JPS6146012B2 - - Google Patents
Info
- Publication number
- JPS6146012B2 JPS6146012B2 JP54064927A JP6492779A JPS6146012B2 JP S6146012 B2 JPS6146012 B2 JP S6146012B2 JP 54064927 A JP54064927 A JP 54064927A JP 6492779 A JP6492779 A JP 6492779A JP S6146012 B2 JPS6146012 B2 JP S6146012B2
- Authority
- JP
- Japan
- Prior art keywords
- higher fatty
- weight
- fatty acid
- parts
- polyolefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 30
- 239000000194 fatty acid Substances 0.000 claims description 30
- 229930195729 fatty acid Natural products 0.000 claims description 30
- 150000004665 fatty acids Chemical class 0.000 claims description 27
- 229920000098 polyolefin Polymers 0.000 claims description 25
- -1 Borate ester Chemical class 0.000 claims description 19
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 239000004327 boric acid Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 9
- 235000021355 Stearic acid Nutrition 0.000 description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000008117 stearic acid Substances 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- 239000002216 antistatic agent Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- NKFNBVMJTSYZDV-UHFFFAOYSA-N 2-[dodecyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCCN(CCO)CCO NKFNBVMJTSYZDV-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001642 boronic acid derivatives Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- NDLNTMNRNCENRZ-UHFFFAOYSA-N 2-[2-hydroxyethyl(octadecyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCCCCN(CCO)CCO NDLNTMNRNCENRZ-UHFFFAOYSA-N 0.000 description 1
- BITAPBDLHJQAID-KTKRTIGZSA-N 2-[2-hydroxyethyl-[(z)-octadec-9-enyl]amino]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCN(CCO)CCO BITAPBDLHJQAID-KTKRTIGZSA-N 0.000 description 1
- RIZOAHWIOYVVDL-UHFFFAOYSA-N 2-[docosyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCCCCCCCCN(CCO)CCO RIZOAHWIOYVVDL-UHFFFAOYSA-N 0.000 description 1
- MJWIPTSHMLSLFE-UHFFFAOYSA-N 2-[hexadecyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCCN(CCO)CCO MJWIPTSHMLSLFE-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910021551 Vanadium(III) chloride Inorganic materials 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- HIAAVKYLDRCDFQ-UHFFFAOYSA-L calcium;dodecanoate Chemical compound [Ca+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O HIAAVKYLDRCDFQ-UHFFFAOYSA-L 0.000 description 1
- HRBZRZSCMANEHQ-UHFFFAOYSA-L calcium;hexadecanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O HRBZRZSCMANEHQ-UHFFFAOYSA-L 0.000 description 1
- BMQVRJOWNGSIEG-UHFFFAOYSA-L calcium;icosanoate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCC([O-])=O BMQVRJOWNGSIEG-UHFFFAOYSA-L 0.000 description 1
- ZCZLQYAECBEUBH-UHFFFAOYSA-L calcium;octadec-9-enoate Chemical compound [Ca+2].CCCCCCCCC=CCCCCCCCC([O-])=O.CCCCCCCCC=CCCCCCCCC([O-])=O ZCZLQYAECBEUBH-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229940063002 magnesium palmitate Drugs 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229940057948 magnesium stearate Drugs 0.000 description 1
- BJZBHTNKDCBDNQ-UHFFFAOYSA-L magnesium;dodecanoate Chemical compound [Mg+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BJZBHTNKDCBDNQ-UHFFFAOYSA-L 0.000 description 1
- ABSWXCXMXIZDSN-UHFFFAOYSA-L magnesium;hexadecanoate Chemical compound [Mg+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O ABSWXCXMXIZDSN-UHFFFAOYSA-L 0.000 description 1
