JPS61225388A - Method for patterning fabric - Google Patents

Method for patterning fabric

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Publication number
JPS61225388A
JPS61225388A JP60062990A JP6299085A JPS61225388A JP S61225388 A JPS61225388 A JP S61225388A JP 60062990 A JP60062990 A JP 60062990A JP 6299085 A JP6299085 A JP 6299085A JP S61225388 A JPS61225388 A JP S61225388A
Authority
JP
Japan
Prior art keywords
pattern
fabric
dyeing
dye
anionic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP60062990A
Other languages
Japanese (ja)
Other versions
JPS6253636B2 (en
Inventor
安部 一男
健 渡辺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YAMAGATA PREF GOV
Original Assignee
YAMAGATA PREF GOV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by YAMAGATA PREF GOV filed Critical YAMAGATA PREF GOV
Priority to JP60062990A priority Critical patent/JPS61225388A/en
Publication of JPS61225388A publication Critical patent/JPS61225388A/en
Publication of JPS6253636B2 publication Critical patent/JPS6253636B2/ja
Granted legal-status Critical Current

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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、配色した色糊又は気泡を攪拌して自然に発生
する柄模様又は作意的に配色した模様を織物上に表現す
る織物の柄付は方法に関するものである。
Detailed Description of the Invention (Industrial Field of Application) The present invention is directed to the production of textiles that produce naturally occurring patterns or artificially colored patterns on textiles by stirring colored pastes or air bubbles. Patterning is about method.

(従来の技術及び問題点) 従来、墨流し模様や糊流し模様を織物上に表現するには
、柄模様を作成したところに白生地の織物をのせて転写
する方法がとられている。
(Prior Art and Problems) Conventionally, in order to express a suminagashi pattern or a glue-nagashi pattern on a fabric, a method has been used in which a white fabric is placed on a patterned pattern and transferred.

しかし、これらの方法は特殊な技術と複雑な工程によっ
て行われている。
However, these methods are performed using special techniques and complicated processes.

例えば、墨流し染めとしては、水面に染料又は墨汁を滴
下し、若干の攪拌によって自然に発生する水面の模様を
、和紙や白生地に転写する技術が知られている。
For example, as for suminagashi dyeing, a technique is known in which dye or ink is dripped onto the water surface and a pattern on the water surface that is naturally generated by slight stirring is transferred onto Japanese paper or white fabric.

しかしこの方法は、白生地織物に模様を転写した場合、
水と織物との毛細管現象で柄模様のにじみ出しが起こり
、そのパターンを鮮明に写し取ることは困難である。
However, with this method, when the pattern is transferred to white fabric,
The pattern oozes out due to capillary action between water and the fabric, making it difficult to clearly copy the pattern.

この他、従来から行われている糊流し染めは、染料と染
色用糊剤で色糊を作り、それを配色して攪拌することに
よって自然に発生する流動的で偶発的に混色された柄模
様を作り出し、その上に白生地織物を置き、模様の転写
を行っている。
In addition, the traditional glue-nagashi dyeing method creates a colored paste using dye and a dyeing paste, and then arranges the colors and stirs them to create a naturally flowing pattern with mixed colors. A white fabric is placed on top of it, and the pattern is transferred.

しかしこの方法は、染料を固着するため、生地に色糊を
付着させたまま30分〜60分の蒸熱処理を必要とする
。そのため、処理が不充分だと柄模様の色流れを起こす
などの欠点がある。また色糊の水洗時には非常に糊の除
去が難しく、洗浄しにくいのが欠点であり、処理するm
物も短いものに限定されている。
However, this method requires steaming for 30 to 60 minutes while the color paste remains attached to the fabric in order to fix the dye. Therefore, if the processing is insufficient, there are drawbacks such as color bleeding in the pattern. Also, when washing colored glue with water, it is very difficult to remove the glue, making it difficult to clean, which is a drawback.
Items are also limited to short items.

もし、この流動的な柄模様を織物上に表現しようとすれ
ば、前記糊流し染めの他、紋織物で表現する方法がある
If you want to express this fluid pattern on a fabric, there is a method other than the above-mentioned glue-nagashi-dyed method, such as using a patterned fabric.

しかしこの場合、多くの色相を表現するためには多種類
の色糸と膨大な紋紙を必要とし、一つの絞柄パターン内
で無断階の色相に変化する糊流しの微妙な色彩バランス
と流動的模様の表現を、織物の柄としてとらえることが
非常に困難である。
However, in this case, in order to express many hues, many types of colored threads and a huge amount of paper are required, and the delicate color balance and fluidity of the glue nagashi, which changes to various hues within one shibori pattern, is required. It is extremely difficult to understand the expression of a pattern as a pattern on a textile.

また連続的な模様の性質上、一完全としてとらえること
が難しいことや、手数をかける割合に採算が採れないこ
となどから、付加価値があるにもかかわらずこれらの色
流し模様をデザインとした織物は普及していないのが現
状である。
Furthermore, due to the continuous nature of the pattern, it is difficult to perceive it as a complete piece, and the amount of labor involved is not profitable, so fabrics designed with these color-washing patterns despite the added value Currently, it is not widespread.

しかし、墨流し模様や糊流し模様を織物上に表現するこ
とは、人工的にデザインされたものと違ってその図柄と
色彩バランスは自然で流動的で偶発性があり、意匠的な
立場からみてもデザイン的価値が充分あり、且つ付加価
値が高いためその実用化が望まれていた。
However, when suminagashi patterns and nori-nagashi patterns are expressed on textiles, unlike those that are artificially designed, the designs and color balance are natural, fluid, and accidental, and even from a design standpoint. It has been desired to put it into practical use because it has sufficient design value and high added value.

(問題を解決するための手段) 本発明は上記の如き従来の問題を解決するものであり、
織物に柄付けするに際して、緯糸となる絹又は綿繊維の
糸にカチオン基を導入した後、該緯糸を織り幅と同一大
きさの枠に巻き取り、この巻き取った枠をアニオン性染
料と染色用糊剤又はアニオン性染料と起泡性のあるアニ
オン性或いは非イオン性界面活性剤を攪拌して形成した
柄模様上に置き、該柄模様を常温で緯糸に転写染着した
後、この緯糸を柄模様の順に供給し織物とする方法と、
経糸となる絹又は綿繊維の糸にカチオン基を導入した後
、該経糸を仮織し、この仮織布をアニオン性染料と染色
用糊剤又はアニオン性染料と起泡性のあるアニオン性或
いは非イオン性界面活性剤を攪拌して形成した柄模様上
に置き、該柄模様を常温で仮織布に転写染色した後、こ
れを経糸として供給し、織物とする方法及び絹又は綿の
織物にカチオン基を導入した後、アニオン性染料と染色
用糊剤又はアニオン性染料と起泡性のあるアニオン性或
いは非イオン性界面活性剤を攪拌して形成した柄模様上
に置き、該柄模様を常温で織物に転写染色させることを
特徴とする織物の柄付は方法である。
(Means for solving the problem) The present invention solves the conventional problems as described above,
When patterning a fabric, a cationic group is introduced into the silk or cotton fiber thread that becomes the weft, and then the weft is wound into a frame of the same size as the weaving width, and this wound frame is dyed with an anionic dye. A sizing agent or anionic dye and a foaming anionic or nonionic surfactant are stirred and placed on the pattern formed, and the pattern is transferred and dyed onto the weft at room temperature, and then the weft is dyed. A method of supplying woven fabrics in the order of patterns,
After introducing cationic groups into silk or cotton fiber threads that serve as warp threads, the warp threads are temporarily woven, and this temporary woven fabric is treated with an anionic dye and a dyeing paste or an anionic dye and a foaming anionic or cotton fiber. A method of placing a nonionic surfactant on a pattern formed by stirring, transferring the pattern to a temporary woven fabric at room temperature, and then supplying it as a warp to make a fabric, and a silk or cotton fabric. After introducing a cationic group into the dye, place it on a pattern formed by stirring an anionic dye and a dyeing paste or an anionic dye and a foaming anionic or nonionic surfactant. A patterning method for textiles is characterized by transferring and dyeing the textiles at room temperature.

