JPS61280046A - Optical recording system - Google Patents

Optical recording system

Info

Publication number
JPS61280046A
JPS61280046A JP60121493A JP12149385A JPS61280046A JP S61280046 A JPS61280046 A JP S61280046A JP 60121493 A JP60121493 A JP 60121493A JP 12149385 A JP12149385 A JP 12149385A JP S61280046 A JPS61280046 A JP S61280046A
Authority
JP
Japan
Prior art keywords
crystal
information
optical recording
liq
liquid crystal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60121493A
Other languages
Japanese (ja)
Inventor
Toyoichi Nakamura
中村 豊一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP60121493A priority Critical patent/JPS61280046A/en
Publication of JPS61280046A publication Critical patent/JPS61280046A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To enable the recording of information having high S/N and capable of being reloaded by using different and uniform oriented states of a liq. crystal group in recording and erasing information. CONSTITUTION:A voltage is applied between transparent electrodes 3 and 5, an electric field is impressed on a high molecular liq. crystal 4 to heat the crystal to about 90 deg.C and the liq. crystal is oriented in the direction vertical to a glass substrate. Accordingly, an optical recording medium providing a dark field under crossed Nicols even when cooled is formed. Then when high- density energy light 7 is irradiated while rotating the optical recording medium 1 around the central axis without impressing a voltage between the electrodes 3 and 5, the high molecular liq. crystal at the irradiated part is oriented in the direction different from the initial orientation, namely in the direction parallel to the glass substrate, by the shearing stress due to the rotation and the information can be recorded by the bright field under crossed Nicols. The voltage is applied between the transparent electrodes 3 and 5, light is irradiated on the recorded part of the liq. crystal while impressing an electric field on the high molecular liq. crystal 4 to locally heat the part, hence the crystal is returned to the initial uniform orientation and the information is erased.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、書換え可能な情報記録方式に関するものであ
る。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a rewritable information recording system.

〔従来技術とその問題点〕[Prior art and its problems]

従来、書換え可能な情報記録方式としては、磁気光学材
料を用い磁気光学効果を利用した光磁気記録方式および
無機系材料を用い相変化を利用した書換え可能な情報記
録方式が知られている。
Conventionally, as rewritable information recording systems, there are known magneto-optical recording systems that use magneto-optical materials and utilize the magneto-optic effect, and rewritable information recording systems that use inorganic materials and utilize phase change.

しかしながら光磁気記録方式においては、S/N比が〜
40dBと低いことに加え部分消去できないという欠点
を有する。また無機系材料を用い相変化を利用した記録
方式においては、S/N比が59dBと向上しているも
ののS/N比はまだ十分ではない。
However, in the magneto-optical recording method, the S/N ratio is ~
In addition to being as low as 40 dB, it has the disadvantage that it cannot be partially erased. Furthermore, in a recording method using an inorganic material and utilizing phase change, although the S/N ratio has improved to 59 dB, the S/N ratio is still not sufficient.

また、このような記録方式に用いられる記録媒体の製法
においては、スパッタ等を用いているので製造コストが
かかるという欠点を有する。
Furthermore, the method of manufacturing a recording medium used in such a recording method uses sputtering or the like, which has the disadvantage of high manufacturing costs.

以上のような従来技術の欠点を解消するために、高分子
液晶を用いた記録方式が特開昭59−10930号公報
および特開昭59−35989号公報において提案され
ている。かかる方式においては、書込みあるいは消去に
おいて液晶の無配向状態を用いるため、入射光が散乱さ
れ、検出機構が制限される為、S/N比が悪いという欠
点を有する。
In order to overcome the above-mentioned drawbacks of the prior art, recording systems using polymeric liquid crystals have been proposed in Japanese Patent Laid-Open Nos. 59-10930 and 1987-35989. In such a method, since the non-aligned state of the liquid crystal is used for writing or erasing, incident light is scattered and the detection mechanism is limited, resulting in a poor S/N ratio.

〔発明の目的〕[Purpose of the invention]

本発明の目的は、高分子液晶を用いた記録方式であって
、高いS/N比を実現できる書換え可能な情報記録方式
を提供することにある。
SUMMARY OF THE INVENTION An object of the present invention is to provide a rewritable information recording system that uses polymer liquid crystal and can achieve a high S/N ratio.

〔発明の構成〕[Structure of the invention]

本発明は、高分子液晶を用いた光記録媒体に情報を記録
し、記録された情報を消去する光記録方式において、均
一に初期分子配向した高分子液晶に対して、光ビームの
照射と光記録媒体の回転による分子配向力を与え、前期
初期配向とは異なる方向に均一配向させることにより情
報の書込みを行い、加熱と同時に電場を印加し、高分子
液晶を初期の均一配向に戻すことにより前期書込まれた
情報を消去することを特徴としている。
In an optical recording method for recording information on an optical recording medium using a polymer liquid crystal and erasing the recorded information, the present invention is directed to the irradiation of a light beam to a polymer liquid crystal with uniform initial molecular orientation. Information is written by applying a molecular orientation force by rotating the recording medium to uniformly orient it in a direction different from the initial orientation, and by applying an electric field at the same time as heating to return the polymer liquid crystal to its initial uniform orientation. It is characterized by erasing information written in the previous period.

