JPS6159281B2 - - Google Patents
Info
- Publication number
- JPS6159281B2 JPS6159281B2 JP53043268A JP4326878A JPS6159281B2 JP S6159281 B2 JPS6159281 B2 JP S6159281B2 JP 53043268 A JP53043268 A JP 53043268A JP 4326878 A JP4326878 A JP 4326878A JP S6159281 B2 JPS6159281 B2 JP S6159281B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- polypeptide
- quaternary nitrogen
- containing cellulose
- cellulose ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001184 polypeptide Polymers 0.000 claims description 16
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 16
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 16
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 15
- 229920003086 cellulose ether Polymers 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 2
- 238000011282 treatment Methods 0.000 description 22
- 230000000694 effects Effects 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000000787 lecithin Substances 0.000 description 2
- 235000010445 lecithin Nutrition 0.000 description 2
- 229940067606 lecithin Drugs 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 239000002453 shampoo Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- -1 polyoxyethylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
この発明はポリペプチドと第４級窒素含有セル
ロースエーテルとを必須配合成分とする、髪仕上
げ効果のすぐれた毛髪処理剤組成物に関する。
最近、毛髪をとりまく環境はパーマネントウエ
ーブ、ヘアカラー、ホツトカラー、ドライヤーな
どの普及によつてますます厳しくなつており、ヘ
アリンス、ヘアトリートメントなどの毛髪処理剤
は、髪仕上げ効果のさらに改善されたものが要求
されるようになつた。
この種の毛髪処理剤は、これまでにも毛髪仕上
げ効果を出すために油性成分、レシチン、ラノリ
ン、ポリペプチドなどが添加されているのである
が、そうした従来製品では、毛髪の滑らかな仕上
りとより美しい髪づくりを要望する消費者にとつ
ては、もはや満足するに足る髪仕上げ効果を奏す
ることはできなくなつている。
その原因を分析すると、もともとこれらの添加
成分は毛髪に対する吸着力が弱く、単品では髪仕
上げ効果の小さいものである。
即ち、ヘアリンスやヘアトリートメントは、共
存する界面活性剤や水によつて、上記添加成分が
すすぎ洗い時に容易に流失してしまう。
この発明者は、最近の消費者の要望に応えるべ
く髪仕上げ効果のさらにすぐれた毛髪処理剤の開
発研究に鋭意努力した結果、基本的にポリペプチ
ドと第４級窒素含有セルロースエーテルとの組み
合せが、所期の目的を満足する新事実を見出すこ
とができた。
すなわち、この発明の毛髪処理剤組成物は、平
均分子量2000〜30000のポリペプチド0.1〜30％
（％は以下、重量基準）、第４級窒素含有率0.5〜
3.5％の第４級窒素含有セルロースエーテル0.05
〜５％を含有することを特徴とする。
なお、本明細書において毛髪処理剤とは、毛髪
の処理を主目的とするヘアリンスおよびヘアトリ
ートメント剤を意味し、毛髪洗浄を主目的とする
ヘアシヤンプーを含まないものとする。
さらに詳しく説明すると、必須成分の一つであ
るポリペプチドは下記一般式で表わされるように
アミノ基とカルボキシル基を併わせもつ物質で、
本質的にはこの発明はその製造の由来を問うもの
ではないが、実用的にはコラーゲン蛋白質の加水
分解物が好ましい。
（ただしＲはアルキル基を示す）
しかし、ポリペプチドの平均分子量はこの発明
にとつて本質的に重要な因子であり、2000〜
30000の範囲にあることが必要である。
なぜなら、平均分子量が2000未満の場合は、髪
の仕上げ効果が発現せず、この発明の目的が達成
されないからであり、また平均分子量が30000を
越える場合は、髪仕上げ効果が小さいだけでな
く、水不溶性となつて外観を劣化させ商品価値を
損なうためである。
またポリペプチドの配合量は、毛髪処理剤組成
物中に0.1〜30％必要で、0.1％未満であると、髪
仕上げ効果が小さく、30％を超えると水溶性が不
十分となり、商品価値および外観を劣化させる。
一方、この発明においてもう一つの必須成分で
ある第４級窒素含有セルロースエーテルは、下記
一般式の化合物で代表されるものであり、毛髪処
理剤組成物中に0.05〜５％配合することが必要で
ある。
ただし、式中R1、R2、R3はＨまたは
で表わされる置換基で、それぞれ異なるR4、
R5、R6、R7、ｍ、ｎ、ｐ、ｑをとりうる。
ｍ、ｎ、ｑはそれぞれ０ないし10の整数、ｐは
０ないし３の整数、R4、R5、R6はＨまたは
CH3、R7はCH3、C2H5またはC3H7、Ｘはハロゲ
ン、ｌは100から20000の数である。
また、グルコース単位あたりの（ｍ＋ｎ＋ｑ）
の平均値は１から３であり、ｐの平均値は0.1か
