JPS6151567B2 - - Google Patents
Info
- Publication number
- JPS6151567B2 JPS6151567B2 JP17199879A JP17199879A JPS6151567B2 JP S6151567 B2 JPS6151567 B2 JP S6151567B2 JP 17199879 A JP17199879 A JP 17199879A JP 17199879 A JP17199879 A JP 17199879A JP S6151567 B2 JPS6151567 B2 JP S6151567B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- weight
- formula
- finish
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 210000004209 hair Anatomy 0.000 claims description 93
- 239000000834 fixative Substances 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 20
- 229920001296 polysiloxane Polymers 0.000 claims description 13
- 239000002202 Polyethylene glycol Substances 0.000 claims description 12
- 229920001223 polyethylene glycol Polymers 0.000 claims description 12
- 239000004925 Acrylic resin Substances 0.000 claims description 11
- 229920000178 Acrylic resin Polymers 0.000 claims description 11
- -1 R5 is H Chemical group 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 description 24
- 239000011347 resin Substances 0.000 description 18
- 229920005989 resin Polymers 0.000 description 18
- 239000008266 hair spray Substances 0.000 description 8
- 230000006378 damage Effects 0.000 description 7
- 230000003699 hair surface Effects 0.000 description 7
- 230000001680 brushing effect Effects 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 206010044625 Trichorrhexis Diseases 0.000 description 4
- 239000003906 humectant Substances 0.000 description 4
- 239000006210 lotion Substances 0.000 description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000004909 Moisturizer Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000001333 moisturizer Effects 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 230000003700 hair damage Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000003719 hair strength Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Description
本発明は、毛髪に対し高いセツト性を付与し、
毛髪を種々の損傷から保護し得る毛髪固定剤に関
する。
一般に毛髪固定剤には、毛髪をセツト処理する
際に使用するセツトローシヨン及びセツトしたス
タイルを保持するためのヘアスプレーがある。通
常、毛髪固定剤は、毛髪固定用樹脂と種種の可塑
剤とから構成されており、水分による悪影響、即
ちカール保持力の低減およびべたつき等の悪い仕
上り感を除くために、できる限り水分を吸収又は
透過しないような組成とされている。そのため、
従来の毛髪固定剤を使用した場合、毛髪は必要な
水分量を保持できないためパサつき、しなやかさ
に欠け、破断強度が極度に弱くなる。従つて、セ
ツトする際やセツトを除去する際のブラツシング
等の機械力により、毛髪は損傷を受け、枝毛や切
毛を生じてしまう。特に、セツトローシヨンを用
いてドライヤー等による熱処理を行ないながら毛
髪をセツトする際に、上述の毛髪の損傷は著し
い。
このような事情から、理想的な毛髪固定剤は、
毛髪表面に均一な毛髪固定用樹脂皮膜を形成する
ことにより毛髪にセツト保持性および自然な仕上
り感を与え、加えて毛髪自身を健康な状態に維持
し得るものでなければならない。即ち、毛髪の適
性水分を維持し、こしがあり、自然な、かつしな
やかな毛髪を保つものでなければならないし、ま
た熱及びブラツシング等の機械力などの外的要因
から毛髪を保護するものでなければならない。
本発明者は、以上の要求を満足し得る毛髪固定
剤について鋭意研究を行なつた結果、汎用の毛髪
固定用樹脂であるアニオン系またはノニオン系樹
脂よりも吸湿性が高く、しかも仕上りがべとつか
ずに毛髪との付着力が強く、更にカール保持性の
ある両性高分子、特に両性アクリル系樹脂と、毛
髪の内部に吸収され毛髪の保湿効果を高め、自然
なしなやかさと、こしを与える低分子量のポリエ
チレングリコール（分子量200〜800）とを含有す
る毛髪固定剤が上述の要求を満足し得ることを見
出した。
また発明者らは、ある種のシリコーン油を更に
含有せしめることにより、毛髪表面に樹脂を均一
に付着させることができ、また光沢はもちろん潤
滑性を毛髪に与え、しかもセツトする際またはセ
ツトを除去する際のブラツシング等の機械力によ
り受ける毛髪の損傷を防止する効果を助長し得る
ことを見出した。
本発明はこのような知見に基づきなされたもの
である。即ち、本発明によると、下記の一般式(1)
に示すＡ，Ｂ単位からなる両性アクリル系樹脂
（分子量：30000ないし100000）0.3ないし10重量
％、一般式(2)のａ，ｂ，ｃ単位からなるポリオキ
シアルキレン変性オルガノポリシロキサン0.05な
いし３重量％、および200ないし800の分子量を有
するポリエチレングリコール0.02ないし３重量％
を含有することを特徴とする毛髪固定剤組成物が
提供される。
一般式(1)
Ａ：
Ｂ：
