JPS6129103B2 - - Google Patents
Info
- Publication number
- JPS6129103B2 JPS6129103B2 JP14124281A JP14124281A JPS6129103B2 JP S6129103 B2 JPS6129103 B2 JP S6129103B2 JP 14124281 A JP14124281 A JP 14124281A JP 14124281 A JP14124281 A JP 14124281A JP S6129103 B2 JPS6129103 B2 JP S6129103B2
- Authority
- JP
- Japan
- Prior art keywords
- battery
- exothermic agent
- current collector
- cylindrical
- collector plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011810 insulating material Substances 0.000 claims description 5
- 238000010248 power generation Methods 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000007773 negative electrode material Substances 0.000 description 2
- 239000007774 positive electrode material Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 1
- 229940083898 barium chromate Drugs 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000003832 thermite Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/30—Deferred-action cells
- H01M6/36—Deferred-action cells containing electrolyte and made operational by physical means, e.g. thermal cells
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Primary Cells (AREA)
Description
【発明の詳細な説明】
本発明は、発熱剤を備えた熱電池に関するもの
で、１個の電池で複数の負荷に対して同時に電力
を供給できる熱電池を提供するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a thermal battery equipped with a heat generating agent, and provides a thermal battery that can simultaneously supply power to a plurality of loads with one battery.
熱電池は良く知られるように、数百度という高
温で作動するため、短時間に大電流を取出すのに
適しており、これまで種々な改良がなされてき
た。しかし、近年電子機器の高度化と多様化によ
つて、この種の緊急用，非常用電源も、同時に数
種類の負荷に電力を供給することが要求される事
例が多くなつた。 As is well known, thermal batteries operate at high temperatures of several hundred degrees, making them suitable for drawing large amounts of current in a short period of time, and various improvements have been made to date. However, as electronic devices have become more sophisticated and diversified in recent years, there have been many cases in which this type of emergency power source is required to simultaneously supply power to several types of loads.
本発明は、これらの要求に応えることができ、
かつ信頼性の高い構造の電池を供給するものであ
る。 The present invention can meet these demands,
Moreover, it supplies batteries with a highly reliable structure.
従来このように電池をケース内で分割する工夫
としては、例えば実公昭49−96号公報がある。こ
れは電池を４分割し、各群間にマイカ等の絶縁物
を挿入し、これら４分割の電池を直列に接続し
て、高い電圧を得ようとするものである。また同
時に、大形の極板を成形すると、１枚の極板内で
も不均一が生じ易いので、これを面積の等しい1/
４円として個々に成形して別々の群とし、後にこ
れらを接続して１個の電池を得るものである。し
かしこの方法では、大きさの異なる種類の負荷に
電力を供給することが困難である。またテルミツ
ト等の発熱剤を均等に着火することも容易ではな
い。 As a conventional idea for dividing the battery within the case, there is, for example, Japanese Utility Model Publication No. 49-96. This involves dividing the battery into four parts, inserting an insulator such as mica between each group, and connecting these four parts in series to obtain a high voltage. At the same time, when molding a large electrode plate, non-uniformity is likely to occur even within one electrode plate.
They are individually molded into four circles to form separate groups, and later connected to form one battery. However, with this method, it is difficult to supply power to loads of different sizes. Furthermore, it is not easy to evenly ignite exothermic agents such as thermite.
他の例は、特公昭37−18119号公報のように、
偶数に等分割した極板ブロツクに分け、各ブロツ
クを正極と負極とに分け、大容量のニツケル−カ
ドミウム電池を得ようとする工夫もある。この例
は各ブロツクは正極あるいは負極のブロツクで電
池群ではない。 Other examples include Japanese Patent Publication No. 37-18119,
Another idea is to divide the electrode plate into an even number of equally divided blocks and divide each block into a positive electrode and a negative electrode in an attempt to obtain a large-capacity nickel-cadmium battery. In this example, each block is a positive or negative electrode block and is not a battery group.
本発明の熱電池は、円筒形の電池ケース内に、
発熱剤を備える複数の扇形の電池を絶縁材により
相互に区画して配置し、中央部に前記の各電池に
共通の１個の火道口を設けたことを特徴とする。 The thermal battery of the present invention has a cylindrical battery case with
The present invention is characterized in that a plurality of fan-shaped batteries each containing a heat generating agent are arranged and separated from each other by an insulating material, and a vent common to each of the batteries is provided in the center.
