JPS61267261A - Flat battery with leads - Google Patents

Flat battery with leads

Info

Publication number
JPS61267261A
JPS61267261A JP60108734A JP10873485A JPS61267261A JP S61267261 A JPS61267261 A JP S61267261A JP 60108734 A JP60108734 A JP 60108734A JP 10873485 A JP10873485 A JP 10873485A JP S61267261 A JPS61267261 A JP S61267261A
Authority
JP
Japan
Prior art keywords
terminal plates
leads
plate
steps
positive electrode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP60108734A
Other languages
Japanese (ja)
Inventor
Shintaro Suzuki
信太郎 鈴木
Koji Fujita
宏次 藤田
Yoshiaki Asami
阿佐美 義明
Fumiko Honma
本間 富美子
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FDK Twicell Co Ltd
Original Assignee
Toshiba Battery Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Battery Co Ltd filed Critical Toshiba Battery Co Ltd
Priority to JP60108734A priority Critical patent/JPS61267261A/en
Publication of JPS61267261A publication Critical patent/JPS61267261A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/172Arrangements of electric connectors penetrating the casing
    • H01M50/174Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
    • H01M50/176Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for prismatic or rectangular cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/547Terminals characterised by the disposition of the terminals on the cells
    • H01M50/55Terminals characterised by the disposition of the terminals on the cells on the same side of the cell
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/552Terminals characterised by their shape
    • H01M50/553Terminals adapted for prismatic, pouch or rectangular cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/562Terminals characterised by the material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Connection Of Batteries Or Terminals (AREA)

Abstract

PURPOSE:To firmly connect metal plate leads to a positive and a negative electrode terminal plates without increasing the total height of a flat battery, by bonding the leads with electroconductive adhesive layers to the steps of the terminal plates. CONSTITUTION:A positive electrode terminal plate 21 has a thickness of 0.05mm or the like and a peripheral step 26 about 0.1mm lower than the central portion of the plate. The form of a negative electrode terminal plate 23 is similar to that of the positive electrode terminal plate 21. A frame-shaped sealing electric insulator 27 made of a copolymer of ethylene and acrylic acid is interposed between the mutually-facing peripheral steps 26 of the terminal plates 21, 23. The insulator 27 and the terminal plates 21, 23 are heated and pressed so that they are bonded together by fusion. As a result, an electricity generation assembly comprising a positive electrode depolarizing mix sheet 22, a negative sheet 24 and a separator 25 is hermetically sealed. Nickel plate leads 29a, 29b, each of which has a thickness of 0.05mm and is coated on one side with an electroconductive adhesive layer 28a or 28b made of an acrylic adhesive wherein carbon powder is dispersed, are stuck to the steps 26 of the terminal plates 21, 23 so that the leads are electrically coupled to the steps.

Description

【発明の詳細な説明】 〔発明の技術分野〕 本発明は、リード付扁平形電池の改良に関するものであ
る。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to improvements in leaded flat batteries.

〔発明の技術的背景とその問題点〕[Technical background of the invention and its problems]

近年、電子機器の小形化、薄型化に伴ない、それらの電
源となる電池にも薄型化の要求が高まっている。かかる
要求に対応するために、第2図に示す構造の総高ざがQ
、 5 mmという超薄の扁平形電池が開発部れている
。即ち、図中の1は正極合剤シート2を担持した正極端
子板である。図中の3はリチウム等からなる負極シート
4を担持した負極端子板である。これら端子板1.3は
それらの正極合剤シート2及び負極シート4の間にセ・
ヤレータ5を介在して積層づれていると共に、各端子板
1.3の対向する周縁部の間に熱融着性樹脂からなる枠
状の絶縁封口体6が介在している。そして、前記各端子
板1.3と絶縁封口体6とを加熱加圧してそれらを相互
に融着することにより発電要素としての正極合剤シート
2.負極シート4及びセパレータ5を密封口している。
In recent years, as electronic devices have become smaller and thinner, there has been an increasing demand for thinner batteries that power these devices. In order to meet this requirement, the total height of the structure shown in Figure 2 is
The development department is developing an ultra-thin 5 mm flat battery. That is, 1 in the figure is a positive electrode terminal plate that supports a positive electrode mixture sheet 2. 3 in the figure is a negative electrode terminal plate carrying a negative electrode sheet 4 made of lithium or the like. These terminal plates 1.3 are separated between the positive electrode mixture sheet 2 and the negative electrode sheet 4.
The terminal plates 1.3 are stacked one on top of the other with a layer 5 interposed therebetween, and a frame-shaped insulating sealing body 6 made of heat-fusible resin is interposed between the opposing peripheral edges of each terminal plate 1.3. Then, each terminal plate 1.3 and the insulating sealing body 6 are heated and pressurized to fuse them together, thereby forming a positive electrode mixture sheet 2.3 as a power generation element. The negative electrode sheet 4 and separator 5 are sealed.

