JPS6146426B2 - - Google Patents
Info
- Publication number
- JPS6146426B2 JPS6146426B2 JP56107980A JP10798081A JPS6146426B2 JP S6146426 B2 JPS6146426 B2 JP S6146426B2 JP 56107980 A JP56107980 A JP 56107980A JP 10798081 A JP10798081 A JP 10798081A JP S6146426 B2 JPS6146426 B2 JP S6146426B2
- Authority
- JP
- Japan
- Prior art keywords
- infrared
- far
- powder
- emissivity
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 8
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004568 cement Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910052573 porcelain Inorganic materials 0.000 claims description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims 1
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 239000000919 ceramic Substances 0.000 description 17
- 239000000203 mixture Substances 0.000 description 6
- 230000005855 radiation Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- -1 nugnesia Chemical compound 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 235000013594 poultry meat Nutrition 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Gas Burners (AREA)
- Compositions Of Oxide Ceramics (AREA)
Description
〔発明の目的〕
(産業上の利用分野)
この発明は熱輻射体として利用する遠赤外線放
射セラミツクス体を得る方法に関する。
(従来の技術)
従来、暖房や乾燥装置に用いられるている遠赤
外線放射体は、近赤外から赤外領域において高い
放射率を示す高純度なジルコニア、アルミナ、チ
タニアなどの新素材からなるセラミツクスが用い
られて居り、常時高温で加熱するような構造体を
有し且つ高温下で使用に耐えられるよう高温下で
の焼結を必要とした。従つて、従来の遠赤外線放
射体は価格が高く入手が困難であつた。
(本発明の解決しようとする問題点)
この発明は高温度で焼結による調整を要するこ
となく適温で適切な波長域(特に遠赤外線領域)
で適切な放射率をもつた安価な遠赤外線放射体を
常温で硬化せしめることで容易に得ることを目的
としている。
食品、生鮮野菜、魚介類、人体のように水分の
多い遠赤外線被射体は特有の遠赤外線波長を吸収
する特性をもつている。このような物質に対して
は近赤外線から赤外線にかけての放射は必要でな
くむしろより長波長の遠赤外線を必要とする。
〔問題点を解決するための手段〕
このような遠赤外線放射セラミツクス体を得る
には、遠赤外線の波長領域で高放射率の放射特性
をもつ物質を組み合わせ常温で水和硬化能を有
し、しかも水和硬化物が高温で分解することのな
いアルミナセメントを硬化剤として使用すること
で調整できる。
本発明によるセラミツクスにおいて主成分とな
る焼成白磁は遠赤外線機能を有した焼結体粉末で
あり容易に入手できる。またアルミナ粉末も同じ
ように遠赤外線放射機能を有しており安価に入手
できる。更にこれらに2−15%加えられるシリ
カ、ヌグネシア、酸化第一鉄、炭素、炭化珪素粉
末は全体として遠赤外線の放射率を高めることが
できる。
而も更に0.5−10の配合添加するアルミナセメ
ントは常温でこれらセラミツクス混合体を容易に
結合するバインダー兼硬化剤としての役割をもつ
ものである。
即ち、上記混合セラミツクスに0.5−10%アル
ミナセメントと5−20%の水とを添加し混練し成
型したセラミツクス体は常温で自ら水和硬化し硬
い遠赤外線放射セラミツクス体となる。これは従
来のキヤスタブル耐火物と同様な使用の態様を示
すものである。
本発明によるセラミツクスは高温焼結せしめる
ものでないが常温自己硬化型の強い結合を有する
遠赤外線放射体であり、このままで遠赤外線放射
体として使用に耐えるものである。更に高強度の
構造材の目的を合わせ持たせるためには1700℃の
温度で高温焼成させることができる。因に現在で
の未焼成品の耐熱限度は1600℃であり、圧縮荷重
15.6tOn/cm2に十分耐える強度を有している。
(発明の作用)
本発明の特徴であるアルミナセメントを配合使
用することにより調整されたセラミツクスは任意
の形状に常温で容易に硬化成型できるとともに適
度の強度をもち高い遠赤外線放射率を有してい
る。
本発明によるセラミツクスから放射される遠赤
外線の被放射物質におよぼす効果は従来のそれに
比べて優れた効果を示した。
その実施例を以下に示す。
(実施例)
本発明による遠赤外線放射セラミツクス体の配
合例を示すと表−1の通りである。これら配合に
よつて均一に混合したセラミツクス粉末は最後の
工程で水とよく混合し、その混合体を予め定めた
型に流し込み常温で放置乾燥効果せしめるもので
ある。
このようにして調整しセラミツクス体は遠赤外
線を高い放射率で放射する放射特性を示す。その
配合例No.1,3,6の放射率曲線を示すと図面の
通りである。
このようにして調整したセラミツクス体から放
射する遠赤外線の乾燥効果を牛肉やトリ肉などの
食肉、野菜、きのこ類を対象に調べた結果これら
の乾燥状態および減水率は従来の対流伝熱を主体
とする熱風乾燥のそれに比べて極めて優れた成果
を示した。同時に省エネ効果も示した。
[Object of the Invention] (Industrial Application Field) This invention relates to a method for obtaining a far-infrared emitting ceramic body used as a heat radiator. (Prior technology) Conventionally, far-infrared radiators used in heating and drying equipment are ceramics made of new materials such as high-purity zirconia, alumina, and titania, which exhibit high emissivity in the near-infrared to infrared region. was used, had a structure that was constantly heated at high temperatures, and required sintering at high temperatures to withstand use at high temperatures. Therefore, conventional far-infrared radiators are expensive and difficult to obtain. (Problems to be Solved by the Present Invention) This invention is capable of achieving a suitable wavelength range (particularly far infrared region) at an appropriate temperature without requiring adjustment by sintering at high temperatures.
