの処理剤を均一にコーティングすることかでき、しか
もブリッジングの少ない−を前発泡粒子の製造方法に関
するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing pre-expanded polystyrene resin particles coated with a treatment agent, and in particular,
The present invention relates to a method for producing pre-expanded particles that can be uniformly coated with a treatment agent of t and has less bridging.

ポリスチレン、f−樹脂の予備発泡粒子−を全便に入れ
加熱・冷却して発泡成形品を製造i)−る際に、−r備
発泡粒子のブロッキングを助+l−するためと、成形時
の冷7J+サイクルを短縮))−る等の1−1的のため
、粒子の表面を脂肪酸アミド、脂肪族アミン、脂肪酸金
属塩、パラフィン油、ポリエチレンワックス等の処理剤
でコーティングした予備発泡粒子を用いることが知られ
ている。
Pre-expanded particles of polystyrene or f-resin are placed in a container and heated and cooled to produce a foamed molded product. For 1-1 purposes such as shortening the 7J+ cycle), use pre-expanded particles whose surfaces are coated with a treatment agent such as fatty acid amide, aliphatic amine, fatty acid metal salt, paraffin oil, polyethylene wax, etc. It has been known.

前記処理剤を用いた公知のコーティング技術には次のよ
うな方法かある。
Known coating techniques using the above-mentioned processing agents include the following methods.

■予備発泡11仔の処理; 樹脂粒子と処理剤とをリボンブレンダー等のミキサー内
に入れて混合する。
■Processing of the pre-foamed 11 particles; Put the resin particles and the processing agent into a mixer such as a ribbon blender and mix.

■r備発泡時の処理: 樹脂粒子をt前発泡槽内に移送するスクリューフィーダ
内に処理剤を送給し、槽内でスチーム発泡処理する。
■Processing during pre-foaming: A processing agent is fed into a screw feeder that transports resin particles into a pre-foaming tank, and steam foaming is performed in the tank.

■r備発泡後の処理: r備発泡粒子と処理剤とをリホンブレンダー等のミキサ
ー内に入れて混合する。
■Processing after foaming: The foamed particles and processing agent are placed in a mixer such as a Riphon blender and mixed.

しかしながらに述した従来の処理方法にはそれぞれ次の
ような問題点かある。
However, each of the conventional processing methods described above has the following problems.

■の場合、樹脂粒子にコーティング処理した?LPfi
発泡処理するまてに時間がかかるため、脂肪酸アミF等
の処理剤によっては樹脂粒子表面か変質する虞れがある
。また、コーティングか別に装置されたミキサーによる
混合処理であるため、予備発泡作業と連続して行なうこ
とができず、手間がかかり作業効率が良くない。
In the case of ■, have the resin particles been coated? LPfi
Since it takes time to carry out the foaming treatment, there is a possibility that the surfaces of the resin particles may be altered depending on the treatment agent such as fatty acid amide F. Furthermore, since the coating process is mixed using a separate mixer, it cannot be carried out continuously with the pre-foaming process, which is time consuming and inefficient.

■の場合、スクリューフィーダによる混合であり、処理
剤の添加量は樹脂粒子に対し0.01〜1重?%程度と
@量なので、ミキシングゾーンの滞溜時間を長くせねば
ならず、通常のミキサーによる場合と比較して混合効率
が非常に低い。
In the case of (2), the mixing is done using a screw feeder, and the amount of processing agent added is 0.01 to 1 part per weight of the resin particles. %, the residence time in the mixing zone must be increased, and the mixing efficiency is very low compared to when using a normal mixer.

処理剤が粉末の場合、多量の溶剤に溶解するか水等に分
散してエマルジョン化して使用する必要があり、溶媒あ
るいは分散媒の影響が問題となる。
When the processing agent is a powder, it must be used by dissolving it in a large amount of solvent or dispersing it in water or the like to form an emulsion, and the influence of the solvent or dispersion medium becomes a problem.

予備発泡槽内に送給されて来る樹脂粒子に溶液とした処
理剤が混入していると、該発泡槽内のドレンが多くなっ
て予備発泡粒子の湿りが大となる。
If the resin particles fed into the pre-foaming tank contain a treatment agent in solution, the amount of drainage in the foaming tank will increase and the wetness of the pre-foamed particles will increase.