〔構成の詳細な説明〕[Detailed explanation of configuration]

本発明の基本的動作原理を説明する。高分子液晶として
は、種々のものが知られているが(刊行物「表面J 、
 Vo 1,20. No、 9 (1982)、  
P479〜491、広信社出版)、本発明には、温度。
The basic operating principle of the present invention will be explained. Various types of polymer liquid crystals are known (Publication "Surface J",
Vo 1,20. No. 9 (1982),
P479-491, Koshinsha Publishing), the present invention includes temperature.

電場およびせん断応力により変化する性質を有する高分
子液晶を用いる必要があり、これには主鎖ポリマーに液
晶基を付加したいわゆる側鎖型高分子液晶が特に適して
いる。本発明の動作は、液晶基の配向効果に基づくもの
である。
It is necessary to use a polymer liquid crystal that has properties that change with electric field and shear stress, and so-called side chain type polymer liquid crystals, in which liquid crystal groups are added to the main chain polymer, are particularly suitable for this purpose. The operation of the present invention is based on the alignment effect of liquid crystal groups.

ガラス転移温度1等方相転移温度を適度に調整された高
分子液晶は、一般に室温では通常のポリマーと同様に固
体状態であるが、等方相近くもしくはそれ以上の温度で
は適度の粘土のため、低分子液晶と同様の外場応答性を
示す。即ち、例えば、誘電異方性が正の液晶基を有する
高分子液晶は、電場印加のもとで、液晶基の分子長軸方
向は電場方向に配向する。室温まで戻すとその配向状態
はそのまま保持される。同じく等方相近くもしくはそれ
以上の温度で高分子液晶を回転すると回転方向に流動配
向し、室温まで戻すとその配向状態はそのまま保持され
る。
Glass transition temperature 1 Polymer liquid crystals whose isotropic phase transition temperature has been appropriately adjusted are generally in a solid state at room temperature like ordinary polymers, but at temperatures close to or higher than the isotropic phase, they are in a moderately clayey state. , exhibits external field responsiveness similar to that of low-molecular liquid crystals. That is, for example, in a polymeric liquid crystal having a liquid crystal group with positive dielectric anisotropy, when an electric field is applied, the long axis direction of the molecules of the liquid crystal group is aligned in the direction of the electric field. When the temperature is returned to room temperature, the orientation state is maintained as it is. Similarly, when a polymeric liquid crystal is rotated at a temperature close to or higher than the isotropic phase, it becomes fluidly oriented in the direction of rotation, and when returned to room temperature, the oriented state is maintained as it is.

本発明は、上記2つの異なる均一な配向状態にもとづき
、情報の記録及び消去を行うものである。
The present invention records and erases information based on the two different uniform orientation states.

高分子液晶が相変化するのに必要な温度T1と配向する
のに必要な電圧■1を与えると高分子液晶は一定方向に
均一に配向する。この状態で冷却すると、電圧を切って
も高分子液晶の配向した状態は維持される。
When a temperature T1 necessary for phase change of the polymer liquid crystal and a voltage 1 necessary for alignment are applied, the polymer liquid crystal is uniformly aligned in a certain direction. When cooled in this state, the oriented state of the polymer liquid crystal is maintained even if the voltage is turned off.

以上のように均一に初期分子配向した高分子液晶に対し
て、高密度エネルギー光を照射し温度T1に上昇させ、
高分子液晶を回転させることによって、高分子液晶に回
転流動によるせん断応力を加えれば上記配向とは異なる
配向状態が得られ、冷却すればこの状態は維持される。
The polymer liquid crystal with uniform initial molecular orientation as described above is irradiated with high-density energy light to raise the temperature to T1,
By rotating the polymer liquid crystal and applying shear stress due to rotational flow to the polymer liquid crystal, an orientation state different from the above-mentioned orientation can be obtained, and this state is maintained when the polymer liquid crystal is cooled.

これにより光記録が可能になる。This enables optical recording.

以上のようにしてなされた記録を消去するには、高分子
液晶に電圧■1を印加した状態で全面を加熱し温度T1
にすれば高分子液晶を初期の均一配向に戻すことにより
記録の全面消去が可能である。
To erase the records made in the above manner, the entire surface of the polymer liquid crystal is heated to a temperature of T1 while a voltage of 1 is applied.
By doing so, it is possible to erase the entire recording by returning the polymer liquid crystal to its initial uniform orientation.

