JPS61247654A - Adhesive of sodium silicate - Google Patents

Adhesive of sodium silicate

Info

Publication number
JPS61247654A
JPS61247654A JP9613286A JP9613286A JPS61247654A JP S61247654 A JPS61247654 A JP S61247654A JP 9613286 A JP9613286 A JP 9613286A JP 9613286 A JP9613286 A JP 9613286A JP S61247654 A JPS61247654 A JP S61247654A
Authority
JP
Japan
Prior art keywords
heat
sodium silicate
adhesive
resistant
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9613286A
Other languages
Japanese (ja)
Inventor
桜田 康之
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP9613286A priority Critical patent/JPS61247654A/en
Publication of JPS61247654A publication Critical patent/JPS61247654A/en
Pending legal-status Critical Current

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Landscapes

  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は軽量にして耐火断熱性の極めて優れた軽量、耐
熱、消音、断熱、保温材と、これにジルコンやアルミナ
、シリカ、セラミック他高温耐熱材と接着材との混合物
他各種無機質及び有機質の耐熱接着剤を更に混合して作
る軽量、耐熱、耐薬、消音、断熱、保温材と更に上記物
質を成形施工した表面に溶融点以上の高温を加えて表面
を溶解1−て後、冷却し、冷却後にできるセラミック化
粧板等に関するもので、特にそのための接着剤に関する
ものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention provides a lightweight, heat-resistant, sound-deadening, heat-insulating, and heat-insulating material that is lightweight and has extremely excellent fire-resistant and heat-insulating properties, and a combination of this material with high-temperature heat-resistant materials such as zircon, alumina, silica, and ceramics, and an adhesive. A lightweight, heat-resistant, chemical-resistant, sound-deadening, heat-insulating, heat-retaining material made by further mixing a mixture of various inorganic and organic heat-resistant adhesives, and then applying a high temperature above the melting point to the surface formed by molding the above substances to melt the surface.1 The present invention relates to ceramic decorative laminates and the like that can be produced after cooling, and particularly to adhesives therefor.

従来、軽量断熱材に珪酸す) IJJウムみを混合して
成形した耐火物はあったが、珪酸ナトリウムは耐熱性は
あっても耐水性が無(、湿気や蒸気や水に当ると溶けた
り破壊されるために使用する範囲も限られ屋外では使用
することもできなかった。
In the past, there were refractories made by mixing IJJ umami into lightweight insulation materials, but although sodium silicate is heat resistant, it is not water resistant (and does not melt when exposed to moisture, steam, or water). Because it was destroyed, its range of use was limited, and it could not be used outdoors.

本発明はこれ等の欠点を除いたものであり、珪酸ナトリ
ウムにアクリル系樹脂及び又はポリエステル系樹脂等を
加えて耐水耐薬性な増し湿気や蒸気や水や薬品等に対し
ても極めて強い耐熱、断熱、消音、保温材を製造するた
めのものである。
The present invention eliminates these drawbacks, and adds acrylic resin and/or polyester resin to sodium silicate to increase water and chemical resistance. It is used to produce insulation, sound deadening, and heat retention materials.

本発明で使用される珪酸ナトリウム系接着剤には任意の
接着性高分子化合物を使用することができるが、アクリ
ル系樹脂やポリエステル系樹脂が好適に使用され得る。
Any adhesive polymer compound can be used for the sodium silicate adhesive used in the present invention, and acrylic resins and polyester resins are preferably used.

珪酸ナトリウムとアクリル系樹脂又Fiポリエステル系
樹脂等との混合物は珪酸ナトリウムの比率を少なくする
と耐水耐薬性は増加しても耐熱性を減少するので、使用
温度や耐水性や結露防止等に応じて配合を変更される。
For mixtures of sodium silicate and acrylic resins or Fi polyester resins, etc., if the proportion of sodium silicate is reduced, the water and chemical resistance will increase but the heat resistance will decrease. The formulation is changed.