予備発泡粒子の湿りは、成形特金型キャビティ内へ予備
発泡粒子を充填する際の充填不良や、或いは予備発泡粒
子の熟成サイロ内におけるブリッジング現象の発生によ
り予備発泡粒子を圧送する際の空送不良の原因となる。
Wetness of the pre-expanded particles can be caused by poor filling when filling the pre-expanded particles into the special mold cavity, or by bridging phenomenon in the maturing silo of the pre-expanded particles. This may cause delivery failure.

このため、予備発泡粒子を乾燥するための装置が必要と
なる。
For this reason, a device for drying the pre-expanded particles is required.

また前記■の方法によると処理剤が樹脂粒子の全表面に
均一・にコーティングされにくく、局部的にコーティン
グされがちになるので、発泡粒子のブリッジングが多い
という問題点もある。
Furthermore, according to method (2) above, it is difficult to uniformly coat the entire surface of the resin particles with the treatment agent, and the coating tends to be localized, so there is also the problem that bridging of the expanded particles occurs frequently.

■の場合、予備発泡粒子は発泡Iiηの樹脂粒子に比較
して体積が20〜60倍に増大しているため、ミキサー
も大容積のものが必要となり、作業が大がかりとなる。
In the case of (2), the volume of the pre-expanded particles is 20 to 60 times larger than that of the resin particles of the foamed Iiη, so a mixer with a large capacity is required, and the work becomes extensive.

しかも発泡して表面h1が拡大した予備発泡粒子の全面
に微■の処理剤を均一・にコーティングすることは不可
filに近い。上述した従来例とそれらの問題点から理
解されるように、処理剤のコーティングにおいては、 (1)微量の処理剤を均一に予備発泡粒子にコーティン
グすること、および槽壁面への付着等による処理剤のロ
スか少ないこと、 (II )処理剤のコーティングに起因したブリッジン
グ等の発生を防止すること、 の一つの課題を同時に解決しなければならない。
Furthermore, it is nearly impossible to uniformly coat the entire surface of the pre-expanded particles whose surface h1 has expanded with a fine amount of treatment agent. As can be understood from the above-mentioned conventional examples and their problems, coating with a processing agent requires (1) uniform coating of a small amount of the processing agent on the pre-expanded particles, and treatment by adhesion to the tank wall surface, etc. The following problems must be solved at the same time: (II) preventing the occurrence of bridging, etc. caused by the coating of the processing agent.

17かるに、前記従来例のコーティング法を検討すると
、これらはミキサーやスクリューフィーダ等の/lJ合
装置を使用したtlJ合−L段に頼っていた点において
共通している。
17. However, when considering the conventional coating methods mentioned above, they have in common that they rely on a tlJ combination-L stage using a /lJ combination device such as a mixer or a screw feeder.

従って、徴蹴の処理剤を効率良くコーディング=I−る
手段として、かかる従来の機械的7F9合法を踏襲する
ことは11−策でない。一方、コーティングすべき樹脂
粒子−はq体物であるため、その全1r11に均一にコ
ーディングを実施1−るには粒子を回転させるか処理剤
中に浸γ貞するかのいずれかしか方法がない。
Therefore, it is not a good idea to follow the conventional mechanical 7F9 method as a means of efficiently coding the processing agent of the kick. On the other hand, since the resin particles to be coated are q-objects, the only way to uniformly coat all of them is to rotate the particles or immerse them in a treatment agent. do not have.

本発明は、研究の結果、処理剤を霧化して樹脂粒子−と
接触させること、およびこの接触を霧化処理剤の流れの
中に樹脂粒子をおくことによって−1・述のような「0
段を採らなくてよいことを(+!、出した、。
As a result of research, the present invention has been developed by atomizing a processing agent and bringing it into contact with resin particles, and by placing the resin particles in the flow of the atomized processing agent, and thereby achieving the "0.
I learned that I didn't have to take the dan (+!).

本発明は、このような技i41的背];[の1°になさ
れたbのて、その目的と1−るところは、桧1脂粒子の
コーティングを処理剤を霧化して行なうことにより、徴
Mの処理剤で均一なコーティングを実現すると同時に、
粒子間のブリッジングの発生を防止するにある。
The present invention is based on such technique i41];[b made at 1°b, and its purpose and purpose is to coat the cypress oil particles by atomizing the treatment agent. At the same time as achieving uniform coating with the treatment agent of CHI M,
The purpose is to prevent bridging between particles.

