JPS6172819A - Bagform mat for seal for exhaust gas purifying device - Google Patents

Bagform mat for seal for exhaust gas purifying device

Info

Publication number
JPS6172819A
JPS6172819A JP19627284A JP19627284A JPS6172819A JP S6172819 A JPS6172819 A JP S6172819A JP 19627284 A JP19627284 A JP 19627284A JP 19627284 A JP19627284 A JP 19627284A JP S6172819 A JPS6172819 A JP S6172819A
Authority
JP
Japan
Prior art keywords
mat
honeycomb catalyst
exhaust gas
seal
case
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19627284A
Other languages
Japanese (ja)
Inventor
Yoshihiko Kitamura
嘉彦 北村
Sadao Nakao
中尾 貞夫
Akemasa Sugiyama
明正 杉山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dainichi Nippon Cables Ltd
Nippon Reinz Co Ltd
Original Assignee
Dainichi Nippon Cables Ltd
Nippon Reinz Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dainichi Nippon Cables Ltd, Nippon Reinz Co Ltd filed Critical Dainichi Nippon Cables Ltd
Priority to JP19627284A priority Critical patent/JPS6172819A/en
Publication of JPS6172819A publication Critical patent/JPS6172819A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2853Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2839Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2853Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing
    • F01N3/2867Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration using mats or gaskets between catalyst body and housing the mats or gaskets being placed at the front or end face of catalyst body

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

PURPOSE:To close a gap between a mat and a honeycomb catalyst, around with the mat is wound, and to prevent leak of exhaust gas, by a method wherein a heat resistant seal material is wrapped with a heat resistant cover so as to prevent leak thereof to forms a bagform mat for seal having cushion properties. CONSTITUTION:A bagform mat 1 for seal is formed such that a heat resistance seal material 3 is wrapped with a heat resistant cover 2 so as to prevent leak thereof. In which case, a bag, formed by a metallic foil, a wire net with fine meshes, carbon fiber cloth, is used as the cover 2. Heat resistant fiber, wire materials, powdery materials, are used as the seal material 3. Further, cushion properties are provided for the mat 1 to prevent the occurrence of unevenness in size and production of vibration. In operation, after the mat 1 is wound around the whole in a direction A of length of the side peripheral part of the honeycomb catalyst 4, the catalyst is contained in the expansion part of a semisplitlike case 5 to form a purifying device. This enables enclosure of a gap between the honeycomb catalyst 4 and the case 5, and permits prevention of leak of exhaust gas.

Description

【発明の詳細な説明】 〔利用分野〕 本発明は、排気ガス浄化装置におけるハニカム触媒の側
周方向の長さの全てにわたり巻回して使用される気密性
にすぐれるシール用袋状マットに関するものである。
[Detailed Description of the Invention] [Field of Application] The present invention relates to a sealing bag-shaped mat with excellent airtightness that is used by being wound over the entire length of a honeycomb catalyst in the lateral circumferential direction in an exhaust gas purification device. It is.

〔従来の技術〕[Conventional technology]

従来、ハニカム形に一体成形されたセフミック製などの
筒体と触媒とからなる自動車排気ガスなどを浄化するた
めのハニカム触媒の両端の周縁部に金網を・カーμ巻し
て形成したクッション体を設け、ハニカム触媒の備局部
には波形状の金網を巻回してこれをケースの膨大部に収
容してなる自動車排気ガスの浄化装置が知られていた。
Conventionally, a cushion body was formed by wrapping a wire mesh around the periphery of both ends of a honeycomb catalyst for purifying automobile exhaust gas, etc., which was made of a cylinder body made of Cefmic or the like integrally molded into a honeycomb shape and a catalyst. An automobile exhaust gas purification device is known in which a corrugated wire mesh is wound around the central part of the honeycomb catalyst, and the wire mesh is housed in the large part of the case.

クッション体及び波形状の金網は、ハニカム触媒の寸法
の大きいバラツキに順応しつつそれを弾力的に支持して
振動よシ保護すると共に、ケースとハニカム触媒のあい
だからの排気ガスのリークを防止するだめのものである
The cushion body and the corrugated wire mesh accommodate large variations in the dimensions of the honeycomb catalyst, elastically support it, protect it from vibration, and prevent leakage of exhaust gas from between the case and the honeycomb catalyst. It's useless.