ところで、前述した扁平形電池から電子機器などにエネ
ルギを取り出すためには、従来より第3図又は第4図に
示す如くリード全両端子板1.3に接続している。
By the way, in order to extract energy from the above-mentioned flat battery to an electronic device or the like, conventionally all leads are connected to both terminal plates 1.3 as shown in FIG. 3 or FIG. 4.

即ち、第3図に示すリード付扁平形電池は正負極の端子
板1.3に銅などの金属製リード7a、7bli半田8
a、8bf介して接続した構造になっている。しかしな
から、力りかる構造の電池では半田の溶融による熱が負
極シート4、セパレータ5又は絶縁封口体6を溶かす危
険性かあり、しかも半田8の盛上りによって接続部での
総高式が高くなり、超薄の扁平形電池の長所が損なわれ
るという問題があった。
That is, the leaded flat battery shown in FIG.
It has a structure in which it is connected through a and 8bf. However, in batteries with a strong structure, there is a risk that the heat generated by the melting of the solder will melt the negative electrode sheet 4, separator 5, or insulating sealing body 6, and furthermore, the overall height at the connection part will be reduced due to the swelling of the solder 8. There is a problem in that the battery becomes expensive and the advantages of ultra-thin flat batteries are lost.

一方、第4図図示のリード付線平形電池は正負極の端子
板1.3に金属製リード7a、7bをスポット溶接によ
り接続した構造になっている。かかる構造の電池によれ
は第3図図示の電池のような総高さが高くなるという問
題は軽減できる。しかしながら、スポット溶接の際の熱
によって、第3図図示の電池と同様、負極シート4、セ
/−,0レータ5又は絶縁封口体6などが溶か芒れて電
池性能を悪化きせるという危険性があった。
On the other hand, the leaded wire flat battery shown in FIG. 4 has a structure in which metal leads 7a and 7b are connected to positive and negative terminal plates 1.3 by spot welding. With a battery having such a structure, the problem that the total height becomes high as in the battery shown in FIG. 3 can be alleviated. However, as with the battery shown in Figure 3, there is a risk that the heat generated during spot welding may melt or destroy the negative electrode sheet 4, the cell/cell generator 5, the insulating seal 6, etc., and deteriorate the battery performance. was there.

1   〔発明の目的〕 本発明は、負極シート、セパレータ又は絶縁封口体の溶
融や総高でか高くなることなく正負極の端子板にリード
を強固に接続したリード付線平形電池を提供しようとす
るものである。
1 [Object of the Invention] The present invention aims to provide a wire flat battery with leads in which the leads are firmly connected to the terminal plates of the positive and negative electrodes without melting of the negative electrode sheet, separator, or insulating sealing member or increasing the total height. It is something to do.

〔発明の概要〕[Summary of the invention]

本発明は、正負極の端子板の対向する周縁部の間に熱融
着性樹脂からなる枠状の絶縁封口体を介在ブせ、それら
端子板及び封口体の空間内に発電要素全密封口した電池
において、前記各端子板の周縁に段差を設け、これら端
子板の段部に板状の金属製リード全導電性接着層を介し
て接着、接続したこと全特徴とするものである。
The present invention interposes a frame-shaped insulating sealing body made of heat-fusible resin between the opposing peripheral edges of positive and negative terminal plates, and provides a total sealing hole for the power generating element in the space between the terminal plates and the sealing body. The battery is characterized in that a step is provided at the periphery of each of the terminal plates, and the plate-shaped metal lead is bonded and connected to the step part of the terminal plate through a fully conductive adhesive layer.

かかる本発明によれば、リードを導電性接着層を介して
正負極の端子板に接続することにより。
According to the present invention, the leads are connected to the positive and negative terminal plates via the conductive adhesive layer.

従来のような半田やスポット溶接によるリードの接続の
場合に生じる負極シート等の溶融、劣化を回避でき、し
かもリードを端子板周縁に形成した段部に接続すること
により、所期の電池の総高式を維持できる。
It is possible to avoid the melting and deterioration of the negative electrode sheet, etc. that occurs when connecting leads by soldering or spot welding as in conventional methods.In addition, by connecting the leads to the step formed on the periphery of the terminal plate, the intended overall battery life can be avoided. Able to maintain high style.

上記端子板としては、ステンレス製やニッケル製のもの
を使用できる。
The terminal board may be made of stainless steel or nickel.

上記絶縁封口体全形成する熱融着性樹脂としては、例え
ばエチレン−アクリル酸共重合体。
The heat-fusible resin used to form the entire insulation sealing body is, for example, an ethylene-acrylic acid copolymer.

