JPS61246512A - Burner - Google Patents

Burner

Info

Publication number
JPS61246512A
JPS61246512A JP60085707A JP8570785A JPS61246512A JP S61246512 A JPS61246512 A JP S61246512A JP 60085707 A JP60085707 A JP 60085707A JP 8570785 A JP8570785 A JP 8570785A JP S61246512 A JPS61246512 A JP S61246512A
Authority
JP
Japan
Prior art keywords
catalyst body
catalyst
combustion
temperature
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP60085707A
Other languages
Japanese (ja)
Other versions
JPH0623606B2 (en
Inventor
Jiro Suzuki
次郎 鈴木
Atsushi Nishino
敦 西野
Yasuhiro Takeuchi
康弘 竹内
Yukiyoshi Ono
之良 小野
Masato Hosaka
正人 保坂
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP60085707A priority Critical patent/JPH0623606B2/en
Publication of JPS61246512A publication Critical patent/JPS61246512A/en
Publication of JPH0623606B2 publication Critical patent/JPH0623606B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/46Details, e.g. noise reduction means
    • F23D14/72Safety devices, e.g. operative in case of failure of gas supply
    • F23D14/78Cooling burner parts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D14/00Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
    • F23D14/12Radiant burners
    • F23D14/18Radiant burners using catalysis for flameless combustion

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Gas Burners (AREA)

Abstract

PURPOSE:To increase the amount of combustion per unit area and make it possible to perform a high load combustion by providing a cooling passage at least at one of the internal section and outer periphery of a catalyst body. CONSTITUTION:There are provided an internal cooling passage which is formed cylindrically with iron, stainless steel, etc. and one end of which is connected to the outlet opening of a cooling blower 13 via an external cooling passage, and the other end of which penetrates a catalyst body 6, and an external cooling passage 15 which surrounds the internal wall 12 in order to cool its outer periphery and which is partially formed with a wall made of glass, etc., which is connected to the outlet opening of the blower 13. Since the internal cooling passage 14 which penetrates the inner section of the catalyst body 6 receives the heat radiated from the catalyst body 6 over the whole of the passage, the temperature of the catalyst body 6 is difficult to rise, and the inner wall 12 which is cooled by the external cooling passage 15 also prevents the temperature rise in the catalyst body 6.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は液体または気体燃料を用いて燃焼させる装置に
関するもので、暖房、乾燥、給湯等の加熱熱源として用
いられる。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to an apparatus for burning liquid or gaseous fuel, and is used as a heating heat source for heating, drying, hot water supply, etc.

従来の技術 従来の触媒燃焼装置を第3図に示す。第3図で1は触媒
体で多数の燃焼孔2を有する。予混合パイプ3よシ燃料
ガスと空気の混合気は予混合気室4へ入り、前記の燃焼
孔2で燃焼する。燃焼反応によって触媒体1は高温とな
シ、その熱は外周に設けられたガラス5f:通じて放射
されている。また触媒体1の下流には排気ガスが排出さ
れている。
Prior Art A conventional catalytic combustion apparatus is shown in FIG. In FIG. 3, reference numeral 1 denotes a catalyst body having a large number of combustion holes 2. The mixture of fuel gas and air enters the premixing chamber 4 through the premixing pipe 3 and is combusted in the combustion hole 2 described above. The catalyst body 1 reaches a high temperature due to the combustion reaction, and the heat is radiated through the glass 5f provided on the outer periphery. Furthermore, exhaust gas is discharged downstream of the catalyst body 1.

また触媒体1の上流には予熱着火用ヒータ6が設けられ
ている。
Further, a preheating ignition heater 6 is provided upstream of the catalyst body 1.

発明が解決しようとする問題点 しかし、このような構成のものでは、高負荷燃焼に困M
をもたらす欠点があった。その理由を以下に述べる。限
られた面積の触媒体1で多量の燃料ガスを燃焼させると
、前記触媒体1は燃焼量に応じて高温化していく。この
高温化することにより、■、触媒が寿命的に劣化する。
Problems to be Solved by the Invention However, with such a configuration, it is difficult to perform high-load combustion.
There were drawbacks that led to The reason for this is explained below. When a large amount of fuel gas is burned in the catalyst body 1 having a limited area, the temperature of the catalyst body 1 increases in accordance with the amount of combustion. As a result of this high temperature, (1) the catalyst deteriorates in terms of its lifespan.