ポリスチレン系樹脂予備発泡体の製造工程において、か
かるコーディング処理を実施するには予備発泡−「程の
前或いは復のいずれでも良いが、好ましくは−e備発/
I!I槽内の樹脂粒子にスチームを供給する段階または
予備発泡後の予備発泡粒子を熟成サイロへ空送する段階
に実現することか望ましい。
In the manufacturing process of polystyrene resin pre-foaming, such coating treatment may be carried out either before or after the pre-foaming process, but preferably after the pre-foaming process.
I! It is preferable to realize this at the stage of supplying steam to the resin particles in the I tank or at the stage of air transporting the pre-expanded particles after pre-foaming to a maturing silo.

ここで、実施例の説明に先立つ゛C本発明のポリスチレ
ン系樹脂予備発泡粒子の製造装置について説明する。第
1図において、1はポリスチレン系発泡粒子・の原料ホ
ッパー、2はスクリューフィーダで、樹脂粒子を原料ホ
ッパー1より−f−備発泡機3へ送給する。4はf備発
泡槽、5はその1ニ部に設けられた介備発泡粒−rの出
「1.6は予備発泡粒子のホッパー、7は詠ホッパー6
から供給された予備発泡粒子−を熟成サイロ8へ送給す
る空送ダクトである。この空送ダクト7のホッパ−6側
端部は、送粒ブロワ−9に接続されており、この送粒ブ
ロワ−9は前記ホッパー6がら空送ダクト7内に供給さ
れたPi発泡粒子を111f記サイロ8へ加圧気体によ
り浮遊させつつ空送する。
Here, prior to the description of Examples, an apparatus for producing pre-expanded polystyrene resin particles of the present invention will be described. In FIG. 1, 1 is a raw material hopper for polystyrene foam particles, and 2 is a screw feeder, which feeds resin particles from the raw material hopper 1 to a -f-equipped foaming machine 3. 4 is a foaming tank f, 5 is a foamed grain-r outlet provided in its first part; 1.6 is a hopper for pre-foamed grains, and 7 is a hopper 6.
This is an air transport duct that transports the pre-expanded particles supplied from the silo to the aging silo 8. The end of the air feeding duct 7 on the side of the hopper 6 is connected to a particle feeding blower 9, and this particle feeding blower 9 transfers the Pi expanded particles supplied from the hopper 6 into the air feeding duct 7 to The material is air-fed to the silo 8 while being suspended by pressurized gas.

樹脂粒子は、′r−備発泡摺4内においてスチーム供給
を受けるが、このとき、そのスチーム中に処理剤を供給
して該処理剤を霧化させることによってコーティングを
行なうのが次に述べるコ。−ティング方法であり、特願
昭54−56268号において明らかにしているもので
ある。
The resin particles are supplied with steam in the foaming slide 4, and at this time, coating is performed by supplying a treatment agent into the steam and atomizing the treatment agent, as described below. . This is a method disclosed in Japanese Patent Application No. 56268/1983.

1−なわち、この方法は、処理剤としてソルビタンモノ
パルミテート(アルコール溶液。以ドの実施例において
同じ。)を使用しており、該ソルビタンモノパルミテー
トを霧化する・1段として前記スチームを使用した例で
ある。第1図、第2図に小したように樹脂粒子−はスク
リューフィーダ2により予備発泡槽4の下部に供給し、
該予備発泡槽中の樹脂粒子−に対してスチームSを供給
するスチームダクト11内に、処理剤コーティング装置
A1を装備し、スチーム流にのせて処理剤であるソルヒ
タンモノステアレートを糟4に供給″l−る。
1- That is, this method uses sorbitan monopalmitate (alcoholic solution, same in the following examples) as a processing agent, and the sorbitan monopalmitate is atomized and the steam is used as the first stage. This is an example using . As shown in FIGS. 1 and 2, resin particles are fed to the lower part of the pre-foaming tank 4 by a screw feeder 2,
A treatment agent coating device A1 is installed in the steam duct 11 that supplies steam S to the resin particles in the pre-foaming tank, and solhitan monostearate, which is a treatment agent, is applied to the slurry 4 on the steam flow. Supply "l-ru."

