JPS61262708A - Single mode optical fiber for 1.5 micron band - Google Patents
Single mode optical fiber for 1.5 micron bandInfo
- Publication number
- JPS61262708A JPS61262708A JP60106431A JP10643185A JPS61262708A JP S61262708 A JPS61262708 A JP S61262708A JP 60106431 A JP60106431 A JP 60106431A JP 10643185 A JP10643185 A JP 10643185A JP S61262708 A JPS61262708 A JP S61262708A
- Authority
- JP
- Japan
- Prior art keywords
- base material
- core
- furnace
- refractive index
- kept
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/01—Manufacture of glass fibres or filaments
- C03B37/012—Manufacture of preforms for drawing fibres or filaments
- C03B37/014—Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
- C03B37/01446—Thermal after-treatment of preforms, e.g. dehydrating, consolidating, sintering
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/01—Manufacture of glass fibres or filaments
- C03B37/012—Manufacture of preforms for drawing fibres or filaments
- C03B37/01205—Manufacture of preforms for drawing fibres or filaments starting from tubes, rods, fibres or filaments
- C03B37/01211—Manufacture of preforms for drawing fibres or filaments starting from tubes, rods, fibres or filaments by inserting one or more rods or tubes into a tube
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/01—Manufacture of glass fibres or filaments
- C03B37/012—Manufacture of preforms for drawing fibres or filaments
- C03B37/014—Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
- C03B37/01466—Means for changing or stabilising the diameter or form of tubes or rods
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2201/00—Type of glass produced
- C03B2201/06—Doped silica-based glasses
- C03B2201/08—Doped silica-based glasses doped with boron or fluorine or other refractive index decreasing dopant
- C03B2201/12—Doped silica-based glasses doped with boron or fluorine or other refractive index decreasing dopant doped with fluorine
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B2203/00—Fibre product details, e.g. structure, shape
- C03B2203/10—Internal structure or shape details
- C03B2203/22—Radial profile of refractive index, composition or softening point
- C03B2203/24—Single mode [SM or monomode]
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野コ
本発明は1.jtクロン帯に零分散波長をもつシングル
モード光ファイバに関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Fields] The present invention is based on 1. This invention relates to a single mode optical fiber having a zero dispersion wavelength in the jt Chron band.
[背景技術と問題点コ
石英系ガラス光ファイバは、光の波長が1.5〜t、g
tクロンの領域において、伝送損失が最小となる。した
がって光ファイバを用いた伝送システムで中継間隔を最
大にしようとすれば、波長が1.5ミクロン帯の光を用
いる必要がある。[Background technology and problems] Silica-based glass optical fibers have light wavelengths of 1.5 to t, g.
In the region of t cron, the transmission loss is minimum. Therefore, in order to maximize the repeater spacing in a transmission system using optical fibers, it is necessary to use light with a wavelength of 1.5 microns.
この場合、高い伝送速度で情報を送ろうとすれば、マル
チモードファイバよりもずっと広い伝速帯域をもつシン
グルモード光ファイバが用いられる。そして非常に高い
伝送速度で情報を送ろうとすれば、使用する光波長にお
いて、光ファイバの分散効果を最小にする必要がある。In this case, if information is to be transmitted at a high transmission rate, a single mode optical fiber is used, which has a much wider transmission band than a multimode fiber. In order to transmit information at very high transmission speeds, it is necessary to minimize the dispersion effect of optical fibers at the optical wavelengths used.
現在通常用いられている波長が1.32クロン用のシン
グルモード光ファイバは、波長が1.3ミクロン付近で
、材料分散と構造分散が相殺され、分散相が零となるよ
うに設計されている。Single-mode optical fibers for wavelengths of 1.32 microns, which are currently in common use, are designed so that material dispersion and structural dispersion cancel each other out at wavelengths around 1.3 microns, resulting in zero dispersed phase. .
これに対し、1.5ミクロン帯でシングルモード光ファ
イバを使用し、かつ、この波長で分散を小さくするには
、2つの方法がある。1つは光フアイバ構造を1.5ミ
クロン帯で零分散となるように設計することであり、他
の1つは下記文献(1)で述べられているように、1.
