JPS61205181A - Recording material - Google Patents
Recording materialInfo
- Publication number
- JPS61205181A JPS61205181A JP60045414A JP4541485A JPS61205181A JP S61205181 A JPS61205181 A JP S61205181A JP 60045414 A JP60045414 A JP 60045414A JP 4541485 A JP4541485 A JP 4541485A JP S61205181 A JPS61205181 A JP S61205181A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- color
- adhesive
- recording material
- coloring layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/243—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/243—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
- G11B2007/24302—Metals or metalloids
- G11B2007/24306—Metals or metalloids transition metal elements of groups 3-10
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/243—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising inorganic materials only, e.g. ablative layers
- G11B2007/24318—Non-metallic elements
- G11B2007/2432—Oxygen
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/253—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of substrates
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/254—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/256—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers improving adhesion between layers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/257—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of layers having properties involved in recording or reproduction, e.g. optical interference layers or sensitising layers or dielectric layers, which are protecting the recording layers
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、音声２画像、電気信号を記憶、再生するため
の記録材料に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a recording material for storing and reproducing audio, two-image, and electrical signals.
従来の技術
音声２画像、電気信号を記憶、再生するために、従来か
ら磁気および光記憶方式がとられている。BACKGROUND OF THE INVENTION Magnetic and optical storage systems have conventionally been used to store and reproduce audio, video, and electrical signals.
光記憶方式のものは磁気記憶方式に較べて記憶密度が高
くできることから注目されて来ている。光記憶方式のも
のは、アクリル樹脂基板上に形成されたＴｅＣ記録膜等
に信号に応じてレーザー光を照射して熱モードで記録膜
に孔をあけることにより情報を記録するものと、記録膜
としてＴａＯｘ膜等を用いてレーザー光照射によシ熱モ
ードで晶質−徘晶質の変化を行なわせ、光反射率の異な
る状態を作る方式が一般的である。Optical storage systems are attracting attention because they can achieve higher storage densities than magnetic storage systems. Optical storage systems record information by irradiating a TeC recording film formed on an acrylic resin substrate with a laser beam in response to a signal and making holes in the recording film in thermal mode. A common method is to use a TaOx film or the like to change crystallinity to wandering crystallinity in a thermal mode by laser beam irradiation, thereby creating states with different light reflectances.
発明が解決しようとする問題点
従来のこれらの記録材料は、いずれも熱モードによる状
態変化を利用したものであり、書き込み速度も遅く、ま
た必ずしも耐熱性に優れたものではなく信頼性に難点が
あった。Problems to be Solved by the Invention All of these conventional recording materials utilize state changes due to thermal mode, have slow writing speeds, do not necessarily have excellent heat resistance, and have problems with reliability. there were.
問題点を解決するための手段
本発明は、従来の熱モードによる記録材料とは性質を異
にする光モードによる発色材である遷移金属酸化物、特
に酸化タングステン（ＷＯ，）もしくは酸化モリブデン
（ＭＯＯＢ ） を用い、発色材に保護基板を接着する
ことで安定した発色状態（メモリー状態）を保持する新
しいタイプの記録材料である。特に、発色層を設けた基
板と保護基板を接着するための接着剤にプロトン供与体
を添加することにより、発色層の発色効率を向上するこ
とができ、さらには、発色層上に予め保護膜を設けるこ
とにより、さらに信頼性を向上することができる。なお
、プロトン供与体とは、イオン解離等によ＃）Ｈを放出
しうる化合物の総称とする。Means for Solving the Problems The present invention utilizes transition metal oxides, particularly tungsten oxide (WO,) or molybdenum oxide (MOOB), which are optical mode coloring materials that have properties different from conventional thermal mode recording materials. ) is a new type of recording material that maintains a stable coloring state (memory state) by bonding a protective substrate to the coloring material. In particular, by adding a proton donor to the adhesive for bonding the substrate on which the coloring layer is provided and the protective substrate, the coloring efficiency of the coloring layer can be improved. By providing this, reliability can be further improved. Note that the proton donor is a general term for compounds that can release H by ionic dissociation or the like.
作用
無色状態のＷＯ，もしくはＭ２Ｏ３層に、バンドギャッ
プ以上のエネルギーを有する光を当てると、光の照射さ
れた部分が青色もしくは藍色に発色する。この発色状態
は熱や電解もしくは化学的に逆反応を行なわない限シ長
く退色がないので、この色変化を利用して光記録を行な
うことができる。Effect: When a colorless WO or M2O3 layer is irradiated with light having an energy greater than the band gap, the irradiated area develops a blue or indigo color. Since this color development state does not fade for a long time unless a reverse reaction is performed by heat, electrolysis, or chemical, optical recording can be performed using this color change.