本発明において、絹又は綿繊維の糸、及びこれらの織物
にカチオン基を導入する薬品としては、3−クロロ−2
−ヒドロキシプロピルトリメチルアンモニウムクロライ
ド、グリシジルトリメチルアンモニウムクロライド、3
−クロロ−2−ヒドロキシプロピルジメチルドデシルア
ンモニウムクロライド、3−クロロ−2−ヒドロキシプ
ロピル−2−ヒドロキシエチルジメチルアンモニ、ラム
クロライド等が使用されるが、中でも3−クロロ−2−
ヒドロキシプロピルトリメチルアンモニウムクロライド
が極めて効果的である。
In the present invention, 3-chloro-2 is used as a chemical for introducing cationic groups into silk or cotton fiber threads and textiles thereof.
-Hydroxypropyltrimethylammonium chloride, glycidyltrimethylammonium chloride, 3
-Chloro-2-hydroxypropyldimethyldodecylammonium chloride, 3-chloro-2-hydroxypropyl-2-hydroxyethyldimethylammonium, lamb chloride, etc. are used, among which 3-chloro-2-
Hydroxypropyltrimethylammonium chloride is highly effective.

カチオン基の導入には、助剤としてアルカリを使用する
が、NaOH,KOH,Na1CO,、等が有効で、絹
繊維の場合は、物性に影響しない使用量の限度におさえ
れば、特にNaOHが効果的である。
To introduce cationic groups, an alkali is used as an auxiliary agent, and NaOH, KOH, NaCO, etc. are effective, and in the case of silk fibers, NaOH is particularly effective as long as the amount used is kept to a limit that does not affect the physical properties. It is true.

以上の薬品を用いて絹又は綿繊維を前処理した後、糸の
染色と製織を行い織物とする。又、白生地織物の場合も
同様の前処理を行って柄付けをする。
After pre-treating silk or cotton fibers using the above chemicals, the threads are dyed and woven into fabrics. In addition, in the case of white fabric fabric, the same pretreatment is performed to give it a pattern.

まず、柄模様作成に使用する染料は、反応性染料、酸性
染料、直接染料の一種類を使用する。併用する糊剤はア
ルギン酸ナトリウム、カルボキシメチルセルローズ、加
工でんぷん、セルロース誘導体、ガラクトマンナン、こ
んにゃく粉等が使用可能であるが、水洗が容易なものと
してはアルギン酸ナトリウムを使用する方が望ましい。
First, the dye used to create the pattern is one of reactive dyes, acid dyes, and direct dyes. As the sizing agent used in combination, sodium alginate, carboxymethyl cellulose, modified starch, cellulose derivatives, galactomannan, konnyaku powder, etc. can be used, but it is preferable to use sodium alginate as it is easy to wash with water.

また起泡剤はアニオン性又は非イオン性の界面活性剤を
使用し、高級アルコール硫酸エステルナトリウム塩、ア
ルキルベンゼンスルホン酸ソーダ塩、ポリオキシエチレ
ンエーテル硫酸トリエタノールアミン、シ*F!脂肪酸
エステル、ラウリル硫酸ナトリウム、合成アルコールエ
トキシサルフェートトリエタノールアミン、合成アルコ
ールエトキシサルフェートソーダ塩等が使用できる。
In addition, anionic or nonionic surfactants are used as foaming agents, such as higher alcohol sulfate sodium salt, alkylbenzenesulfonic acid sodium salt, polyoxyethylene ether sulfate triethanolamine, and C*F! Fatty acid esters, sodium lauryl sulfate, synthetic alcohol ethoxysulfate triethanolamine, synthetic alcohol ethoxysulfate sodium salt, etc. can be used.

次に、第1の発明について詳述するに、カチオン基を導
入した絹又は綿繊維の緯糸A1を、第1図に示す矩形状
の巻き取り枠、即ちその線巾Wが製織される織物の織幅
と同一長さとした枠1上に33本/cmのピッチで巻き
取る(第3図参照)。
Next, to explain the first invention in detail, the weft yarn A1 of silk or cotton fiber into which a cationic group has been introduced is wound into a rectangular winding frame shown in FIG. It is wound up at a pitch of 33 threads/cm on a frame 1 whose length is the same as the weaving width (see Figure 3).

アニオン性染料と染色用糊剤とを用いて色糊とし、その
色糊を配色し熊手様の道具で自在に攪拌するなどして流
動的な柄模様を現出させる。
A colored paste is made using an anionic dye and a dyeing paste, and the colored paste is colored and stirred freely with a rake-like tool to create a fluid pattern.

そして、前記柄模様の上に緯糸A1を巻き取った枠1を
置き、常温で30〜60秒経過すると転写が完了し、柄
模様が枠1に巻いた緯糸A1の表面に浮上してくる。
Then, the frame 1 with the weft yarn A1 wound thereon is placed on the pattern, and after 30 to 60 seconds have elapsed at room temperature, the transfer is completed and the pattern comes to the surface of the weft yarn A1 wound around the frame 1.

この時点を転写の終点として色糊から枠1を取り去り、
耳印として織物の耳となる部分の一方向に色糊でサイン
カラーを付け、糸A1を枠1から取り外し、カセ糸状と
して水洗・乾燥後順次緯糸として製織する。なお、この
場合柄模様転写のこの緯糸と、従来からの一般染色法に
よる糸とを組み合わせて製織することもできる。
Taking this point as the end point of the transfer, remove frame 1 from the colored glue,
A signature color is applied with colored glue to one direction of the part of the fabric that will become the selvage as a selvage mark, and the thread A1 is removed from the frame 1, washed and dried as a skein thread, and then sequentially woven as a weft thread. In this case, it is also possible to weave by combining the pattern-transferred weft yarn with a conventional general dyeing yarn.

緯糸巻き取り枠ごとの柄継ぎ方法は、柄模様作成時の色
糊攪拌を再現できるように、配色及び攪拌を行うことに
よって、布面に表現する柄模様の柄継ぎ部分を連続させ
て製織することが可能である。また、必要とする織り上
がり長だけの緯糸に対して、柄転写ごとに配色と攪拌を
再現性あるものとしてコントロールすれば、充分必要長
の織物を製織することができる。
The pattern joining method for each weft winding frame is to weave the pattern joint part of the pattern to be expressed on the fabric surface continuously by coloring and stirring so as to reproduce the stirring of colored glue when creating the pattern. Is possible. Furthermore, if the coloring and agitation are reproducibly controlled for each pattern transfer for the weft threads of the required weaving length, it is possible to weave a woven fabric of sufficient length.