また、電圧■1を印加したままレーザー光等により局部
的に加熱し温度T、にすれば部分消去も可能になる。
Furthermore, partial erasure is also possible by heating the area locally with a laser beam or the like to a temperature T while applying the voltage (1).

〔実施例〕〔Example〕

以下、本発明の実施例を図面に基づいて説明する。 Embodiments of the present invention will be described below based on the drawings.

第1図は、本発明の一実施例の光記録方式に用いる光記
録媒体の一例を示す模式的断面図、第2図および第3図
は、情報の書込み(記録)および消去をそれぞれ説明す
るための図である。
FIG. 1 is a schematic cross-sectional view showing an example of an optical recording medium used in an optical recording system according to an embodiment of the present invention, and FIGS. 2 and 3 illustrate writing (recording) and erasing of information, respectively. This is a diagram for

第1図において、光記録媒体1は、例えば直径20cm
のガラス基板2上にITOを透明電極として設けた上に
、下記構造式 %式% の高分子液晶4を加熱し、ディピングにより塗布し、ス
ペーサ(図示せず)にて厚みを10μmとし、さらにI
TOを透明電極5として設けたガラス基板6を設けるこ
とにより構成される。光記録媒体の構造はこれに限るも
のではなく、光ビームの吸収効率を上げるため光吸収層
、もしくは光反射層を光記録媒体中に設置してもよい。
In FIG. 1, the optical recording medium 1 has a diameter of, for example, 20 cm.
ITO was provided as a transparent electrode on a glass substrate 2, and then a polymer liquid crystal 4 having the following structural formula % was applied by heating and dipping, and the thickness was made 10 μm using spacers (not shown). I
It is constructed by providing a glass substrate 6 on which TO is provided as a transparent electrode 5. The structure of the optical recording medium is not limited to this, and a light absorption layer or a light reflection layer may be provided in the optical recording medium in order to increase the absorption efficiency of the light beam.

以上のような光記録媒体1の透明電極3−5間に電圧を
与え高分子液晶4に電場(>3V/μm)を印加しなが
ら約90℃に加熱すると液晶基がガラス基板に対し垂直
に配向し、冷却しても直交ニコル下において暗視野を与
える光記録媒体が作成される。
When a voltage is applied between the transparent electrodes 3 and 5 of the optical recording medium 1 as described above and the polymer liquid crystal 4 is heated to about 90°C while applying an electric field (>3V/μm), the liquid crystal group becomes perpendicular to the glass substrate. An optical recording medium is created which provides a dark field under crossed Nicols even when oriented and cooled.

次に、第2図に示すように透明電極3−5間に電圧を印
加せずに光記録媒体1を中心軸の回りに600〜180
0 r p mで回転させながら高密度エネルギー光7
、例えばHe−Neレーザ(10mW、10m5)を照
射したところ、照射された部分の高分子液晶は、回転流
動によるせん断芯力により、初期配向とは異なる方向、
即ちガラス基板に対し平行に配向し、直交ニコル下で明
視野を与える情報記録ができた。S/N比は70dBで
あった。
Next, as shown in FIG. 2, the optical recording medium 1 is rotated 600 to 180 degrees around the central axis without applying a voltage between the transparent electrodes 3 and 5.
High-density energy light 7 while rotating at 0 rpm
For example, when irradiated with a He-Ne laser (10mW, 10m5), the polymer liquid crystal in the irradiated area will be oriented in a direction different from the initial orientation due to the shear core force caused by rotational flow.
In other words, it was possible to record information that was oriented parallel to the glass substrate and provided a bright field under crossed Nicols conditions. The S/N ratio was 70 dB.

以上のようにして記録された情報を消去するには、第3
図に示すように光記録媒体1の透明電極3−5間に電圧
を与え高分子液晶4に電場(〉3■/μm)を印加しな
がら、高分子液晶の記録された部分に高密度エネルギー
光7、例えばレーザを照射して局部的に約90℃に加熱
すると、初期の均一配向に戻り、情報が消去され、再び
暗視野を与える情報記録媒体が再生された。以上は、部
分消去の場合であるが、適切な加熱手段により全面を加
熱すれば全面消去が可能となることは明らかである。
To erase the information recorded in the above manner,
As shown in the figure, while applying a voltage between the transparent electrodes 3 and 5 of the optical recording medium 1 and applying an electric field (〉3μ/μm) to the polymer liquid crystal 4, high-density energy is applied to the recorded portion of the polymer liquid crystal. When locally heated to about 90° C. by irradiation with light 7, for example a laser, the initial uniform orientation was restored, the information was erased, and the information recording medium giving a dark field was reproduced again. The above is a case of partial erasing, but it is clear that erasing the entire area becomes possible by heating the entire surface with an appropriate heating means.