5μ帯の使用波長で非常に狭いスペクトル幅をもつ光源
を用いることである。On the other hand, there are two methods for using a single mode optical fiber in the 1.5 micron band and reducing dispersion at this wavelength. One is to design the optical fiber structure to have zero dispersion in the 1.5 micron band, and the other is to design the optical fiber structure to have zero dispersion in the 1.5 micron band.
The purpose of this method is to use a light source with a wavelength of 5 μ band and a very narrow spectral width.
文献(1)Malyan、P、J、and MCdOn
na、Ap、102kmunrepe102k mon
owode flber system exper1
mentat 140 Mbit/s wlth
an 1njectlon−1ocked 1
.52μ1llaser transmltter+E
Iactron、Lett、19B2,18pp 44
5−447. (102に一無中継、140Mblt/
s+のシングルモードファイバの実験システム)。Literature (1) Malyan, P. J. and MCdOn
na, Ap, 102kmunrepe102k mon
owode flber system exper1
mentat 140 Mbit/s wth
an 1njectlon-1ocked 1
.. 52μ1laser transmltter+E
Iactron, Lett, 19B2, 18pp 44
5-447. (No relay on 102, 140Mblt/
s+ single mode fiber experimental system).
本発明は後に詳述するが1.5ミクロン帯で零分散とな
るシングルモード光ファイバを得ることにある。The purpose of the present invention is to obtain a single mode optical fiber having zero dispersion in the 1.5 micron band, which will be described in detail later.
シングルモード光ファイバにおいて、零分散波長を1.
3ミクロンから1.5ミクロンに移すには、下記の文献
■に述べられているように、光ファイバのコア径をより
細(するとともに、コアとクラッドとの屈折率差Δnを
増大させる必要がある。In a single mode optical fiber, the zero dispersion wavelength is set to 1.
In order to move from 3 microns to 1.5 microns, it is necessary to make the core diameter of the optical fiber thinner (as well as increase the refractive index difference Δn between the core and the cladding), as described in the following document (■). be.
文献■Cohen、L、(i、LInC,、and F
renchj、G。Literature ■Cohen, L, (i, LInC,, and F
renchj, G.
“Tallorlng zero chromatlc
dlsperslon ll。“Tallorlng zero chromatlc
dlsperslon ll.
the I 、5〜1 、Bμta low−loss
+ 5pectral regon ofslngla
mode Nbres”+ EIoctrom、Let
t、1979.15pp 334−335. (シング
ルモードファイバの零分散を1.5〜1.6μ諺波長帯
の低損失領域への移動)。the I, 5-1, Bμta low-loss
+5pectral region ofslngla
mode Nbres”+ EIoctrom, Let
t, 1979.15pp 334-335. (Moving the zero dispersion of single-mode fiber to the low-loss region of the 1.5-1.6μ wavelength band).
Δnを増大させることにより、2つの理由により、伝送
損失が生ずるという問題が発生する。一つはΔnを増大
させるため、コアに添加するゲルマニウムを多くするこ
とによって光の散乱損失が増加することであり、他の一
つはΔnを増大させることは、コアとクラッドの線膨張
係数の差を増大させ、光フアイバ内のコアとクラッドの
界面での応力の増大をもたらし、これが伝送損失の増加
をひき起すことになる。このことは下記の文献■に述べ
られている。Increasing Δn causes a problem of transmission loss for two reasons. One is that increasing Δn increases light scattering loss by adding more germanium to the core, and the other is that increasing Δn increases the linear expansion coefficient of the core and cladding. This increases the difference, leading to increased stress at the core-cladding interface within the optical fiber, which causes increased transmission loss. This is described in the following document (■).
文献■Anslle、B、J、et at、Nonom
ode flberwith ultra−1ow 1
oss and mln1mu+* dlspersl
onat 1.55”Electron、Lett、l
98218 pp 842−844゜(1,55μ謬波
長帯で超低損失と最小分散をもつシングルモードファイ
バ)。Literature ■Anslle, B. J. et at, Nonom
ode flberwith ultra-1ow 1
oss and mln1mu+*dlspersl
onat 1.55"Electron, Lett, l
98218 pp 842-844° (single mode fiber with ultra-low loss and minimum dispersion in the 1,55μ error band).