これらの製織布は、従来から行われている白生地に糊流
し染めしたものと同じ色彩と流動模様効果が製織布に現
出し、更に絵際の若干ずれた柄足が発生し、従来の絣的
効果がプラスされた織物となる。
These woven fabrics have the same color and flow pattern effect as the traditional method of starch dyeing on white fabric, and also have a slightly misaligned pattern on the edge of the pattern, which is different from the conventional method. The fabric has an added Kasuri-like effect.

従来から公知の糊流し染め手法は、捺染プリントに近僚
した手法の仕上がりであるのに対して、本発明法は、そ
の柄模様が従来の糊流し染めの柄を緯糸に表現すること
を可能とすることによって柄模様が絣調に布面に現出し
、型紙捺染では絶対に得られない独特の付加価値ある新
しい織物のが得られるものである。
While the conventionally known glue flow dyeing method has a finish that is similar to textile printing, the method of the present invention makes it possible to express the pattern of conventional glue flow dyeing on the weft. By doing so, the pattern appears on the fabric surface in a Kasuri-like manner, resulting in a new fabric with unique added value that cannot be obtained by pattern printing.

もし、あらかじめカチオン基を導入せずに、無処理の絹
又は綿糸に対して同様の染色処理をしても、染料固着の
ための蒸熱処理が必要となり、蒸熱処理のために30〜
60分処理する間に柄模様の色° 流れを起こす危険が
あり、色原れを起こした場合は全く商品価値がないもの
となる。従ってカチオン基を導入しない絹又は綿糸に確
実な柄模様の転写は難しかった。しかも作業的にも繁雑
で手間がか\す、これまでに染色方法が確立しなかった
理由でもある。
Even if a similar dyeing treatment is applied to untreated silk or cotton yarn without introducing cationic groups in advance, steaming treatment will be required to fix the dye, and if the
There is a risk that the color of the pattern will run during the 60 minutes of processing, and if this occurs, the product will have no commercial value. Therefore, it has been difficult to reliably transfer patterns onto silk or cotton threads that do not have cationic groups introduced therein. Moreover, the process is complicated and time-consuming, which is why no dyeing method has been established until now.

本発明は、カチオン基の導入が瞬時に染料を固着させる
作用に着目したもので、前述の染料固着の熱処理を省く
ことによって、これまでできなかった織糸への柄付は方
法を確立した。
The present invention focuses on the effect of the introduction of cationic groups to instantly fix dyes, and by omitting the heat treatment described above for fixing dyes, we have established a method for attaching patterns to weaving yarns, which was previously impossible.

また染色堅ろう度は、従来の一般染色法と本発明法を比
較した場合、極めて堅ろう性のあることもメリットであ
り、第1表の通りである。
Furthermore, when comparing the dyeing fastness of the conventional general dyeing method and the method of the present invention, it is an advantage that the dyeing fastness is extremely fast, as shown in Table 1.

更に第1の発明では、織り糸に模様を転写する際に色糊
の洗浄の繁雑さを改善するために、織り糸への新しい染
色方法を確立したものである。
Furthermore, in the first invention, a new method for dyeing woven threads has been established in order to improve the complexity of cleaning colored paste when transferring a pattern to woven threads.

すなわち、アニオン性又は非イオン性の界面活性剤によ
る気泡と、アニオン性染料である反応性染料、直接染料
、酸性染料のいずれか一種を気泡と混合し、その泡を平
面上に巻き取り枠1の幅に配色し、棒状などの道具で自
在に攪拌することによって柄模様を作りだす。
That is, bubbles caused by an anionic or nonionic surfactant are mixed with any one of anionic dyes such as reactive dyes, direct dyes, and acidic dyes, and the bubbles are taken up on a flat surface and placed on a winding frame 1. Patterns are created by distributing colors to the width of the paper and stirring freely with tools such as sticks.

その柄模様の表面に、前述と同様の緯糸A1を巻き取っ
た枠1を接面させ、巻き取った糸A1の表面に柄模様が
均一に浮上した時点で耳印のサインカラーを一方に付し
て柄転写を終了する。
The surface of the pattern is brought into contact with the frame 1 wound with the same weft yarn A1 as described above, and when the pattern pattern has uniformly surfaced on the surface of the wound yarn A1, the sign color of the earmark is applied to one side. to finish pattern transfer.

転写時間は60〜120秒間を要し、転写終了と同時に
枠全体を水洗いし、柄模様の順にカセ糸状に外し、脱水
乾燥して転写した緯糸A1を柄の順に供給して製織する
The transfer time takes 60 to 120 seconds, and at the same time as the transfer is completed, the entire frame is washed with water, removed in the order of the pattern in the form of a skein, and the dehydrated, dried and transferred weft yarn A1 is supplied in the order of the pattern for weaving.

この方法は、洗浄しにくい色糊による柄転写を改善した
もので、柄転写終了後は糸A1に水を散布し、水洗を完
了させることによって柄の転写と染料固着が簡単に迅速
にできる。
This method improves the pattern transfer using colored glue, which is difficult to wash.After the pattern transfer is completed, water is sprayed on the thread A1, and the washing is completed, thereby easily and quickly transferring the pattern and fixing the dye.

次に、第2の発明について説明するに、カチオン基を導
入した絹又は綿繊維の経糸A2に、柄模様の転写を前述
の染料と泡による転写と同様の処理で行うことによって
織物の経糸にも柄模様を転写することができる。
Next, to explain the second invention, a pattern is transferred to the warp A2 of silk or cotton fiber into which a cationic group has been introduced, by the same process as the transfer using the dye and foam described above, to the warp of the fabric. It is also possible to transfer patterns.

即ち、従来から行われているホグシ織は、第8図に示す
ように、仮織として経糸A2を平行におさえて緯糸A3
で粗く織り上げ、それを捺染後蒸熱して染料を染着させ
る方式がとられ、製織したものは捺染された柄の絵際の
ずれた部分が柄足とされており、絣織やホグシ織ではそ
れが特徴とされている。
That is, as shown in FIG. 8, the conventional hogushi weaving is performed by holding the warp A2 parallel to the weft A3 as a temporary weave.
The method is to roughly weave it with a cloth, and then steam it after printing to dye it with dye.The woven part of the woven pattern is made of a misaligned part of the edge of the printed pattern. That is what makes it so special.

本発明では、カチオン基を導入した経糸A2を仮織し、
柄模様の転写は泡と染料を混合したもので配色し、例え
ば攪拌道具として棒状などの道具を用いて攪拌し、自然
に発生した流動的な柄模様を仮織布に瞬時に染着固着し
、織物を製造する方式を確立したものである。
In the present invention, the warp A2 into which cationic groups have been introduced is tentatively woven,
The pattern is transferred using a mixture of foam and dye, which is stirred using a stirring tool such as a rod, and the naturally occurring fluid pattern is instantly dyed and fixed onto the temporary fabric. , which established a method for manufacturing textiles.

即ち仮織長の必要とする長さにアニオン性又は非イオン
性の界面活性剤を用いて泡をつくり、アニオン性染料で
ある反応性染料、直接染料、酸性染料のうち一種の染料
を泡と混合し、平面上に織り幅と織り上げ長だけ配色し
た泡を敷き詰め、それを攪拌して柄模様を作り、その表
面に必要な転写長の仮織布を両側から持ち、柄模様の平
面と平行に仮織布を接面させ転写する。
That is, foam is created using an anionic or nonionic surfactant to the required length of the provisional weave, and one type of dye among anionic dyes such as reactive dyes, direct dyes, and acid dyes is added to the foam. Mix it, spread the colored foam on a flat surface for the weaving width and finished weaving length, stir it to create a pattern, hold the temporary woven fabric of the necessary transfer length on the surface from both sides, and place it parallel to the plane of the pattern. The temporary fabric is brought into contact with the paper and transferred.