■、予混合気室3の予混合ガスを発火させる。という2
つの問題が生じるもので、このため単位面積あたシの燃
焼量に限界があり友。このような問題を防ぐために、ガ
ラス6f、薄く、かつ熱透過性の良い材料を用いて触媒
体1の高温化を防止する、あるいは、触媒体1に白金族
系の触[−全担持させて、予混合ガスの発火を抑制する
等の手段が従来は講じられていた。
(2) The premixed gas in the premixture chamber 3 is ignited. 2
Therefore, there is a limit to the amount of combustion per unit area. In order to prevent such problems, the temperature of the catalyst body 1 can be prevented by using glass 6f, a thin material with good heat permeability, or the catalyst body 1 can be made of a platinum group catalyst [-- fully supported on the catalyst body 1]. Conventionally, measures have been taken to suppress ignition of the premixed gas.

本発明はさらにこのような問題点を抜本的に解決し、単
位面積当りの燃焼量を増加せしめ、よりコンパクトな触
媒体で高負荷燃焼を可能とするものである。
The present invention further fundamentally solves these problems, increases the amount of combustion per unit area, and enables high-load combustion with a more compact catalyst body.

問題点を解決する几めの手段 そして上記問題点を解決する本発明の技術的手段は、上
記の触媒体の内部と外周の少なくとも一方に冷却用経路
を設けるものである。
An elaborate means for solving the problems and a technical means of the present invention for solving the above problems is to provide a cooling path in at least one of the inside and the outer periphery of the catalyst body.

作用 この技術的手段による作用は次のようになる。action The effect of this technical means is as follows.

すなわち、触媒体の外周を冷却する流体によって、触媒
体は外周よシ冷却され、内部を通過する流体によって内
部よシ低温化する。そして全体的に触媒が低温となるた
めに、前述のような、触媒の寿命劣化9発火が生じにく
くなる。むろん低温になシすぎれば触媒が不活性となシ
ネ完全燃焼するため、冷却用流体の量は所定の温度を保
つべく設定されているものである。
That is, the outer circumference of the catalyst body is cooled by the fluid that cools the outer circumference of the catalyst body, and the temperature of the inside of the catalyst body is lowered by the fluid passing through the inside. Since the temperature of the catalyst as a whole becomes low, catalyst life deterioration 9 and ignition as described above are less likely to occur. Of course, if the temperature is too low, the catalyst becomes inactive and complete combustion occurs, so the amount of cooling fluid is set to maintain a predetermined temperature.

実施例 以下、本発明の一実施例を第1図とともに説明する。6
は触媒体で、耐熱材料、アルミナ、シリカ、カルシア等
の素材を用いている。そして触媒体1には多数の燃焼孔
7が設けられている。予混合パイプ8の上流には空気お
よび燃料ガスの供給部(図示せず)が設けられている。
EXAMPLE Hereinafter, an example of the present invention will be described with reference to FIG. 6
The catalyst body is made of heat-resistant materials such as alumina, silica, and calcia. The catalyst body 1 is provided with a large number of combustion holes 7. Upstream of the premixing pipe 8, an air and fuel gas supply section (not shown) is provided.