（式中、R1およびR3はＨまたはCH3、R2はC1
ないしC18のアルキル基、R4およびR6はC1ないし
C4のアルキレン基、R5はＨ、CH3またはC2H5、
ｍ／ｎは1/4ないし4/1のモル比である。）
一般式(2)
ａ：R′1またはR′2（OCqH2q）xＯ（CH2）p−
ｂ：
The present invention imparts high setting properties to hair,
This invention relates to a hair fixative that can protect hair from various damages. Generally, hair fixatives include setting lotions used to set hair and hair sprays for maintaining the set style. Usually, hair fixatives are composed of a hair fixing resin and various plasticizers, and absorb as much moisture as possible to eliminate the negative effects of moisture, such as reduced curl retention and poor finish such as stickiness. Or, it has a composition that does not allow it to pass through. Therefore,
When conventional hair fixatives are used, the hair becomes dry, lacks flexibility, and has extremely low breaking strength because it cannot retain the necessary amount of moisture. Therefore, mechanical forces such as brushing when setting or removing sets damage the hair, resulting in split ends and cut ends. In particular, when hair is set using a setting lotion while being subjected to heat treatment using a dryer or the like, the above-mentioned damage to the hair is significant. Under these circumstances, the ideal hair fixative is
By forming a uniform hair-fixing resin film on the hair surface, it must be able to give the hair set retention and a natural finish, and in addition, it must be able to maintain the hair itself in a healthy condition. In other words, it must maintain the proper moisture content of the hair, keep it stiff, natural, and supple, and it must also protect the hair from external factors such as heat and mechanical forces such as brushing. There must be. As a result of intensive research into a hair fixative that satisfies the above requirements, the present inventor found that it has higher hygroscopicity than anionic or nonionic resins, which are general-purpose hair fixing resins, and has a non-sticky finish. Ampholytic polymers, especially amphoteric acrylic resins, which have strong adhesion to hair and curl retention properties, and low molecular weight compounds that are absorbed into the hair and enhance the moisturizing effect of the hair, giving it natural suppleness and stiffness. It has been found that a hair fixative containing polyethylene glycol (molecular weight 200-800) can satisfy the above requirements. In addition, the inventors have found that by further containing a certain type of silicone oil, the resin can be uniformly adhered to the hair surface, and it can provide not only shine but also lubricity to the hair, and also be effective during setting or removing the set. It has been found that this method can promote the effect of preventing hair damage caused by mechanical forces such as brushing. The present invention has been made based on this knowledge. That is, according to the present invention, the following general formula (1)
0.3 to 10% by weight of an amphoteric acrylic resin (molecular weight: 30,000 to 100,000) consisting of A and B units shown in , and 0.05 to 3% by weight of a polyoxyalkylene-modified organopolysiloxane consisting of a, b, and c units of general formula (2) %, and 0.02 to 3% by weight of polyethylene glycol with a molecular weight of 200 to 800.
