JPS61263902A - Plant blight controlling agent - Google Patents

Plant blight controlling agent

Info

Publication number
JPS61263902A
JPS61263902A JP10456985A JP10456985A JPS61263902A JP S61263902 A JPS61263902 A JP S61263902A JP 10456985 A JP10456985 A JP 10456985A JP 10456985 A JP10456985 A JP 10456985A JP S61263902 A JPS61263902 A JP S61263902A
Authority
JP
Japan
Prior art keywords
active constituent
formula
ethanolamine
controlling agent
inositol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10456985A
Other languages
Japanese (ja)
Other versions
JPH0482123B2 (en
Inventor
Yasuo Honma
保男 本間
Yutaka Arimoto
裕 有本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RIKEN Institute of Physical and Chemical Research
Original Assignee
RIKEN Institute of Physical and Chemical Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RIKEN Institute of Physical and Chemical Research filed Critical RIKEN Institute of Physical and Chemical Research
Priority to JP10456985A priority Critical patent/JPS61263902A/en
Publication of JPS61263902A publication Critical patent/JPS61263902A/en
Publication of JPH0482123B2 publication Critical patent/JPH0482123B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE:A controlling agent, containing ethanolamine, etc., as an active constituent, capable of exhibiting improved controlling effect on blast of rice plants, powdery mildew of vegetables, gray mold of decorative plants, e.g. petunia, having high safety without fear of environmental pollution and useful as an agricultural chemical. CONSTITUTION:A plant blight controlling agent containing a compound selected from ethanolamine, L-inositol and phytic acid (inositol hexaphosphate) constitut ing partially phosphatidyl ethanolamine expressed by formula I (X is formula II) and phosphatidyl inositol expressed by formula I (X is formula III) which are phospholipids present in animal and plant tissues, and having characteristics as a safe non-pollution agricultural chemical without any fear of environmental pollution as an active constituent. The above-mentioned active constituent is directly applied or formulated with a carrier or adjuvant into the dosage form of dust, wettable powder, emulsion, etc., and applied. Preferably, the com pounding ratio of the active constituent is about 10-90% as the emulsion or wettable powder, etc., and about 0.1-10% as the duct, etc.

Description

【発明の詳細な説明】 (発明の技術分野) 本iaは、エタノールアミ7、L−イノシット及びフィ
チン酸から選ばれる化合物をH効成分とする植物病害防
除剤に関する。
DETAILED DESCRIPTION OF THE INVENTION (Technical Field of the Invention) The present invention relates to a plant disease control agent containing a compound selected from ethanolamide 7, L-inosit, and phytic acid as an H-active ingredient.

(発明の背景) 農薬O使用による土壌汚染や作物残留毒性が、いわゆる
[f公害として礼金問題となって以来、特に安全性O高
い農薬θ開発が1まれてきた。本郷明者らもかかる観点
から鋭意研究を打つ九結果、先に大豆し7チ/が野菜類
うどんこ病や稲いもち病に効果を有することを見出した
。そθ後、本発明者は、そθ作用機構について研究を行
ったところ、大豆レシチンO抗菌力は、病原菌O浸入抑
制作J!4VCあることを見出した。大豆レシチンは、
≠つυリン脂[、すなわち、ホス7アチゾルエタノール
アミン、ホス7アチゾルイノシトーIし、ホス7アチノ
ルコリン、ホス7アチノルセリンかう構成すれておシ、
ホス7γナノル基にそれぞれエタノールアミン1イノシ
トール、コリンが結合した化合物である。
(Background of the Invention) Since soil contamination and residual toxicity in crops due to the use of agricultural chemicals have become a key money issue as so-called [F pollution], efforts have been made to develop particularly safe agricultural chemicals θ. Akira Hongo and his colleagues also carried out intensive research from this point of view, and as a result, they discovered that 7 g of soybeans was effective against powdery mildew of vegetables and rice blast. After that, the present inventor conducted research on the mechanism of action of soybean lecithin O, and found that the antibacterial activity of soybean lecithin O was effective in suppressing the infiltration of pathogenic bacteria. I discovered that there are 4 VCs. Soybean lecithin is
≠ phospholipid [i.e., phos-7 atisol ethanolamine, phos-7 atisol inosyto I, phos-7 atinorcholine, phos-7 atinorserine, etc.]
It is a compound in which ethanolamine-1-inositol and choline are bound to the phos-7γ nanol group, respectively.