そして、予混合パイプ8より予混合気室9へ入った混合
ガスは触媒体60表面に担持した白金族系の触媒によっ
て燃焼する。また、このような触媒の反応を十分に行う
ため触媒体6はヒータ10によって予じめ所定の温度に
加熱されているものである。前記触このような構成にお
いて、本発明では冷却用の送風機13、この送風機13
の吐出口に次にのべる外部冷却路を介して一端を連通し
、他端は触媒体6t−貫通する鉄またはステンレス等で
筒状に形成した内部冷却経路14、および内壁12の外
周を冷却するように内壁12を包囲し、一部分を送風機
13の吐出口に接続したガラス等の壁で形成した外部冷
却経路15を設けている。この2つの冷却経路の有する
作用を以下に述べる。
The mixed gas that enters the premix chamber 9 from the premix pipe 8 is combusted by a platinum group catalyst supported on the surface of the catalyst body 60. Further, in order to sufficiently carry out such a catalytic reaction, the catalytic body 6 is heated in advance to a predetermined temperature by a heater 10. In the above-mentioned configuration, the present invention includes a cooling blower 13, and this blower 13.
One end communicates with the discharge port of the catalytic converter via the next external cooling path, and the other end cools the internal cooling path 14 formed in a cylindrical shape made of iron or stainless steel or the like that passes through the catalyst body 6t, and the outer periphery of the inner wall 12. An external cooling path 15 is provided, which is formed of a wall made of glass or the like, which surrounds the inner wall 12 and is partially connected to the outlet of the blower 13. The effects of these two cooling paths will be described below.

予混合ガスは触媒体6の上流面より燃焼を始め、下流面
に致る間に、燃焼孔7の中でその反応を終らさせている
。このような触媒燃焼の特徴は、燃焼熱のうち、多くの
割合が触媒体6を加熱するために、触媒体6が高温化し
やすいことである。したがって小さなサイズの媒触体6
で燃焼を大とすることに限界があることは前述のとおり
である。
The premixed gas starts to burn from the upstream side of the catalyst body 6 and completes its reaction in the combustion hole 7 while reaching the downstream side. A feature of such catalytic combustion is that since a large proportion of the combustion heat heats the catalyst body 6, the temperature of the catalyst body 6 tends to increase. Therefore, the small size of the medium 6
As mentioned above, there is a limit to increasing the combustion rate.

そして触媒体6の熱は輻射によって放散するものである
が、従来のようにガラスを予混合気室9の内壁に用いた
だけではまだ十分に熱を放射しきれない。なぜならば、
ガラスでは熱の大半は透過せず、ガラス自体が吸収し、
ガラスが高温化するからである。高温になったガラスは
触媒体の熱を十分に吸収しないため、触媒体の熱の放散
は不十分で高温化しやすいものであった。
The heat of the catalyst body 6 is dissipated by radiation, but if glass is used for the inner wall of the premixture chamber 9 as in the past, the heat cannot be sufficiently radiated. because,
Most of the heat does not pass through glass; it is absorbed by the glass itself.
This is because the glass becomes hot. Since the heated glass does not sufficiently absorb the heat of the catalyst, the heat dissipation of the catalyst is insufficient and the temperature easily rises.

しかるに、本発明の構成では、触媒体6の内部を貫通す
る内部冷却経路14は、触媒体6が放射する熱を経路全
体で受熱するため触媒体6の温度は上昇しにくく、また
外部冷却経路15によって冷却される内壁12も同じく
、触媒体6の温度上昇を防止している。むろんこの場合
、触媒体6と内壁12、および内部冷却経路14間に介
在している断熱材11を介しての熱伝導による触媒体6
の冷却も若干性なわれているが、この熱伝導による冷却
は、接触部のみを低温とし触媒体6の温度不均一を生じ
させるため好ましいものではない。
However, in the configuration of the present invention, the internal cooling path 14 penetrating the inside of the catalyst body 6 receives the heat radiated by the catalyst body 6 throughout the path, so that the temperature of the catalyst body 6 is difficult to rise. The inner wall 12 cooled by the catalyst member 15 also prevents the temperature of the catalyst body 6 from rising. Of course, in this case, the catalyst body 6 is heated by heat conduction through the heat insulating material 11 interposed between the catalyst body 6, the inner wall 12, and the internal cooling path 14.
However, this cooling by heat conduction is not preferable because it causes only the contact portion to be at a low temperature and causes temperature non-uniformity in the catalyst body 6.