〔解決すべき問題点〕[Problems to be solved]

しかしながら、従来のクッション性と波形状の金網を介
在させる方式では、弾力的支持性にはすぐれるものの排
気ガスのリーク分の割合が5〜7チにも達し、ケースと
ハニカム触媒とのあいだの気密性に劣るという問題があ
った。
However, although the conventional method using cushioning and corrugated wire mesh has excellent elastic support, the rate of exhaust gas leakage reaches 5 to 7 inches, and the gap between the case and the honeycomb catalyst increases. There was a problem with poor airtightness.

〔問題点の解決手段〕[Means for solving problems]

本発明は、上記の問題点の兎服を目的としてなしたもの
であシ、耐熱性のV−μ材を耐熱性のカバーでシール材
が漏出しないように包蔵してなるクッション性を有する
シール用袋状マットを提供するものであり、これはハニ
カム触媒の側周方向の長さの全てにわたり巻き付けて使
用されるものである。
The present invention was made with the aim of solving the above-mentioned problem, and is a seal having cushioning properties, which is made by enclosing a heat-resistant V-μ material with a heat-resistant cover to prevent the sealant from leaking. The present invention provides a bag-shaped mat for use in a honeycomb catalyst, which is used by being wrapped around the entire circumferential length of a honeycomb catalyst.

〔実施例〕〔Example〕

第1図のように本発明のシール用袋状マット1は、耐熱
性のカバー2で耐熱性のシール材8をシール材が漏出し
ないように包蔵したものよりなっている。耐熱性のカバ
ーとしては、シール材の包蔵作業性や得られるマットの
耐振性、浄化装置の振動によシ微細化したシール材の漏
出防止性などの点で例えば金属箔、網目の細かい金網、
カーボン繊維クロスなどからなる袋が好ましく用いられ
るが、これに限定されず例えばシール材を包み込む方式
のシート様のものなどであってもよい。また、耐熱性の
シール材としては、例えば石綿、岩綿、七ラミック繊維
、カーボン繊維、ガラス繊維、スフブラーμ、金属繊維
のような耐熱性繊維、外径の小さいコイルのような耐熱
性線材、砂、炭酸力μシウム、金属粉、マイクロバルー
ンのような耐熱性粉粒体などが用いられる。耐熱性粉粒
体は、金属箔のようなフィルム状のものからなる袋に封
入することがそれらの漏出防止性の点で望ましい。
As shown in FIG. 1, the sealing bag-shaped mat 1 of the present invention is comprised of a heat-resistant sealing material 8 enclosed in a heat-resistant cover 2 to prevent the sealing material from leaking. As a heat-resistant cover, for example, metal foil, fine-mesh wire mesh,
A bag made of carbon fiber cloth or the like is preferably used, but the bag is not limited to this, and may be a sheet-like bag that wraps around the sealing material. In addition, heat-resistant sealing materials include, for example, asbestos, rock wool, heptaramic fiber, carbon fiber, glass fiber, Suffular μ, heat-resistant fibers such as metal fibers, heat-resistant wire materials such as coils with a small outer diameter, Sand, μsium carbonate, metal powder, heat-resistant powder such as micro balloons, etc. are used. It is desirable to encapsulate the heat-resistant powder in a bag made of a film-like material such as metal foil in order to prevent leakage.

本発明の7−/vJ@袋状マツ)1は、例えば第2図の
ようにマットを小さい袋状区画1aに区分するなどして
シール材が偏らないようにすることが、浄化装置に適用
した場合のシール性の点で望ましい。
7-/vJ@bag-shaped pine) 1 of the present invention can be applied to a purification device by dividing the mat into small bag-shaped sections 1a as shown in Fig. 2 to prevent the sealing material from being biased. This is desirable in terms of sealability when

また、シール用袋状マットlはクッション性を有してい
ることが、ハニカム触媒の寸法のバラツキを許容しつつ
ハニカム触媒を耐振的に、かつ、ハニカム触媒の破損の
原因となる過分な圧力がかからないようにケースに収容
するために必要である。さらに、シール用袋状マットは
ハニカム触媒の側肩部に容易に巻き付けることができる
程度の屈曲性を有していることが望ましい。
In addition, the sealing bag-shaped mat l has cushioning properties, which makes the honeycomb catalyst vibration-resistant while allowing for variations in the dimensions of the honeycomb catalyst, and prevents excessive pressure that may cause damage to the honeycomb catalyst. It is necessary to store it in a case so that it does not get damaged. Further, it is desirable that the sealing bag-shaped mat has enough flexibility to be easily wrapped around the side shoulder portion of the honeycomb catalyst.