配合比率は無水珪酸95チ〜20q6アクリル系樹脂1
5q6〜80%の場合と、無水珪酸95チ〜20%ぼり
エステル系樹脂5チ〜80%の他、珪酸ナトリウム95
%〜20%アクリル系樹脂3係〜70%又はアクリル系
樹脂3係〜70チ等及び又は珪酸ナトリウムと澱粉、シ
リコン、酢酸ビニル等信の高分子接着剤とを配合するこ
ともある。
The blending ratio is 95 to 20q6 silicic anhydride to 1 part acrylic resin.
5q6~80%, 95~20% silicic anhydride, 5~80% ester resin, and 95~80% sodium silicate.
% to 20% acrylic resin 3 to 70% or acrylic resin 3 to 70%, or sodium silicate and a polymeric adhesive such as starch, silicon, or vinyl acetate may be blended.

本発明の接着剤を使用する場合には、例えば蛭石の粉末
に珪酸ナトリウム80チアクリル系樹脂15チ〜20%
にポリエステル系樹脂を混合17てエンジンその他の燃
焼装置やyl?lティラー他の排気や蒸気の断熱材とし
て、これをエンジン用マフラーの表面にラスを張りその
外側よりスプレィ等によって被覆するとエンジン始動後
1時間で無被覆部分は赤熱し温度Fi400tZ’前後
になるが被横部分に指先を接触させても熱いと感する程
度で火傷を負うととはない。又珪酸ナトリウム80多〜
60チアクリル系樹脂15チ〜25%、ポリエステル系
樹脂5%句15チの範囲で配合比率を種々に変えて混合
して成形物を作ったり壁体等に吹付けた場合、耐熱性を
失わず極めて耐薬、耐水性の優れた耐熱、消音、断熱、
耐水保温、結露防止材料を得ることができる。
When using the adhesive of the present invention, for example, vermiculite powder is mixed with 80% sodium silicate and 15% to 20% thiacrylic resin.
17 Mix polyester resin with engine and other combustion equipment and yl? If this is used as a heat insulator for tiller and other exhaust gas and steam, and it is applied by applying lath to the surface of an engine muffler and spraying it from the outside, the uncoated part will become red hot within an hour after the engine starts, reaching a temperature of around 400tZ'. Even if you touch the covered part with your fingertips, you will only feel the heat and will not get burned. Also sodium silicate 80~
60 Thiacrylic resin 15% to 25% and polyester resin 5% 15% When mixed at various blending ratios to make molded products or sprayed on walls, etc., the product will not lose heat resistance. Extremely chemical resistant, water resistant, heat resistant, sound deadening, heat insulating,
Water-resistant, heat-retaining, and anti-condensation materials can be obtained.

本発明では水溶性、揮発性のうち何れか一方に溶ける接
着剤を混合することによって自由に使い分けて使用でき
、又、遠隔地のプラントを施工する場合でも従来製品の
如く工場で型枠内に流込み史に蒸気で蒸したり、或は乾
燥炉内で焼いてできた品物を遠隔地に輸送する必要もな
い。
The present invention can be used freely by mixing adhesives that are soluble in either water-soluble or volatile adhesives, and even when constructing a plant in a remote location, it can be used in a formwork at a factory like conventional products. There is no need to transport products that have been steamed or baked in a drying oven to a remote location during pouring.