前者の難点を解消する方法として、コアにゲルマニウム
を添加し、屈折率を上げる代りに、クラッドの屈折率を
下げる方法がある。最も極端な場合が、コアを純石英に
し、クラッドを石英よりも低い屈折率に下げた光ファイ
バである。この構造は本質的にゲルマニウム入りコアの
光ファイバより低損失の可能性があり、1.:Nクロン
帯の零分散光ファイバではすでに下記の文献に)によっ
てよ(知られている。クラッドには通常フッ素が添加さ
れる。One way to solve the former problem is to add germanium to the core to lower the refractive index of the cladding instead of increasing the refractive index. The most extreme case is an optical fiber whose core is made of pure quartz and whose cladding has a refractive index lower than that of quartz. This structure inherently has the potential for lower loss than germanium-filled core optical fibers; 1. :N-band zero-dispersion optical fiber is already known from the following literature.The cladding is usually doped with fluorine.
文献(4)R,Csencgfts at al、“F
abrication oflow−1oss si
ngle−+5ode fiber″ In τe
chnlcalD1gest、Toplcal Mse
tlng on 0ptlcal FlborComm
unlcatlon 1984.TU 13. (低損
失シングルモードファイバの構造)。Reference (4) R, Csencgfts at al, “F
abrication offlow-1oss si
ngle−+5ode fiber″ In τe
chnlcalD1gest, Toplcal Mse
tlng on 0ptlcal FlborComm
unlcatlon 1984. TU 13. (Structure of low loss single mode fiber).
後者のコアとクラッドの界面の応力を解消する方法とし
て、コアの屈折率分布をステップ状ではなく、三角形杖
にすることにより界面の応力集中を緩和させることが提
案され、ゲルマニウム入りコアで1.55 ミクロンで
零分散であり、ある程度低損失が実現されている。この
点前掲文献■参照。As a method of resolving the latter stress at the interface between the core and the cladding, it has been proposed to reduce the stress concentration at the interface by making the refractive index distribution of the core triangular rather than step-like. It has zero dispersion at 55 microns and achieves a certain degree of low loss. On this point, refer to the above-mentioned document ■.
[発明の目的コ
本発明は以上述べた技術手法を組合せて応用し、1.5
ミクロン帯に零分散波長をもち、かつ、非常に低い伝送
損失の光フアイバ構造を提供しようとするものである。[Purpose of the Invention] The present invention combines and applies the above-mentioned technical methods to achieve 1.5
The objective is to provide an optical fiber structure that has a zero dispersion wavelength in the micron band and has extremely low transmission loss.
[問題を解決するための手段]
第1図に本発明シングルモード光ファイバの屈折率分布
を示す。図は中心線より横軸に半径方向距離をとり、縦
軸に屈折率をとっている。図示のようにコアの中央部^
は純石英であり、クラッドCは純石英によるコアの中央
部4よりも屈折率を低(シ、コアの中央部4とクラッド
Cの界面 6は徐々に屈折率を変化させる層よりなる。[Means for Solving the Problem] FIG. 1 shows the refractive index distribution of the single mode optical fiber of the present invention. In the figure, the horizontal axis represents the radial distance from the center line, and the vertical axis represents the refractive index. As shown, the center of the core ^
is pure quartz, and the cladding C has a refractive index lower than that of the central part 4 of the core made of pure quartz.The interface 6 between the central part 4 of the core and the cladding C consists of a layer whose refractive index gradually changes.
このような構造の光ファイバは、光エネルギーの最も集
中するコアの中央部^は純石英であるため、光の吸収損
失を非常に小さくでき、またコアとクラフトの線膨張率
係数差によるコア/クラッド界面の応力集中を回避する
ことができるので、界面での応力に起因する損失増を軽
減することができる。In an optical fiber with such a structure, the central part of the core where the light energy is most concentrated is made of pure silica, so light absorption loss can be extremely small. Since stress concentration at the cladding interface can be avoided, an increase in loss due to stress at the interface can be reduced.