本発明のシーμ用袋状マツ)1を用いての浄化装置の作
製は、例えば次のようにして行われる。
A purifying device using the bag-shaped pine for sea μ of the present invention) 1 is produced, for example, as follows.

すなわち、第8図のように本発明のシール用袋状マット
1を、円筒状に一体成形されたハニカム触[4の側肩部
の長さ方向(5)の全体に、かつ、側周方向の長さの全
てにわたシ巻き付けてこれを半割状のケー75の膨大部
に収賽することにより浄化装置が作製される。シール用
袋状マットをハニカム触媒の側周方向の長さの全てにわ
たシ巻き付けることにより、ハニカム触媒を振動によシ
破損させることなくケース内に収容維持することができ
る。
That is, as shown in FIG. 8, the sealing bag-shaped mat 1 of the present invention is applied over the entire lengthwise direction (5) of the side shoulder part of the honeycomb contact [4] integrally molded into a cylindrical shape, and also in the side circumferential direction. A purifying device is manufactured by wrapping the entire length of the wafer and collecting it in the enlarged part of the half-shaped case 75. By wrapping the sealing bag-shaped mat all the way around the length of the honeycomb catalyst in the lateral circumferential direction, the honeycomb catalyst can be housed and maintained in the case without being damaged by vibration.

一方、第4図のようにシール用袋状マットをハニカム触
媒の側肩部の長さ方向の一部に、かつ、側周方向の長さ
の全てにわたり巻き付けて、側肩部の長さ方向の一部の
みにシール用袋状マットが使用された浄化装置としても
よい。なお、6は金網を多層に重ねて形成したクッショ
ン体、7は波形状の金網である。
On the other hand, as shown in Fig. 4, a sealing bag-shaped mat is wrapped around a part of the side shoulder of the honeycomb catalyst in the length direction and the entire circumferential length of the side shoulder. It is also possible to have a purification device in which a sealing bag-shaped mat is used only in a part of the filtration system. Note that 6 is a cushion body formed by stacking wire mesh in multiple layers, and 7 is a corrugated wire mesh.

〔発明の効果〕〔Effect of the invention〕

本発明のシール用袋状マットによれば、排気ガス浄化装
置におけるハニカム触媒とケースとのあいだを気密的に
閉塞できて、排気ガスのリークがより確実に防止される
According to the sealing bag-shaped mat of the present invention, the gap between the honeycomb catalyst and the case in the exhaust gas purification device can be airtightly closed, and leakage of exhaust gas can be more reliably prevented.

また、本発明のシール用袋状マットは耐振性にすぐれて
おり、ハニカム触媒の側周方向の長さの全てにわたり巻
き付けられるので、ハニカム触媒の振動による破損が有
効に防止される。さらに、断熱性も有しているので、シ
ール用袋状マットの設置幅に対応してハニカム触媒の冷
却を有効に防止することができて、ハニカム触媒の排気
ガスに対する高率処理能力状態の維持が可能となる。
Furthermore, the sealing bag-shaped mat of the present invention has excellent vibration resistance and can be wrapped around the entire length of the honeycomb catalyst in the lateral circumferential direction, thereby effectively preventing damage to the honeycomb catalyst due to vibration. Furthermore, since it has heat insulating properties, it is possible to effectively prevent cooling of the honeycomb catalyst depending on the installation width of the sealing bag-shaped mat, and maintain the high rate processing capacity of the honeycomb catalyst for exhaust gas. becomes possible.