- WMJYMUUIWPPMGJ-UHFFFAOYSA-L magnesium;icosanoate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCC([O-])=O WMJYMUUIWPPMGJ-UHFFFAOYSA-L 0.000 description 1
- AXLHVTKGDPVANO-UHFFFAOYSA-N methyl 2-amino-3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoate Chemical compound COC(=O)C(N)CNC(=O)OC(C)(C)C AXLHVTKGDPVANO-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
- JFZDUSDRGGZYDF-UHFFFAOYSA-M potassium;icosanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCCCC([O-])=O JFZDUSDRGGZYDF-UHFFFAOYSA-M 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- MRQYKJNZWPCFNB-UHFFFAOYSA-M sodium;icosanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCC([O-])=O MRQYKJNZWPCFNB-UHFFFAOYSA-M 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 1
- YQLFJUAFJLSPPF-CVBJKYQLSA-L zinc (Z)-docos-13-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCCCCCC([O-])=O YQLFJUAFJLSPPF-CVBJKYQLSA-L 0.000 description 1
- 229940098697 zinc laurate Drugs 0.000 description 1
- 229940012185 zinc palmitate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229940057977 zinc stearate Drugs 0.000 description 1
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 1
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 1
- GJAPSKMAVXDBIU-UHFFFAOYSA-L zinc;hexadecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCC([O-])=O GJAPSKMAVXDBIU-UHFFFAOYSA-L 0.000 description 1
- CCTYJGNBCQQCKM-UHFFFAOYSA-L zinc;icosanoate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCCCC([O-])=O CCTYJGNBCQQCKM-UHFFFAOYSA-L 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Description
本発明は帯電防止性の改良されたポリオレフイ
ン組成物に関する。とくに本発明は帯電防止性の
改良されたチーグラー型触媒により製造されたポ
リオレフインを主成分とする組成物に関する。
プラスチツクなかでもポリオレフインは、静電
気を帯びやすく、このためポリオレフイン成形物
は表面に空気中の塵、ほこりが吸着されてその商
品価値を損うことが多い。そこでポリオレフイン
に帯電防止剤を練り込んで静電特性を改善するこ
とが行われている。この場合、帯電防止剤はポリ
オレフイン成形物の表面にブリードアウトしてそ
の効果を発揮すると考えられている。かかる目的
で配合される帯電防止剤としては、成形直後のみ
でなく長期にわたつて帯電防止効果を有し、しか
もブリードアウトにより成形物表面を汚染しない
ことが要求される。以上の観点からこれまで種々
の帯電防止剤を配合したポリオレフイン組成物が
提案されている。このうち、高級脂肪酸モノグリ
セライドの硼酸エステルがポリオレフインの帯電
防止剤として使用できることも知られている。し
かしながら、高級脂肪酸モノグリセライドの硼酸
エステルは、チーグラー型触媒で製造されたポリ
オレフイン中の触媒残渣から生じる塩酸を捕捉す
る目的で配合される高級脂肪酸の金属塩と併用し
た際、その効果が著しく損われることが判明し
た。
本発明は上記問題を解決すべくなされたもので
あり、高級脂肪酸モノグリセライドの硼酸エステ
ルと高級脂肪酸の金属塩とを併用しても優れた帯
電防止効果が得られるポリオレフイン組成物を提
供することを目的とする。
すなわち本発明は、ポリオレフイン100重量部
に対し高級脂肪酸モノグリセライドの硼酸エステ
ル0.05ないし0.4重量部、および高級脂肪酸0.01な
いし1.0重量部を配合してなる帯電防止性の改良
されたポリオレフイン組成物である。
本発明でいうポリオレフインとは、エチレン、
プロピレン、１−ブテン、１−ペンテン、１−ヘ
キセン、１−ヘプテン、１−オクテン、３−メチ
ル−１−ペンテン、４−メチル−１−ペンテン等
のα−オレフインの単独重合体もしくはこれらの
α−オレフインの２つ以上からなる共重合体等を
挙げることができる。本発明ではこれらのうちで
も、有機金属化合物、例えばトリエチルアルミニ
ウム、ジエチルアルミニウムモノクロリド、アル
ミニウムセスキクロリド等と遷移金属のハロゲン
化合物、例えば三塩化チタン、四塩化チタン、三
塩化バナジウム等からなるいわゆるチーグラー型
触媒を用いて製造されたポリオレフインを用いた
場合、より効果的である。本発明では、上記した
ポリオレフインのうちでもとくに密度0.91ないし
0.935ｇ／cm3のエチレン・プロピレン共重合体、
エチレン・１−ブテン共重合体もしくはエチレ
ン・４−メチル−１−ペンテン共重合体を好まし
く用いることができる。
本発明で用いられる高級脂肪酸モノグリセライ
ドの硼酸エステルとは、高級脂肪酸モノグリセラ
イドと硼酸もしくは硼酸の低級アルコールエステ
ルとをエステル化またはエステル交換反応させる
か、あるいはグリセリンと硼酸もしくは硼酸の低
級アルコールエステルとをエステル化もしくはエ
ステル交換反応させ、その後高級脂肪酸とエステ
ル化反応させることにより得られるものである。
なお、本発明における高級脂肪酸としてはカプ
リン酸、ラウリン酸、ミリスチン酸、パルミチン
酸、ステアリン酸、アラキジン酸、ベヘニン酸、
オレイン酸、エルカ酸等を挙げることができる。
また低級アルコールとしてはメタノール、エタノ
ール、ｎ−プロピルアルコール、イソプロピルア
ルコール、ｎ−ブタノール、ｔ−ブタノール等を
挙げることができる。
本発明における高級脂肪酸金属塩とは、前記し
た高級脂肪酸のアルカリもしくはアルカリ土類金
属塩を言い、例えばパルミチン酸ナトリウム、ス
テアリン酸ナトリウム、アラキジン酸ナトリウ
ム、パルミチン酸カリウム、ステアリン酸カリウ