柄模様が仮織した経糸上に充分浮上した時点を転写終了
時とする。
The time when the pattern has sufficiently surfaced on the tentatively woven warp threads is defined as the time when the transfer is completed.

次に両端を持ち上げ板織布に充分な水を散布して水洗し
、付着している泡を除去する。
Next, lift both ends and sprinkle enough water on the woven board fabric to wash it and remove any bubbles that may have adhered to it.

泡の除去が終われば水洗完了となり、転写された柄模様
のパターンは染着固着され、色流れを全く起こすことが
ない。これを湿った仮織幅のタオルに巻き取って水分の
除去を行う。
Once the bubbles have been removed, the washing process is complete, and the transferred pattern is dyed and fixed, with no color bleeding at all. The moisture is removed by winding it up in a wet tent towel.

次に前述と同様の転写条件を設定し、順次転写処理を施
し、転写を完了した仮織布を風乾して本織物用の経糸と
して供給する。
Next, transfer conditions similar to those described above are set, transfer processing is performed sequentially, and the temporarily woven fabric after the transfer is air-dried and supplied as warp for the main fabric.

製織方法は、緯糸に一般染色法で染色した普通の絹糸を
用いてもよく、又本発明法で転写したものを使用しても
よい。
In the weaving method, ordinary silk threads dyed by a general dyeing method may be used for the wefts, or silk threads transferred by the method of the present invention may be used.

製織された織物は、従来のホグシ織りと絣織りに類似す
るが、柄模様の現出がこれまでには得られない鮮明なも
のであり、商品価値のある新規性の高い製品が得られる
The woven fabric is similar to conventional hogushi weaving and kasuri weaving, but the pattern appears more vividly than ever before, resulting in a highly novel product with commercial value.

なお、以上はアニオン性染料とアニオン性又は非イオン
性の界面活性剤で染色する場合について説明したが、ア
ニオン性染料と染色用糊剤で染色する場合については前
記第1発明での説明と同じである。
In addition, although the case of dyeing with an anionic dye and an anionic or nonionic surfactant has been described above, the case of dyeing with an anionic dye and a dyeing paste is the same as the explanation in the first invention. It is.

以上の第1発明及び第2発明で述べた染色方法によって
、柄模様を経糸又は緯糸に転写した織糸は、今までの染
法では絶対に得ることのできない新規性の高いものであ
る。
The woven yarn in which the pattern is transferred to the warp or weft by the dyeing method described in the first and second inventions is highly novel and cannot be obtained by conventional dyeing methods.

例えばカチオン基を導入せず、緯糸とする絹糸を第1図
の枠に巻き取り、泡と染料で配色し攪拌したところに接
面し、柄模様を転写した後水洗した場合、染料固着が不
完全で柄模様が洗い流されてしまい、柄模様を転写した
織物の製造は全く不可能となる。従って絹又は綿繊維へ
のカチオン基の導入は染料固着と密接な関係があり、本
発明では必要かつ絶対の条件である。
For example, if you do not introduce a cationic group and wind the silk yarn to be used as a weft into the frame shown in Figure 1, color it with foam and dye, and then wash it with water after coloring it with foam and dye and washing it with water, the dye will not stick. If the pattern is completely removed, the pattern will be washed away, making it completely impossible to manufacture fabrics with the pattern transferred. Therefore, the introduction of cationic groups into silk or cotton fibers is closely related to dye fixation, and is a necessary and absolute condition for the present invention.

これらの方法の確立によって、今まで得ることのできな
かった柄模様を転写した付加価値の高い織物を製造する
ことができる。
By establishing these methods, it will be possible to produce fabrics with high added value that have patterns that have not been previously available.

更に第3の発明について説明するに、糊流し染めではそ
の方式独特の柄模様が得られるが、織物に柄模様を転写
する際の熱処理の繁雑さを改善するために熱処理を省き
、常温瞬時に染料固着し、容易に染色することのできる
染色方式を確立したものである。
Furthermore, to explain the third invention, a pattern unique to this method can be obtained by glue flow dyeing, but in order to improve the complexity of heat treatment when transferring the pattern to the fabric, heat treatment is omitted, and it can be dyed instantly at room temperature. This method established a dyeing method that allows the dye to fix and is easily dyed.

即ち、アニオン性染料と染色用糊剤とを用いて色糊とし
、その色糊を配置し、熊手様の道具でその表面を自在に
かくはんするなどして、流動的な柄模様を作り、カチオ
ン基を導入した絹又は綿織物をその表面に接面させ、常
温で30〜60秒後柄模様が織物表面に毛細管現象によ
り浮上したところで転写を完了し、水洗・乾燥し織物の
柄付けを完了する。
That is, anionic dyes and dyeing pastes are used to make colored paste, the colored paste is arranged, and the surface is freely stirred with a rake-like tool to create a fluid pattern, and cationic The silk or cotton fabric into which the group has been introduced is brought into contact with the surface of the fabric, and after 30 to 60 seconds at room temperature, the transfer is completed when the pattern appears on the surface of the fabric due to capillary action, and the patterning of the fabric is completed by washing and drying. .

例えばカチオン基を導入しない織物に、同様の柄付は処
理をし水洗した場合、染料固着が不完全で柄模様が洗い
流されて、柄模様の転写固着が不可能である。従って、
絹又は綿織物へのカチオン基の導入が染料固着と密接な
関係があり、本発明では必要かつ絶対の条件である。
For example, if a similar patterning treatment is applied to a fabric without introducing cationic groups and then washed with water, dye fixation will be incomplete and the pattern will be washed away, making it impossible to transfer and fix the pattern. Therefore,
Introduction of cationic groups into silk or cotton fabrics is closely related to dye fixation and is a necessary and absolute condition in the present invention.

従来の糊流し染めは、色糊を付着させたまま染料固着の
熱処理をする必要があり、熱処理は極め° てむずかし
く色流れの危険性がある。また熱処理装置のスパンも限
定されるために短尺の処理が多く、製品もネクタイ、ス
カーフ等の小物類が多い現状である。
Conventional starch flow dyeing requires heat treatment to fix the dye while the color paste remains attached, and heat treatment is extremely difficult and there is a risk of color running. Furthermore, because the span of the heat treatment equipment is limited, many short pieces are processed, and many of the products are small items such as ties and scarves.

本発明はこれらの問題を解決するものであり、染料固着
が常温で瞬時に完了するために熱処理装置を必要とせず
、長尺物の柄付けも楽にできる。
The present invention solves these problems, and since dye fixation is completed instantaneously at room temperature, no heat treatment equipment is required, and long articles can be easily patterned.

また、処理時間と熱処理エネルギーも節約できるととも
に、染色物の堅ろう度も第1表のように極めて堅ろうで
あることなど、多くのメリットがあり、工業的にも極め
て有用な染色方法を確立したものである。
In addition, it has many advantages, such as saving processing time and heat treatment energy, and the fastness of the dyed product is extremely strong as shown in Table 1, and it has established a dyeing method that is extremely useful industrially. It is.