ら0.8、好ましくは0.2から0.5である。
この発明の目的にとつて好ましい第４級窒素含
有セルロースエーテルの商品名を挙げると、ユニ
オンカーバイド社製ポリマーJR−125、ポリマー
JR−400、ポリマーJR−30Mなどがある。
この発明の毛髪処理剤組成物は、上述したポリ
ペプチドおよび第４級窒素含有セルロースエーテ
ルを必須成分とするほか、汎用のヘアリンス、ヘ
アトリートメント等に含まれている常用成分、た
とえば界面活性剤、油性成分、レシチン、溶剤、
香料、殺菌剤、色素、キレート剤、紫外線吸収
剤、無機電解質、水溶性高分子などを用途に応じ
て適宜に配合することができる。
この発明の毛髪処理剤組成物によれば、従来の
毛髪化粧品に比べ、確実にすぐれた髪仕上げ効果
を得ることができる。
それは、必須成分のポリペプチドと第４級窒素
含有セルロースエーテルとが毛髪表面に吸着力の
強い複合塩を形成し、その被覆は水洗いでも流失
し難く、適度の水分保持性能を発揮するからだと
考えられる。
以下、実施例を挙げてこの発明の効果を具体的
に説明する。
なお、実施例では髪仕上げ効果として、下記の
要領で毛髪のまとまり易さ、櫛通り易さ、動摩擦
係数を評価するとともに、商品外観の適否をテス
トした。
Γ毛髪のまとまり易さ
毛束を毛髪処理剤組成物で処理し、標準品（比
較例１）を対照にしてテスター20名が一対比較法
により評価した。
評価基準は
＋＋：標準品よりまとまり易い
＋：標準品よりややまとまり易い
±：標準品と同等
Γ櫛通り易さ
髪のまとまり易さと同様の方法で評価した。
Γ動摩擦係数
毛束を毛髪処理剤組成物で処理したのち、フリ
クシヨン・コエフイシエント・メーター
（Friction Coefficient meter）で測定した。
Γ商品外観
毛髪処理剤組成物を所定の条件下で１ケ月保存
し、その外観を肉眼で観察して評価する。すなわ
ち、分離や沈殿析出等が生じていれば、商品価値
をそこねるので不適当×とし、それがなければ適
当〇とする。
実施例１〜２、比較例１〜３
ステアリルトリメチルアンモニウムクロライド
３％、プロピレングリコール10％、エタノール10
％、からなる混合系にポリペプチドおよび第４級
窒素含有セルロースエーテルを配合し、残部、精
製水を添加してヘアリンスを調製した。その性能
を評価した結果を表３に示す。
The present invention relates to a hair treatment composition having excellent hair finishing effects, which contains a polypeptide and a quaternary nitrogen-containing cellulose ether as essential ingredients. Recently, the environment surrounding hair has become increasingly harsh due to the spread of permanent waves, hair colors, hot colors, hair dryers, etc., and hair treatment agents such as hair rinses and hair treatments are becoming more and more effective. It has become required. This type of hair treatment agent has previously added oil-based ingredients, lecithin, lanolin, polypeptides, etc. to produce a hair finishing effect, but such conventional products do not provide a smooth finish to the hair. For consumers who desire beautiful hair, it is no longer possible to achieve a hair finishing effect that satisfies consumers. An analysis of the cause reveals that these added ingredients originally have a weak adsorption power to the hair, and when used alone, they have little effect on hair finishing. That is, in hair rinses and hair treatments, the above-mentioned additive components are easily washed away during rinsing due to coexisting surfactants and water. In order to meet recent consumer demands, the inventor made extensive efforts to research and develop a hair treatment agent with even better hair finishing effects, and as a result, the inventor discovered that the combination of a polypeptide and a quaternary nitrogen-containing cellulose ether was basically discovered. , we were able to discover new facts that satisfied our intended purpose. That is, the hair treatment composition of the present invention contains 0.1 to 30% of polypeptides having an average molecular weight of 2,000 to 30,000.