ム、アラキジン酸カリウム、ラウリン酸マグネシ
ウム、パルミチン酸マグネシウム、ステアリン酸
マグネシウム、アラキジン酸マグネシウム、オレ
イン酸マグネシウム、ラウリン酸カルシウム、パ
ルミチン酸カルシウム、ステアリン酸カルシウ
ム、アラキジン酸カルシウム、オレイン酸カルシ
ウム、エルカ酸カルシウム、ラウリン酸亜鉛、パ
ルミチン酸亜鉛、ステアリン酸亜鉛、アラキジン
酸亜鉛、エルカ酸亜鉛、オレイン酸亜鉛等を挙げ
ることができる。
本発明は、ポリオレフインに対する帯電防止剤
として、高級脂肪酸モノグリセライドの硼酸エス
テルと高級脂肪酸とを併用することによりポリオ
レフインに滑剤や塩酸吸収剤として配合される高
級脂肪酸金属塩により生じる帯電防止効果の低滅
を防止することができた点にある。
ポリオレフインに対する高級脂肪酸モノグリセ
ライドの硼酸エステルおよび高級脂肪酸の配合量
は、ポリオレフイン100重量部に対し、高級脂肪
酸モノグリセライドの硼酸エステル0.05ないし
0.4重量部、好ましくは0.10ないし0.30重量部であ
り、高級脂肪酸0.01ないし1.0重量部、好ましく
は0.05ないし0.5重量部であり、とくにポリオレ
フインへの高級脂肪酸金属塩の配合量に比例して
その1/4〜４倍の範囲内で配合量を増減させるこ
とが好ましい。高級脂肪酸モノグリセライドの硼
酸エステルの配合量が上記範囲より少な過ぎると
帯電防止効果が劣り、逆に多過ぎると成形物表面
に析出して粉ふき現象を生じたりして成形物の商
品価値を低下させる。一方、高級脂肪酸の配合量
が少な過ぎると本発明の効果が得られず、逆に多
過ぎるとポリオレフインの物性を低下させたり、
成形機を錆させたりする。
なお本発明の組成物には、更に帯電防止効果を
迅速に発現するために一般式
The present invention relates to polyolefin compositions with improved antistatic properties. In particular, the present invention relates to compositions based on polyolefins produced by Ziegler-type catalysts with improved antistatic properties. Among plastics, polyolefin is easily charged with static electricity, and for this reason, polyolefin molded products often attract dirt and dust in the air to their surfaces, reducing their commercial value. Therefore, attempts have been made to incorporate antistatic agents into polyolefins to improve their electrostatic properties. In this case, it is thought that the antistatic agent bleeds out onto the surface of the polyolefin molded product and exhibits its effect. The antistatic agent blended for this purpose is required to have an antistatic effect not only immediately after molding but also for a long period of time, and not to contaminate the surface of the molded product due to bleed-out. From the above viewpoint, polyolefin compositions containing various antistatic agents have been proposed. Among these, it is also known that borate esters of higher fatty acid monoglycerides can be used as antistatic agents for polyolefins. However, when borate esters of higher fatty acid monoglycerides are used in combination with metal salts of higher fatty acids, which are blended for the purpose of capturing hydrochloric acid generated from catalyst residues in polyolefins produced using Ziegler type catalysts, their effectiveness is significantly impaired. There was found. The present invention has been made to solve the above problems, and an object of the present invention is to provide a polyolefin composition that can provide an excellent antistatic effect even when a boric acid ester of a higher fatty acid monoglyceride and a metal salt of a higher fatty acid are used in combination. shall be. That is, the present invention is a polyolefin composition with improved antistatic properties, which contains 0.05 to 0.4 parts by weight of a boric acid ester of a higher fatty acid monoglyceride and 0.01 to 1.0 parts by weight of a higher fatty acid to 100 parts by weight of the polyolefin. The polyolefin referred to in the present invention refers to ethylene,