O− OHホスイアチジン鹸 0CI−12G)(jNH2ホスファチジルエタノール
アミンH2 これらの≠つのりん脂質のうち、生物検定法により病原
菌Q侵入抑制が顕著であったのは、ホスファチジルエタ
ノールアミン及びホス7アチノルイノシトールであった
Among these phospholipids, phosphatidylethanolamine and phos-7-acynolinositol showed remarkable inhibition of pathogen Q invasion by bioassay method. there were.

そこで、本発明音らは、上記2つO化合物Oホスファチ
ノル基に結合している原子団の遊離θ化合物、すなわち
、エタノールアミン、イノジットあるいはその誘導体で
あるフィチン酸(イノシットヘギサ’)7m)について
数夜試験を行ったところ、後述O試験例θ如く優れた防
除効果を示すこと、特にフィチン酸は、耐性菌に対して
極めて顕著な防除効果を示すことを見出し、本発明の化
合物が、植物病害防除剤として極めて有効である知見を
得て、本発明を完成したもOである。
Therefore, the inventors of the present invention investigated the free θ compounds of the atomic groups bonded to the phosphatinol groups of the two O compounds mentioned above, namely, ethanolamine, inosit, or its derivative phytic acid (inosithegisa') 7m). As a result of the tests, it was found that the compound of the present invention exhibits an excellent control effect as shown in Test Example θ, which will be described later, and that phytic acid in particular has an extremely remarkable control effect against resistant bacteria. It was O who completed the present invention by obtaining the knowledge that it is extremely effective as a drug.

(発明の目的) 本発明の目的は、安全性の高い且つ優れた防除効果を有
する植物病害防除剤を提供することにある。
(Objective of the Invention) An object of the present invention is to provide a plant disease control agent that is highly safe and has an excellent control effect.

(発明の構成) 本発明の有効成分は、エタノールアミン、イノシトール
、フィチン酸であり、これらθ化合物は、動植物組織中
に存在するりん脂質θホス7アチジルエタノールアミン
、ホス7アチノルイノシトール〇一部を構成する化合物
であって、その使用に当っては、環境汚染の恐れは全く
なく、極めて安全な無公害農薬としてθ特色を有するも
■である。
(Structure of the Invention) The active ingredients of the present invention are ethanolamine, inositol, and phytic acid. When used, there is no risk of environmental pollution, and it is an extremely safe, non-polluting pesticide that has the characteristics of θ.

本発明の植物病害防除剤は、各種植物病害例えば、稲い
もち病、野菜5ictうkんこ病、ペチュニア等0観嘗
植物の灰色かび病等に対して卓効を示す。
The plant disease control agent of the present invention is highly effective against various plant diseases such as rice blast, vegetable powdery mildew, and gray mold on 0-year-old plants such as petunia.