(% is based on weight below), quaternary nitrogen content 0.5~
3.5% quaternary nitrogen-containing cellulose ether 0.05
It is characterized by containing ~5%. In this specification, the hair treatment agent refers to a hair rinse and a hair treatment agent whose main purpose is to treat hair, and does not include a hair shampoo whose main purpose is to clean hair. To explain in more detail, polypeptide, which is one of the essential components, is a substance that has both an amino group and a carboxyl group, as represented by the general formula below.
Essentially, this invention does not question the origin of its production, but for practical purposes, collagen protein hydrolysates are preferred. (However, R represents an alkyl group.) However, the average molecular weight of the polypeptide is an essentially important factor for this invention;
Must be in the range of 30000. This is because if the average molecular weight is less than 2,000, the hair finishing effect will not be achieved and the object of this invention will not be achieved.If the average molecular weight is more than 30,000, not only will the hair finishing effect be small, but the hair finishing effect will not be achieved. This is because it becomes water-insoluble, deteriorating its appearance and impairing its commercial value. In addition, the amount of polypeptide blended in the hair treatment composition is required to be 0.1 to 30%; if it is less than 0.1%, the hair finishing effect will be small, and if it exceeds 30%, the water solubility will be insufficient, which will reduce the commercial value. Deteriorate appearance. On the other hand, the quaternary nitrogen-containing cellulose ether, which is another essential component in this invention, is represented by the compound of the following general formula, and must be blended in the hair treatment composition in an amount of 0.05 to 5%. It is. However, in the formula, R 1 , R 2 , R 3 are H or substituents represented by, each different R 4 ,
R 5 , R 6 , R 7 , m, n, p, and q can be taken. m, n, q are each an integer from 0 to 10, p is an integer from 0 to 3, R 4 , R 5 , R 6 are H or
CH 3 and R 7 are CH 3 , C 2 H 5 or C 3 H 7 , X is a halogen, and l is a number from 100 to 20,000. Also, (m+n+q) per glucose unit
The average value of p is from 1 to 3, and the average value of p is from 0.1 to 0.8, preferably from 0.2 to 0.5. Preferred trade names of quaternary nitrogen-containing cellulose ethers for the purpose of this invention include Polymer JR-125 manufactured by Union Carbide;
There are JR-400, Polymer JR-30M, etc. In addition to the above-mentioned polypeptide and quaternary nitrogen-containing cellulose ether as essential components, the hair treatment composition of the present invention also contains common ingredients contained in general-purpose hair rinses, hair treatments, etc., such as surfactants, oil-based Ingredients, lecithin, solvent,
Flavors, bactericidal agents, pigments, chelating agents, ultraviolet absorbers, inorganic electrolytes, water-soluble polymers, and the like can be blended as appropriate depending on the purpose. According to the hair treatment composition of the present invention, it is possible to reliably obtain superior hair finishing effects compared to conventional hair cosmetics. This is thought to be because the essential components polypeptide and quaternary nitrogen-containing cellulose ether form a complex salt with strong adsorption power on the hair