Provided is a hair fixative composition comprising: General formula (1) A: B: (In the formula, R 1 and R 3 are H or CH 3 , R 2 is C 1
to C 18 alkyl group, R 4 and R 6 are C 1 to
C4 alkylene group, R5 is H, CH3 or C2H5 ,
m/n is a molar ratio of 1/4 to 4/1. ) General formula (2) a: R′ 1 or R′ 2 (OC q H 2q ) x O(CH 2 ) p − b:
【式】および／または[expression] and/or
【式】
ｃ：−Si（R′1）3または
[Formula] c:-Si(R′ 1 ) 3 or
【式】
（式中、R′はメチル基または１部がフエニル
基、R′2は水素またはC1ないしC5のアルキル基、
ｐは１ないし５、ｑは２または３、ｘはオキシア
ルキレン基の平均数、ｓおよびＴはそれぞれ
〔―Si（R′1）2O〕―、〔―SiR′1（CH2）pO（ＣqＨ2q
Ｏ）xR′2〕Ｏ〕―
単位の平均数を表わし、且つｘ，ｓおよびＴは、
ポリオキシアルキレン基を当該共重合体全量の25
ないし70重量％含有し、粘度10ないし100センチ
ストークス（25℃）を満足するような数値であ
る。）
本発明の毛髪固定剤においては、毛髪固定用樹
脂として、吸湿性が高く、しかも仕上りがベとつ
かずに毛髪との付着力が強く、更にカール保持性
のある前述の一般式(1)で示すＡ，Ｂ単位からなる
両性アクリル系樹脂が使用されるが、この樹脂の
みでは潤滑性が不充分であるため、これに前述の
一般式(2)で示すａ，ｂ，ｃ単位からなるポリオキ
シアルキレン変性オルガノポリシロキサンを加え
ることにより、樹脂膜を毛髪表面に均一に拡散す
るとともに、樹脂表面の潤滑性を向上させ、それ
によつてブラツシング等の機械力から毛髪の損傷
を防ぎ、加えて毛髪に光沢を与えることができ
る。また本発明の毛髪固定剤においては、更に保
湿剤としてポリエチレングリコールが添加されて
いる。
本発明の毛髪固定剤組成物における両性アクリ
ル系樹脂の含有量は0.3ないし10重量％であり、
好ましくは１〜３重量％である。0.3重量％未満
では、本発明の効果が得られず、特にカール保持
性が劣り、10重量％を越えると、仕上り性が劣
り、特に仕上りが重く、ごわつき好ましくない。
また、ｍ／ｎが1/4未満では樹脂自体の吸湿性が
高過ぎ、カール保持性が劣り、仕上りがべたつ
き、4/1を越えると樹脂自体が硬くなり、仕上り
がごわつき好ましくない。
本発明の毛髪固定剤組成物におけるポリオキシ
アルキレン変性オルガノポリシロキサンとして
は、ポリオキシアルキレン基を該重合体全重量に
対して25ないし70重量％、好ましくは40ないし60
重量％含有し、且つ25℃において10ないし100セ
ンチストークスの粘度を有するものが好ましい。
即ち、該重合体全重量に対するポリオキシアルキ
レン基の量が25重量％未満の場合には、毛髪固定
用樹脂との相溶性が悪くなり、そのため樹脂膜が
濁り、仕上り時の光沢が劣化し、70重量％を越え
るとカール保持性が劣り、又潤滑性が劣り、好ま
しくない。また、粘度が低いと潤滑性が劣り、高
すぎると毛髪処理後の仕上りが重くなり、べたつ
き好ましくない。ポリオキシアルキレン変性オル
ガノポリシロキサンの添加量は毛髪固定剤組成物
重量の0.05ないし３重量％、好ましくは0.1ない
し0.2重量％であるが、0.05重量％未満では潤滑
性が劣り、３重量％を越えると仕上り性が劣化
し、好ましくない。
本発明の毛髪固定剤組成物においては、毛髪内
部に吸着し、毛髪の適正水分量を維持するため
に、更に保湿剤として、200ないし800の分子量を
有するポリエチレングリコールが0.02ないし３重
量％添加される。なお、エチレングリコール、ジ
エチレングリコール、トリエチレングリコール、
トリメチレングリコール、β―ブチレングリコー
ル、グリセリン等の低分子多価アルコールも保湿
性に優れているとされているが、これら物質は両
性アクリル系樹脂に吸着してしまうので保湿剤と
しての効果を発揮しない。また、これら物質の量
を増加させたとしても、高分子物質を可塑化し過
ぎ、仕上り性が劣るという弊害が生ずる。また、
分子量が800を越えるポリエチレングリコールは
毛髪の内部に吸着せず、保湿剤としての効果を発
揮しない上、仕上り性も劣化させる。保湿剤の量
が0.02重量％未満では、毛髪内部まで吸着する量
が不充分で保湿剤の効果が得られず、３重量％を
越えると、保湿剤が毛髪表面に多量に残存し、仕
上りを劣化させる。
本発明の毛髪固定剤組成物は、上記３成分の外
に種々の、通常この種の組成物に添加されている
化合物を含有することができる。例えば、溶剤と
してエタノールまたは水、エアゾールタイプのヘ
アスプレー用のプロペラントガスとして種々のハ
ロゲン化炭化水素、LPG、ジメチルエーテル等を
配合することができる。更に、本発明の目的を外
れない機能を有するものであるなら、化粧品汎用
基材、香料、色素等を添加することができる。
以上説明した本発明の毛髪固定剤組成物により
本発明の効果が得られる理由は明確ではないが、
恐らく次のように考えられる。即ち、両性アクリ
ル系樹脂は、分子構造面から明らかなように正，
負両方のイオン部を有しており、そのため毛髪へ
の吸着性が良好で、しかもそれ自体柔軟性があ
る。また、両性アクリル系樹脂は、その皮膜界面
に配位すると思われるシリコンの助けを借りて毛
髪の界面張力より低い界面張力を得、そのため毛
髪表面上に均一に拡散して均一な皮膜を形成し、
毛髪に対しカール保持性はもちろん柔軟性をも与
える。加えて、樹脂皮膜界面に配位するシリコン
は、毛髪に光沢はもちろん優れた潤滑性をも与
え、ブラツシング等による毛髪の損傷を防止する
効果を発揮する。また、分子量が200ないし800の
ポリエチレングリコールは、毛表皮を透過して毛
皮質中に入り、保湿剤としての効果を発揮して毛
髪の適正水分量を保持する。更にポリエチレング
リコールは、ドライヤー等を用いた際の過度の熱
による水分の発散を防止し、それによつて毛髪の
パサつきを防ぎ、しなやかさおよびこしを保持
し、毛髪の破断強度を弱めずセツト時のブラツシ
ング等の機械力から毛髪を保護する。
以下に本発明の実施例を示し、本発明を更に具
体的に説明する。
実施例 １
表１に示す組成の毛髪固定剤を調整し、ポンプ
式スプレータイプのセツトローシヨンとして下記
各試験法により評価を行なつた。その結果を表２
に示す。なお、両性アクリル系樹脂としては下記
の式〔〕に示すもの、ポリオキシエチレン変性
オルガノポリシロキサンとしては式〔〕に示す
ものを用いた。
(1) カール保持性
長さ25cm、重さ２ｇの毛束に本発明の毛髪固定