本発明のf!1*J病害防除剤を適用する場合、上記有
効成分化合物を直接に゛適用するか、通常当該技術分野
において知られている1441IIJJI剤と同様に適
当な固体担体、液体担体、乳化分散剤等を用いて粒剤、
粉剤、乳剤、水和剤、錠剤、油剤、噴霧剤、煙噴剤等■
任意O剤!に製達j化して適用することができる。これ
ら■担体としてはミクレー、カオリ/、ぺ/トナイト、
酸性白土、珪膿土、炭酸カルシウム、固体担体トシて、
ニトロセルロース、7J/グ/、アラビアゴム等々が、
ま九液体担体として、氷、メタノール、エタノール、ア
セトン、ジメチルホルムアミド、エチレ/グリニ1−ル
等々が挙げられる。また、製剤上、一般に使用される補
助剤、例えば高級アルコールの硫酸エステル、ポリオ中
ジエチレンーアルキル中アリルエーテルアルキルΦアリ
ル゛・ポリエチV/・グリコールエーテル、アルキル・
アリル嘩ソルビタ/モノ2ウレート、アルキル・アリル
・スルホネート、アルキルスルホy酸tm、アルキルア
リールスルホ/酸塩、□第j級ア/モニウム塩、ポリア
ルギレ/オキサイド、リグニンスルホ/酸ソーダ、ジナ
フテルメタンスIレホ/酸ソーダ、/ヨ糖脂肪酸エステ
ル、ソルピタ/j[mエステル、モノグリセライド、I
リグロビレ/グリコールi11#JJsエステル等を適
宜配合することができる。有効成分θ配合割合は、乳剤
、水和剤等としては、70〜90%程度が適当であり、
粉剤、油剤等としては、O0/〜10%程度が適当であ
るが、使用目的によってこれら0濃度を適宜増減しても
よい。
f of the present invention! When applying the 1*J disease control agent, the above-mentioned active ingredient compound can be applied directly, or a suitable solid carrier, liquid carrier, emulsifying dispersant, etc. Using granules,
Powders, emulsions, wettable powders, tablets, oils, sprays, smoke propellants, etc.■
Optional O agent! It can be manufactured and applied. These carriers include Miclay, Kaori/, Pe/tonite,
Acid clay, pyogenes, calcium carbonate, solid carrier,
Nitrocellulose, 7J/g/, gum arabic, etc.
Liquid carriers include ice, methanol, ethanol, acetone, dimethylformamide, ethylene/grinyl, and the like. In addition, adjuvants commonly used in formulations, such as sulfuric esters of higher alcohols, diethylene in polyol, allyl ether in alkyl Φallyl polyethylene V/ glycol ether, alkyl
Allyl sorbita/monodiurate, alkyl allyl sulfonate, alkyl sulfo acid tm, alkylaryl sulfo/acid, □J-class am/monium salt, polyargyre/oxide, lignin sulfo/acid soda, dinaphthermethane Ireho/acid soda,/yosaccharide fatty acid ester, sorpita/j [m ester, monoglyceride, I
Ligloville/glycol i11#JJs ester etc. can be blended as appropriate. The appropriate blending ratio of the active ingredient θ is about 70 to 90% for emulsions, hydrating agents, etc.
For powders, oils, etc., O0/~10% is appropriate, but these 0 concentrations may be increased or decreased as appropriate depending on the purpose of use.

次に、本発明の植物病害防除剤p実施例を示す。Next, Examples of the plant disease control agent of the present invention will be shown.

実施例/(水和剤) エタノールアミンtO部、モノグリセライド70部、f
”7ノ/j′部、カゼイ/酸ソーダj部、を混合粉砕し
て水和剤を得る。水で約7000倍に播釈して使用する
Examples/(Wettable powder) ethanolamine tO parts, monoglyceride 70 parts, f
A wettable powder is obtained by mixing and pulverizing 7 parts/j parts of casei/j parts of acid soda. It is used by dispersing it approximately 7,000 times with water.

実施例−(水和A) L−イノシット♂0部、ホワイトカーde 7.2部、
リクニンスルホン酸ナトリウム壇一部、ホリオ中シエチ
レノアルキルエーテル≠部およヒタレー12部を混合粉
砕して水和剤を得る。水で約1000倍に稀釈して使用
する。
Example - (Hydration A) 0 parts of L-inosit♂, 7.2 parts of white car de,
A wettable powder is obtained by mixing and pulverizing one part of sodium licunin sulfonate, one part of siethylenoalkyl ether in Holio, and 12 parts of Hytale. Use by diluting approximately 1000 times with water.

実施例3(粉剤) フイテ/酸to部をモノグリセライド10部およびでん
ぷん70部と混合したもID2j部をメルク73部と混
合して粉剤を得る。
Example 3 (Powder) A powder is obtained by mixing part of Fuite/acid with 10 parts of monoglyceride and 70 parts of starch and mixing part of ID2j with 73 parts of Merck.

実施例≠(乳剤) エタノールアミン≠O部、グリ層ライド10部、ポリノ
ロビレ/グリコール脂肪酸エステル1部、メタノール/
J’部および水50部を混合溶解して乳剤を得る。
Example ≠ (emulsion) Ethanolamine ≠ O part, Gurilayeride 10 parts, polynolobile/glycol fatty acid ester 1 part, methanol/
Part J' and 50 parts of water are mixed and dissolved to obtain an emulsion.