以下具体的な実施例について述べる。Specific examples will be described below.
本発明の光ファイバの製造方法としては、一般に知られ
ているCVD法、 MCVD法などによってもよいが、
以下VAD法(軸つけ法)を利用して作製した実施例に
ついて説明する。The optical fiber of the present invention may be manufactured by the generally known CVD method, MCVD method, etc.
Examples manufactured using the VAD method (axial attachment method) will be described below.
[実施例]
VAD法により作製した純シリカからなる多孔質母材を
、一旦1100℃の炉内に挿入した、この際、炉内には
雰囲気ガスとしてHeをEl/分、Cn2を200 c
c/分の流量で流しておき、多孔質母材内のOH基を十
分に低減させた。[Example] A porous base material made of pure silica produced by the VAD method was once inserted into a furnace at 1100 °C. At this time, the atmosphere gas in the furnace was He at El/min and Cn2 at 200 °C.
It was allowed to flow at a flow rate of c/min to sufficiently reduce the OH groups in the porous matrix.
次に、この多孔質母材を1400℃の炉内に挿入し、収
縮させた。この際、炉内にはHeのみ5Q/分の流量で
流した。Next, this porous base material was inserted into a 1400° C. furnace and shrunk. At this time, only He was flowed into the furnace at a flow rate of 5 Q/min.
さらに、この収縮した多孔質母材を1840℃の炉内に
挿入し、透明ガラス母材とした。この際、炉内にはSi
F4を2fi/分の流量で流した。Furthermore, this shrunken porous base material was inserted into a furnace at 1840°C to obtain a transparent glass base material. At this time, there is Si in the furnace.
F4 was flowed at a flow rate of 2fi/min.
次にこの透明ガラス母材を外径3Nに延伸したロッドを
準備した。一方間様にVAD法で合成したロッドを挿入
し、管外部より加熱しながら5iF4=CQ2102を
流し、管と棒とのすき間を清浄にしながらつぶしていっ
た。得られたプリフォームを加熱延伸し、さらにこの外
周部に火炎加水分解によるSiO2スートを堆積させた
。この堆積体を加熱処理炉でフッ素の添加処理及び透明
ガラス化を行った。Next, a rod was prepared by stretching this transparent glass base material to an outer diameter of 3N. On the other hand, a rod synthesized by the VAD method was inserted into the gap, and 5iF4=CQ2102 was poured from the outside of the tube while being heated, and the gap between the tube and the rod was cleaned and crushed. The obtained preform was heated and stretched, and SiO2 soot was deposited on the outer periphery by flame hydrolysis. This deposited body was subjected to fluorine addition treatment and transparent vitrification in a heat treatment furnace.
以上により得られたプリフォームをクラッドCの外径1
25μ謡に線引したところ、第1図に示すような屈折率
分布のシングルモードファイバが得られた。なおコア中
央部^の外径^′は3.5μ■、界面名の最大外径6′
は5.5μ厘比屈折率差Δnは0.65%である。The preform obtained in the above manner has an outer diameter of 1
When drawn to a diameter of 25 μm, a single mode fiber with a refractive index distribution as shown in FIG. 1 was obtained. The outer diameter of the central part of the core is 3.5 μ■, and the maximum outer diameter of the interface is 6'.
is 5.5μ, and the relative refractive index difference Δn is 0.65%.
この光ファイバの特性を測定したところ、零分散波長が
!、54μ−であった。また1、55μ■波長での損失
は0 、26 dB/kvsと損失の低い!、5μ■帯
零分故ファイバか得られた。When we measured the characteristics of this optical fiber, we found that it had a zero dispersion wavelength! , 54 μ-. In addition, the loss at 1.55μ■ wavelength is 0.26 dB/kvs, which is low! , a 5μ band zero-fraction fiber was obtained.