発色状態の退色は、特に空気中の酸素により化学的に進
行するものでアシ、これを防止するためには発色層上に
保護膜を設けるとよいが、好ましくは酸素透過性の低い
基体でコートすることにより達成できる。Fading of the colored state progresses chemically, especially due to oxygen in the air. To prevent this, it is best to provide a protective film on the colored layer, but it is preferable to coat it with a substrate with low oxygen permeability. This can be achieved by
また１発色反応（ホトクロミズム）の効率向上は、発色
層及び発色層と接する上部層にプロトン供与体を担持さ
せることによシ達成できる。Furthermore, the efficiency of the one-color reaction (photochromism) can be improved by supporting a proton donor on the coloring layer and the upper layer in contact with the coloring layer.
実施例 以下、本発明の詳細な説明する。Example The present invention will be explained in detail below.
実施例１ 第１図に示すように、ガラス、プラスチックス。Example 1 As shown in Figure 1, glass and plastics.
金属もしくはセラミックスからなる基板１上に蒸着法も
しくはスパッタ法によりＷＯ３もしくはＭｏｂ。WO3 or Mob is deposited on a substrate 1 made of metal or ceramics by vapor deposition or sputtering.
からなる発色層２を１０００人から２ｏｏｏｏ人の厚さ
に設ける。基板にＮ２レーザを用いてパルス光（λ＝３
３７．１ ｎ ｍ 、 ｔ＝２００ｐ８ ）を照射し
たところ、光が当たった部分が青色に発色した。発色後
基板の発色層側に接着剤３を用いて保護基板４としてガ
ラス板を接着した。接着後試料を７０°Ｃの恒温槽中で
保存試験をした。保護基板を設けない比較例の試料は、
２４時間で＃１とんど無色状態に戻ったが、保護基板を
接着した試料は２０００時間後も初期状態に比べほとん
ど劣化（−３％以内）せず安定な状態を示すことが判か
った。また、保護基板４を設けることにより発色層が機
械的破損を免れ信頼性の高いものであった。A coloring layer 2 consisting of the following is provided to a thickness of 1,000 to 2000 people. Pulsed light (λ=3
When irradiated with 37.1 nm, t=200p8), the area that was exposed to the light developed a blue color. After coloring, a glass plate was bonded as a protective substrate 4 to the coloring layer side of the substrate using adhesive 3. After adhesion, the sample was subjected to a storage test in a constant temperature bath at 70°C. The comparative sample without a protective substrate is
Although most of #1 returned to its colorless state after 24 hours, it was found that the sample with the protective substrate attached showed a stable state with almost no deterioration (within -3%) compared to the initial state even after 2000 hours. . Furthermore, by providing the protective substrate 4, the coloring layer was protected from mechanical damage and was highly reliable.
本実施例で使用した接着剤は、エポキシ系、ポリエステ
ル系、アクリレート系、シアノアクリレート系、エポキ
シアクリレート系、スピロアセタール系が効果的であり
、その他、酢酸ビニル系。Effective adhesives used in this example include epoxy, polyester, acrylate, cyanoacrylate, epoxy acrylate, and spiroacetal adhesives, as well as vinyl acetate adhesives.
ポリビニルアルコール系、クロロプレン、ニトリル−ｆ
ム系、ユリア系、メラミン系、フェノール系。Polyvinyl alcohol, chloroprene, nitrile-f
Mu-based, urea-based, melamine-based, phenol-based.
ポリウレタン系の各接着剤も使用できた。Polyurethane adhesives could also be used.
ｆ比、保護基板は前述のガラスの他、アクリル樹脂、塩
化ビニル樹脂、ポリエチレン、ポリプロピレン、ナイロ
ン、ポリエステル、ポリ塩化ビニリデン、ポリアミド、
ポリイミド、塩酸ゴム、ポリアセタール、ポリカーボネ
ート、ポリスチレン。In addition to the above-mentioned glass, the f ratio and protective substrate can be made of acrylic resin, vinyl chloride resin, polyethylene, polypropylene, nylon, polyester, polyvinylidene chloride, polyamide,
Polyimide, hydrochloric acid rubber, polyacetal, polycarbonate, polystyrene.