〔適用例、比較例〕[Application examples, comparative examples]

適用例1 直径10c+a、長さ20ccm、通過風量(圧力差二
276[1111水柱)40001/分のセラミック製
ハニカム触媒の側肩部に、厚さ70μmの銅箔製袋にロ
ックウールを封入して形成したシール用袋状マット(幅
16ca、長さ#7cm、厚さ5.0 mm )を巻き
付けて、これをステンレス製ケース内に収容することに
よシ排気ガス浄化装置(第8図仕様)を作製した。
Application example 1 Rock wool is sealed in a copper foil bag with a thickness of 70 μm on the side shoulder of a ceramic honeycomb catalyst with a diameter of 10 c+a, a length of 20 ccm, and a passing air flow rate (pressure difference of 2276 [1111 water columns)] of 40001/min. By wrapping the formed sealing bag-shaped mat (width 16 ca, length #7 cm, thickness 5.0 mm) and storing it in a stainless steel case, an exhaust gas purification device (Fig. 8 specifications) is created. was created.

なお、浄化装置におけるハニカム触媒の外周とステンレ
ス製ケースの内面との間隙は8.7 amであ・った。
In addition, the gap between the outer periphery of the honeycomb catalyst and the inner surface of the stainless steel case in the purification device was 8.7 am.

また、評価試験のためにハニカム触媒の両端は、あらか
じめステンレス線で閉塞し、通気不可とした。
In addition, for the evaluation test, both ends of the honeycomb catalyst were closed with stainless steel wire in advance to prevent ventilation.

次に、上記の排気ガス浄化装置を600℃の恒温槽内に
設置し、かつ、これに20Gの振動を与えた状態で該浄
化装置におけるケースの一方の開口を真空ポンプに接続
し、このポンプを作動して浄化装置内を276ffII
11水柱の減圧状態とし、この状態におけるケースの他
方の開口より流入する空気量を測定し、この測定値をリ
ーク量q(1/分)と評価して次式によシシール能(曇
)を求めた。
Next, the above exhaust gas purification device was installed in a constant temperature chamber at 600°C, and one opening of the case of the purification device was connected to a vacuum pump while applying 20G of vibration to it. 276ffII inside the purification device by operating the
11. Set the water column to a reduced pressure state, measure the amount of air flowing in from the other opening of the case in this state, evaluate this measured value as the leakage amount q (1/min), and calculate the sealing ability (fog) using the following formula. I asked for it.

ンー ル能 (%)  = −x  l  0 0試験
開始より10分後、10時間後のシール能を表に示した
Sealing ability (%) = -x l 0 0 The sealing ability 10 minutes and 10 hours after the start of the test is shown in the table.

適用例2 厚さ1mmの石英ガラス繊維クロヌからなる袋にセラミ
ック繊維わたを充てんしてなるシール用袋状マットを用
いたほかは適用例1と同様にして排気ガス浄化装置を作
製し、そのシール能を調べた。
Application Example 2 An exhaust gas purification device was manufactured in the same manner as Application Example 1, except that a sealing bag-like mat made by filling a bag made of quartz glass fiber Kuronu with a thickness of 1 mm with ceramic fiber cotton was used. I researched Noh.

結果を表に示した。The results are shown in the table.

適用例8 直径0.25mmのステンレス線をメリヤス編して形成
した網目が10メツシユの金網をカール巻きして6層重
ねたクッション体をハニカム触媒の両端の周縁部に設け
、一方、直径9.25mmのステンレス線を円筒状にメ
リヤス編して形成した網目が7メツシユの金網を偏平に
し、これに波付は圧縮加工を施した波形状(山と谷の差
約1 ctn )の金網(長さ11 cm )と、幅5
 cmの適用例1と同じ仕様のシール用袋状マットを組
合せて用い、これらを横に並べてハニカム触媒の側周部
に設けたほかは適用例1と同様にして排気ガス浄化装置
(第4図仕様)を作製し、そのシール能を調べた。結果
を表に示した。
Application Example 8 A cushion body consisting of 6 layers of wire mesh formed by knitting stainless steel wire with a diameter of 0.25 mm and having a mesh size of 10 meshes was provided on the periphery of both ends of a honeycomb catalyst. A wire mesh with a 7-mesh mesh formed by knitting 25 mm stainless steel wire into a cylindrical shape is flattened, and the corrugation is a wire mesh (long) with a corrugated shape (difference between peaks and valleys of about 1 ctn) that has been compressed. length 11 cm) and width 5
An exhaust gas purification device (Fig. Specifications) were prepared and their sealing ability was investigated. The results are shown in the table.