surface, and the coating is difficult to wash away even when washed with water, and exhibits appropriate moisture retention performance. It will be done. Hereinafter, the effects of this invention will be specifically explained with reference to Examples. In addition, in the examples, as hair finishing effects, ease of hair bundling, ease of combing, and coefficient of dynamic friction were evaluated in the following manner, and suitability of product appearance was tested. Ease of bundling of Γ hair Hair strands were treated with a hair treatment composition and evaluated by 20 testers using a paired comparison method using a standard product (Comparative Example 1) as a control. The evaluation criteria were as follows: ++: Easier to tame than the standard product +: Slightly more tangled than the standard product ±: Easier to comb through the Γ comb, equivalent to the standard product Evaluation was made in the same manner as the ease of combing hair. Γ Dynamic Friction Coefficient After treating a hair bundle with a hair treatment composition, it was measured using a Friction Coefficient meter. Γ Product Appearance The hair treatment composition was stored under predetermined conditions for one month, and its appearance was visually observed and evaluated. In other words, if separation, precipitation, etc. occur, the product value will be impaired and it will be marked as unsuitable ×, and if there is no such occurrence, it will be marked as suitable. Examples 1-2, Comparative Examples 1-3 Stearyltrimethylammonium chloride 3%, propylene glycol 10%, ethanol 10
A hair rinse was prepared by blending the polypeptide and quaternary nitrogen-containing cellulose ether into a mixed system consisting of %, and adding purified water to the remainder. Table 3 shows the results of evaluating the performance.
【表】
表１によれば、ポリペプチドを添加した比較例
２は、市販品の比較例１に比べて同程度の髪仕上
げ効果を示すにすぎないが、ポリペプチドと第４
級窒素含有セルロースエーテルを併用した実施例
１および２のヘアリンスは、よりすぐれた髪仕上
げ効果を示すことが明らかである。また、平均分
子量1000のポリペプチドを用いた比較例３のヘア
リンスは、第４級窒素含有セルロースエーテルと
併用しても何らその効果を示さない。
実施例３〜４、比較例４〜５
プレシヤンプータイプのヘアトリートメントを
調製して、その性能を調べた。
すなわち、油性成分として100秒流動パラフイ
ン20％、ワセリン２％、ステアリルアルコール２
％、グリセリンモノステアレート２％、乳化剤と
してポリオキシエチレン（平均EO付加モル数
10）セチルエーテル３％、パルミチン酸ソーダ
0.5％、水層成分としてグリセリン５％とからな
る混合系にポリペプチドと第４級窒素含有セルロ
ースエーテルを配合し、残部、精製水を添加して
得られたヘアトリートメントの性能を試験した。[Table] According to Table 1, Comparative Example 2 in which polypeptide was added showed only the same level of hair finishing effect as Comparative Example 1, which was a commercially available product;
It is clear that the hair rinses of Examples 1 and 2 in combination with nitrogen-containing cellulose ether exhibit better hair finishing effects. Furthermore, the hair rinse of Comparative Example 3 using a polypeptide with an average molecular weight of 1000 does not exhibit any effect when used in combination with quaternary nitrogen-containing cellulose ether. Examples 3-4, Comparative Examples 4-5 Pre-shampoo type hair treatments were prepared and their performance was investigated. That is, as oily ingredients, 100 seconds liquid paraffin 20%, vaseline 2%, stearyl alcohol 2
%, glycerin monostearate 2%, polyoxyethylene as emulsifier (average number of moles of EO added)
10) Cetyl ether 3%, sodium palmitate
Polypeptide and quaternary nitrogen-containing cellulose ether were blended into a mixed system consisting of 0.5% glycerin and 5% glycerin as a water layer component, and purified water was added to the balance, and the performance of the hair treatment was tested.