Homopolymers of α-olefins such as propylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 3-methyl-1-pentene, 4-methyl-1-pentene, or these α - Copolymers consisting of two or more olefins, etc. can be mentioned. Among these, in the present invention, a so-called Ziegler type compound consisting of an organometallic compound such as triethylaluminum, diethylaluminum monochloride, aluminum sesquichloride, etc. and a transition metal halogen compound such as titanium trichloride, titanium tetrachloride, vanadium trichloride, etc. It is more effective when using a polyolefin produced using a catalyst. In the present invention, among the above-mentioned polyolefins, particularly those having a density of 0.91 to
0.935g/ cm3 ethylene-propylene copolymer,
Ethylene/1-butene copolymer or ethylene/4-methyl-1-pentene copolymer can be preferably used. The boric acid ester of higher fatty acid monoglyceride used in the present invention is obtained by esterifying or transesterifying higher fatty acid monoglyceride with boric acid or a lower alcohol ester of boric acid, or by esterifying glycerin with boric acid or a lower alcohol ester of boric acid. Alternatively, it can be obtained by carrying out a transesterification reaction and then carrying out an esterification reaction with a higher fatty acid. In addition, the higher fatty acids in the present invention include capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, behenic acid,
Examples include oleic acid and erucic acid.
Examples of lower alcohols include methanol, ethanol, n-propyl alcohol, isopropyl alcohol, n-butanol, and t-butanol. The higher fatty acid metal salt in the present invention refers to the above-mentioned alkali or alkaline earth metal salts of higher fatty acids, such as sodium palmitate, sodium stearate, sodium arachidate, potassium palmitate, potassium stearate, potassium arachidate, Magnesium laurate, magnesium palmitate, magnesium stearate, magnesium arachidate, magnesium oleate, calcium laurate, calcium palmitate, calcium stearate, calcium arachidate, calcium oleate, calcium erucate, zinc laurate, zinc palmitate, Zinc stearate, zinc arachidate, zinc erucate, zinc oleate, etc. can be mentioned. The present invention uses a boric acid ester of a higher fatty acid monoglyceride and a higher fatty acid together as an antistatic agent for polyolefin, thereby reducing the antistatic effect caused by the higher fatty acid metal salt blended into polyolefin as a lubricant or hydrochloric acid absorbent. This could have been prevented. The amount of boric acid ester of higher fatty acid monoglyceride and higher fatty acid added to polyolefin is 0.05 to 0.05 to 100 parts by weight of boric acid ester of higher fatty acid monoglyceride per 100 parts by weight of polyolefin.
0.4 parts by weight, preferably 0.10 to 0.30 parts by weight, 0.01 to 1.0 parts by weight of higher fatty acids, preferably 0.05 to 0.5 parts by weight, and especially 1/1 part by weight in proportion to the amount of higher fatty acid metal salt blended in the polyolefin. It is preferable to increase or decrease the blending amount within a range of 4 to 4 times. If the amount of boric acid ester of higher fatty acid monoglyceride is too small than the above range, the antistatic effect will be poor, and if it is too large, it will precipitate on the surface of the molded product and cause a dusting phenomenon, reducing the commercial value of the molded product. . On the other hand, if the amount of higher fatty acids blended is too small, the effects of the present invention cannot be obtained, and if it is too large, the physical properties of the polyolefin may be deteriorated.