実施例(1) 珪酸ソーダー60fにアクリル系樹脂(三井東圧アルマ
ーテックスL−1042)2 Ofを加え、更にこれに
水50f〜80fを混入して攪拌したものに無機物パー
ライトsor、蛭石70f、@酸カルシウム502を混
入してから更に水301を加えて良く混合1−て攪拌し
板状に成形したものを良(乾燥してから熱伝導率を計っ
たところ0.03であり、又板の表面に3600Cの熱
を1分間加えても板の表面が3wi位の深さに真赤に溶
けたが、空気冷却してセラミ、り状になり1crn離れ
た周辺や反対側を指で押しても熱を少1−も感じなかっ
た。
Example (1) Acrylic resin (Mitsui Toatsu Almartex L-1042) 2 Of was added to 60 f of silicate soda, and 50 to 80 f of water was added to this and stirred, and the inorganic pearlite sor, vermiculite 70 f, @Calcium acid 502 was mixed, then water 301 was added, mixed well, stirred, and formed into a plate.The thermal conductivity was measured after drying and was 0.03. Even if I applied heat of 3600C to the surface of the board for 1 minute, the surface of the board melted into a deep red color to a depth of about 3wi, but when I cooled it with air, it became like a ceramic, and even when I pressed the periphery or the opposite side 1crn away with my finger, it melted. I didn't feel the slightest bit of heat.

実施例(2) 珪酸ソーダー6Ofにアクリル系樹脂(三井東圧アルマ
ーテックスL−1060)20fを加え、更にこれに水
50tを混入して攪拌したものに無機物パーライト50
1、蛭石150fを混入したものに更に水302を加え
て良(混合して攪拌し板状に成形したものを良く乾燥し
てからバーナーで表面を加熱して表面を溶解させてから
放置したところ表面が緑色の溶岩のようになった。これ
はセラミックス化粧板として各種の分野に使用すること
ができるものであった。
Example (2) 20 f of acrylic resin (Mitsui Toatsu Alumatex L-1060) was added to 6 Of of silicate soda, and 50 t of water was added to this and stirred, and inorganic pearlite 50 was added.
1. Add 302 ml of water to the mixture of 150 f of vermiculite and mix well (mix, stir, form into a plate, dry thoroughly, heat the surface with a burner to dissolve the surface, and then leave it. However, the surface became green lava-like.This could be used as a ceramic decorative board in various fields.

本発明の接着剤を使用することにより、現地で材料を調
達してミキサーで混合して適度の粘度に混合しコテ、へ
ケ、流込みバキュームによる流込等で施工するか、スプ
レィのみで完了するととができるため、工費は低摩で施
工は簡単且つその溶融点は1400t:’以上、熱伝導
率0.03゜比重は0.3〜0.6の無機物のため腐蝕
変質せず、且つカビの発生、虫害に対する心配は無く、
その上耐寒、防音、保温、消音効果は極めて太き(従っ
て各種構造物の内外装材、保温断熱材、防音吸音消音材
、耐火、耐熱材、結露防止材、或は又セラミック化粧板
として使用でき大変便利である。用途としては保温、断
熱、耐熱、防火、防音、吸音、消音、結露防止の他、船
舶。
By using the adhesive of the present invention, materials can be procured locally, mixed in a mixer to a suitable viscosity, and the work can be completed by pouring with a trowel, spade, pouring vacuum, etc., or by just spraying. As a result, the construction cost is low and the construction is easy.The melting point is over 1400t:', the thermal conductivity is 0.03°, and the specific gravity is 0.3 to 0.6.As it is an inorganic material, it does not undergo corrosion or deterioration. There is no need to worry about mold growth or insect damage.
In addition, it has extremely cold resistance, soundproofing, heat retention, and sound deadening effects (therefore, it can be used as interior and exterior materials for various structures, heat insulation materials, soundproofing, sound absorbing, and sound deadening materials, fireproofing, heatproofing materials, dew condensation prevention materials, or ceramic decorative boards. It is very convenient. Applications include heat retention, heat insulation, heat resistance, fire prevention, soundproofing, sound absorption, sound deadening, and prevention of condensation, as well as for ships.

自動車、電車、列車、航空機等の外板の内側と内張との
間にスプレィして使用すると耐熱、防火、断熱、結露防
止、保温等の効果があり、又冷蔵庫の内張、冷暖房機器
又は住宅等の内外装、家具、書庫、金庫、ロシカー等の
内外装、鉄骨。
When sprayed between the inside and lining of the exterior panels of automobiles, trains, trains, aircraft, etc., it has effects such as heat resistance, fire prevention, insulation, condensation prevention, and heat retention, and can also be used on the lining of refrigerators, air conditioning equipment, etc. Interior and exterior of houses, furniture, archives, safes, Russian cars, etc., and steel frames.