処理剤コーティング装置A、は、スチームダクト11内
に配置したスプレィノズル12(第3図)と、註ノズル
12の中央7ノズル13に接続した処理剤供給r前踏1
4と、該ノズルの環状ノズル15に接続したスチーム供
給管路16及び図外の加圧空気系、同処理剤定量ポンプ
から構成されている。また、スプレィノズルの向きはス
チームダクトll内のスチームSの流れの方向と平行に
設定し、スブレスノズルの4D置はスチームダクト11
内の中央である。なお、第2図中、17は予備51泡中
の樹脂粒子を攪rLする攪拌翼、18はいわゆるジャマ
棒である。
The processing agent coating device A includes a spray nozzle 12 (FIG. 3) arranged in a steam duct 11, and a processing agent supply r front 1 connected to the center seven nozzles 13 of the nozzles 12.
4, a steam supply pipe 16 connected to the annular nozzle 15 of the nozzle, a pressurized air system (not shown), and a treatment agent metering pump. In addition, the direction of the spray nozzle is set parallel to the flow direction of the steam S in the steam duct 11, and the 4D position of the spray nozzle is set in the steam duct 11.
It is in the center. In FIG. 2, 17 is a stirring blade for stirring the resin particles in the preliminary foam 51, and 18 is a so-called jammer rod.

このコーディング方法の場合、ソルビタンモノパルミテ
ートは発泡のためのスチームSにより霧化され、そのス
チーム流にのって樹脂粒子の流れ中に分散供給される。
In this coating method, sorbitan monopalmitate is atomized by steam S for foaming, and is dispersed and supplied into the flow of resin particles along with the steam flow.

以上は予備発泡に使用するスチームによって処理剤を霧
化する例であるが、次に述べる本発明の実施例は、予備
発泡粒子・を熟成サイロ8へ送給する加圧空気によって
処理剤を霧化する例である。
The above is an example in which the processing agent is atomized by the steam used for pre-foaming, but in the embodiment of the present invention described below, the processing agent is atomized by pressurized air that feeds the pre-foamed particles to the maturing silo 8. This is an example of

〔実施例〕〔Example〕

本実施例は、第1図のコーティング装置A2における空
送ダクト7の内部に配置したスブレスノズル22からの
処理剤を」−記加圧空気により霧化して予備発泡粒子に
噴霧する例である。スブレスノズル22は第3図に示す
ものと同様のものを第4図に示したように空送ダクト7
の中心に配置する。第5図はコーティング装置A2の全
容を示し、処理液としてのソルビタンモノパルミテート
は、タンク23内に貯溜してあり、定量(ポンプ24に
より供給管路25を通じてスプレィノズル22に送られ
る。26は加圧空気の供給系で、圧縮エアを供給q′C
路27を通じてスプレィノズル22へ送られる。
This example is an example in which the treatment agent from the Sbress nozzle 22 disposed inside the pneumatic duct 7 in the coating apparatus A2 of FIG. 1 is atomized by pressurized air and sprayed onto the pre-expanded particles. . The Sbress nozzle 22 is similar to that shown in FIG.
Place it in the center. FIG. 5 shows the entire structure of the coating apparatus A2, in which sorbitan monopalmitate as a treatment liquid is stored in a tank 23, and is sent to the spray nozzle 22 via a supply pipe 25 by a pump 24. The compressed air supply system supplies compressed air q'C
is sent to the spray nozzle 22 via channel 27.

上記装置A2においては、予備発泡粒子−が樹脂粒子の
数−1−(j5にもなっているのて、空送ダクト7のコ
ーティング部を通過1−る−を備発泡粒子の111とツ
ルどタンモノパルミデートの噴出111を相応させるよ
うに定量方式等適当な管理方式を採る。空送ダクト7内
を流れる予備発泡粒子と加圧空気は複雑な動きをしてお
り、これに対してスプレィノズル22よりソルビタンモ
ノパルミテートを供給するので、これか上記加圧空気に
よって霧化され空気中に混合希釈されると共に、予備発
泡粒子表面に均一に付着1−る。
In the above device A2, since the number of pre-expanded particles is -1- (also j5), the number of pre-expanded particles passing through the coating part of the air conveyance duct 7 is mixed with 111 of the expanded particles. An appropriate control method such as a quantitative method is adopted to match the ejection 111 of tanmonopalmidate.The pre-expanded particles and pressurized air flowing in the air conveyance duct 7 move in a complicated manner, and the spray Since sorbitan monopalmitate is supplied from the nozzle 22, it is atomized by the pressurized air, mixed and diluted in the air, and uniformly adheres to the surface of the pre-expanded particles.