さらに本発明では、公知糊流し染めを簡略化するために
、色糊のかわりに界面活性剤と染料で作った着色された
気泡を用い、柄模様を作り、熱処理を省き常温固着させ
、従来の繁雑かつ困難であった糊流し染めの熱処理と色
糊洗浄を容易にすることを目的とした、気泡と染料によ
る柄付は方法を確立したものである。
Furthermore, in the present invention, in order to simplify the known glue flow dyeing process, colored bubbles made from surfactants and dyes are used instead of colored paste to create patterns, and heat treatment is omitted and the dyeing is fixed at room temperature. The method of creating patterns using air bubbles and dyes was established to facilitate the complicated and difficult process of heat treatment and washing of colored paste.

即ちアニオン性染料と起泡剤を用いて気泡を作り、配色
用の着色気泡とし、その着色された気泡を平面上に各色
を適宜に配置し、配色したところを攪拌用棒様の道具で
全面的又は部分的に自在に攪拌し、流動模様を現出させ
る。
In other words, bubbles are created using an anionic dye and a foaming agent to create colored bubbles for coloring, the colored bubbles are arranged in appropriate colors on a flat surface, and the colored bubbles are then painted over the entire surface with a stirring rod-like tool. Agitate the target or part freely to create a fluid pattern.

その表面に、カチオン基を導入した絹又は綿織物を接面
させ、常温で30〜60秒後柄模様が織物表面に毛細管
現象により浮上したところで、水洗・乾燥することによ
って織物の柄付けを完了する。
A silk or cotton fabric into which cationic groups have been introduced is brought into contact with the surface of the fabric, and after 30 to 60 seconds at room temperature, a pattern appears on the surface of the fabric due to capillary action, and the patterning of the fabric is completed by washing and drying. .

例えば、カチオン基を導入しない織物に、同様の柄付は
処理をし水洗した場合、染料固着が不完全で柄模様が洗
い流されてしまい、柄模様の転写固着が不可能である。
For example, if a similar patterned fabric is treated with water and washed without introducing cationic groups, dye fixation will be incomplete and the pattern will be washed away, making it impossible to transfer and fix the pattern.

また従来の糊流し染めの色糊の洗浄は、仏法れの危険を
伴い技術的に極めて難しく、糊流し染めを付加価値のあ
るものにした所以である。
In addition, cleaning the colored paste of conventional glue nagashi dyeing is technically extremely difficult due to the risk of blemishes, which is what made glue nagashi dyeing an added value.

本発明の起泡剤使用は上記の問題を解決するものであり
、柄模様の転写後の洗浄は水洗のみでよく極めて簡単で
ある。
The use of the foaming agent of the present invention solves the above-mentioned problems, and cleaning after transfer of the pattern is extremely simple, requiring only water washing.

次に実施例により本発明を説明するが、本発明はこれに
限定されるものではない。
Next, the present invention will be explained with reference to Examples, but the present invention is not limited thereto.

実施例1゜ 絹紬糸(84中/2本片)IKgを、3−クロロ−2−
ヒドロキシプロピルトリメチルアンモニウムクロライド
5%、 NaOH12g/ lの溶液で浴比1:20、
80℃で60分処理後水洗し、酢酸1a+A/j!、常
温で10分浸漬し、湯洗いの後水洗して乾燥した。
Example 1 I kg of silk pongee thread (84 medium/2 pieces) was mixed with 3-chloro-2-
A solution of 5% hydroxypropyltrimethylammonium chloride and 12 g/l of NaOH in a bath ratio of 1:20.
After treatment at 80°C for 60 minutes, wash with water and add acetic acid 1a+A/j! , immersed at room temperature for 10 minutes, washed with hot water, then washed with water and dried.

この糸を、第1図の枠(100c+w X 38cm)
に製織する順に33本/cIのピッチで90cmの間隔
に第3図のように巻き取った。
Place this thread in the frame shown in Figure 1 (100c+w x 38cm)
The fabric was wound up at intervals of 90 cm at a pitch of 33 threads/cI as shown in Fig. 3 in the order of weaving.

すなわち第2図のように、あらかじめ糸A1をボビン2
にあげて枠1を巻き取り装置3にセントし、ガイド4を
通した糸A1の一端を枠1に結び付け、手でハンドル5
を回転させることにより、枠1が回転すると同時に螺子
棒6が回転し、該螺子棒6に螺合したガイド4が左方向
に移動し、糸A1が製織類に枠1に巻き取られる。第3
図は巻き終わった状態を示している。
That is, as shown in Fig. 2, the thread A1 is placed in advance on the bobbin 2.
Place the frame 1 on the winding device 3, tie one end of the thread A1 passed through the guide 4 to the frame 1, and pull the handle 5 by hand.
By rotating the frame 1, the threaded rod 6 rotates at the same time as the threaded rod 6, the guide 4 screwed onto the threaded rod 6 moves to the left, and the thread A1 is wound around the frame 1 in a weaving material. Third
The figure shows the finished state.

次に、配色用色糊として第2表のA−Dまでとし、Eは
グランド用色糊とする。
Next, the colored pastes A to D in Table 2 are used as the coloring paste, and E is used as the colored paste for the ground.

このグランド用色糊を平らに敷き詰め、その上に配色用
の各色糊を第5図のプラスチック製しぼ第2表1$11
の制動 第3表□泡□ り出し容器7に入れ、配色後熊手様の道具で自在に攪拌
して多色の流動模様を作成した。
Spread this colored glue for the ground evenly, and then apply each colored glue for the color scheme on top of it.
Braking Table 3 □ Foam □ The mixture was placed in a dispensing container 7, and after coloring, it was freely stirred with a rake-like tool to create a multicolored flowing pattern.

次ぎに、その表面に、枠1に巻いた糸A1を接触させ、
約40秒後、均一に柄模様が表面に現れたところで色糊
のサインカラーを枠の一方につけ、枠全体を取り去り、
カセにして順次水洗脱水する。
Next, the thread A1 wound around the frame 1 is brought into contact with the surface,
After about 40 seconds, when the pattern appears uniformly on the surface, apply a signature color of colored paste to one side of the frame, remove the entire frame,
Place in a basket and wash and dehydrate sequentially.

この操作を必要とする織り上げの長さに相当する緯糸量
に対して繰り返し同様の操作を行った。枠と枠ロフト別
ごとの柄継ぎは、配色と攪拌をコントロールし流動槽を
設定した。
The same operation was repeated for the amount of weft corresponding to the length of weaving that required this operation. The pattern joints for each frame and frame loft were controlled by color scheme and agitation, and a fluidized tank was set up.

この緯糸A1を乾燥して柄模様の順にカセに番号を付し
、その糸をボビンに巻き返してシャトル用の管巻きを行
い、柄模様の順に製織する。
This weft yarn A1 is dried, numbers are attached to the skeins in the order of the pattern, the yarn is wound back onto the bobbin to be wound into a tube for a shuttle, and weaving is carried out in the order of the pattern.

次に織物設計として、繊維は半自動織機を使用し、耳印
を合わせながら製織した。
Next, for the textile design, the fibers were woven using a semi-automatic loom, matching the earmarks.

経糸はカチオン基を導入しない一般染色法で淡色の黄緑
色に染色した絹糸(21中/2本)を整経して使用した
。組織は平織とし、引込みゲージを25羽/cm1本人
、密度経24本/am、緯26本/cmとして製織した
The warp threads were warped silk threads (2 out of 21) dyed pale yellow-green using a general dyeing method that does not introduce cationic groups. The structure was a plain weave, and the draw gauge was 25 threads/cm per piece, the density was 24 threads/am, and the weft was 26 threads/cm.