比較例 シール用袋状マットを用いた部分を、波形状の金網とし
たはかは、適用例3と同様にして排気ガス浄化装置を作
製し、そのシール能を調べた。結果を表に示した。
Comparative Example An exhaust gas purification device was fabricated in the same manner as in Application Example 3, using a corrugated wire mesh as the part where the sealing bag-shaped mat was used, and its sealing performance was investigated. The results are shown in the table.

シール能 (96) 適用例1  1.0     1.2 /21.1        1.0 〃81.8        2.0 比較例   7.8     7.1Seal Noh (96) Application example 1 1.0 1.2 /21.1 1.0 81.8 2.0 Comparative example 7.8 7.1

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明のシール用袋状マットの実施例の説明断
面図、第2図は他の実施例の斜視図、第8図、第4図は
シール用袋状マットを適用した浄化装置の構造例を表わ
した断面図である。 1ニジ−μ用袋状マット、2:耐熱性のカバー、8:耐
熱性のシール材、4:ハニカム触媒、5:ケース。
Fig. 1 is an explanatory sectional view of an embodiment of the sealing bag-shaped mat of the present invention, Fig. 2 is a perspective view of another embodiment, and Figs. 8 and 4 are purification devices to which the sealing bag-shaped mat is applied. FIG. 2 is a cross-sectional view showing a structural example of. 1: Niji-μ bag-shaped mat, 2: heat-resistant cover, 8: heat-resistant sealing material, 4: honeycomb catalyst, 5: case.

Claims (1)

【特許請求の範囲】[Claims] 1 一体に形成されたハニカム触媒をケースに収容して
なる排気ガス浄化装置における前記ハニカム触媒の側周
方向の長さの全てにわたって巻き付けられる、耐熱性の
シール材を耐熱性のカバーでシール材が漏出しないよう
に包蔵してなるクッション性を有するシール用袋状マッ
ト。
1. In an exhaust gas purification device in which an integrally formed honeycomb catalyst is housed in a case, a heat-resistant sealing material is wrapped around the entire circumferential length of the honeycomb catalyst with a heat-resistant cover. A sealing bag-shaped mat with cushioning properties that prevents leakage.
JP19627284A 1984-09-18 1984-09-18 Bagform mat for seal for exhaust gas purifying device Pending JPS6172819A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19627284A JPS6172819A (en) 1984-09-18 1984-09-18 Bagform mat for seal for exhaust gas purifying device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19627284A JPS6172819A (en) 1984-09-18 1984-09-18 Bagform mat for seal for exhaust gas purifying device

Publications (1)

Publication Number Publication Date
JPS6172819A true JPS6172819A (en) 1986-04-14

Family

ID=16355041

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19627284A Pending JPS6172819A (en) 1984-09-18 1984-09-18 Bagform mat for seal for exhaust gas purifying device

Country Status (1)

Country Link
JP (1) JPS6172819A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH061719U (en) * 1992-06-08 1994-01-14 中央発條株式会社 Exhaust gas purification device for vehicles by ceramics catalyst
WO1994010431A1 (en) * 1992-10-23 1994-05-11 Fibre Techniques Limited Method of producing fibrous material components
GB2451328A (en) * 2007-07-20 2009-01-28 Nichias Corp Low thermal conductivity holding material for catalytic converter

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH061719U (en) * 1992-06-08 1994-01-14 中央発條株式会社 Exhaust gas purification device for vehicles by ceramics catalyst
WO1994010431A1 (en) * 1992-10-23 1994-05-11 Fibre Techniques Limited Method of producing fibrous material components
GB2451328A (en) * 2007-07-20 2009-01-28 Nichias Corp Low thermal conductivity holding material for catalytic converter
US8128882B2 (en) 2007-07-20 2012-03-06 Nichias Corporation Catalytic converter, holding material for catalytic converter and production method thereof
GB2451328B (en) * 2007-07-20 2012-10-31 Nichias Corp Catalytic converter, holding material for catalytic converter and production method thereof
GB2491482A (en) * 2007-07-20 2012-12-05 Nichias Corp Low thermal conductivity holding material for catalytic converter
GB2491482B (en) * 2007-07-20 2013-01-16 Nichias Corp Catalytic converter,holding material for catalytic converter and production method thereof

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