The aim is to easily obtain an inexpensive far-infrared radiator with an appropriate emissivity by curing it at room temperature. Far-infrared ray-emitting objects that contain a lot of water, such as food, fresh vegetables, seafood, and the human body, have the characteristic of absorbing specific far-infrared wavelengths. For such substances, radiation in the range from near-infrared to infrared is not necessary, but rather far-infrared radiation with longer wavelengths is required. [Means for solving the problem] In order to obtain such a far-infrared emitting ceramic body, materials having radiation characteristics of high emissivity in the far-infrared wavelength region are combined, and have hydration hardening ability at room temperature. Moreover, it can be adjusted by using alumina cement, whose hydrated hardened product does not decompose at high temperatures, as a hardening agent. The fired white porcelain, which is the main component in the ceramics according to the present invention, is a sintered powder having far-infrared function and is easily available. Alumina powder also has a far-infrared radiation function and can be obtained at low cost. Furthermore, silica, nugnesia, ferrous oxide, carbon, and silicon carbide powder added in an amount of 2 to 15% can increase the far-infrared emissivity as a whole. Moreover, the alumina cement added in an amount of 0.5 to 10 has the role of a binder and hardening agent that easily binds these ceramic mixtures at room temperature. That is, a ceramic body made by adding 0.5-10% alumina cement and 5-20% water to the above-mentioned mixed ceramics, kneading and molding the mixture hydrates and hardens by itself at room temperature to become a hard far-infrared emitting ceramic body. This shows a mode of use similar to that of conventional castable refractories. Although the ceramic according to the present invention is not sintered at a high temperature, it is a far-infrared radiator that self-cures at room temperature and has strong bonds, and can be used as a far-infrared radiator as it is. Furthermore, in order to serve the purpose of a high-strength structural material, it can be fired at a high temperature of 1700°C. Incidentally, the current heat resistance limit for unfired products is 1600℃, and the compressive load
It has sufficient strength to withstand 15.6tOn/cm 2 . (Operation of the invention) Ceramics prepared by blending and using alumina cement, which is a feature of the present invention, can be easily hardened and molded into any shape at room temperature, have moderate strength, and have high far-infrared emissivity. There is. The effect of the far infrared rays emitted from the ceramics of the present invention on the radiated material was superior to that of the conventional method. Examples are shown below. (Example) Table 1 shows formulation examples of far-infrared emitting ceramic bodies according to the present invention. The ceramic powder uniformly mixed with these formulations is thoroughly mixed with water in the final step, and the mixture is poured into a predetermined mold and left to dry at room temperature. The ceramic body adjusted in this manner exhibits radiation characteristics that emit far-infrared rays at a high emissivity. The emissivity curves of Blend Example Nos. 1, 3, and 6 are shown in the drawing. The drying effect of far infrared rays emitted from the ceramic body prepared in this way was investigated on meat such as beef and poultry, vegetables, and mushrooms, and the results showed that the drying state and water loss rate of these were mainly due to conventional convection heat transfer. It showed extremely superior results compared to that of hot air drying. At the same time, it also showed an energy saving effect.
