JPS6175879A - 炭素繊維用サイジング剤 - Google Patents
炭素繊維用サイジング剤Info
- Publication number
- JPS6175879A JPS6175879A JP19436484A JP19436484A JPS6175879A JP S6175879 A JPS6175879 A JP S6175879A JP 19436484 A JP19436484 A JP 19436484A JP 19436484 A JP19436484 A JP 19436484A JP S6175879 A JPS6175879 A JP S6175879A
- Authority
- JP
- Japan
- Prior art keywords
- tables
- formulas
- carbon fibers
- general formula
- sizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000049 Carbon (fiber) Polymers 0.000 title claims description 47
- 239000004917 carbon fiber Substances 0.000 title claims description 47
- 239000003795 chemical substances by application Substances 0.000 title claims description 37
- 238000004513 sizing Methods 0.000 title claims description 34
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title description 9
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000004417 polycarbonate Substances 0.000 claims description 11
- 229920000515 polycarbonate Polymers 0.000 claims description 11
- 239000004593 Epoxy Substances 0.000 claims description 9
- 229930185605 Bisphenol Natural products 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 12
- 239000002131 composite material Substances 0.000 description 15
- 230000000694 effects Effects 0.000 description 13
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- -1 aromatic glycidyl ethers Chemical class 0.000 description 8
- 229920005989 resin Polymers 0.000 description 8
- 239000011347 resin Substances 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 238000009941 weaving Methods 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 238000001308 synthesis method Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 238000009499 grossing Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 2
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- JRTVEUGOGWTHTR-UHFFFAOYSA-N dodecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCC JRTVEUGOGWTHTR-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- LRMHFDNWKCSEQU-UHFFFAOYSA-N ethoxyethane;phenol Chemical compound CCOCC.OC1=CC=CC=C1 LRMHFDNWKCSEQU-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- UISARWKNNNHPGI-UHFFFAOYSA-N terodiline Chemical compound C=1C=CC=CC=1C(CC(C)NC(C)(C)C)C1=CC=CC=C1 UISARWKNNNHPGI-UHFFFAOYSA-N 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19436484A JPS6175879A (ja) | 1984-09-17 | 1984-09-17 | 炭素繊維用サイジング剤 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19436484A JPS6175879A (ja) | 1984-09-17 | 1984-09-17 | 炭素繊維用サイジング剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6175879A true JPS6175879A (ja) | 1986-04-18 |
JPH048543B2 JPH048543B2 (enrdf_load_stackoverflow) | 1992-02-17 |
Family
ID=16323348
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP19436484A Granted JPS6175879A (ja) | 1984-09-17 | 1984-09-17 | 炭素繊維用サイジング剤 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6175879A (enrdf_load_stackoverflow) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108004778A (zh) * | 2016-10-28 | 2018-05-08 | 中国石油化工股份有限公司 | 一种碳纤维用聚碳酸酯树脂基悬浮液上浆剂及其制备方法 |
WO2019026008A1 (en) * | 2017-08-01 | 2019-02-07 | Sabic Global Technologies B.V. | AQUEOUS POLYMERIC DISPERSIONS, PROCESSES FOR MAKING SUCH AQUEOUS POLYMER DISPERSIONS AND BOREHOLE FIBER WHEAT |
CN110959055A (zh) * | 2017-08-01 | 2020-04-03 | 沙特基础工业全球技术有限公司 | 水性聚合物分散体、制备其的方法和上浆纤维束 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5277289A (en) * | 1975-12-19 | 1977-06-29 | Asahi Chemical Ind | Carbon fibre use sizing agent |
JPS55160380A (en) * | 1979-05-28 | 1980-12-13 | Fujitsu Ltd | Magnetic tape unit |
-
1984
- 1984-09-17 JP JP19436484A patent/JPS6175879A/ja active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5277289A (en) * | 1975-12-19 | 1977-06-29 | Asahi Chemical Ind | Carbon fibre use sizing agent |
JPS55160380A (en) * | 1979-05-28 | 1980-12-13 | Fujitsu Ltd | Magnetic tape unit |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108004778A (zh) * | 2016-10-28 | 2018-05-08 | 中国石油化工股份有限公司 | 一种碳纤维用聚碳酸酯树脂基悬浮液上浆剂及其制备方法 |
CN108004778B (zh) * | 2016-10-28 | 2021-12-07 | 中国石油化工股份有限公司 | 一种碳纤维用聚碳酸酯树脂基悬浮液上浆剂及其制备方法 |
WO2019026008A1 (en) * | 2017-08-01 | 2019-02-07 | Sabic Global Technologies B.V. | AQUEOUS POLYMERIC DISPERSIONS, PROCESSES FOR MAKING SUCH AQUEOUS POLYMER DISPERSIONS AND BOREHOLE FIBER WHEAT |
CN110959055A (zh) * | 2017-08-01 | 2020-04-03 | 沙特基础工业全球技术有限公司 | 水性聚合物分散体、制备其的方法和上浆纤维束 |
Also Published As
Publication number | Publication date |
---|---|
JPH048543B2 (enrdf_load_stackoverflow) | 1992-02-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0127198B1 (en) | Preimpregnated reinforcements and high strength composites therefrom | |
US4107128A (en) | Carbon fiber composition | |
JP6903897B2 (ja) | エポキシ樹脂組成物、並びにこれを用いた成形品、プリプレグ及び繊維強化プラスチック | |
JPS6234876B2 (enrdf_load_stackoverflow) | ||
US4751258A (en) | Sizing agents for carbon yarns | |
JPS6128074A (ja) | 炭素繊維用水性サイジング剤 | |
WO2014030636A1 (ja) | エポキシ樹脂組成物及びこれを用いたフィルム、プリプレグ、繊維強化プラスチック | |
JPS63315671A (ja) | 炭素繊維用サイジング剤 | |
KR0166977B1 (ko) | 섬유 강화 플라스틱용 에폭시 수지 조성물 | |
JP6156569B2 (ja) | 炭素繊維強化プラスチック用エポキシ樹脂組成物、並びにこれを用いたフィルム、プリプレグ及び炭素繊維強化プラスチック | |
JP2017226745A (ja) | エポキシ樹脂組成物、並びにこれを用いたフィルム、プリプレグ及び繊維強化プラスチック | |
JPS5813781A (ja) | 耐擦過性にすぐれた炭素繊維 | |
JPS6175879A (ja) | 炭素繊維用サイジング剤 | |
DE69427119T2 (de) | Epoxydharze auf der basis von substiuiertem resorcinol | |
JPS6233872A (ja) | 炭素繊維用サイジング剤 | |
US3642698A (en) | Epoxy resin curing with imidazole alkyl acid phosphate salt catalyst | |
JP2016084372A (ja) | プリプレグ及び繊維強化プラスチック | |
JP5252869B2 (ja) | 繊維強化複合材料用エポキシ樹脂組成物及びプリプレグ | |
JPS634000B2 (enrdf_load_stackoverflow) | ||
JPS60104578A (ja) | 炭素繊維用サイジング剤 | |
JPS60246872A (ja) | 炭素繊維用サイジング剤 | |
JPH04234423A (ja) | 向上した貯蔵安定性を有するエポキシマトリックス樹脂組成物 | |
JP6433762B2 (ja) | 電線被覆向け複合材料用エポキシ樹脂組成物 | |
JPS61252365A (ja) | 炭素繊維用サイジング剤 | |
TW202300550A (zh) | 上漿劑組成物、碳纖維材料與複合材料 |