剤を0.5ｇ散布し、充分に櫛通しを行なつて毛束
全体に毛髪固定剤を馴じませ、その後毛束をロツ
ドに巻いて70ないし80℃の温度で１時間乾燥し、
次いで毛束をデシケータ中にて冷却し、カールの
ついた毛束をロツドから外し、25℃、80％RHの
箱内につるして、次の要領でカール保持性を評価
した。
即ち、箱内につるした直後の毛束の長さをカー
ル保持率100％とし、カールが伸びきつて元に復
元した毛束の長さ（25cm）をカール保持率０％と
し、下式に基いてカール保持率を算出した。ただ
し、数値は２時間後のカール保持率とする。
カール保持率（％）＝Ｌ−Ｌｔ／Ｌ−Ｌ０×100
〔式中、Ｌはカールしていない元の毛束の長さ
（25cm）、Ｌtは２時間後の毛束の長さ、L0は25
℃、80％RHの箱内に入れた直後の毛束の長さ〕
(2) 仕上り性
長さ25cm、重さ10ｇの無損傷の毛髪で毛束を作
り、これに本発明の毛髪固定剤を2.0ｇ散布し、
充分に櫛通しを行なつて毛束全体に毛髪固定剤を
馴じませ、乾燥後に20名のテスターにより、ごわ
つきの無さ、べたつきの無さ、光沢および櫛通し
易さの評価を行なつた。
評価基準
〇：良好
△：やや悪い
×：悪い
(3) 熱損傷防止性
仕上り性評価試験と同様の条件で処理された毛
束に毛髪固定剤を2.0ｇ散布し、充分に櫛通しを
行なつて毛束全体に毛髪固定剤を馴じませ、70〜
80℃の熱風で５分間乾燥して下記の基準により評
価を行なつた。
(イ) 熱または熱風による毛髪表面の荒れ（パサつ
き）：パサつきが無ければ〇、若干パサつきを
感じれば△、パサつきがあれば×、と評価す
る。
(ロ) 熱または熱風による毛髪強度の低下（枝毛、
切れ毛）：熱風乾燥処理の後、ナイロン製ブラ
シで100回ブラツシングを施し、毛髪100本あた
りの枝毛、切れ毛の発生本数を数える。
一般式〔〕
一般式〔〕
[Formula] (wherein, R' is a methyl group or a partially phenyl group, R' 2 is hydrogen or a C 1 to C 5 alkyl group,
p is 1 to 5, q is 2 or 3, x is the average number of oxyalkylene groups, s and T are respectively [-Si(R' 1 ) 2 O]-, [-SiR' 1 (CH 2 ) p O (C q H 2q
O) x R' 2 ]O] - represents the average number of units, and x, s and T are
The polyoxyalkylene group is 25% of the total amount of the copolymer.
The content is 70% by weight and the viscosity is 10 to 100 centistokes (25°C). ) In the hair fixative of the present invention, the above-mentioned general formula (1) is used as a hair fixing resin, which has high hygroscopicity, does not leave a sticky finish, has strong adhesion to hair, and has curl retention properties. An amphoteric acrylic resin consisting of A and B units represented by is used, but since this resin alone has insufficient lubricity, it is added to this resin consisting of a, b, and c units represented by the general formula (2) above. By adding polyoxyalkylene-modified organopolysiloxane, the resin film is uniformly spread over the hair surface, and the lubricity of the resin surface is improved, thereby preventing hair damage from mechanical forces such as brushing. It can give shine to hair. Moreover, in the hair fixative of the present invention, polyethylene glycol is further added as a humectant. The content of the amphoteric acrylic resin in the hair fixative composition of the present invention is 0.3 to 10% by weight,
Preferably it is 1 to 3% by weight. If it is less than 0.3% by weight, the effects of the present invention cannot be obtained, and curl retention is particularly poor, and if it exceeds 10% by weight, the finish is poor, especially the finish is heavy and stiff, which is not desirable.
If m/n is less than 1/4, the hygroscopicity of the resin itself will be too high, the curl retention will be poor, and the finish will be sticky, while if m/n exceeds 4/1, the resin itself will become hard and the finish will be stiff, which is undesirable. The polyoxyalkylene-modified organopolysiloxane in the hair fixative composition of the present invention contains polyoxyalkylene groups in an amount of 25 to 70% by weight, preferably 40 to 60% by weight based on the total weight of the polymer.
% by weight and has a viscosity of 10 to 100 centistokes at 25°C.