以下、本発明を実施例により説明する。 The present invention will be explained below using examples.
第１図は本発明による熱電池の側面図、第２図
はその拡大横断面図、第３図は第２図−′線
断面図である。 FIG. 1 is a side view of a thermal battery according to the present invention, FIG. 2 is an enlarged cross-sectional view thereof, and FIG. 3 is a cross-sectional view taken along the line 2-' in FIG.
１は有底円筒形の電池ケースで、後述のような
電池を収納し、上部開口部は蓋により密閉してあ
り、蓋には各電池の端子２が相互に絶縁して取り
つけてある。 Reference numeral 1 denotes a cylindrical battery case with a bottom, which houses batteries as described below, and has an upper opening sealed with a lid, and the terminals 2 of each battery are attached to the lid so as to be insulated from each other.
３ａ，３ｂ，３ｃ，３ｄは円板状の発電要素を
扇形に分割したものの積層体から構成した扇形の
電池で、それらの極板の面積は相異なる要求負荷
に正比例するようになつている。例えば、機器が
４種類の負荷電流３Ａ，５Ａ，２Ａ，６Ａを同時
に必要とするならば、電池３ａ，３ｂ，３ｃ，３
ｄの極板面積の比は３：５：２：６の割合に分け
る。もちろん負荷の数と大きさによつて、電池の
数と極板の面積比は任意に変更することができ
る。 3a, 3b, 3c, and 3d are sector-shaped batteries constructed from a stack of disk-shaped power generation elements divided into sectors, and the areas of their electrode plates are directly proportional to different required loads. For example, if a device requires four types of load currents 3A, 5A, 2A, and 6A at the same time, batteries 3a, 3b, 3c, and
The ratio of the electrode plate areas of d is divided into a ratio of 3:5:2:6. Of course, the number of batteries and the area ratio of the electrode plates can be changed arbitrarily depending on the number and size of loads.
電池３ａ〜３ｄは独立で、互いに電気的な接続
は存在しない。４は各電池間に介在させた絶縁材
で、例えばアスベストからなる。５は電池とケー
ス１の間に介在させた断熱層である。 Batteries 3a to 3d are independent and have no electrical connection to each other. Reference numeral 4 denotes an insulating material interposed between each battery, which is made of asbestos, for example. 5 is a heat insulating layer interposed between the battery and the case 1.
６は各電池の発熱剤に共通な円筒形の貫通火道
口であり、絶縁材により相互に区画し全体として
円柱状を構成するよう電池ケース内に配置された
電池の中央部に設けられ、各電池はこの貫通火道
口に、発熱剤の着火点を発熱剤面積に比例した円
弧端面として露出させている。この構成は、各電
池がそれぞれ有する発熱剤、例えば金属鉄粉と塩
素酸カリあるいは金属ジルコニウムとクロム酸バ
リウム等を同時に着火させて、均一な温度上昇速
度を得るのに重要である。すなわち、各電池の発
熱剤が火道口６に露出する円弧部分の長さは各極
板の面積に正比例するので、極板の大きさに関係
なく、均一な温度上昇速度が得られる。 Reference numeral 6 denotes a cylindrical through-hole which is common to the exothermic agent of each battery, and is provided in the center of the battery arranged in the battery case so that it is separated from each other by an insulating material and forms a columnar shape as a whole. In the battery, the ignition point of the exothermic agent is exposed at this through vent as an arcuate end face proportional to the area of the exothermic agent. This configuration is important for simultaneously igniting the exothermic agents that each battery has, such as metal iron powder and potassium chlorate, or metal zirconium and barium chromate, to obtain a uniform temperature rise rate. That is, since the length of the arc portion where the exothermic agent of each battery is exposed to the vent 6 is directly proportional to the area of each electrode plate, a uniform temperature rise rate can be obtained regardless of the size of the electrode plate.
この電池を実際に製造するには、各々中央に円
形の孔６を有する円形の正極集電板７，正極活物
質８，電解質層９，負極活物質１０，負極集電板
１１，発熱剤１２等を成形しておき、これらを前
記のようにして定められる面積比の扇形に切断し
各々対応する分割比を積層すればよい。各電池を
構成する積層体中の負極集電板は隣接するセルの
正極集電板を兼ねている。 To actually manufacture this battery, a circular positive electrode current collector plate 7, each having a circular hole 6 in the center, a positive electrode active material 8, an electrolyte layer 9, a negative electrode active material 10, a negative electrode current collector plate 11, and a heat generating agent 12 are required. etc., cut them into fan shapes with the area ratio determined as described above, and stack them at the corresponding division ratios. The negative electrode current collector plate in the laminate that constitutes each battery also serves as the positive electrode current collector plate of the adjacent cell.