ム８８樹脂等のプラスチックおよび基板１が透明テする
場合は、ム／、Ｃｕ、Ｔｉ、ステンレス鋼等の金属薄板
も使用できた。なお、発色層としてプロトンをインター
カレーシランしうる他の遷移金属酸化物、例エバ、ｖ２
ｏ、 （基カッ色） ｔ Ｎｂ２０ｓ（ｆ色） 、 Ｔ
ｉＯ２（青色）等も発色効率が低いものの使用できた。When the substrate 1 is made of transparent material such as plastic such as Mu88 resin, thin metal plates such as Mu, Cu, Ti, and stainless steel may also be used. In addition, other transition metal oxides capable of intercalating silane protons as a coloring layer, such as Eva, v2
o, (base color) t Nb20s (f color), T
iO2 (blue) etc. could also be used although the coloring efficiency was low.
実施例２
実施例１と同様に基板１上に発色層２を設け、次に接着
剤３を用いて保護基板４を発色層側に接着した。接着後
、Ｎ２レーザを用いてパルス光（λ＝３３７．１ ｎｍ
ｌ 、 ｔ＝２００ｐＩ９ ）を照射したところ、光
照射部が青色に発色した。発色後実施例１と同様に７０
℃における保存試験をしたところ、発色濃度の低下はほ
とんどなく安定していることが判かった。本実施例で使
用できた接着剤は、エポキシ系、エポキシアクリレート
系、エステルアクリレート系、シアノアクリレート系、
スピロアセタール系、酢酸ビニル系、ポリビニルアルコ
ール系、クロロプレン、ニトロゴム系、エリア系、メラ
ミン系、フェノール系、ポリウレタン系の各接着剤であ
った。Example 2 A coloring layer 2 was provided on a substrate 1 in the same manner as in Example 1, and then a protective substrate 4 was adhered to the coloring layer side using an adhesive 3. After bonding, pulsed light (λ = 337.1 nm
1, t=200pI9), the light irradiated area developed a blue color. After color development, 70% as in Example 1.
When a storage test was carried out at ℃, it was found that the coloring density was stable with almost no decrease. The adhesives that could be used in this example were epoxy, epoxy acrylate, ester acrylate, cyanoacrylate,
The adhesives were spiroacetal, vinyl acetate, polyvinyl alcohol, chloroprene, nitro rubber, area, melamine, phenol, and polyurethane.
また、保護基板としてはガラス、金属板、もしくは、ポ
リ塩化ビニリデン、ポリアクリレート。In addition, the protective substrate can be glass, metal plate, polyvinylidene chloride, or polyacrylate.
ポリ塩化ビニル、ポリスチレン、ポリアミド、ポリイミ
ド、ポリカーボネート、ＡＢＳ樹脂、ポリウレタン、シ
リコーン’ＷＩＪ脂、セルロースアセテート、天然ゴム
、ポリエステル、ナイロン、フェノール樹脂、エリア樹
脂、アクリルフタレート、ポリイソブチン、ポリアセタ
ール、ポリスルホン。Polyvinyl chloride, polystyrene, polyamide, polyimide, polycarbonate, ABS resin, polyurethane, silicone WIJ resin, cellulose acetate, natural rubber, polyester, nylon, phenolic resin, area resin, acryl phthalate, polyisobutyne, polyacetal, polysulfone.
ポリエーテル、ポリビニルアルコール、エポキシ樹脂、
メタクリル樹脂等のプラスチックが使用できた。このう
ち、ガラス、金属、アクリル系樹脂。polyether, polyvinyl alcohol, epoxy resin,
Plastics such as methacrylic resin could be used. Among these, glass, metal, and acrylic resin.
塩化ビニリデン、ポリイミド、ポリアミド等の酸素透過
性の低いと思われる保護基板がよシ効果的であった。Protective substrates that are thought to have low oxygen permeability, such as vinylidene chloride, polyimide, and polyamide, were most effective.
実施例３
実施例２と同様に基板１に発色層２を設け、接着剤３を
用いて保護基板４を接着した。各材料は実施例２と同じ
材料を用いた。Example 3 As in Example 2, a coloring layer 2 was provided on a substrate 1, and a protective substrate 4 was attached using an adhesive 3. The same materials as in Example 2 were used for each material.
ただし、光照射による発色層の発色効率を高めるため接
着剤にプロトン供与体を０．０１％から６％添加した。However, in order to increase the coloring efficiency of the coloring layer upon light irradiation, 0.01% to 6% of a proton donor was added to the adhesive.