That is, if the amount of polyoxyalkylene groups is less than 25% by weight based on the total weight of the polymer, the compatibility with the hair fixing resin will be poor, and the resin film will become cloudy and the finished gloss will deteriorate. If it exceeds 70% by weight, curl retention and lubricity will be poor, which is not preferable. Furthermore, if the viscosity is low, the lubricity will be poor, and if the viscosity is too high, the finish after hair treatment will be heavy and sticky, which is undesirable. The amount of polyoxyalkylene-modified organopolysiloxane added is 0.05 to 3% by weight, preferably 0.1 to 0.2% by weight, based on the weight of the hair fixative composition, but if it is less than 0.05% by weight, the lubricity will be poor, and if it exceeds 3% by weight. and the finish quality deteriorates, which is not desirable. In the hair fixative composition of the present invention, 0.02 to 3% by weight of polyethylene glycol having a molecular weight of 200 to 800 is further added as a humectant in order to adsorb into the hair and maintain the appropriate moisture content of the hair. Ru. In addition, ethylene glycol, diethylene glycol, triethylene glycol,
Low-molecular-weight polyhydric alcohols such as trimethylene glycol, β-butylene glycol, and glycerin are also said to have excellent moisturizing properties, but these substances are adsorbed to amphoteric acrylic resins, so they are not effective as humectants. do not. Furthermore, even if the amount of these substances is increased, the polymeric substance will be too plasticized, resulting in poor finishing properties. Also,
Polyethylene glycol with a molecular weight exceeding 800 does not adsorb to the inside of the hair, is not effective as a moisturizer, and also deteriorates the finish. If the amount of moisturizer is less than 0.02% by weight, the amount absorbed to the inside of the hair will be insufficient and the moisturizing effect will not be obtained, and if it exceeds 3% by weight, a large amount of the moisturizer will remain on the hair surface and the finish will be affected. deteriorate. The hair fixative composition of the present invention can contain, in addition to the above three components, various compounds that are usually added to this type of composition. For example, ethanol or water can be blended as a solvent, and various halogenated hydrocarbons, LPG, dimethyl ether, etc. can be blended as a propellant gas for aerosol type hair sprays. Furthermore, general-purpose cosmetic base materials, fragrances, pigments, etc. can be added as long as they have functions that do not depart from the purpose of the present invention. Although the reason why the effects of the present invention can be obtained by the hair fixative composition of the present invention explained above is not clear,
It can probably be thought of as follows. That is, as is clear from the molecular structure, amphoteric acrylic resin has positive,
It has both negative and negative ionic moieties, so it has good adsorption to hair and is flexible itself. In addition, amphoteric acrylic resins obtain an interfacial tension lower than that of hair with the help of silicone, which is thought to be coordinated at the interface of the film, and therefore diffuse evenly over the hair surface to form a uniform film. ,
It gives curl retention as well as flexibility to the hair. In addition, the silicone coordinating at the interface of the resin film not only provides gloss but also provides excellent lubricity to the hair, and is effective in preventing damage to the hair due to brushing and the like. In addition, polyethylene glycol with a molecular weight of 200 to 800 penetrates the hair epidermis and enters the fur, exhibiting the effect as a humectant and maintaining the appropriate moisture content of the hair. Furthermore, polyethylene glycol prevents moisture from escaping due to excessive heat when using a hair dryer, etc., thereby preventing the hair from becoming dry, maintaining suppleness and stiffness, and improving the strength of the hair when it is set without weakening its breaking strength. Protects hair from mechanical forces such as brushing. Examples of the present invention will be shown below to further specifically explain the present invention. Example 1 A hair fixative having the composition shown in Table 1 was prepared and evaluated as a pump spray type setting lotion using the following test methods. Table 2 shows the results.
Shown below. As the amphoteric acrylic resin, one shown in the following formula [] was used, and as the polyoxyethylene-modified organopolysiloxane, one shown in the formula [] was used. (1) Curl retention Sprinkle 0.5g of the hair fixative of the present invention on a hair bundle with a length of 25cm and a weight of 2g, comb thoroughly to apply the hair fixative to the entire hair bundle, and then Wrap the hair bundle into a rod and dry for 1 hour at a temperature of 70 to 80 degrees Celsius.