It may cause the molding machine to rust. The composition of the present invention further includes the general formula:
【式】（但し、Ｒは炭素数８ない
し22のアルキル基）で表わされるアルキルジエタ
ノールアミン、例えばラウリルジエタノールアミ
ン、パルミチルジエタノールアミン、ステアリル
ジエタノールアミン、オレイルジエタノールアミ
ン、ベヘニルジエタノールアミン等を配合するこ
とが好ましい。本発明の組成物には更にポリオレ
フインに通常用いられる酸化防止剤、紫外線吸収
剤、防曇剤、ブロツキング防止剤、着色剤、充填
剤、スリツプ剤、その他の添加剤を配合すること
ができる。
本発明の組成物を得る方法としては、例えばタ
ンブラーブレンダー、ヘンシエルミキサー、リボ
ンブレンダー等の混合機にポリオレフイン、高級
脂肪酸モノグリセライドの硼酸エステルおよび高
級脂肪酸を所定量計量後投入し、混合後、押出
機、ミキシングロール、バンバリーミキサー等で
混練する方法を採用することができる。
本発明の組成物は射出成形品、中空成形品、フ
イルム等の用途に有用である。
次に実施例を挙げて本発明をより具体的に説明
する。
実施例 １
ジエチルアルミニウムクロリドとトリエチルア
ルミニウム２：３の混合物と四塩化チタンとから
なる触媒により製造されたエチレン・４−メチル
−１−ペンテン共重合体（メルトインデツクス
2.3、密度0.926ｇ／cm3、エチレン含有率96.9モル
％）100重量部、２，６−ジ−tert−ブチル−ｐ
−クレゾール0.1重量部、ステアリン酸カルシウ
ム0.1重量部、ステアリン酸0.1重量部、およびラ
ウリル酸モノグリセライドと硼酸との２：１（モ
ル比）の混合物を加熱して得た。
の構造式を有する高級脂肪酸モノグリセライドの
硼酸エステル（以下MGBEと略す）0.15重量部を
配合してヘンシエルミキサーで混合した後、さら
に押出機で溶融混練後ペレツト化した。このペレ
ツトを40mmφ押出機で180℃に溶融した後、イン
フレーシヨンフイルム成形法により厚さ30μのフ
イルムを製造した。このようにして得られたフイ
ルムに対し、下記の方法で静電特性を測定した。
結果を第１表に示す。
表面抵抗 タケダ理研製TR−84型
表面抵抗測定器を用いて温度23℃、湿度65％で
測定した。表面抵抗値が小さい程フイルムの帯電
防止性が大きい。
粉付着テスト 10cm×10cmのフイルムの表面を
脱脂綿で３回こすり、次にポリプロピレンの粉末
を載せて、静かに落下させてフイルム表面への粉
末の付着の度合いを観察した。評価は、
粉末が全く付着しないもの ◎
わずかに付着が認められるもの 〇
付着が目立つもの △
全面に付着するもの ×
で示した。
実施例 ２
実施例１において、高級脂肪酸モノグリセライ
ドの硼酸エステル（MGBE）の配合量を0.3重量
部とする以外は実施例１と同様に行つた。
比較例 １
ステアリン酸を配合しない以外は実施例１と同
様に行つた。結果を第１表に示す。
実施例 ３
実施例１において、更にラウリルジエタノール
アミンを0.1重量部配合する以外は実施例１と同
様にして行つた。
実施例 ４
ステアリン酸の配合量を0.05重量部とする以外
は実施例３と同様に行つた。
比較例 ２
ステアリン酸を配合しない以外は実施例３と同
様に行つた。
以上、実施例１〜４、比較例１〜２の結果を第
１表に示す。It is preferable to blend an alkyldiethanolamine represented by the formula: (wherein R is an alkyl group having 8 to 22 carbon atoms) such as lauryldiethanolamine, palmityldiethanolamine, stearyldiethanolamine, oleyldiethanolamine, behenyldiethanolamine, etc. The composition of the present invention may further contain antioxidants, ultraviolet absorbers, antifogging agents, antiblocking agents, colorants, fillers, slip agents, and other additives commonly used in polyolefins. As a method for obtaining the composition of the present invention, polyolefin, boric acid ester of higher fatty acid monoglyceride, and higher fatty acid are put into a mixer such as a tumbler blender, Henschel mixer, or ribbon blender after being weighed in a predetermined amount, and after mixing, an extruder is used. A method of kneading with a mixing roll, a Banbury mixer, etc. can be adopted. The composition of the present invention is useful for applications such as injection molded products, blow molded products, and films. Next, the present invention will be described in more detail with reference to Examples. Example 1 Ethylene/4-methyl-1-pentene copolymer (melt index
2.3, density 0.926 g/cm 3 , ethylene content 96.9 mol%) 100 parts by weight, 2,6-di-tert-butyl-p
- Obtained by heating 0.1 part by weight of cresol, 0.1 part by weight of calcium stearate, 0.1 part by weight of stearic acid, and a 2:1 (molar ratio) mixture of lauric acid monoglyceride and boric acid. 0.15 parts by weight of higher fatty acid monoglyceride boric acid ester (hereinafter abbreviated as MGBE) having the structural formula was blended in a Henschel mixer, and then melt-kneaded in an extruder and pelletized. The pellets were melted at 180° C. using a 40 mmφ extruder, and then a film with a thickness of 30 μm was produced using an inflation film molding method. The electrostatic properties of the film thus obtained were measured in the following manner.