なお、以上の実施例は本発明の一例を述べたものであり
、本発明はこの実施例にのみ限定されるものではない。
Note that the above embodiment describes an example of the present invention, and the present invention is not limited only to this embodiment.

例えば、加熱温度は用いる高分子液晶の等方相温度に依
存するものであり、種々の温度条件の材料により選択可
能なことは勿論である。
For example, the heating temperature depends on the isotropic phase temperature of the polymer liquid crystal used, and can of course be selected depending on the material under various temperature conditions.

〔発明の効果〕〔Effect of the invention〕

本発明によれば、情報の記録および消去において液晶基
の異なる均一な配向状態を用いることにより、従来知ら
れている散乱状態を用いる場合と比較して高いS/N比
を持つ、書換え可能な情報記録が可能となる。
According to the present invention, by using different uniform alignment states of liquid crystal groups in recording and erasing information, the rewritable Information recording becomes possible.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例に用いられる情報記録媒体の
一例を示す断面図、 第2図は第1図の情報記録媒体における記録を説明する
ための図、 第3図は、第1図の情報記録媒体における消去を説明す
るための図である。 1・・・光記録媒体 2.6・・・ガラス基板 3、訃・・透明電極 4・・・高分子液晶 7・・・高密度エネルギー光 代理人 弁理士  岩 佐 義 幸 1 光t!tjtd林 第1図 第2図
FIG. 1 is a sectional view showing an example of an information recording medium used in an embodiment of the present invention, FIG. 2 is a diagram for explaining recording in the information recording medium of FIG. 1, and FIG. FIG. 3 is a diagram for explaining erasure in the information recording medium shown in the figure. 1... Optical recording medium 2. 6... Glass substrate 3, Transparent electrode 4... Polymer liquid crystal 7... High-density energy light Agent Patent attorney Yoshiyuki Iwasa 1 Light t! tjtd forest fig. 1 fig. 2

Claims (1)

【特許請求の範囲】[Claims] (1)高分子液晶を用いた光記録媒体に情報を記録し、
記録された情報を消去する光記録方式において、均一に
初期分子配向した高分子液晶に対して、光ビームの照射
と光記録媒体の回転による分子配向力を与え、前期初期
配向とは異なる方向に均一配向させることにより情報の
書込みを行い、加熱と同時に電場を印加し、高分子液晶
を初期の均一配向に戻すことにより前記書込まれた情報
を消去することを特徴とする光記録方式。
(1) Recording information on an optical recording medium using polymer liquid crystal,
In the optical recording method for erasing recorded information, a molecular alignment force is applied to a polymer liquid crystal with a uniform initial molecular orientation by irradiation with a light beam and rotation of an optical recording medium, which causes the molecules to be oriented in a direction different from the initial orientation. An optical recording method characterized in that information is written by uniformly aligning the crystal, and the written information is erased by applying an electric field at the same time as heating to return the polymer liquid crystal to its initial uniform alignment.
JP60121493A 1985-06-06 1985-06-06 Optical recording system Pending JPS61280046A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60121493A JPS61280046A (en) 1985-06-06 1985-06-06 Optical recording system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60121493A JPS61280046A (en) 1985-06-06 1985-06-06 Optical recording system

Publications (1)

Publication Number Publication Date
JPS61280046A true JPS61280046A (en) 1986-12-10

Family

ID=14812527

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60121493A Pending JPS61280046A (en) 1985-06-06 1985-06-06 Optical recording system

Country Status (1)

Country Link
JP (1) JPS61280046A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62283433A (en) * 1986-02-04 1987-12-09 レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング Reversibly optical information memorization
US5150339A (en) * 1989-04-24 1992-09-22 Hitachi, Ltd. Optical disk medium and its application method and system
JP2006332609A (en) * 2005-04-28 2006-12-07 Semiconductor Energy Lab Co Ltd Memory device and semiconductor device
US7550181B2 (en) 1999-01-08 2009-06-23 Dai Nippon Printing Co., Ltd. Information recording medium
US8264889B2 (en) 2005-04-28 2012-09-11 Semiconductor Energy Laboratory Co., Ltd. Memory device and semiconductor device

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62283433A (en) * 1986-02-04 1987-12-09 レ−ム・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング Reversibly optical information memorization
US5150339A (en) * 1989-04-24 1992-09-22 Hitachi, Ltd. Optical disk medium and its application method and system
US7550181B2 (en) 1999-01-08 2009-06-23 Dai Nippon Printing Co., Ltd. Information recording medium
JP2006332609A (en) * 2005-04-28 2006-12-07 Semiconductor Energy Lab Co Ltd Memory device and semiconductor device
US8264889B2 (en) 2005-04-28 2012-09-11 Semiconductor Energy Laboratory Co., Ltd. Memory device and semiconductor device

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