このような目的の断熱材としてはアスベストセラミック
繊維、鉱物繊維系のものが選ばれる。すなわち本発明は
輻射による冷却によって触媒面の温度を均一に低下する
ことを狙ったもので、伝熱による冷却が局部的になるの
で内部冷却経路14と触媒体6を断熱している。また上
記実施例では外部と内部の双方から冷却しているが、触
媒体6のサイズが狭い場合にはいずれか一方でもよいも
のである。触媒体6のサイズが広い場合は、触媒体6の
各部と冷却経路の距離の差による温度ムラが生じ部分的
な高温化が生じる。この場合は内部冷却経路を設け、か
つその数を任意に選択すればよいものである。
Asbestos ceramic fibers and mineral fibers are selected as heat insulating materials for this purpose. That is, the present invention aims at uniformly lowering the temperature of the catalyst surface by cooling by radiation, and since the cooling by heat transfer is localized, the internal cooling path 14 and the catalyst body 6 are insulated. Further, in the above embodiment, cooling is performed from both the outside and the inside, but if the size of the catalyst body 6 is small, either one may be used. When the size of the catalyst body 6 is wide, temperature unevenness occurs due to the difference in distance between each part of the catalyst body 6 and the cooling path, resulting in a partial increase in temperature. In this case, internal cooling paths may be provided and the number thereof may be arbitrarily selected.

次に請求の範囲第2項について説明する。Next, the second claim will be explained.

触媒体6の熱を受ける内壁12、内部冷却経路14の受
熱面、すなわち触媒体6と対面する部分に熱吸収処理を
施したものである。熱吸収処理は金属に対するサンドブ
ラスト加工、酸化被膜処理。
The inner wall 12 that receives the heat of the catalyst body 6 and the heat-receiving surface of the internal cooling path 14, that is, the portion facing the catalyst body 6, are subjected to heat absorption treatment. Heat absorption treatments include sandblasting and oxide coating on metals.

黒色塗装、溶射等を行ない、金属素材より熱吸収率のよ
い表面を得るものである。もし吸収率(輻射率ともいう
)が低ければ熱は反射し、触媒体6は高温となる。この
ような第2項の発明を付加することによって単位面積当
りの燃焼量を増加しても、発火あるいは触媒の高温劣化
は防止できる。
It is coated with black paint, thermal spraying, etc. to obtain a surface with better heat absorption than metal materials. If the absorption rate (also called emissivity) is low, heat will be reflected and the catalyst body 6 will have a high temperature. By adding the second aspect of the invention, even if the amount of combustion per unit area is increased, ignition or high-temperature deterioration of the catalyst can be prevented.

次に請求の範囲第3項を第2図とともに説明する。なお
、上記実施例と同一部分には同一番号を付して説明を略
し、異なる部分を中心に説明する。
Next, claim 3 will be explained with reference to FIG. 2. It should be noted that the same parts as in the above embodiment are given the same numbers and the explanation thereof will be omitted, and the explanation will focus on the different parts.

予混合気室9の内壁12の放熱部および内部冷却経路1
4の放熱部、すなわち両者の冷却流体側に放熱用のフィ
ン16を多数設けたものである。触媒体6と内壁12、
または内部冷却経路14の温度差が大きいほど、触媒体
6の輻射量は増え、低温化する。この目的のため、両者
の放熱部にフィンを設けたものである。この発明を付加
することによって本発明の効果は一層大となるものであ
る。
Heat radiation part of inner wall 12 of premixture chamber 9 and internal cooling path 1
A large number of heat radiating fins 16 are provided on the heat radiating portion of No. 4, that is, on the cooling fluid side of both. catalyst body 6 and inner wall 12,
Alternatively, as the temperature difference in the internal cooling path 14 increases, the amount of radiation from the catalyst body 6 increases and the temperature decreases. For this purpose, fins are provided on both heat dissipation parts. By adding this invention, the effects of the present invention will be further enhanced.

次に請求の範囲第4項について説明する。Next, Claim 4 will be explained.

触媒として白金族系の白金、バラジュウム等を担持させ
た場合、発火を抑制する効果をもつ、燃焼用触媒として
白金族は極めて活性が高いことは良く知られている。し
かし、ただ酸化反応を活発に行うだけではなく、発火を
抑制する機能も有する。
It is well known that platinum group metals such as platinum and baradium are extremely active as combustion catalysts that have the effect of suppressing ignition when supported as a catalyst. However, it not only actively performs oxidation reactions, but also has the function of suppressing ignition.