[比較例コ
コアとして純SiO2からなるロッドを準備する以外は
、実施例と同様な製法により、第2図に示すクラッドC
の外径C’125μm、コア4″の外径4″′4.8μ
■、比屈折率差0.65%の光ファイバを作製した。[Comparative example The clad C shown in FIG.
outer diameter C'125μm, outer diameter of core 4''4''4.8μm
(2) An optical fiber with a relative refractive index difference of 0.65% was produced.
この光ファイバの特性を測定したところ、零分散波長が
!、54μ閣であった。また、1.55μm波長での損
失値は0.32dB/kmであった。When we measured the characteristics of this optical fiber, we found that it had a zero dispersion wavelength! , it was 54 μkaku. Further, the loss value at a wavelength of 1.55 μm was 0.32 dB/km.
[効果コ
以上説明したうように本発明においては、コアが純石英
、クラッドがフッ素を添加した石英ガラスによりなる1
、5ミクロン帯シングルモードファイバにおいて、コア
とクラッドの界面がコアからクラッドに向って屈折率が
徐々に小さくなるように構成されており、コアとクラッ
ドの界面が純石英から順次フッ素の増加する層よりなっ
ているので、コアとクラッドの線膨張係数の差によって
生ずる集中応力もこの層によって緩和され、前記実施例
と比較例に示されるように損失の減少ができるものであ
る。[Effects] As explained above, in the present invention, the core is made of pure quartz and the cladding is made of fluorine-doped silica glass.
In the 5-micron band single mode fiber, the interface between the core and the cladding is constructed so that the refractive index gradually decreases from the core to the cladding, and the interface between the core and the cladding is composed of layers in which fluorine content increases sequentially from pure quartz. Therefore, the concentrated stress caused by the difference in linear expansion coefficient between the core and the cladding is also alleviated by this layer, and the loss can be reduced as shown in the examples and comparative examples.
また、コアのゲルマニウムを含存するものに比べ、光の
集中するコアが純石英よりなっているので、この点でも
損失はすくなく、波長1.5ミクロン帯ですぐれた伝送
帯域特性を備えるシングルモードファイバが得られる。In addition, compared to a core containing germanium, the core on which the light is concentrated is made of pure silica, so there is less loss in this respect as well, making it a single mode fiber with excellent transmission band characteristics in the 1.5 micron wavelength band. is obtained.
第1図は本発明のシングルモードファイバの屈折率分布
および寸法を示す。
第2図は従来のシングルモードファイバの屈折率及び寸
法を示す。
^・・・コア中央部、治・・・界面、C・・・クラッド
、4′・・・コア。FIG. 1 shows the refractive index profile and dimensions of the single mode fiber of the present invention. FIG. 2 shows the refractive index and dimensions of a conventional single mode fiber. ^...Central part, cure...interface, C...cladding, 4'...core.
Claims (1)
よりなる1.5ミクロン帯シングルモードファイバにお
いて、コアとクラッドの界面の屈折率がコアからクラッ
ドに向って徐々に小さくなっていることを特徴とする1
.5ミクロン帯用シングルモード光ファイバ。A 1.5-micron band single mode fiber whose core is pure quartz and whose cladding is fluorine-doped silica glass is characterized in that the refractive index at the interface between the core and cladding gradually decreases from the core to the cladding. Do 1
.. Single mode optical fiber for 5 micron band.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60106431A JPS61262708A (en) | 1985-05-17 | 1985-05-17 | Single mode optical fiber for 1.5 micron band |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60106431A JPS61262708A (en) | 1985-05-17 | 1985-05-17 | Single mode optical fiber for 1.5 micron band |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS61262708A true JPS61262708A (en) | 1986-11-20 |
Family
ID=14433466
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60106431A Pending JPS61262708A (en) | 1985-05-17 | 1985-05-17 | Single mode optical fiber for 1.5 micron band |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS61262708A (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS649406A (en) * | 1987-07-02 | 1989-01-12 | Kokusai Denshin Denwa Co Ltd | Optical fiber |