エチレン−酢酸ビニル共重合体等を挙けることができる
Examples include ethylene-vinyl acetate copolymer.

上記金属製リードは5例えは銅、ニッケル或いはアルミ
ニウム等から形成てれる。
The metal lead is made of, for example, copper, nickel, or aluminum.

上記導電性接着剤としては、例えはカーダン粉末又は銀
、ニッケルなどの金属微粉末をアクリル系接着剤やエポ
キシ系接着剤に分散した常温硬化型のもの等を使用でき
る。
As the above-mentioned conductive adhesive, for example, a room-temperature curing type adhesive in which cardan powder or fine metal powder such as silver or nickel is dispersed in an acrylic adhesive or an epoxy adhesive can be used.

〔発明の実施例〕[Embodiments of the invention]

以下1本発明の実施例を第1図を参照して説明する。 An embodiment of the present invention will be described below with reference to FIG.

図中の21は焼成二酸化マンガン、グラファイト及びポ
リテトラフロロエチレンを混合した正極合剤シート22
を担持したステンレス製の正極端子板である。この正極
端子板2ノは厚さが005玉で、周縁が中央より約0.
1 mm低くなるように段差を有する。図中の23はリ
チウムからなる負極シート24を担持したステンレス製
の負極端子板であシ、この負極端子板23は前記正極端
子板21と同様な形状をなしている。
21 in the figure is a positive electrode mixture sheet 22 that is a mixture of calcined manganese dioxide, graphite, and polytetrafluoroethylene.
This is a stainless steel positive electrode terminal plate that carries . This positive terminal plate 2 has a thickness of 0.05 mm, and the peripheral edge is approximately 0.0 mm thick from the center.
It has a step that is 1 mm lower. Reference numeral 23 in the figure denotes a stainless steel negative electrode terminal plate carrying a negative electrode sheet 24 made of lithium, and this negative electrode terminal plate 23 has the same shape as the positive electrode terminal plate 21 described above.

前記各端子板21.23は、それらに担持した正極合剤
シート22及び負極シート24の間に非水電解′ti、
を含浸したポリプログレン不蛾亜からなるセパレータ2
5を介在づせると共に、各端子板21.23周縁の段差
が対称的になるように対向配置でれている。なお、非水
電解液は1 molAの過塩素酸リチウムを溶解した炭
酸プロピレンから形成でれている。また、前記正負極の
端子板21.23の対向する周縁部(段部)26にはエ
チレン−アクリル酸共重合体からなる枠状の絶縁封口体
27が介在きれ、これら各端子板21.23と絶縁封口
体27を加熱加圧して融着することにより発電要素とし
ての前記正極合剤シート22.負極シート24及びセノ
Rレータ25を密封口している。こうした電池は総高式
が0,50龍1段部26での厚でか0.3 mmのもの
である。そして、前記各端子板21゜23の段部26に
は片面にカーダン粉末を分散したアクリル系接着剤から
なる導電性接看層28a、28bを塗布した厚@ 0.
05 mmのニッケルリード板29a 、29bか夫々
貼着、接続でれている。
Each of the terminal plates 21 and 23 has a non-aqueous electrolyte between the positive electrode mixture sheet 22 and the negative electrode sheet 24 supported thereon.
Separator 2 made of polypropylene impregnated with
5 are interposed between the terminal plates 21 and 23, and the terminal plates 21 and 23 are arranged to face each other so that the steps at the peripheral edges of the terminal plates 21 and 23 are symmetrical. The non-aqueous electrolyte was formed from propylene carbonate in which 1 molA of lithium perchlorate was dissolved. Further, a frame-shaped insulating sealing body 27 made of ethylene-acrylic acid copolymer is interposed between the opposing peripheral edge portions (step portions) 26 of the positive and negative terminal plates 21.23, and each of these terminal plates 21.23 By heating and pressurizing and fusing the insulating sealing body 27 with the positive electrode mixture sheet 22. as a power generation element. The negative electrode sheet 24 and the Senor Rator 25 are sealed. Such a battery has a total height of 0.50 mm and a thickness of 0.3 mm at the first step 26. The stepped portions 26 of each of the terminal plates 21 and 23 are coated with conductive adhesive layers 28a and 28b made of an acrylic adhesive in which cardan powder is dispersed on one side.
05 mm nickel lead plates 29a and 29b are pasted and connected, respectively.

しかして、本実施例の霜、池、前述した第3図図示の半
田によりリードを接続した電池(従来例1)並ひに前述
した第4図図示のリードをスポット溶接により接続した
電池(従来例2)を100個用意し、これら各′電池に
ついて開路電圧の不良数及びリード接続部を含めた電池
総高埒の測定による不良数を調べた。その結果を1記表
に示した。
Therefore, the frost and pond of this embodiment, the battery (conventional example 1) whose leads are connected by solder as shown in FIG. Example 2) 100 batteries were prepared, and the number of defects in each of these batteries was determined by measuring the number of defects in open circuit voltage and the total height of the battery including the lead connection portion. The results are shown in Table 1.