重油タンク、ガソリンタンク、同パイプラインや冷却水
、水や蒸気配管等の外装の他消音機器に使用して防音効
果、消音効果をあげることができる。またセラミ、り化
粧板として住宅用建材として使用する他、ソーラハウス
用機器、高層ビル用鉄骨の耐火被覆、海洋開発、宇宙開
発用基地の施設用断熱材等としても有効であると共に火
災の発生時表面に黒くすすが付着するだけで消火し煙や
有毒がスが発生したりすることは全くな−。
It can be used for the exterior of heavy oil tanks, gasoline tanks, pipelines, cooling water, water and steam piping, etc., as well as for noise reduction equipment, to improve soundproofing and silencing effects. In addition to being used as building materials for houses as ceramic and decorative boards, they are also effective as equipment for solar houses, fireproof coatings for steel frames for high-rise buildings, and insulation materials for marine and space development bases, etc., and are also effective in preventing fires. When the fire is extinguished, only black soot adheres to the surface, and no smoke or toxic gas is emitted.

Claims (1)

【特許請求の範囲】[Claims] 珪酸ナトリウムに高分子接着剤を添加したことを特徴と
する珪酸ナトリウム系接着剤。
A sodium silicate adhesive characterized by adding a polymer adhesive to sodium silicate.
JP9613286A 1986-04-25 1986-04-25 Adhesive of sodium silicate Pending JPS61247654A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9613286A JPS61247654A (en) 1986-04-25 1986-04-25 Adhesive of sodium silicate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9613286A JPS61247654A (en) 1986-04-25 1986-04-25 Adhesive of sodium silicate

Publications (1)

Publication Number Publication Date
JPS61247654A true JPS61247654A (en) 1986-11-04

Family

ID=14156863

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9613286A Pending JPS61247654A (en) 1986-04-25 1986-04-25 Adhesive of sodium silicate

Country Status (1)

Country Link
JP (1) JPS61247654A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011074414A1 (en) * 2009-12-18 2011-06-23 日東電工株式会社 Aqueous dispersion adhesive composition, and adhesive sheet
JP2012528066A (en) * 2009-05-28 2012-11-12 ダウ グローバル テクノロジーズ エルエルシー Modified geopolymer compositions, methods and uses

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49329A (en) * 1972-04-14 1974-01-05
JPS5045822A (en) * 1973-08-31 1975-04-24
JPS50149719A (en) * 1974-05-22 1975-12-01
JPS5334635A (en) * 1976-09-13 1978-03-31 Toyota Motor Co Ltd Surface treatment method of light alloy cylinder
JPS54126227A (en) * 1978-03-24 1979-10-01 Yasuyuki Sakurada Light weight* heat resistant insulating material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49329A (en) * 1972-04-14 1974-01-05
JPS5045822A (en) * 1973-08-31 1975-04-24
JPS50149719A (en) * 1974-05-22 1975-12-01
JPS5334635A (en) * 1976-09-13 1978-03-31 Toyota Motor Co Ltd Surface treatment method of light alloy cylinder
JPS54126227A (en) * 1978-03-24 1979-10-01 Yasuyuki Sakurada Light weight* heat resistant insulating material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012528066A (en) * 2009-05-28 2012-11-12 ダウ グローバル テクノロジーズ エルエルシー Modified geopolymer compositions, methods and uses
WO2011074414A1 (en) * 2009-12-18 2011-06-23 日東電工株式会社 Aqueous dispersion adhesive composition, and adhesive sheet
JP2011127038A (en) * 2009-12-18 2011-06-30 Nitto Denko Corp Water-dispersible pressure-sensitive adhesive composition and pressure-sensitive adhesive sheet

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