The results are shown in Table 1. Surface resistance Measured using a Takeda Riken model TR-84 surface resistance measuring device at a temperature of 23°C and a humidity of 65%. The smaller the surface resistance value, the greater the antistatic property of the film. Powder adhesion test The surface of a 10 cm x 10 cm film was rubbed three times with absorbent cotton, then polypropylene powder was placed on it and gently dropped to observe the degree of adhesion of the powder to the film surface. The evaluation was as follows: No powder adhesion at all ◎ Slight adhesion ○ Adhesion noticeable △ Adhesion all over the surface × Example 2 The same procedure as in Example 1 was carried out except that the amount of boric acid ester of higher fatty acid monoglyceride (MGBE) was 0.3 parts by weight. Comparative Example 1 The same procedure as Example 1 was carried out except that stearic acid was not blended. The results are shown in Table 1. Example 3 The same procedure as in Example 1 was carried out except that 0.1 part by weight of lauryl diethanolamine was further added. Example 4 The same procedure as in Example 3 was carried out except that the amount of stearic acid blended was 0.05 parts by weight. Comparative Example 2 The same procedure as in Example 3 was carried out except that stearic acid was not blended. The results of Examples 1 to 4 and Comparative Examples 1 to 2 are shown in Table 1.
【表】【table】
【表】
実施例 ５
トリエチルアルミニウムと四塩化チタンとから
なる触媒により製造されたエチレン・１−ブテン
共重合体（メルトインデツクス2.1、密度0.930
ｇ／cm3）100重量部、２，６−ジ−tert−ブチル
−ｐ−クレゾール0.1重量部、ステアリン酸カル
シウム0.15重量部、ステアリン酸0.05重量部、実
施例１で用いた高級脂肪酸モノグリセライドの硼
酸エステル（MGBE）0.15重量部を配合する以外
は実施例１と同様にフイルムを成形し、試験し
た。結果を第２表に示す。
比較例 ３
ステアリン酸を配合しない以外は実施例５と同
様に行つた。結果を第２表に示す。[Table] Example 5 Ethylene/1-butene copolymer produced with a catalyst consisting of triethylaluminum and titanium tetrachloride (melt index 2.1, density 0.930)
g/cm 3 ) 100 parts by weight, 0.1 parts by weight of 2,6-di-tert-butyl-p-cresol, 0.15 parts by weight of calcium stearate, 0.05 parts by weight of stearic acid, boric acid ester of higher fatty acid monoglyceride used in Example 1 A film was molded and tested in the same manner as in Example 1, except that 0.15 parts by weight of (MGBE) was added. The results are shown in Table 2. Comparative Example 3 The same procedure as in Example 5 was carried out except that stearic acid was not blended. The results are shown in Table 2.
Claims (1)
酸モノグリセライドの硼酸エステル0.05ないし
0.4重量部、および高級脂肪酸0.01ないし1.0重量
部を配合してなる帯電防止性の改良されたポリオ
レフイン組成物。1 Borate ester of higher fatty acid monoglyceride 0.05 to 100 parts by weight of polyolefin
A polyolefin composition with improved antistatic properties, which contains 0.4 parts by weight and 0.01 to 1.0 parts by weight of a higher fatty acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6492779A JPS55157635A (en) | 1979-05-28 | 1979-05-28 | Polyolefin composition having improved antistatic property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6492779A JPS55157635A (en) | 1979-05-28 | 1979-05-28 | Polyolefin composition having improved antistatic property |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55157635A JPS55157635A (en) | 1980-12-08 |
| JPS6146012B2 true JPS6146012B2 (en) | 1986-10-11 |
Family
ID=13272153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6492779A Granted JPS55157635A (en) | 1979-05-28 | 1979-05-28 | Polyolefin composition having improved antistatic property |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55157635A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62189824U (en) * | 1986-05-22 | 1987-12-03 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023153302A1 (en) * | 2022-02-09 | 2023-08-17 | 三井化学株式会社 | Cyclic olefin resin composition, molded article and optical component |
-
1979
- 1979-05-28 JP JP6492779A patent/JPS55157635A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62189824U (en) * | 1986-05-22 | 1987-12-03 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55157635A (en) | 1980-12-08 |
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