表 なお、開路電圧が不良である従来の箪池全分解し、不良
原因を調べたところ、リチウム、負極シート、セパレー
タが熱によって一部溶融。
In addition, when we completely disassembled a conventional Mipon that had a defective open-circuit voltage and investigated the cause of the defect, we found that the lithium, negative electrode sheet, and separator were partially melted by the heat.

損傷を受けたことに起因することがわかった。It was found that this was caused by damage.

また1本発明のリード付線平形電池は、周縁に段部26
が設けられているため1反り発生を抑制でき、しかも封
口体27の断面積を小さくできることにより発電要素へ
の水分の透過も抑制でき%電池性能の向上を達成できる
In addition, the leaded wire flat battery of the present invention has a stepped portion 26 on the periphery.
Since this is provided, the occurrence of warping can be suppressed, and the cross-sectional area of the sealing body 27 can be made small, so that the permeation of moisture into the power generating element can also be suppressed, thereby achieving an improvement in battery performance.

〔発明の効果〕〔Effect of the invention〕

以上詳述した如く1本発明によれば負極シート、セパレ
ータ等の溶融や総高芒か高くなることなく、正負極の端
子板にリードを強固に接続でき、ひいては高性能で超薄
のリード付線平形電池を提供できる。
As detailed above, according to the present invention, it is possible to firmly connect the leads to the terminal plates of the positive and negative electrodes without melting the negative electrode sheet, separator, etc. or increasing the total height. We can provide linear flat batteries.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の一実施例を示すリード付線平形電池の
断面図、第2図は扁平形電池の断面図、第3図及び第4
図は夫々従来のリード付線平形電池の断面図である。 21・・・正極端子板、22・・・正極合剤シート、2
3・・・負極端子板、24・・・負極シート、25・・
・セパレータ、26・・・段部、22・・・枠状の絶縁
封口体、2.11 a 、 28 b−導電性接着層、
29a、29b・・・ニッケルリード板。
FIG. 1 is a sectional view of a leaded wire flat battery showing an embodiment of the present invention, FIG. 2 is a sectional view of a flat battery, and FIGS.
Each figure is a cross-sectional view of a conventional leaded wire flat battery. 21... Positive electrode terminal plate, 22... Positive electrode mixture sheet, 2
3...Negative electrode terminal plate, 24...Negative electrode sheet, 25...
- Separator, 26... step part, 22... frame-shaped insulating sealing body, 2.11 a, 28 b - conductive adhesive layer,
29a, 29b...Nickel lead plate.

Claims (1)

【特許請求の範囲】[Claims] 正負極の端子板の対向する周縁部の間に熱融着性樹脂か
らなる枠状の絶縁封口体を介在させ、それら端子板及び
封口体の空間内に発電要素を密封口した扁平形電池にお
いて、前記各端子板の周縁に段差を設け、これら端子板
の段部に板状の金属製リードを導電性接着層を介して接
着、接続したことを特徴とするリード付き扁平形電池。
In a flat battery in which a frame-shaped insulating sealing body made of heat-fusible resin is interposed between the opposing peripheral edges of positive and negative terminal plates, and a power generation element is sealed in the space between the terminal plates and the sealing body. A flat battery with leads, characterized in that a step is provided at the periphery of each of the terminal plates, and plate-shaped metal leads are bonded and connected to the step portions of the terminal plates via a conductive adhesive layer.
JP60108734A 1985-05-21 1985-05-21 Flat battery with leads Pending JPS61267261A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60108734A JPS61267261A (en) 1985-05-21 1985-05-21 Flat battery with leads

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60108734A JPS61267261A (en) 1985-05-21 1985-05-21 Flat battery with leads

Publications (1)

Publication Number Publication Date
JPS61267261A true JPS61267261A (en) 1986-11-26

Family

ID=14492170

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60108734A Pending JPS61267261A (en) 1985-05-21 1985-05-21 Flat battery with leads

Country Status (1)

Country Link
JP (1) JPS61267261A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002324584A (en) * 2001-04-24 2002-11-08 Toshiba Battery Co Ltd Flat nonaqueous electrolyte secondary battery with lead terminal
EP1067611A4 (en) * 1998-03-26 2005-11-16 Tdk Corp Electrode for cell, method of manufacturing the same and cell

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1067611A4 (en) * 1998-03-26 2005-11-16 Tdk Corp Electrode for cell, method of manufacturing the same and cell
JP2002324584A (en) * 2001-04-24 2002-11-08 Toshiba Battery Co Ltd Flat nonaqueous electrolyte secondary battery with lead terminal

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