試料にＮ２ レーザを用いて光書き込みを行なったとこ
ろ、接着剤にプロトン供与体を添加した試料は添加しな
い試料に比べ濃く、すなわち光学密度にして、２倍から
１ｏ倍濃く発色することが判かった。発色後の安定性は
７０°Ｃ，２０００時間の保存試験の結果実施例２と同
様に極めて優れていた。When optical writing was performed on the sample using an N2 laser, it was found that the sample in which a proton donor was added to the adhesive developed a darker color than the sample without the addition, that is, the optical density was 2 to 10 times darker. Ta. The stability after color development was extremely excellent as in Example 2 as a result of a storage test at 70°C for 2000 hours.
本実施例で検討して効果の確認できたプロトン供与体と
しては、メチルアルコール２エチルアルコール、フチル
アルコール、エチレングリコール。Examples of proton donors whose effects were confirmed through investigation in this example include methyl alcohol, 2-ethyl alcohol, phthyl alcohol, and ethylene glycol.
クレゾール、フェノール、ハイドロキノン等のＯＨ基を
有する化合物、水、アクリル酸、メタクリル酸、ギ酸、
酢酸、４シュウ酸、マレイン醗。Compounds with OH groups such as cresol, phenol, and hydroquinone, water, acrylic acid, methacrylic acid, formic acid,
Acetic acid, 4-oxalic acid, maleic acid.
マロン酸、こはく酸、安息香酸、アジピ／酸、酪識、吉
草酸、テレフタール酸、ポリアクリル酸。Malonic acid, succinic acid, benzoic acid, adipic acid, butyric acid, valeric acid, terephthalic acid, polyacrylic acid.
ヒドロキシ酸、アルコキシ酸、オキソ酸、トルエンスル
ホン酸、フタンスルフィン酸、スルホ安息香酸等の有機
酸、塩酸、硝酸、リン酸、ケイ酸。Hydroxy acids, alkoxy acids, oxo acids, organic acids such as toluenesulfonic acid, phthanesulfinic acid, sulfobenzoic acid, hydrochloric acid, nitric acid, phosphoric acid, silicic acid.
硫酸等の無機酸であった。又、酸類とアルコール類を同
時に添加することより大きな効果が得られた。さらに微
粒状のシリカ（ＳｉＯ２） にプロトン供与体を担持
して接着剤に添加する方法やシランカップリング剤を添
加する方法も効果的であった。It was an inorganic acid such as sulfuric acid. Further, a greater effect was obtained than by adding acids and alcohols at the same time. Furthermore, a method in which a proton donor is supported on fine-grained silica (SiO2) and added to the adhesive, and a method in which a silane coupling agent is added are also effective.
実施例４
第２図に示すごと〈実施例１と同様に基板１に発色層２
を１０００人から２００００人設ける。Example 4 As shown in FIG.
1,000 to 20,000 people.
次に第２図のように、発色層２上に保護膜５を数千人の
厚さに積層する。この保護膜は、Ｓ１０□。Next, as shown in FIG. 2, a protective film 5 is laminated on the coloring layer 2 to a thickness of several thousand layers. This protective film is S10□.
ｋ１２０３．ＴｉＯ２，ＺｒＯ２，Ｖ２Ｏ５，Ｎｂ２Ｏ
５，Ｔａ２０５もしくはＣｒ２Ｏ３により形成する。そ
してこの保護膜作成時、すなわち蒸着時もしくはスピナ
ーコーテング時または保護膜作成後に基板をプロトン供
与体ガス雰囲気中に保存することによりプロトン供与体
を保護膜に担持させた。その後実施例２と同様に接着剤
３を用いて保護基板４を接着する。k1203. TiO2, ZrO2, V2O5, Nb2O
5. Formed from Ta205 or Cr2O3. The proton donor was supported on the protective film by storing the substrate in a proton donor gas atmosphere during the formation of the protective film, that is, during vapor deposition or spinner coating, or after the formation of the protective film. Thereafter, the protective substrate 4 is bonded using the adhesive 3 in the same manner as in Example 2.
接着剤、保護基板およびプロトン供与体の各材料は実施
例３記載のものを使用した。その結果、プロトン供与体
を保護膜６に担持することにより、光書き込みによる発
色濃度のよシ高い記録材料が得られた。The materials described in Example 3 were used for the adhesive, the protective substrate, and the proton donor. As a result, by supporting the proton donor on the protective film 6, a recording material with a higher color density by optical writing was obtained.