Next, the hair bundle was cooled in a desiccator, and the curled hair bundle was removed from the rod and hung in a box at 25° C. and 80% RH, and curl retention was evaluated in the following manner. In other words, the length of the hair bundle immediately after hanging in the box is considered to be 100% of the curl retention rate, and the length of the hair bundle (25 cm) that has been restored to its original shape after the curl has grown out is considered to be 0% of the curl retention rate. Based on this, the curl retention rate was calculated. However, the numerical value is the curl retention rate after 2 hours. Curl retention rate (%) = L - L t / L - L 0 × 100 [In the formula, L is the length of the original uncurled hair bundle (25 cm), and L t is the length of the hair bundle after 2 hours. Well, L 0 is 25
Length of the hair bundle immediately after placing it in a box at ℃ and 80% RH] (2) Finishing property A hair bundle is made from undamaged hair with a length of 25 cm and a weight of 10 g, and the hair fixative of the present invention is applied to this hair bundle. Spread 2.0g of
Thoroughly comb the hair to apply the hair fixative to the entire hair strand, and after drying, 20 testers evaluated the lack of stiffness, stickiness, shine, and ease of combing. . Evaluation criteria 〇: Good △: Fairly bad ×: Bad (3) Heat damage prevention property Spray 2.0g of hair fixative on hair strands treated under the same conditions as in the finish evaluation test, and thoroughly comb through the hair. Apply the hair fixative to the entire hair bundle, and
It was dried with hot air at 80°C for 5 minutes and evaluated according to the following criteria. (b) Roughness of the hair surface due to heat or hot air (dryness): If there is no dryness, the hair is evaluated as ○, if it feels slightly dry, it is △, and if it is dry, it is evaluated as ×. (b) Decreased hair strength due to heat or hot air (split ends,
Hair breakage): After hot air drying, brush 100 times with a nylon brush and count the number of split ends and breakage per 100 hairs. General formula [] General formula []
【表】【table】
【表】
前記組成物No.１ないし15のうち、No.１，No.14お
よびNo.15は本発明の組成物であり、組成物No.２な
いし13は比較例である。
表２から明らかなように、本発明の組成物は、
セツトローシヨンとしてカール保持性、仕上り性
および熱損傷防止性が非常に優れており、これに
対し比較例はかなり劣つた性能しか示していな
い。即ち、ポリエチレングリコールを含有しない
No.２は熱処理によつて毛髪はパサつき、損傷し易
く、ポリオキシエチレン変性オルガノポリシロキ
サンを含まないNo.３は毛髪の仕上り性特に光沢お
よび櫛通し性が劣り、更にポリエチレングリコー
ルおよびポリオキシエチレン変性オルガノポリシ
ロキサンを共に含まないNo.４は仕上り性および熱
損傷防止性ともにかなり劣る。本発明の両性アク
リル系樹脂よりも両性ユニツトが少ない樹脂を使
用したNo.５では仕上りがごわつき好ましくなく、
逆に両性ユニツトが多い樹脂を使用したNo.６では
カール保持性および仕上りのべたつきがあり好ま
しくない。本発明の範囲外の高分子量のポリエチ
レングリコールを使用したNo.７では毛髪表面上に
ポリエチレングリコールが残存し、仕上りがべた
つき好ましくない。また本発明の範囲外の低分子
量の多価アルコールであるジエチレングリコー
ル、トリメチレングリコール、β―ブチレングリ
コールをそれぞれ用いたNo.８，９，10は毛髪内部
に吸着しきれず、樹脂を可塑化し過ぎ、カール保
持性および仕上り性を劣化させるので好ましくな
い。本発明の範囲外のポリオキシエチレン変性オ
ルガノポリシロキサンを用いたNo.11，12，13につ
いては、まずポリオキシエチレン含有量が少ない
No.11では光沢が劣り、多すぎるNo.12では光沢が劣
るのはもちろん仕上りがべたつき、櫛通しも劣
り、また、粘度が高いNo.13では仕上りがべたつき
好ましくない。
市販セツトローシヨンについても同様の評価を
行なつたところ、カール保持性が優れているもの
は仕上りがごわつき、仕上りがごわつかないもの
はカール保持性が劣り、仕上りがべたつき、全て
の項目を満足し得るものはない。
実施例 ２
以下に示す組成の本発明の毛髪固定剤を調整
し、エアゾールタイプのヘアスプレーとして下記
各試験法により評価を行ない、市販ヘアスプレー
と比較した。その結果を表３に示す。
(1) カール保持性
長さ25cm、重さ２ｇの毛束に水を0.5ｇ散布し
その後、毛束をロツドに巻き70〜80℃の温度で１
時間乾燥させ、その後、毛髪をデシケーター中に
て冷却し、カールのついた毛束をロツドから外
し、ヘアスプレーを0.5ｇ散布し、25℃：80％RH
の箱内につるして、実施例１に記載した要領で２
時間後のカール保持率を算出しカール保持性を評
価した。
(2) 仕上り性
長さ25cm、重さ10ｇの毛束にヘアスプレーを毛
束全体に均一に２ｇ散布し、乾燥後にテスター20
名により、ごわつきのなさ、べたつきのなさ、光
沢及び櫛通り易さについて評価を行なつた。
評価基準
〇 良い
△ やや悪い
× 悪い
組 成
両性アクリル系樹脂（式〔〕に示すもので
ｍ／ｎ＝1/2、平均分子量60000） ：1.0重量％
ポリエチレングリコール（分子量600）
：0.05重量％
ポリオキシエチレン変性オルガノポリシロキサ
ン（式〔〕に示すものでポリオキシエチレン
含有量：60％、粘度30cs） ：0.1重量％
香 料 ：少量
エタノール ：48.85重量％
トリクロルモノフルオロメタン ：20.0重量％
ジクロルジフルオロメタン ：30.0重量％[Table] Among the compositions No. 1 to 15, No. 1, No. 14, and No. 15 are compositions of the present invention, and compositions No. 2 to 13 are comparative examples. As is clear from Table 2, the composition of the present invention is
As a setting agent, the curl retention properties, finishing properties, and heat damage prevention properties are very excellent, whereas the comparative examples show considerably inferior performance. That is, it does not contain polyethylene glycol.
With No. 2, the hair becomes dry and easily damaged due to heat treatment, and with No. 3, which does not contain polyoxyethylene-modified organopolysiloxane, the finish of the hair, especially gloss and combability, is poor. No. 4, which does not contain ethylene-modified organopolysiloxane, is considerably inferior in both finish quality and heat damage prevention properties. No. 5, which uses a resin with fewer amphoteric units than the amphoteric acrylic resin of the present invention, has a stiff finish, which is not desirable.
On the other hand, No. 6, which uses a resin with a large amount of amphoteric units, is undesirable because it has poor curl retention and a sticky finish. In No. 7, which used polyethylene glycol with a high molecular weight outside the scope of the present invention, the polyethylene glycol remained on the hair surface, resulting in an undesirable sticky finish. In addition, Nos. 8, 9, and 10, which use low molecular weight polyhydric alcohols outside the scope of the present invention, such as diethylene glycol, trimethylene glycol, and β-butylene glycol, respectively, cannot be completely adsorbed inside the hair, and the resin becomes too plasticized. This is not preferable because it deteriorates curl retention and finishing properties. Regarding Nos. 11, 12, and 13 that use polyoxyethylene-modified organopolysiloxane outside the scope of the present invention, first of all, the polyoxyethylene content is low.