なお、集電板には鉄、ステンレス鋼、正極活物
質にはFe2S，CaCrO4、電解質にはLiC−KC
共融塩、負極活物質にはリチウム、カルシウム、
マグネシウムが用いられる。 The current collector plate is iron or stainless steel, the positive electrode active material is Fe 2 S, CaCrO 4 , and the electrolyte is LiC-KC.
Eutectic salt, negative electrode active material contains lithium, calcium,
Magnesium is used.
以上から明らかなように、本発明によれば、次
のような効果が得られる。 As is clear from the above, according to the present invention, the following effects can be obtained.
(1) 負荷の大きさと必要数に応じて、扇形を任意
の数と大きさに分割することができて、あらゆ
る部分の放電々流密度を同一にすることがで
き、安定な放電々圧特性を得ることができる。(1) The fan shape can be divided into arbitrary numbers and sizes according to the size of the load and the required number, and the discharge current density can be made the same in all parts, resulting in stable discharge pressure characteristics. can be obtained.
(2) 発熱剤の着火に必要な着火点の大きさを、発
熱剤の面積に比例して設けることができるの
で、均一な着火が可能である。熱電池は発熱剤
の熱により活性化されて始めて電圧を発生する
ので、発熱が遅れを生じると、電圧上昇が遅れ
るが、このような不都合はない。(2) Uniform ignition is possible because the size of the ignition point necessary for igniting the exothermic agent can be set in proportion to the area of the exothermic agent. Since a thermal battery generates voltage only after it is activated by the heat of the exothermic agent, if there is a delay in heat generation, the voltage rise will be delayed, but there is no such inconvenience.
(3) 各電池に共通の火道口を有して、ただ１つの
着火源で電池を活性化することができるので、
各電池を同時に着火することができる。(3) Since each battery has a common vent and can be activated with only one ignition source,
Each battery can be ignited simultaneously.
第１図は本発明の電池の実施例を示す側面図、
第２図はその拡大横断面図、第３図は第２図−
′断面図である。
１……ケース、２……端子、３ａ〜３ｄ……電
池、４……絶縁材、６……火道口、１２……発熱
剤。
FIG. 1 is a side view showing an embodiment of the battery of the present invention;
Figure 2 is an enlarged cross-sectional view, Figure 3 is Figure 2-
'It is a sectional view. DESCRIPTION OF SYMBOLS 1... Case, 2... Terminal, 3a-3d... Battery, 4... Insulating material, 6... Fire vent, 12... Exothermic agent.
Claims (1)
よび発熱剤を順に積層した複数の扇形電池を、絶
縁材により相互に区画し全体として円柱状を構成
するよう電池ケース内に配置するとともに、円柱
状の中央部分に各電池の発熱剤に共通な円筒形の
貫通火道口を設け、各電池は発熱剤の着火点を発
熱剤面積に比例した円弧端面として前記円筒形の
貫通火道口に露出させている熱電池。1. A plurality of sector-shaped batteries in which a sector-shaped positive electrode current collector plate, a power generation element, a negative electrode current collector plate, and a heat generating agent are laminated in order are separated from each other by insulating material and arranged in a battery case so as to form a cylindrical shape as a whole. A cylindrical through-hole common to the exothermic agent of each battery is provided in the central part of the cylinder, and each battery is exposed to the cylindrical through-hole as an arcuate end face proportional to the area of the exothermic agent with the ignition point of the exothermic agent. Thermal battery.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14124281A JPS5842176A (en) | 1981-09-07 | 1981-09-07 | Thermal battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14124281A JPS5842176A (en) | 1981-09-07 | 1981-09-07 | Thermal battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5842176A JPS5842176A (en) | 1983-03-11 |
| JPS6129103B2 true JPS6129103B2 (en) | 1986-07-04 |
Family
ID=15287391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14124281A Granted JPS5842176A (en) | 1981-09-07 | 1981-09-07 | Thermal battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5842176A (en) |
-
1981
- 1981-09-07 JP JP14124281A patent/JPS5842176A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5842176A (en) | 1983-03-11 |
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