JPH01102507A (en) * | 1987-10-16 | 1989-04-20 | Sumitomo Electric Ind Ltd | Optical fiber |
JPH01107211A (en) * | 1987-10-21 | 1989-04-25 | Sumitomo Electric Ind Ltd | Environmental resistant optical fiber |
JPH01107210A (en) * | 1987-10-21 | 1989-04-25 | Sumitomo Electric Ind Ltd | Environmental resistant optical fiber |
WO1991013038A1 (en) * | 1990-02-28 | 1991-09-05 | Otc Limited | A rare-earth doped fibre |
WO1993002018A1 (en) * | 1991-07-15 | 1993-02-04 | The University Of Sydney | Light transmitting device having regions of differing refractive index |
US5655039A (en) * | 1995-12-22 | 1997-08-05 | Corning, Inc. | Nonlinear optical loop mirror device including dispersion decreasing fiber |
WO1999022258A1 (en) * | 1997-10-29 | 1999-05-06 | Sumitomo Electric Industries, Ltd. | Dispersion-shifted optical fiber |
WO2011110617A1 (en) * | 2010-03-10 | 2011-09-15 | Heraeus Quarzglas Gmbh & Co. Kg | Method and tubular semi-finished product for producing an optical fiber |
CN113264670A (en) * | 2021-04-13 | 2021-08-17 | 江苏永鼎股份有限公司 | Method for preparing large-size fluorine-doped quartz tube and fluorine-doped quartz tube |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS6017405A (en) * | 1983-04-21 | 1985-01-29 | アメリカン・テレフォン・アンド・テレグラフ・カムパニー | Single mode optical guide fiber having trapezoidal refractive index distribution |
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- 1985-05-17 JP JP60106431A patent/JPS61262708A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6017405A (en) * | 1983-04-21 | 1985-01-29 | アメリカン・テレフォン・アンド・テレグラフ・カムパニー | Single mode optical guide fiber having trapezoidal refractive index distribution |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS649406A (en) * | 1987-07-02 | 1989-01-12 | Kokusai Denshin Denwa Co Ltd | Optical fiber |
JPH01102507A (en) * | 1987-10-16 | 1989-04-20 | Sumitomo Electric Ind Ltd | Optical fiber |
JPH01107211A (en) * | 1987-10-21 | 1989-04-25 | Sumitomo Electric Ind Ltd | Environmental resistant optical fiber |
JPH01107210A (en) * | 1987-10-21 | 1989-04-25 | Sumitomo Electric Ind Ltd | Environmental resistant optical fiber |
WO1991013038A1 (en) * | 1990-02-28 | 1991-09-05 | Otc Limited | A rare-earth doped fibre |
WO1993002018A1 (en) * | 1991-07-15 | 1993-02-04 | The University Of Sydney | Light transmitting device having regions of differing refractive index |
US5655039A (en) * | 1995-12-22 | 1997-08-05 | Corning, Inc. | Nonlinear optical loop mirror device including dispersion decreasing fiber |
US5689596A (en) * | 1995-12-22 | 1997-11-18 | Corning, Inc. | Nonlinear optical loop mirror device providing pulse width switching |
WO1999022258A1 (en) * | 1997-10-29 | 1999-05-06 | Sumitomo Electric Industries, Ltd. | Dispersion-shifted optical fiber |
US6360046B1 (en) | 1997-10-29 | 2002-03-19 | Sumitomo Electric Industries, Ltd. | Dispersion-shifted optical fiber |
WO2011110617A1 (en) * | 2010-03-10 | 2011-09-15 | Heraeus Quarzglas Gmbh & Co. Kg | Method and tubular semi-finished product for producing an optical fiber |
US9085481B2 (en) | 2010-03-10 | 2015-07-21 | Heraeus Quarzglas Gmbh & Co. Kg | Method and tubular semifinished product for producing an optical fiber |
US10118854B2 (en) | 2010-03-10 | 2018-11-06 | Heraeus Quarzglas Gmbh & Co. Kg | Tubular semifinished product for producing an optical fiber |
CN113264670A (en) * | 2021-04-13 | 2021-08-17 | 江苏永鼎股份有限公司 | Method for preparing large-size fluorine-doped quartz tube and fluorine-doped quartz tube |
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