その結果、第4図のとおり紅色12.緑色13.黄紅色
14等多彩な色彩の流動する柄模様の織物が得られた。
As a result, as shown in Figure 4, the color was red 12. Green13. Fabrics with flowing patterns in various colors such as yellow-red and 14 were obtained.

実施例2゜ 絹紬糸(84中/2本片)IKgを、3−クロロ−2−
ヒドロキシプロピルトリメチルアンモニウムクロライド
5%、 NaOH12g/ Itの溶液で浴比1:20
、80℃で60分処理後水洗し、酢酸1ml/It、常
温10分処理後、湯洗い水洗乾燥した。
Example 2 I kg of silk pongee thread (84 medium/2 pieces) was mixed with 3-chloro-2-
Hydroxypropyltrimethylammonium chloride 5%, NaOH 12g/It solution in bath ratio 1:20
, treated at 80° C. for 60 minutes, washed with water, treated with 1 ml/It of acetic acid at room temperature for 10 minutes, washed with hot water, washed with water, and dried.

この糸を第1図の枠(100cm X 3Bcm)に製
織する順に33本/amのピッチで90cmの間隔に第
3図のように巻き取った。すなわち第2図のように、あ
らかじめ糸をボビン2にあげて枠1を巻き取り装置にセ
ットし、ガイド4に通した糸を枠lに結び付け、手でハ
ンドル5を回転させることにより、枠lが回転すると同
時にガイド4が移動し、糸が製織順に枠1に巻き取られ
る。第3図は巻き終わった状態を示している。
This yarn was wound in the weaving order into the frame (100 cm x 3 Bcm) shown in FIG. 1 at a pitch of 33 yarns/am at intervals of 90 cm as shown in FIG. 3. That is, as shown in Fig. 2, the thread is placed on the bobbin 2, the frame 1 is set on the winding device, the thread passed through the guide 4 is tied to the frame l, and the handle 5 is rotated by hand to remove the frame l. At the same time as rotates, the guide 4 moves, and the threads are wound around the frame 1 in the weaving order. Figure 3 shows the finished state.

次に、第3表の様な処方で配色用の染料を含む各色の泡
を作った。
Next, foams of each color containing coloring dyes were made using the formulations shown in Table 3.

気泡の作成は、必要とする染料を含む起泡剤を201の
容器8に入れ、第6図の様に日立製ハンドミキサー(H
F−210) 9の回転部分にビーカー洗浄用のブラシ
9aを付け、201の起泡剤10の入っている容器の中
で回転させ必要量の泡を作った。
To create bubbles, put the foaming agent containing the required dye into container 8 of 201, and use a Hitachi hand mixer (H) as shown in Figure 6.
F-210) A beaker cleaning brush 9a was attached to the rotating part of No. 9, and the beaker was rotated in a container containing the foaming agent 10 of No. 201 to create the necessary amount of foam.

この各色の泡を平面上に敷き詰め、グランドの配色を決
定し、更にその上に各色の泡を21ビーカーに汲み取り
、グランド用の泡の上に適宜意図した配色をした。
The foam of each color was spread on a flat surface to determine the color scheme for the ground, and then the foam of each color was poured into 21 beakers, and the intended color scheme was appropriately applied to the foam for the ground.

次に、その表面を直径3cm、長さ1mの攪拌用棒様の
道具で全体的に自在に攪拌し、第7図のような赤色15
.黄色16.緑色17及び青色18からなる流動模様を
現出させた。
Next, the entire surface was freely stirred using a stirring rod-like tool with a diameter of 3 cm and a length of 1 m.
.. yellow16. A fluid pattern consisting of 17 green colors and 18 blue colors appeared.

前述の枠に巻いた糸を、模様の表面に接面させ60秒後
に、柄模様が表面に均一に浮上した時点で黒い色糊で耳
印としてサインカラーを付け、枠全体を取り去り、その
枠に水を充分散布して水洗した。この糸を水洗後枠から
カセとして取り外し、脱水乾燥した。
The thread wound around the frame mentioned above is brought into contact with the surface of the pattern, and after 60 seconds, when the pattern has uniformly surfaced on the surface, add a signature color with black glue as an ear mark, remove the entire frame, and remove the frame. Spray water thoroughly and wash with water. After washing the thread with water, it was removed from the frame as a skein and dehydrated and dried.

この操作を必要とする織り上げ長の緯糸について順次同
じ操作を繰り返し、転写の終わった緯糸はカセからボビ
ンに巻き取り、シャトル用に管巻きし、製織用として順
次供給した。
The same operation was repeated for the weft yarns of the weaving length that required this operation, and the weft yarns that had been transferred were wound up from the skein onto a bobbin, wound into a tube for a shuttle, and sequentially supplied for weaving.

次に織物設計として、経糸はカチオン基を導入しない一
般染色法により淡色の黄緑色に染色した絹糸(21中7
2本)で整経したものを使用した。
Next, for the textile design, the warp yarns were silk threads dyed pale yellow-green using a general dyeing method that does not introduce cationic groups (7 out of 21
2 warped warps were used.

組織は平織とし、引込みゲージを25羽/cm1本人、
密度経24本/cm、緯26本/cn+として製織した
The fabric is plain weave, and the draw gauge is 25 birds/cm per person.
It was woven with a density of warp 24 threads/cm and weft density 26 threads/cn+.

その結果、多彩な色彩の流動する柄模様の織物が得られ
た。
As a result, a fabric with a flowing pattern in a variety of colors was obtained.

実施例3゜ 絹糸(21中/2本) 2Kgを、3−クロロ−2−ヒ
ドロキシプロピルジメチルドデシルアンモニウムクロラ
イド5%、NaOH10%溶液でpH11に調整し、浴
比1 :20.80℃で60分処理後水洗し、酢酸1y
ell/l、常温10分処理後、湯洗い水洗乾燥した。
Example 3 2 kg of silk thread (2 out of 21) was adjusted to pH 11 with a solution of 5% 3-chloro-2-hydroxypropyldimethyldodecylammonium chloride and 10% NaOH, and was heated at a bath ratio of 1:20 for 60 minutes at 80°C. After treatment, wash with water and add 1y of acetic acid.
After treatment at room temperature for 10 minutes, the sample was washed with hot water, washed with water, and dried.

この糸を経糸とし、従来から行われている方法で第8図
の様に仮織した後、必要長をビームに巻き取った。
This yarn was used as a warp yarn, and after temporary weaving as shown in FIG. 8 by a conventional method, the required length was wound around a beam.

経糸への柄付けとして、前記実施例2で使用した第3表
の処方を用い、染料を含む各色の泡を作った。
To attach patterns to the warp threads, foams of various colors containing dye were made using the formulations shown in Table 3 used in Example 2 above.

気泡の作成は、必要とする染料を含む起泡剤10を2O
fの容器8に入れ、第6図の様に日立製ハンドミキサー
(HP−210”) 9の回転部分にビーカー洗浄用の
ブラシ9aを付け、20ffiの起泡剤の入っている容
器の中で回転させ必要量の泡を作った。
To create bubbles, add the foaming agent 10 containing the required dye to 2O
As shown in Fig. 6, put a brush 9a for cleaning the beaker on the rotating part of a Hitachi hand mixer (HP-210'') 9, and place it in a container containing 20ffi of foaming agent. It was rotated to create the required amount of bubbles.