すなわち予混合気室9には可燃性の混合気が供給されて
いるが、媒触体6が高温となれば、前述の混合気が発火
してしまう。しかし、この場合混合気の発火温度に媒触
体が達していても発火はしないものである。この−見不
思議な現象は、混合気が触媒体6へ向って流れているた
め、混合気自体の温度が高くないからである。しかしこ
の場合も触媒体6と接する混合気の極めて薄い層は発火
温度に達していると思われる。この層がミクロ的に小さ
いために火炎として成長しないので発火として予混合気
室9全体に火炎が広がらないのである。
That is, although a flammable air-fuel mixture is supplied to the premixture chamber 9, if the temperature of the medium catalyst 6 becomes high, the above-mentioned air-fuel mixture will ignite. However, in this case, even if the catalyst reaches the ignition temperature of the air-fuel mixture, it will not ignite. This strange phenomenon occurs because the air-fuel mixture is flowing toward the catalyst body 6, so the temperature of the air-fuel mixture itself is not high. However, in this case as well, the extremely thin layer of the air-fuel mixture in contact with the catalyst body 6 appears to have reached its ignition temperature. Since this layer is microscopically small, it does not grow as a flame, so the flame does not spread throughout the premixture chamber 9 as ignition occurs.

しかし極めて触媒体6が高温になれば、このミクロ的な
層も厚くなり、予混合気室9は発火に致る。
However, if the catalyst body 6 becomes extremely hot, this microscopic layer will also become thick, and the premixture chamber 9 will catch fire.

この現象を抑えるために触媒体6の温度を低下す ・る
工夫が必要なのであるが、触媒として白金族のものをも
ちいれば、高温となっても発火を抑制する機能が大きい
ものである。この現象は白金族系の触媒は反応が極めて
強く、白金の極めて近い所に反応帯を作るため、火炎が
成長しても白金に触れて成長しにくいとされている。こ
のような白金族系の触媒を用いれば、発火が抑制された
分、燃焼量を大きくして高温化できるものである。
In order to suppress this phenomenon, it is necessary to take measures to lower the temperature of the catalyst body 6, but if a platinum group metal is used as the catalyst, it has a great function of suppressing ignition even at high temperatures. The reason for this phenomenon is that platinum group catalysts have extremely strong reactions and form a reaction zone very close to the platinum, so even if the flame grows, it is difficult for it to touch the platinum and grow. If such a platinum group catalyst is used, the amount of combustion can be increased and the temperature can be increased to the extent that ignition is suppressed.

発明の効果 荷化を実現し、このことによって小型で大発熱量の燃焼
装置が可能となる。この燃焼装置はまた、触媒燃焼の本
来の特徴である低NOx等のクリーン性を保持している
。さらに、かがる燃焼装置は、前述の冷却経路に流体と
して空気を用いて暖房用とする、あるいは水を用いて給
湯用として用いることも可能であり、熱交換器としての
機能をも併せて得られるものでもある。
The effects of the invention can be reduced, thereby making it possible to create a compact combustion device with a large calorific value. This combustion device also maintains cleanliness such as low NOx, which is an inherent characteristic of catalytic combustion. Furthermore, the darning combustion device can be used for heating by using air as the fluid in the cooling path mentioned above, or for hot water supply by using water, and also functions as a heat exchanger. There is also something to be gained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例の断面図、第2図は本発明の
他の実施例の断面図、第3図は従来の燃焼装置の断面図
である。 6・・・・・・触媒体、11・・印・断熱材、14・・
・・・・内部冷却経路、16・・・・・・外部冷却経路
、16・・用放熱フィン。 代理人の氏名 弁理士 中 尾 敏 男 はが1名第1
図 14・・・坊@鈴却課路 K・・外#オ却証隊 第2図 6・・・ 触−一1 イツト //・・・fr熱材 14・・・内@4何1り各
FIG. 1 is a cross-sectional view of one embodiment of the present invention, FIG. 2 is a cross-sectional view of another embodiment of the present invention, and FIG. 3 is a cross-sectional view of a conventional combustion apparatus. 6...Catalyst body, 11...mark/insulating material, 14...
... Internal cooling path, 16... External cooling path, radiating fin for 16.... Name of agent: Patent attorney Toshio Nakao (1st person)
Figure 14...Bo @Suzuoka Section K...Outside #Oiketai 2nd Figure 6...Touch-11 It//...Fr Heat Material 14...Inside @4What1ri each

