JPS61277179A - Conductive anisotropic adhesive sheet - Google Patents

Conductive anisotropic adhesive sheet

Info

Publication number
JPS61277179A
JPS61277179A JP11826285A JP11826285A JPS61277179A JP S61277179 A JPS61277179 A JP S61277179A JP 11826285 A JP11826285 A JP 11826285A JP 11826285 A JP11826285 A JP 11826285A JP S61277179 A JPS61277179 A JP S61277179A
Authority
JP
Japan
Prior art keywords
conductive
adhesive sheet
connection
conductive layers
anisotropic adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11826285A
Other languages
Japanese (ja)
Inventor
雅之 中村
末吉 正憲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dexerials Corp
Original Assignee
Sony Chemicals Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sony Chemicals Corp filed Critical Sony Chemicals Corp
Priority to JP11826285A priority Critical patent/JPS61277179A/en
Publication of JPS61277179A publication Critical patent/JPS61277179A/en
Pending legal-status Critical Current

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  • Combinations Of Printed Boards (AREA)
  • Non-Insulated Conductors (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、夫々接続導電層の被着形成された配線基板同
士を接着すると共に、各接続導電層を電気的に接続する
ようにした導電異方性接着シートに関する。
[Detailed Description of the Invention] [Industrial Application Field] The present invention provides a conductive method for bonding wiring boards each having a connecting conductive layer thereon and electrically connecting each connecting conductive layer. This invention relates to an anisotropic adhesive sheet.

C発明の概要〕 本発明は導電異方性接着シートに関し、導電性粒子の集
合体が、所要の配列で熱溶融性接着剤中に含有せしめら
れて構成されることにより、夫々接続導電層の被着形成
された配線基板同士の各接続導電層を、接続抵抗が低く
、隣接接続導電眉間の絶縁抵抗が高く;なり、且つ隣接
接続導電層間の端部に於ける短絡事故が少なくなるよう
に、接続することができるようにしたちである。
C. Summary of the Invention] The present invention relates to an electrically conductive anisotropic adhesive sheet, in which aggregates of electrically conductive particles are contained in a hot-melt adhesive in a desired arrangement, thereby forming a connection conductive layer. Each connection conductive layer between the bonded wiring boards is made to have low connection resistance, high insulation resistance between adjacent connection conductive layers, and to reduce short-circuit accidents at the ends between adjacent connection conductive layers. , so that we can connect.

〔従来の技術〕[Conventional technology]

従来の導電異方性接着シートは、熱溶融性接着剤中に、
低融点半田金属粒子等の導電性粒子を、無秩序に分散し
て構成していた。
Conventional conductive anisotropic adhesive sheets contain hot-melt adhesive,
It was constructed by randomly dispersing conductive particles such as low melting point solder metal particles.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

ところが、かかる導電異方性接着シートを用いて、配線
基板同士を接着すると共に、その各接続導電層を接続す
ると、各接続導電層の接続抵抗があまり低くならなかっ
たり、隣接する接続導電層間の絶縁抵抗が十分に高くな
らなかったり、又各配線基板の接着時にその端部に於い
て、各配線導電層間の接着剤の流失により、導電性粒子
が塊りとなって隣接する接続導電層間を短絡させる虞が
あった。
However, when such a conductive anisotropic adhesive sheet is used to bond wiring boards together and connect their respective connection conductive layers, the connection resistance of each connection conductive layer does not decrease very much, and the connection resistance between adjacent connection conductive layers If the insulation resistance is not high enough, or if the adhesive between each wiring conductive layer is washed away at the end when each wiring board is bonded, conductive particles may clump together and cause problems between adjacent connecting conductive layers. There was a risk of a short circuit.

かかる点に鑑み本発明は、夫、々、接続導電層の被着形
成された配線基板同士の各接続導電層を、接続抵抗が低
く、隣接接続導電層間の絶縁抵抗が高くなり、且つ隣接
接続導電層間の端部に於ける短絡事故が少な(なるよう
に、接続することのできる導電異方性接着シートを提案
しようとするものである。
In view of these points, the present invention provides a structure in which each connecting conductive layer between wiring boards on which connecting conductive layers are deposited has low connection resistance, high insulation resistance between adjacent connecting conductive layers, and The purpose of this paper is to propose a conductive anisotropic adhesive sheet that can connect conductive layers with fewer short-circuit accidents at the ends.

〔問題点を解決するための手段〕[Means for solving problems]

本発明による導電異方性接着シートは、導電性粒子の集
合体が、所要の配列で熱熔融性接着剤中に含有せしめら
れて構成される。
The electrically conductive anisotropic adhesive sheet according to the present invention is constructed by containing aggregates of electrically conductive particles in a desired arrangement in a hot-melt adhesive.