この各色の泡を平面上に敷き詰め、グランドの配色を決
定し、更にその上に各色の泡を21ビーカーに汲み取り
、グランド用の泡の上に適宜意図した配色をした。
The foam of each color was spread on a flat surface to determine the color scheme for the ground, and then the foam of each color was poured into 21 beakers, and the intended color scheme was appropriately applied to the foam for the ground.

次に、その表面を直径3cm、長さ1mの攪拌用棒様の
道具で全体的に自在に攪拌し、第7図のような流動模様
を現出させた。この表面に前述のビームに巻いた仮織布
を引き出し、両端を持ち柄模様の表面に静かに置き60
秒後に仮織布の表面に柄模様が均一に転写され浮上した
時点を転写完了時とした。
Next, the entire surface of the mixture was freely stirred with a stirring rod-like tool having a diameter of 3 cm and a length of 1 m, so that a flowing pattern as shown in FIG. 7 appeared. Pull out the provisional fabric wrapped around the beam mentioned above on this surface, hold both ends and gently place it on the patterned surface for 60 minutes.
After a few seconds, the pattern was uniformly transferred to the surface of the temporary fabric and the moment it floated was defined as the completion of the transfer.

次に、仮織布の両端を持ち上げ、その全面に充分に水を
散布し、泡が完全に洗い流されたことを確認してから仮
織布全体を湿った仮織布幅のタオルに巻き取った。この
柄付けを必要長だけ織り返し行った後、仮織布を巻き取
ったタオルからはずして風乾した。この仮織布から緯糸
を巻き取って経糸ビームに巻き取り織機にセットし、製
織準備した。
Next, lift both ends of the temporary woven fabric, sprinkle water thoroughly over the entire surface, make sure that the bubbles are completely washed away, and then roll the entire temporary woven fabric into a damp towel the width of the temporary woven fabric. Ta. After this patterning was woven back to the required length, the temporary fabric was removed from the rolled up towel and air-dried. Weft yarns were wound from this temporary woven fabric onto a warp beam and set on a loom to prepare for weaving.

使用する緯糸はカチオン基を導入しない一般染色法で染
色した淡色で黄緑色の絹紬糸(84中72本片)を使用
した。組織は平織とし、引込みゲージを25羽/cm1
本人り、密度経24本/cm、緯26本/cmとして製
織した。この結果これまでの技術では得られなかった織
り上げ長だけの流動した連続的模様が織り上がりホグシ
織に類慎した効果で表現することができた。
The weft used was pale yellow-green silk pongee thread (72 pieces out of 84) dyed by a general dyeing method that does not introduce cationic groups. The texture is plain weave, and the draw gauge is 25 feathers/cm1.
The material was woven at a density of 24 threads/cm in warp and 26 threads/cm in weft. As a result, we were able to weave a continuous pattern with a flowing length that was not possible with previous techniques, and it was possible to express it with an effect similar to that of hogushi weaving.

実施例4゜ 白地の絹織物を3−クロロ−2−ヒドロキシプロピルト
リメチルアンモニウムクロライド5%。
Example 4 A white silk fabric was treated with 5% 3-chloro-2-hydroxypropyltrimethylammonium chloride.

NaOH12g/ lの溶液で浴比1 :50.80℃
で60分処理後水洗し、酢酸IIIIl/l、常温で1
0分浸漬し湯洗いの後水洗して乾燥した。
Bath ratio 1:50.80℃ with a solution of NaOH 12g/l
After treatment for 60 minutes, wash with water, add acetic acid III l/l,
It was immersed for 0 minutes, washed with hot water, then washed with water and dried.

次に、配色用色糊として、第1表のA−Dまでとし、E
はグランド用色糊とする。
Next, as color paste for coloring, use A to D in Table 1, and E
is the colored glue for the ground.

このグランド用色糊を平らに敷き詰め、その上に配色用
の各色糊を第5図のプラスチック製しぼり出し容器7に
入れ、配色後熊手様の道具で自在に攪拌して多色の流動
模様を作成した。その表面に前処理した織物を接触させ
、約40秒後、均一に柄模様が表面に現れたところで糊
面から取り外し水洗後乾燥した。
Spread this colored glue for the ground evenly, put each colored glue for coloring on top of it in the plastic squeezing container 7 shown in Figure 5, and after coloring, stir freely with a rake-like tool to create a multicolored flowing pattern. Created. The pretreated fabric was brought into contact with the surface, and after about 40 seconds, when a pattern appeared uniformly on the surface, it was removed from the glued surface, washed with water, and then dried.

その結果多彩な色彩の流動するような柄模様の織物が得
られた。
As a result, a fabric with a fluid pattern in a variety of colors was obtained.

実施例5゜ 経糸が絹、緯糸が綿の白地の絹織物を3−クロロ−2−
ヒドロキシプロピルトリメチルアンモニウムクロライド
5%、 NaOH12g/βの溶液で浴比1 :50.
80℃で60分処理後水洗し、酢酸IIIIl/l、常
温10分処理後、湯洗い水洗乾燥した。
Example 5 A white silk fabric whose warp is silk and weft is cotton is 3-chloro-2-
A solution of 5% hydroxypropyltrimethylammonium chloride and 12g/β of NaOH in a bath ratio of 1:50.
After treatment at 80°C for 60 minutes, it was washed with water, treated with IIIl/l acetic acid at room temperature for 10 minutes, and then washed with hot water, water, and dried.

次に、第3表の様な処方で配色用の染料を含む各色の泡
を作った。気泡の作成は必要とする染料を含む起泡剤を
201の容器に入れて第6図の様に日立製ハンドミキサ
ーIP−210の回転部分にビーカー洗浄用のブラシを
付け202の起泡剤の入っている容器の中で回転させ必
要量の泡を作った。この各色の泡を平面上に敷き詰め、
グランドの配色を決定し、更にその上に各色の泡を21
ビーカーに汲み取り、グランド用の泡の上に適宜意図し
た配色をした。次にその表面を直径3cm、長さ1mの
攪拌用棒様の道具で全体的に自在に攪拌し、第7図のよ
うな流動模様を現出させた。
Next, foams of each color containing coloring dyes were made using the formulations shown in Table 3. To create bubbles, put the foaming agent containing the required dye into the container 201, attach a brush for cleaning the beaker to the rotating part of the Hitachi hand mixer IP-210 as shown in Figure 6, and add the foaming agent 202. The required amount of foam was created by rotating it in the container. Lay out these colored bubbles on a flat surface,
Decide on the color scheme of the ground, and add 21 bubbles of each color on top of it.
Pour it into a beaker and apply the desired color scheme on top of the foam for the ground. Next, the entire surface was freely stirred with a stirring rod-like tool 3 cm in diameter and 1 m in length to create a flowing pattern as shown in Figure 7.

次に前述の織物を模様の表面に接面させ60秒後に、柄
模様が表面に浮上した時点で取り去りこの織物に水を充
分散布して水洗し、乾燥した。
Next, the fabric described above was brought into contact with the surface of the pattern, and after 60 seconds, when the pattern rose to the surface, it was removed, and the fabric was sufficiently sprayed with water, washed, and dried.

その結果、多色の流動模様の柄の織物が製造さ 4゜れ
た。
As a result, a 4-degree fabric with a multicolored fluid pattern was produced.