【表】【table】
【表】
表４に明らかなように、ポリペプチドを単独に
配合した比較例14のヘアトリートメントは、通常
のヘアトリートメントである比較例13に比し、同
程度の髪仕上げ効果を示すにすぎないが、ポリペ
プチドと第４級窒素含有セルロースエーテルを併
用した実施例10および11のヘアトリートメント
は、顕著な髪仕上げ効果を発揮することができ
る。[Table] As is clear from Table 4, the hair treatment of Comparative Example 14, in which the polypeptide was blended alone, shows only the same level of hair finishing effect as Comparative Example 13, which is a normal hair treatment. However, the hair treatments of Examples 10 and 11 in which the polypeptide and the quaternary nitrogen-containing cellulose ether were used together can exhibit a remarkable hair finishing effect.
Claims (1)
30重量％と、第４級窒素含有率0.5〜3.5重量％の
第４級窒素含有セルロースエーテル0.05〜５重量
％を含有することを特徴とする毛髪処理剤組成
物。1 Polypeptide with average molecular weight 2000-30000 0.1-
30% by weight, and 0.05 to 5% by weight of a quaternary nitrogen-containing cellulose ether having a quaternary nitrogen content of 0.5 to 3.5% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4326878A JPS54138133A (en) | 1978-04-14 | 1978-04-14 | Hair preparations |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4326878A JPS54138133A (en) | 1978-04-14 | 1978-04-14 | Hair preparations |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54138133A JPS54138133A (en) | 1979-10-26 |
| JPS6159281B2 true JPS6159281B2 (en) | 1986-12-16 |
Family
ID=12659080
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4326878A Granted JPS54138133A (en) | 1978-04-14 | 1978-04-14 | Hair preparations |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS54138133A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01143784U (en) * | 1988-03-24 | 1989-10-03 | ||
| JPH03119231A (en) * | 1989-09-29 | 1991-05-21 | Mamoru Ogaki | Trough-hand 2 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57144213A (en) * | 1981-03-03 | 1982-09-06 | Kao Corp | Hair treatment |
| JPS635010A (en) * | 1986-06-24 | 1988-01-11 | Kao Corp | Cosmetic |
| US6627183B1 (en) | 1998-07-30 | 2003-09-30 | The Procter & Gamble Company | Hair care compositions |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4954551A (en) * | 1972-05-17 | 1974-05-27 | ||
| US3959463A (en) * | 1972-07-10 | 1976-05-25 | Bristol-Myers Company | Hair dressing compositions containing a hair substantive quaternary resin |
| US3990991A (en) * | 1974-02-01 | 1976-11-09 | Revlon, Inc. | Shampoo conditioner formulations |
| US4080310A (en) * | 1975-06-12 | 1978-03-21 | Beecham Group Limited | Amphoteric conditioning shampoo |
| JPS5338636A (en) * | 1976-09-17 | 1978-04-08 | Sunstar Inc | Hair and skin treatment agent |
-
1978
- 1978-04-14 JP JP4326878A patent/JPS54138133A/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4954551A (en) * | 1972-05-17 | 1974-05-27 | ||
| US3959463A (en) * | 1972-07-10 | 1976-05-25 | Bristol-Myers Company | Hair dressing compositions containing a hair substantive quaternary resin |
| US3990991A (en) * | 1974-02-01 | 1976-11-09 | Revlon, Inc. | Shampoo conditioner formulations |
| US4080310A (en) * | 1975-06-12 | 1978-03-21 | Beecham Group Limited | Amphoteric conditioning shampoo |
| JPS5338636A (en) * | 1976-09-17 | 1978-04-08 | Sunstar Inc | Hair and skin treatment agent |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01143784U (en) * | 1988-03-24 | 1989-10-03 | ||
| JPH03119231A (en) * | 1989-09-29 | 1991-05-21 | Mamoru Ogaki | Trough-hand 2 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54138133A (en) | 1979-10-26 |
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