〔作用〕[Effect]

本発明によれば、導電性粒子の集合体が所要の配列で熱
溶融性接着剤中に含有せしめられているので、この集合
体の配列状態を、接着すべき配線基板の接続導電層のパ
ターンに応じて、選定することにより、各接続導電層の
接続抵抗が低く、隣接接続導電層間の絶縁抵抗が高く成
り、且つ隣接接続導電層間の端部に於ける短絡事故が少
なくなるようにすることができる。
According to the present invention, since aggregates of conductive particles are contained in a hot-melt adhesive in a required arrangement, the arrangement of the aggregates is determined by the pattern of the connecting conductive layer of the wiring board to be bonded. By selecting the conductive layer according to the above, the connection resistance of each connecting conductive layer is low, the insulation resistance between adjacent connecting conductive layers is high, and short-circuit accidents at the ends between adjacent connecting conductive layers are reduced. Can be done.

〔実施例〕〔Example〕

以下に第1図及び第2図を参照して、本発明の一実施例
をその製法と共に詳細に説明しよう。第1図A及び第2
図に示す如く、例えばポリエチレンテレフタレートより
成る剥離シート(3)上に、例えばシルクスクリーン法
により、導電性粒子の集合体(1)を格子状に印刷する
。尚、導電粒子の集合体(1)の密度は、配線基板の接
続導電層の方向に於いて高くし、それと直交する方向に
於いて低くする〔但し、接続導電層の間隔の整数(1,
2,3、・・・)倍とする〕ことができる。
Hereinafter, an embodiment of the present invention will be described in detail together with its manufacturing method with reference to FIGS. 1 and 2. Figures 1A and 2
As shown in the figure, aggregates (1) of conductive particles are printed in a grid pattern on a release sheet (3) made of, for example, polyethylene terephthalate, by, for example, a silk screen method. The density of the conductive particle aggregates (1) is made higher in the direction of the connection conductive layer of the wiring board and lower in the direction orthogonal thereto [however, the density of the conductive particle aggregate (1) is increased in the direction perpendicular to the direction of the connection conductive layer of the wiring board.
2, 3, ...) times].

この導電性粒子の集合体(1)としては、例えば3μm
径の銀粒子及び接着剤としてのフェノール樹脂を夫左同
重量部用意し、これを溶剤としてのトルエン及びメチル
エチルケトンの混合液に溶解したものを、例えば0.3
mm径のド・ノド状としたものである。
The conductive particle aggregate (1) has a diameter of, for example, 3 μm.
Prepare silver particles of the same diameter and the same weight parts of a phenol resin as an adhesive, and dissolve them in a mixture of toluene and methyl ethyl ketone as a solvent, for example, 0.3
It has a do-nod shape with a diameter of mm.

そして、第1図Bに示すごとく、剥離シート(3)及び
導電性粒子の集合体(1)の全体に絶縁体としての熱溶
融性接着剤(2)をコーティングする。この熱溶融性接
着剤(2)は、導電粒子の集合体(1)の接着剤より溶
融温度の低い接着剤、例えばポリエステル系樹脂を用い
る。
Then, as shown in FIG. 1B, the release sheet (3) and the conductive particle aggregate (1) are entirely coated with a hot-melt adhesive (2) as an insulator. This hot-melt adhesive (2) uses an adhesive having a lower melting temperature than the adhesive of the conductive particle aggregate (1), such as a polyester resin.