(発明の効果) 以上の実施例からも明らかなように、本発明はあらかじ
め絹又は綿繊維の糸及びこれらの織物にカチオン基を導
入することにより、従来の染色技法の中で常識的に行わ
れてきた染料固着のための蒸熱処理を省くことができる
とともに、染色時間が短く、工業的価値が大きい。
(Effects of the Invention) As is clear from the above examples, the present invention can be carried out with common sense in conventional dyeing techniques by introducing cationic groups into silk or cotton fiber threads and these fabrics in advance. It is possible to omit the conventional steaming treatment for dye fixation, and the dyeing time is short, which is of great industrial value.

また、現在行われている染色技法と、本発明法による染
色物の染色堅ろう度を比較すると、本発明で染色したも
のは、従来の紐束色物の堅ろう度とは違って高堅ろう度
が得られる。綿も同様である。なぜならば染色するすべ
ての染料がイオン結合方式で染着するためである。
In addition, when comparing the dyeing fastness of dyed products produced by the dyeing techniques currently in use and the method of the present invention, the dyed products dyed using the present invention have a high fastness, unlike the fastness of conventional colored cord bundles. can get. The same goes for cotton. This is because all dyes are dyed using an ionic bonding method.

さらにまた、従来実現できなかった墨流し模様や糊流し
模様を、製織用の織り糸に転写する技術を開発したこと
によって、織物デザイン面からもまた付加価値面からも
工業的に極めて有用であるといった諸効果がある。
Furthermore, we have developed a technology to transfer suminagashi and nori-nagashi patterns onto threads for weaving, which could not be realized in the past.This technology is extremely useful industrially from both a textile design perspective and an added value perspective. effective.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は糸を製織順に平面上に配置するための枠の斜視
図、第2図は巻き取り装置の全体図、第3図は糸を巻き
終わった枠を示す斜視図、第4図は実施例1による織物
を示す平面図、第5図は色糊配色用のプラスチック製し
ぼり出し容器を示す斜視図、第6図は起泡剤と気泡作成
用ミキサーを示す斜視図、第7図は泡と染料によって作
成した流動模様を示す平面図、第8図は仮織布を示す拡
大平面図である。 1・・・枠、2・・・ボビン、3・・・巻き取り装置、
4・・・ガイド、5・・・ハンドル、6・・・螺子棒、
8・・・気泡作成容器、10・・・起泡剤、12・・・
紅色、13・・・緑色、14・・・黄紅色、15・・・
赤色、16・・・黄色、17・・・緑色、18・・・青
色、A1・・・緯糸、A2・・・経糸、A3・・・仮織
の緯糸。 第2図 寸        ト 鰹     派 区 の 派
Figure 1 is a perspective view of a frame for arranging yarn on a plane in the weaving order, Figure 2 is an overall view of the winding device, Figure 3 is a perspective view of the frame after winding the yarn, and Figure 4 is A plan view showing the fabric according to Example 1, FIG. 5 a perspective view showing a plastic squeezing container for coloring the color paste, FIG. 6 a perspective view showing a foaming agent and a mixer for creating bubbles, and FIG. FIG. 8 is a plan view showing a flowing pattern created by foam and dye, and an enlarged plan view showing a temporary woven fabric. 1... Frame, 2... Bobbin, 3... Winding device,
4... Guide, 5... Handle, 6... Screw rod,
8... Bubble creation container, 10... Foaming agent, 12...
Crimson, 13...green, 14...yellow-red, 15...
Red, 16...Yellow, 17...Green, 18...Blue, A1...Weft, A2...Warp, A3...Weft of provisional weave. Diagram 2 Tokatsuo Haku no Ha

Claims (3)

【特許請求の範囲】[Claims] (1)織物に柄付けするに際して、緯糸となる絹又は綿
繊維の糸にカチオン基を導入した後、該緯糸を織り幅と
同一大きさの枠に巻き取り、この巻き取った枠をアニオ
ン性染料と染色用糊剤又はアニオン性染料と起泡性のあ
るアニオン性或いは非イオン性界面活性剤を攪拌して形
成した柄模様上に置き、該柄模様を常温で緯糸に転写染
着した後、この緯糸を柄模様の順に供給し織物とするこ
とを特徴とする織物の柄付け方法。
(1) When patterning a textile, after introducing a cationic group into the silk or cotton fiber thread that will become the weft, the weft is wound into a frame with the same size as the weaving width, and this wound frame is anionic. After stirring the dye and dyeing paste or anionic dye and foaming anionic or nonionic surfactant onto the pattern formed, the pattern is transferred and dyed onto the weft at room temperature. A method for patterning a woven fabric, which is characterized in that the weft yarns are supplied in the order of the pattern to form a woven fabric.
(2)織物に柄付けするに際して、経糸となる絹又は綿
繊維の糸にカチオン基を導入した後、該経糸を仮織し、
この仮織布をアニオン性染料と染色用糊剤又はアニオン
性染料と起泡性のあるアニオン性或いは非イオン性界面
活性剤を攪拌して形成した柄模様上に置き、該柄模様を
常温で仮織布に転写染色した後、これを経糸として供給
し織物とすることを特徴とする織物の柄付け方法。
(2) When patterning a woven fabric, after introducing a cationic group into silk or cotton fiber threads serving as warp threads, the warp threads are tentatively woven;
This temporary woven fabric is placed on a pattern formed by stirring an anionic dye and a dyeing paste or an anionic dye and a foaming anionic or nonionic surfactant, and the pattern is left at room temperature. A method for patterning a woven fabric, which comprises transferring and dyeing a temporary woven fabric and then supplying it as a warp to make a woven fabric.
(3)織物に柄付けするに際して、絹又は綿の織物にカ
チオン基を導入した後、アニオン性染料と染色用糊剤又
はアニオン性染料と起泡性のあるアニオン性或いは非イ
オン性界面活性剤を攪拌して形成した柄模様上に置き、
該柄模様を常温で織物に転写染色させることを特徴とす
る織物の柄付け方法。
(3) When patterning textiles, after introducing cationic groups into silk or cotton textiles, anionic dye and dyeing paste or anionic dye and foaming anionic or nonionic surfactant are added. Stir and place on the pattern formed,
A method for patterning textiles, which comprises transferring and dyeing the pattern onto textiles at room temperature.
JP60062990A 1985-03-27 1985-03-27 Method for patterning fabric Granted JPS61225388A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60062990A JPS61225388A (en) 1985-03-27 1985-03-27 Method for patterning fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60062990A JPS61225388A (en) 1985-03-27 1985-03-27 Method for patterning fabric

Publications (2)

Publication Number Publication Date
JPS61225388A true JPS61225388A (en) 1986-10-07
JPS6253636B2 JPS6253636B2 (en) 1987-11-11

Family

ID=13216314

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60062990A Granted JPS61225388A (en) 1985-03-27 1985-03-27 Method for patterning fabric

Country Status (1)

Country Link
JP (1) JPS61225388A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0284592A (en) * 1988-06-28 1990-03-26 Ikeizumi Orimono Kk Densely dyeing modification processing for raw silk
GR1000269B (en) * 1987-10-05 1992-05-12 Dansk Transfertryk Process for printing by transfering the pattern of a moist membrane and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GR1000269B (en) * 1987-10-05 1992-05-12 Dansk Transfertryk Process for printing by transfering the pattern of a moist membrane and method
JPH0284592A (en) * 1988-06-28 1990-03-26 Ikeizumi Orimono Kk Densely dyeing modification processing for raw silk

Also Published As

Publication number Publication date
JPS6253636B2 (en) 1987-11-11

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