実施例よ(乳剤) L−イノシットtio部、ポリオキシエチレ/アル中ル
アリルエーテルj部、アル中ルスルホ/#IIナトリウ
ムjs1 メタノール、20部およヒ水30部を混合溶
解して乳剤を得る。
Example (Emulsion) L-inositio part, polyoxyethylene/rulyl ether j part in alcohol, rusulpho/#II sodium js1 in alcohol 20 parts of methanol and 30 parts of arsenic water are mixed and dissolved to obtain an emulsion.

次に本発明の薬剤θ種物病害防除効果を試験例によって
具体的に1!明するが、対照薬剤は、実際に使用する場
合0m度で用いた。
Next, the effect of the drug θ of the present invention on controlling plant diseases will be specifically determined by test examples. For clarity, the control agent was used at 0 m degree when actually used.

試験例/(稲いもち病防除試験) 直径lhOcmθ合成樹脂製ポットで、/ポットIO株
宛、稲(品種二十石)を温室内で育成し、第j葉期にお
いて1oesエタノール含有水で所定m度に希釈した本
発明の化合物m液を//ット当りIILO一槽体に散布
した。別途もみがら培地(粉末酵母、エキス、可溶性で
んぷん、しよ糖、もみがらを含む)で培養した稲いもち
病菌θ胞子を水で懸濁して(胞子濃gt:弘X705個
/d)。
Test example / (Rice blast disease control test) Rice (variety Nijukoku) was grown in a greenhouse in a synthetic resin pot with a diameter of lhOcmθ, and the rice (variety Nijukoku) was grown in a greenhouse, and at the J-leaf stage, it was grown in a predetermined amount of water containing 1 oes of ethanol. A diluted solution of the compound of the present invention was sprayed onto one tank of IILO per lot. Rice blast fungus theta spores separately cultured in a rice husk medium (containing powdered yeast, extract, soluble starch, sucrose, and rice husk) were suspended in water (spore concentration gt: 705 HiroX spores/d).

これを槽体に/ポット当り≠〜j″−均一に噴霧接種し
、21!If27℃、湿度りj饅以上の恒温恒湿箱に入
れて発病させ九。接種5臼目において、−葉当りρ病斑
数を求め、防除価を次式に従って算出し友。
Spray this uniformly into a tank/per pot≠~j''- and place it in a constant temperature and humidity box at 21! If 27°C and a humidity of j or higher to develop the disease. Determine the number of ρ lesions and calculate the control value according to the following formula.

こQ結果を第7表に示す。The Q results are shown in Table 7.

試験例コ(ペテユニアQ花弁灰色かび病防除試験)温室
内で栽培し九ペチュニア(開花2〜3日m)を、花便部
から切り取り、水を満たした試験管にさし、/区j−4
とし、10%エタノール含有水に溶解した所定濃度ρ本
発明化合物θIatLを1区についてpo〜、3′O−
均一に噴霧散布した。
Test Example (Peteunia Q petal gray mold control test) Nine petunias (flowering 2-3 days long) grown in a greenhouse were cut from the flower part and placed in a test tube filled with water. 4
The predetermined concentration ρ of the present invention compound θIatL dissolved in 10% ethanol-containing water was added to po~, 3'O-
Sprayed evenly.

ジャガイモせん汁千面摘地で培養し、BLBう/グ処理
にて形成させ九灰色かび病菌 (Botrytlsclnerla ) E)m子を蒸
留水に懸濁させ(胞子濃度/X10’ (I/gnt)
、10dCj花当如)を均一にI!Jill接檎した。
Botrytlsclnerla (Botrytlsclnerla) was cultured on a thousand-faced potato pickled ground and treated with BLB.
, 10dCj (flowers) evenly! Jill greeted me.

接種後、温室に静置し、76時間俵、発病し九それぞれ
ρ花弁上θ病斑数を調査した。防除価の算出法は、次式
に従つ九。
After inoculation, the bales were allowed to stand in a greenhouse for 76 hours, and the number of θ lesions on each ρ petal was investigated after disease onset. The method for calculating the control value is according to the following formula.

同様に、ドッグツノ耐性の灰色かび病菌を用いて試験を
行った。この結果を、t!g2表に示す。
Similarly, a test was conducted using a doghorn-resistant Botrytis blight fungus. This result, t! It is shown in the g2 table.

(本発明の効果) 以上Q試験例から明らかな如く、本発明の有効成分化合
物は、優れた防除効果を示し、且つ、薬害のない安全な
農薬であることが分った。
(Effects of the Present Invention) As is clear from the above Q test examples, the active ingredient compound of the present invention was found to have an excellent pest control effect and to be a safe agricultural chemical without chemical damage.