本発明によつて調理されたセラミツクスは図1
に示した通り遠赤外線領域で高い放射率を有して
おり、イ)ガス化炭化炉、ロ)食品等の乾燥、
ハ)暖房、ニ)リハビリテーシヨン機器の熱源体
として広く応用が可能である。以上から本発明は
首題の目的を達成するまことに有益なものであ
る。
Ceramics prepared according to the present invention are shown in Figure 1.
As shown in , it has a high emissivity in the far infrared region, and is used in a) gasification carbonization furnaces, b) drying of foods, etc.
It can be widely applied as a heat source for c) heating and d) rehabilitation equipment. In view of the foregoing, the present invention is highly beneficial in achieving the object in question.
図面は本発明セラミツクスによる遠赤外線の放
射率曲線である。
The drawing shows a far-infrared emissivity curve of the ceramics of the present invention.
Claims (1)
ミナ(Al2O3)粉末を主成分とし、これに酸化第
一鉄(FeO)、酸化珪素(SiC)、炭素(C)、マ
グネシア(MgO)、シリカ(SiO2)の粉末を少な
くとも一種以上添加し、さらにアルミナセメン
ト、水を混合して混練し成型することを特徴とす
る遠赤外線発生放射セラミツクスの製造法。1 The main components are fired white porcelain (SiO 2 , Al 2 O 3 , Na 2 O) powder and alumina (Al 2 O 3 ) powder, and ferrous oxide (FeO), silicon oxide (SiC), and carbon (C ), magnesia (MgO), and silica (SiO 2 ) powder, and furthermore, alumina cement and water are mixed, kneaded, and molded.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56107980A JPS589871A (en) | 1981-07-09 | 1981-07-09 | Manufacture of far infrared generation radiation ceramics |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56107980A JPS589871A (en) | 1981-07-09 | 1981-07-09 | Manufacture of far infrared generation radiation ceramics |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS589871A JPS589871A (en) | 1983-01-20 |
JPS6146426B2 true JPS6146426B2 (en) | 1986-10-14 |
Family
ID=14472928
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56107980A Granted JPS589871A (en) | 1981-07-09 | 1981-07-09 | Manufacture of far infrared generation radiation ceramics |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS589871A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0237330U (en) * | 1988-09-02 | 1990-03-12 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0309680D0 (en) * | 2003-04-29 | 2003-06-04 | Applied Energy Products Ltd | Improved process for brick manufacture |
JP2009113529A (en) * | 2007-11-02 | 2009-05-28 | Mazda Motor Corp | Mounting structure for vehicle suspension and assembling method |
-
1981
- 1981-07-09 JP JP56107980A patent/JPS589871A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0237330U (en) * | 1988-09-02 | 1990-03-12 |
Also Published As
Publication number | Publication date |
---|---|
JPS589871A (en) | 1983-01-20 |
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