With No. 11, the gloss is poor, with too much No. 12, the gloss is poor, the finish is sticky, and combing is poor, and with No. 13, which has a high viscosity, the finish is sticky, which is not desirable. A similar evaluation of commercially available settling lotions revealed that those with excellent curl retention had a stiff finish, while those with a non-stiff finish had poor curl retention and a sticky finish, and all items were satisfied. There's nothing to gain. Example 2 A hair fixative of the present invention having the composition shown below was prepared and evaluated as an aerosol type hair spray using the following test methods and compared with a commercially available hair spray. The results are shown in Table 3. (1) Curl retention Sprinkle 0.5g of water on a hair bundle with a length of 25cm and a weight of 2g.Then, wrap the hair bundle into a rod and heat it at a temperature of 70 to 80℃.
After drying the hair for an hour, the hair was cooled in a desiccator, the curled hair bundle was removed from the rod, and 0.5g of hairspray was sprayed on the hair, 25℃: 80%RH.
2 in the same manner as described in Example 1.
Curl retention was evaluated by calculating the curl retention rate after a period of time. (2) Finishing property Spray 2g of hairspray evenly over the entire hair bundle with a length of 25cm and a weight of 10g, and after drying, apply a tester 20
Based on the name, evaluations were made on the lack of stiffness, non-stickiness, gloss, and ease of combing. Evaluation criteria: Good △ Slightly bad × Bad Composition Amphoteric acrylic resin (shown in formula [], m/n = 1/2, average molecular weight 60000): 1.0% by weight Polyethylene glycol (molecular weight 600)
: 0.05% by weight Polyoxyethylene-modified organopolysiloxane (as shown in formula [], polyoxyethylene content: 60%, viscosity 30cs) : 0.1% by weight Fragrance: Small amount Ethanol: 48.85% by weight Trichloromonofluoromethane: 20.0 Weight% Dichlorodifluoromethane: 30.0% by weight
【表】【table】
【表】
表３から明らかなように、本発明のヘアスプレ
ー組成物は優れたカール保持力および仕上り性を
示すが、市販のヘアスプレー組成物には全ての特
性を満足するものは見当らない。[Table] As is clear from Table 3, the hair spray composition of the present invention exhibits excellent curl retention and finishing properties, but no commercially available hair spray composition satisfies all of the properties.
Claims (1)
子量30000ないし100000の両性アクリル系樹脂0.3
ないし10重量％、一般式(2)のａ，ｂ，ｃ単位から
なるポリオキシアルキレン変性オルガノポリシロ
キサン0.05ないし３重量％、および200ないし800
の分子量を有するポリエチレングリコール0.02な
いし３重量％を含有することを特徴とする毛髪固
定剤組成物。 一般式(1) Ａ： Ｂ： （式中、R1およびR3はＨまたはCH3、R2はC1
ないしC18のアルキル基、R4およびR6はC1ないし
C4のアルキレン基、R5はＨ、CH3またはC2H5、
ｍ／ｎは1/4ないし4/1のモル比である。） 一般式(2) ａ：R′1またはR′2（OCqH2q）xＯ（CH2）p− ｂ：【式】および／または 【式】 ｃ：−Si（R′1）3または
【式】 （式中、R′1はメチル基または１部がフエニル
基、R′2は水素またはC1ないしC5のアルキル基、
ｐは１ないし５、ｑは２または３、ｘはオキシア
ルキレン基の平均数、ｓおよびＴはそれぞれ 〔―Si（R′1）2O〕―、〔―SiR′1〔（CH2）pO（ＣqＨ
2q
Ｏ）xR′2〕Ｏ〕― 単位の平均数を表わし、且つｘ，ｓおよびＴは、
ポリオキシアルキレン基を当該共重合体全量の25
ないし70重量％含有し、粘度10ないし100センチ
ストークス（25℃）を満足するような数値であ
る。） ２ 前記ポリオキシアルキレン変性オルガノポリ
シロキサンの含有量は0.1ないし0.2重量％である
特許請求の範囲第１項記載の毛髪固定剤組成物。[Claims] 1. An amphoteric acrylic resin having a molecular weight of 30,000 to 100,000 and consisting of A and B units represented by the following general formula (1): 0.3
0.05 to 10% by weight, 0.05 to 3% by weight of a polyoxyalkylene-modified organopolysiloxane consisting of a, b, c units of general formula (2), and 200 to 800% by weight.
A hair fixative composition comprising 0.02 to 3% by weight of polyethylene glycol having a molecular weight of . General formula (1) A: B: (In the formula, R 1 and R 3 are H or CH 3 , R 2 is C 1
to C 18 alkyl group, R 4 and R 6 are C 1 to
C4 alkylene group, R5 is H, CH3 or C2H5 ,
m/n is a molar ratio of 1/4 to 4/1. ) General formula (2) a: R′ 1 or R′ 2 (OC q H 2q ) x O(CH 2 ) p − b: [Formula] and/or [Formula] c: −Si(R′ 1 ) 3 or [Formula] (wherein, R′ 1 is a methyl group or partially phenyl group, R′ 2 is hydrogen or a C 1 to C 5 alkyl group,
p is 1 to 5, q is 2 or 3, x is the average number of oxyalkylene groups, s and T are [-Si(R' 1 ) 2 O]-, [-SiR' 1 [(CH 2 ) p O(C q H
2q
O) x R' 2 ]O] - represents the average number of units, and x, s and T are
The polyoxyalkylene group is 25% of the total amount of the copolymer.