Claims (1)

【特許請求の範囲】[Claims] エタノールアミン、L−イノシット及びフイチン酸から
選ばれる化合物を有効成分とする植物病害防除剤。
A plant disease control agent containing a compound selected from ethanolamine, L-inosit, and phytic acid as an active ingredient.
JP10456985A 1985-05-16 1985-05-16 Plant blight controlling agent Granted JPS61263902A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10456985A JPS61263902A (en) 1985-05-16 1985-05-16 Plant blight controlling agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10456985A JPS61263902A (en) 1985-05-16 1985-05-16 Plant blight controlling agent

Publications (2)

Publication Number Publication Date
JPS61263902A true JPS61263902A (en) 1986-11-21
JPH0482123B2 JPH0482123B2 (en) 1992-12-25

Family

ID=14384076

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10456985A Granted JPS61263902A (en) 1985-05-16 1985-05-16 Plant blight controlling agent

Country Status (1)

Country Link
JP (1) JPS61263902A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH045211A (en) * 1990-04-19 1992-01-09 Isao Sakai Insecticidal antimicrobial agent for green of gold course or the like and preparation thereof
WO1999044422A1 (en) * 1998-03-06 1999-09-10 Toyota Jidosha Kabushiki Kaisha Method for controlling target microorganism
WO2001064832A3 (en) * 2000-02-28 2002-05-23 Miklos Ghyczy Composition for use on plants
WO2001082932A3 (en) * 2000-05-01 2002-07-18 Healthpartners Res Foundation Methods and compositions for enhancing cellular function through protection of tissue components
JP2004509138A (en) * 2000-09-20 2004-03-25 ロンザ ア−ゲ− disinfectant

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH045211A (en) * 1990-04-19 1992-01-09 Isao Sakai Insecticidal antimicrobial agent for green of gold course or the like and preparation thereof
US6861235B1 (en) 1998-03-06 2005-03-01 Toyota Jidosha Kabushiki Kaisha Method for controlling target microorganism
WO1999044422A1 (en) * 1998-03-06 1999-09-10 Toyota Jidosha Kabushiki Kaisha Method for controlling target microorganism
WO2001064832A3 (en) * 2000-02-28 2002-05-23 Miklos Ghyczy Composition for use on plants
US7084126B1 (en) 2000-05-01 2006-08-01 Healthpartners Research Foundation Methods and compositions for enhancing cellular function through protection of tissue components
WO2001082932A3 (en) * 2000-05-01 2002-07-18 Healthpartners Res Foundation Methods and compositions for enhancing cellular function through protection of tissue components
US7786166B2 (en) 2000-05-01 2010-08-31 Healthpartners Research Foundation Methods and compositions for protecting and treating muscarinic receptors through administration of at least one protective agent
US7972595B2 (en) 2000-05-01 2011-07-05 Healthpartners Research Foundation Methods and compositions for protecting and treating at least one muscarinic receptor from dysfunction not resulting from oxidative stress, toxic actions of metals or infectious agents by administering a pyrophosphate analog
US8765711B2 (en) 2000-05-01 2014-07-01 Healthpartners Research Foundation Method for protecting and treating at least one muscarinic receptor from dysfunction resulting from free radical damage
US8772263B2 (en) 2000-05-01 2014-07-08 Healthpartners Research Foundation Methods and compositions for protecting or treating muscarinic receptors through administration of pyrophosphate analog in subjects exposed to toxic or carcinogenic metals or metal ions
US8771681B2 (en) 2000-05-01 2014-07-08 Healthpartners Research Foundation Methods and compositions for protecting and treating muscarinic receptors by administering a pyrophosphate analog to a subject exposed to bacterial, fungal, viral, prion or algal infection
US9072756B2 (en) 2000-05-01 2015-07-07 Healthpartners Research Foundation Methods and compositions for increasing the efficacy of an agent that directly or indirectly affects a muscarinic receptor through administration of a pyrophosphate analog
JP2004509138A (en) * 2000-09-20 2004-03-25 ロンザ ア−ゲ− disinfectant

Also Published As

Publication number Publication date
JPH0482123B2 (en) 1992-12-25

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