次に、第3図及び第4図を参照して、本発明により得ら
れた導電異方性接着シートを用いて、配線基板同士を接
着すると共に、その各接続導電層を電気的に接続する場
合の一例を説明する。(5)及び(6)は互いに接着す
べき配線基板(可撓性配線基板)を示し、夫々例えばポ
リエチレンテレフタレートから成る絶縁基板(5a)、
(6a)上に、夫々帯状で互いに平行な例えばカーボン
あるいは銅から成る接続導電層(5b)、(6b)が互
いに対応するように被着形成されている。しかして、一
方の配線基板(5)の端部の接続導電層(5b)側に本
発明により得られた導電異方性接着シート(4)の接着
剤(2)側を貼付し、しかる後剥離シート(3)を剥が
し、この接着剤(2)上に配線基板(6)の端部の接続
導電層(6b)側を貼付する(第4図A参照)。尚、第
3図では・接着シート(4)上に被着された剥離シート
(3)は図示を省略しである。しかる後、配線基板(5
)、接着シート(4)及び配線基板(6)に対し、例え
ば130℃の温度と、”40kg/antの圧力を30
秒間加える。かくすると、第4図Bに示す如く、接着剤
(2)が溶融し、接続導電層(5b)、(6b)間の導
電粒子の集合体(1)が潰されて、両接続導電層(5b
)、(6b)間を電気的に低抵抗で接続す導電体となる
と共に、熱溶融性接着剤(2)によって配線基板(5)
、(6)が強固にこ接着される。この場合、剥離強度は
1 、71qr / cutとかなり強く成る。又、隣
接する接続導電層(5b)、(6b)間の導電粒子の集
合体(1)は、その間で孤立し、隣接する接続導電層(
5b)、(6b)間を短絡する虞は無い。
Next, with reference to FIGS. 3 and 4, the conductive anisotropic adhesive sheet obtained according to the present invention is used to bond the wiring boards together and to electrically connect the respective connecting conductive layers. An example of the case will be explained. (5) and (6) indicate wiring boards (flexible wiring boards) to be bonded to each other, including an insulating board (5a) made of, for example, polyethylene terephthalate;
Connecting conductive layers (5b) and (6b) made of carbon or copper, for example, are formed on (6a) and are parallel to each other in the form of strips so as to correspond to each other. Then, the adhesive (2) side of the conductive anisotropic adhesive sheet (4) obtained according to the present invention is pasted on the connection conductive layer (5b) side at the end of one wiring board (5), and then The release sheet (3) is peeled off, and the connection conductive layer (6b) side of the end of the wiring board (6) is pasted onto the adhesive (2) (see FIG. 4A). In FIG. 3, the release sheet (3) attached to the adhesive sheet (4) is not shown. After that, connect the wiring board (5
), the adhesive sheet (4) and the wiring board (6) are subjected to a temperature of 130°C and a pressure of 40 kg/ant for 30 minutes.
Add seconds. As a result, as shown in FIG. 4B, the adhesive (2) melts, and the aggregate (1) of conductive particles between the connecting conductive layers (5b) and (6b) is crushed, and both the connecting conductive layers ( 5b
), (6b), and serves as a conductor that electrically connects the wiring board (5) with low resistance.
, (6) are firmly adhered. In this case, the peel strength is quite strong at 1.71 qr/cut. Further, the aggregate (1) of conductive particles between the adjacent connection conductive layers (5b) and (6b) is isolated between them, and the conductive particle aggregate (1) between the adjacent connection conductive layers (5b) and (6b)
There is no risk of short-circuiting between 5b) and (6b).

次に、配線基板(5)、(6)の接続導電層(5b)、
(6b)がカーボンである場合のエージング後の接続導
電層(5b)、(6b)間の抵抗の測定結果を示す。エ
ージング時間が零の場合は、抵抗は1.OkΩであった
。目的物を80℃で夫々48時間及び360時間エージ
ングを行った場合、抵抗は共に1.3にΩであった。
Next, the connection conductive layer (5b) of the wiring board (5), (6),
The results of measuring the resistance between the connecting conductive layers (5b) and (6b) after aging when (6b) is carbon are shown. If the aging time is zero, the resistance is 1. It was OK. When the objects were aged at 80° C. for 48 hours and 360 hours, respectively, the resistance was 1.3Ω.

因に、導電粒子の集合体(1)の成分の内フェノール樹
脂を除去した場合は、エージング時間が零の場合は、抵
抗が1.OkΩであったものが、目的物を80℃で夫々
48時間及び360時間エージングを行ったときの抵抗
は夫々20にΩと高くなった。この場合は、剥離強度も
上述の場合に比し、かなり弱い。
Incidentally, if the phenol resin among the components of the conductive particle aggregate (1) is removed, the resistance will be 1.0 when the aging time is zero. When the target material was aged at 80° C. for 48 hours and 360 hours, the resistance increased to 20 Ω, respectively. In this case, the peel strength is also considerably lower than in the above case.

上述の実施例の場合、フェノール樹脂はカーボンや銅に
接着し易く、又、その熔融温度は130℃である。配線
基板(5)、(6)の絶縁基板(5a)、(6a)の材
料であるポリエチレンテレフタレートの溶融温度は10
0°Cである。更に、熱溶融性接着剤(2)であるポリ
エステル系接着剤の溶融温度は50℃である。
In the case of the above embodiment, the phenol resin easily adheres to carbon and copper, and its melting temperature is 130°C. The melting temperature of polyethylene terephthalate, which is the material of the insulating substrates (5a) and (6a) of the wiring boards (5) and (6), is 10
It is 0°C. Furthermore, the melting temperature of the polyester adhesive, which is the hot-melt adhesive (2), is 50°C.