The content is 70% by weight and the viscosity is 10 to 100 centistokes (25°C). 2. The hair fixative composition according to claim 1, wherein the content of the polyoxyalkylene-modified organopolysiloxane is 0.1 to 0.2% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17199879A JPS5692811A (en) | 1979-12-27 | 1979-12-27 | Hair-setting agent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17199879A JPS5692811A (en) | 1979-12-27 | 1979-12-27 | Hair-setting agent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5692811A JPS5692811A (en) | 1981-07-27 |
| JPS6151567B2 true JPS6151567B2 (en) | 1986-11-10 |
Family
ID=15933623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17199879A Granted JPS5692811A (en) | 1979-12-27 | 1979-12-27 | Hair-setting agent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5692811A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02253190A (en) * | 1989-03-27 | 1990-10-11 | Jeol Ltd | Moving position detecting mechanism |
| JPH082754Y2 (en) * | 1990-05-24 | 1996-01-29 | 矢崎総業株式会社 | Outer pinion type totalizer |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5139037A (en) * | 1982-01-15 | 1992-08-18 | L'oreal | Cosmetic composition for treating keratin fibres, and process for treating the latter |
| LU83876A1 (en) * | 1982-01-15 | 1983-09-02 | Oreal | COSMETIC COMPOSITION FOR TREATMENT OF KERATINIC FIBERS AND METHOD FOR TREATING THE SAME |
| JP2554515B2 (en) * | 1988-01-12 | 1996-11-13 | 株式会社資生堂 | Hair cosmetics |
| US5658557A (en) * | 1989-08-07 | 1997-08-19 | The Procter & Gamble Company | Hair care compositions comprising silicone-containing copolymers |
| EP0878184A3 (en) * | 1989-08-07 | 1998-12-16 | The Procter & Gamble Company | Hair conditioning and styling compositions |
| US5472686A (en) | 1990-12-28 | 1995-12-05 | Nippon Unicar Company Limited | Cosmetic formulations |
| US5468477A (en) * | 1992-05-12 | 1995-11-21 | Minnesota Mining And Manufacturing Company | Vinyl-silicone polymers in cosmetics and personal care products |
| FR2709955B1 (en) * | 1993-09-15 | 1995-10-20 | Oreal | Cosmetic compositions containing a linear polysiloxane-polyoxyalkylene block copolymer and an amphoteric polymer, and their uses. |
| BR9510141A (en) * | 1995-01-09 | 1997-12-30 | Procter & Gamble | Aqueous composition to fix hair |
| US5653969A (en) * | 1996-03-21 | 1997-08-05 | The Procter & Gamble Company | Low residue hair care compositions |
| US5653968A (en) * | 1996-03-21 | 1997-08-05 | The Proctor & Gamble Company | Rinse-off hair care compositions |
| US5665337A (en) * | 1996-03-21 | 1997-09-09 | The Procter & Gamble Company | Low residue hair care compositions using grafted copolymers |
| US5667771A (en) * | 1996-03-21 | 1997-09-16 | The Procter & Gamble Company | Rinse-off hair care compositions using grafted copolymers |
| US5804173A (en) * | 1996-09-04 | 1998-09-08 | The Procter & Gamble Company | Personal care compositions |
| US5863527A (en) * | 1996-09-04 | 1999-01-26 | The Proctor & Gamble Company | Personal care compositions |
| US5916548A (en) * | 1996-09-04 | 1999-06-29 | The Procter & Gamble Company | Personal care compositions |
| US5830447A (en) * | 1996-09-04 | 1998-11-03 | The Procter & Gamble Company | Personal care compositions |
| FR2758334B1 (en) * | 1997-01-14 | 1999-05-21 | Oreal | THICK AQUEOUS COMPOSITION COMPRISING AN AMPHIPHILIC POLYMER AND A POLYOXYALKYLENE SILICONE AND USE IN COSMETICS |
| US6555117B2 (en) | 1997-04-25 | 2003-04-29 | The Procter & Gamble Company | Personal care compositions containing linear toughened silicone grafted polymers |
| US6165457A (en) * | 1997-05-12 | 2000-12-26 | The Procter & Gamble Company | Personal care compositions containing toughened grafted polymers |
| JP4656781B2 (en) * | 2001-09-10 | 2011-03-23 | 株式会社ミルボン | Hair foam |
-
1979
- 1979-12-27 JP JP17199879A patent/JPS5692811A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02253190A (en) * | 1989-03-27 | 1990-10-11 | Jeol Ltd | Moving position detecting mechanism |
| JPH082754Y2 (en) * | 1990-05-24 | 1996-01-29 | 矢崎総業株式会社 | Outer pinion type totalizer |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5692811A (en) | 1981-07-27 |
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