なお、]−記実施例においてはスプレーガンに類似した
ノズルによる霧化方法を例示したのみであるが、本発明
の製造方法はこの例に限定されるものではなく、加圧乱
流による霧化やヘンチュリ効果を利用した霧化あるいは
それらの併用による霧化も可能である。また、処理剤は
脂肪酸アミド、脂肪酸金属塩、パラフィン油等でもよい
Note that although the above examples only exemplify the atomization method using a nozzle similar to a spray gun, the manufacturing method of the present invention is not limited to this example, and the atomization method using pressurized turbulent flow is not limited to this example. It is also possible to atomize using the Hentschli effect or the Hentschli effect, or a combination of these. Further, the processing agent may be a fatty acid amide, a fatty acid metal salt, paraffin oil, or the like.

以上説明したように、本発明によれば、処Fl!刑を霧
化するので、槽壁面への付着等によるロス量も少なく、
しかも@:1【の処理剤で予備発泡粒子の全表面に均一
なコーティングか可能となる。
As explained above, according to the present invention, the location Fl! Since the liquid is atomized, there is less loss due to adhesion to the tank wall, etc.
Furthermore, the treatment agent @:1 enables uniform coating on the entire surface of the pre-expanded particles.

また、均一なコーティングが粒子の全表面に行なわれる
ので、粒−rのブリッジングの発生を防ILできる。
Further, since a uniform coating is applied to the entire surface of the particles, bridging of the particles -r can be prevented from occurring.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明のポリスチレン系樹脂予備発泡粒子の製
造装置を示す模式図、第2図は処理剤コーティング装置
A、及び予備発泡機の平面図、第3図は第2図に粘ける
スプレィノズルの断面図、第4図は本発明の実施例にお
いて使用するスプレィノズルの斜視図、第5図は実施例
における加圧空気の供給装置を示す斜視図である。
Fig. 1 is a schematic diagram showing an apparatus for producing pre-expanded polystyrene resin particles of the present invention, Fig. 2 is a plan view of a processing agent coating device A and a pre-expanding machine, and Fig. 3 is a viscous spray similar to Fig. 2. FIG. 4 is a sectional view of a nozzle, FIG. 4 is a perspective view of a spray nozzle used in an embodiment of the present invention, and FIG. 5 is a perspective view of a pressurized air supply device in an embodiment.

Claims (1)

【特許請求の範囲】[Claims] 発泡性ポリスチレン系樹脂粒子を予備発泡させて予備発
泡粒子を製造する方法において、前記予備発泡粒子は、
この粒子をダクトを通してサイロへ送給する加圧空気で
霧化した処理剤によって、前記ダクト内でコーティング
されることを特徴とするポリスチレン系樹脂予備発泡粒
子の製造方法。
In a method for producing pre-expanded particles by pre-expanding expandable polystyrene resin particles, the pre-expanded particles include:
A method for producing pre-expanded polystyrene resin particles, characterized in that the particles are coated in the duct with a treatment agent atomized by pressurized air that is sent to the silo through the duct.
JP21399486A 1979-05-10 1986-09-12 Production of preexpanded polystyrene based resin particle Granted JPS62109836A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21399486A JPS62109836A (en) 1979-05-10 1986-09-12 Production of preexpanded polystyrene based resin particle

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP5626879A JPS55148134A (en) 1979-05-10 1979-05-10 Manufacture of preparatorily foamed grain of polystyrene resin
JP21399486A JPS62109836A (en) 1979-05-10 1986-09-12 Production of preexpanded polystyrene based resin particle

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP5626879A Division JPS55148134A (en) 1979-05-10 1979-05-10 Manufacture of preparatorily foamed grain of polystyrene resin

Publications (2)

Publication Number Publication Date
JPS62109836A true JPS62109836A (en) 1987-05-21
JPS636584B2 JPS636584B2 (en) 1988-02-10

Family

ID=26397222

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21399486A Granted JPS62109836A (en) 1979-05-10 1986-09-12 Production of preexpanded polystyrene based resin particle

Country Status (1)

Country Link
JP (1) JPS62109836A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01249408A (en) * 1988-03-31 1989-10-04 Kanegafuchi Chem Ind Co Ltd Method for conveying and curing thermoplastic resin prefoamed particle with hot air

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01249408A (en) * 1988-03-31 1989-10-04 Kanegafuchi Chem Ind Co Ltd Method for conveying and curing thermoplastic resin prefoamed particle with hot air

Also Published As

Publication number Publication date
JPS636584B2 (en) 1988-02-10

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