しかして、この実施例の導電異方性接着シートを用いる
と、低温低圧プレスによる、配線基板同士の接着が可能
と成る。
Therefore, by using the conductive anisotropic adhesive sheet of this example, it becomes possible to bond wiring boards together by low temperature and low pressure pressing.

〔発明の効果〕〔Effect of the invention〕

上述せる本発明によれば、夫々接続導電層の被着形成さ
れた配線基板同士の各接続導電層を、接続抵抗が低く、
隣接接続導電層間の絶縁抵抗が高く成り、且つ隣接接続
導電層間の端部に於ける短絡事故が少なくなるように、
接続することのできる導電異方性接着シートを得ること
ができる。
According to the present invention described above, each of the connection conductive layers between the wiring boards on which the connection conductive layers are deposited has a low connection resistance.
In order to increase the insulation resistance between adjacent connected conductive layers and reduce short circuit accidents at the ends between adjacent connected conductive layers,
A conductive anisotropic adhesive sheet that can be connected can be obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明による導電異方性接着シートの製法の工
程を示す断面図、第2図はその製法の工程の一部を示す
平面部分図、第3図は配線基板の接続工程を示す斜視図
、第4図は配線基板の接続工程を示す断面図である。 (1)は導電粒子の集合体、(2)は熱溶融性接着剤、
(3)は剥離シート、(4)は導電異方性接着シート、
(5)、(6)は配線基板である。 第3図
Figure 1 is a cross-sectional view showing the manufacturing process of a conductive anisotropic adhesive sheet according to the present invention, Figure 2 is a partial plan view showing a part of the manufacturing process, and Figure 3 is a wiring board connection process. The perspective view and FIG. 4 are cross-sectional views showing the process of connecting the wiring board. (1) is an aggregate of conductive particles, (2) is a hot melt adhesive,
(3) is a release sheet, (4) is a conductive anisotropic adhesive sheet,
(5) and (6) are wiring boards. Figure 3

Claims (1)

【特許請求の範囲】[Claims]  導電性粒子の集合体が、所要の配列で熱溶融性接着剤
中に含有せしめられて成ることを特徴とする導電異方性
接着シート。
1. A conductive anisotropic adhesive sheet comprising an aggregate of conductive particles contained in a hot-melt adhesive in a desired arrangement.
JP11826285A 1985-05-31 1985-05-31 Conductive anisotropic adhesive sheet Pending JPS61277179A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11826285A JPS61277179A (en) 1985-05-31 1985-05-31 Conductive anisotropic adhesive sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11826285A JPS61277179A (en) 1985-05-31 1985-05-31 Conductive anisotropic adhesive sheet

Publications (1)

Publication Number Publication Date
JPS61277179A true JPS61277179A (en) 1986-12-08

Family

ID=14732269

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11826285A Pending JPS61277179A (en) 1985-05-31 1985-05-31 Conductive anisotropic adhesive sheet

Country Status (1)

Country Link
JP (1) JPS61277179A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6476608A (en) * 1987-09-16 1989-03-22 Shinetsu Polymer Co Aeolotropic conductive adhesive film
US6180226B1 (en) 1996-08-01 2001-01-30 Loctite (R&D) Limited Method of forming a monolayer of particles, and products formed thereby
US6402876B1 (en) 1997-08-01 2002-06-11 Loctite (R&D) Ireland Method of forming a monolayer of particles, and products formed thereby
US6977025B2 (en) 1996-08-01 2005-12-20 Loctite (R&D) Limited Method of forming a monolayer of particles having at least two different sizes, and products formed thereby
JP2017098077A (en) * 2015-11-24 2017-06-01 デクセリアルズ株式会社 Anisotropic conductive film and connection method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6476608A (en) * 1987-09-16 1989-03-22 Shinetsu Polymer Co Aeolotropic conductive adhesive film
US6180226B1 (en) 1996-08-01 2001-01-30 Loctite (R&D) Limited Method of forming a monolayer of particles, and products formed thereby
US6977025B2 (en) 1996-08-01 2005-12-20 Loctite (R&D) Limited Method of forming a monolayer of particles having at least two different sizes, and products formed thereby
US6402876B1 (en) 1997-08-01 2002-06-11 Loctite (R&D) Ireland Method of forming a monolayer of particles, and products formed thereby
JP2017098077A (en) * 2015-11-24 2017-06-01 デクセリアルズ株式会社 Anisotropic conductive film and connection method

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