Claims (4)

【特許請求の範囲】[Claims] (1)多数の燃焼孔を有する触媒体と、前記触媒体へ燃
料と燃焼用空気の混合気を供給する部分と、前記触媒体
と断熱材を介して、触媒体外周または内部に設けられた
冷却経路の少なくとも一方を有する燃焼装置。
(1) A catalyst body having a large number of combustion holes, a part that supplies a mixture of fuel and combustion air to the catalyst body, and a catalyst body provided on the outer periphery or inside the catalyst body via the catalyst body and a heat insulating material. A combustion device having at least one cooling path.
(2)冷却経路の触媒面と相対する受熱面に、輻射吸収
表面処理をした特許請求の範囲第1項記載の燃焼装置。
(2) The combustion device according to claim 1, wherein the heat receiving surface facing the catalyst surface of the cooling path is subjected to radiation absorbing surface treatment.
(3)冷却経路の冷却用流体と接する放熱面に、放熱用
フィンを設けた特許請求の範囲第1項記載の燃焼装置。
(3) The combustion device according to claim 1, wherein a heat radiation fin is provided on the heat radiation surface in contact with the cooling fluid of the cooling path.
(4)触媒体に担持する触媒を白金族系のものとした特
許請求の範囲第1項記載の燃焼装置。
(4) The combustion device according to claim 1, wherein the catalyst supported on the catalyst body is a platinum group catalyst.
JP60085707A 1985-04-22 1985-04-22 Combustion device Expired - Lifetime JPH0623606B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60085707A JPH0623606B2 (en) 1985-04-22 1985-04-22 Combustion device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60085707A JPH0623606B2 (en) 1985-04-22 1985-04-22 Combustion device

Publications (2)

Publication Number Publication Date
JPS61246512A true JPS61246512A (en) 1986-11-01
JPH0623606B2 JPH0623606B2 (en) 1994-03-30

Family

ID=13866294

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60085707A Expired - Lifetime JPH0623606B2 (en) 1985-04-22 1985-04-22 Combustion device

Country Status (1)

Country Link
JP (1) JPH0623606B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0732188A2 (en) * 1995-03-14 1996-09-18 Hoechst Aktiengesellschaft Method for treating a sealable film surface
US5720609A (en) * 1991-01-09 1998-02-24 Pfefferle; William Charles Catalytic method
NL1017021C2 (en) * 2001-01-03 2002-07-05 Nefit Buderus B V Combustion device comprising a cooling.
JP2010127553A (en) * 2008-11-28 2010-06-10 Noritz Corp Combustion apparatus

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5720609A (en) * 1991-01-09 1998-02-24 Pfefferle; William Charles Catalytic method
EP0732188A2 (en) * 1995-03-14 1996-09-18 Hoechst Aktiengesellschaft Method for treating a sealable film surface
EP0732188A3 (en) * 1995-03-14 1998-08-26 Hoechst Trespaphan GmbH Method for treating a sealable film surface
US5914079A (en) * 1995-03-14 1999-06-22 Hoechst Aktiengesellschaft Process for the treatment of a sealable film surface
NL1017021C2 (en) * 2001-01-03 2002-07-05 Nefit Buderus B V Combustion device comprising a cooling.
EP1221571A1 (en) * 2001-01-03 2002-07-10 Nefit Buderus B.V. Cooled combustion apparatus
JP2010127553A (en) * 2008-11-28 2010-06-10 Noritz Corp Combustion apparatus

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Publication number Publication date
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