実施例６
基鈑上に発色層を１０００人から２０ｏｏｏ人設ける工
程において、実施例３記載のプロトン供与体を発色層に
担持する。担持する方法は、発色層の作成時もしくは作
成後プロトン供与体と接触させることによシプロトン供
与体が発色層に吸着し担持される。この基板を用いて、
以下、実施例２と同様の実験をした結果、発色層にプロ
トン供与体を担持することにより、光書き込みによる発
色濃度のより高い記録材料が得られ念。なお、光書き込
みに使用する光源は、Ｎ２レーザに限定されるものでは
なくｓ Ｈｅ ｃａレーザ、ムｒレーザ、Ｘ６光源、
Ｈｇ光源でも使用できる。Example 6 In the step of providing a coloring layer of 1,000 to 20000 layers on a substrate, the proton donor described in Example 3 is supported on the coloring layer. The cyproton donor is adsorbed and supported on the coloring layer by bringing it into contact with a proton donor during or after the coloring layer is formed. Using this board,
Hereinafter, as a result of the same experiment as in Example 2, it was found that by carrying a proton donor in the coloring layer, a recording material with higher coloring density by optical writing could be obtained. Note that the light source used for optical writing is not limited to N2 laser, but also includes s He ca laser, Mur laser, X6 light source,
Can also be used with Hg light source.
発明の効果
以上のように遷移金属酸化物、特にＷＯ，もしくはＭ２
Ｏ３層に接着剤を用いて保護基板を接着することによ！
＋、２００ｐｆｉ以下の速い速度で光書き込みが可能で
、かつ高温における記憶メモリー効果の優れた記録材料
を提供することができる。As described above, the effect of the invention is that transition metal oxides, especially WO or M2
By bonding the protective substrate to the O3 layer using adhesive!
It is possible to provide a recording material that can be optically written at a high speed of +, 200 pfi or less and has an excellent memory effect at high temperatures.
また、発色層自身もしくは、発色層と接する接着剤等に
プロトン供与体を担持することにより、光書き込みによ
る発色効率が向上しＳ／Ｎ比の優れた記録材料となる。Furthermore, by carrying a proton donor on the coloring layer itself or on an adhesive or the like in contact with the coloring layer, the coloring efficiency by optical writing is improved, resulting in a recording material with an excellent S/N ratio.
第１図及び第２図は本発明の記録材料の構成例を示す縦
断面図である。
１・・・・・・基板、２・・・・・・発色層、３・・・
・・・接着剤、４・・・・・・保護基板、５・・・・・
・保護膜。
代理人の氏名 弁理士 中 尾 敏 男 ほか１名／−
−−基版
第２図FIGS. 1 and 2 are longitudinal sectional views showing an example of the structure of the recording material of the present invention. 1...Substrate, 2...Coloring layer, 3...
...Adhesive, 4...Protection board, 5...
·Protective film. Name of agent: Patent attorney Toshio Nakao and 1 other person/-
---Base plate figure 2
Claims (5)
この発色層側に保護用基板を接着剤を用いて接着させた
ことを特徴とする記録材料。(1) Provide a transition metal oxide layer as a coloring layer on the substrate,
A recording material characterized in that a protective substrate is adhered to the coloring layer side using an adhesive.
酸化モリブデンである特許請求の範囲第１項記載の記録
材料。(2) The recording material according to claim 1, wherein the transition metal oxide layer is tungsten oxide or molybdenum oxide.
１項記載の記録材料。(3) The recording material according to claim 1, wherein the adhesive contains a proton donor.
層したことを特徴とする特許請求の範囲第１項記載の記
録材料。(4) The recording material according to claim 1, characterized in that a protective film carrying a proton donor is laminated on the coloring layer.
とする特許請求の範囲第１項記載の記録材料。(5) The recording material according to claim 1, wherein the coloring layer supports a proton donor.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60045414A JPS61205181A (en) | 1985-03-07 | 1985-03-07 | Recording material |
| US06/835,787 US4711815A (en) | 1985-03-07 | 1986-03-03 | Recording medium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60045414A JPS61205181A (en) | 1985-03-07 | 1985-03-07 | Recording material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61205181A true JPS61205181A (en) | 1986-09-11 |
| JPH041413B2 JPH041413B2 (en) | 1992-01-13 |
Family
ID=12718599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60045414A Granted JPS61205181A (en) | 1985-03-07 | 1985-03-07 | Recording material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61205181A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106886116A (en) * | 2015-12-15 | 2017-06-23 | 乐金显示有限公司 | Light control device, the transparent display including it and its manufacture method |
-
1985
- 1985-03-07 JP JP60045414A patent/JPS61205181A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106886116A (en) * | 2015-12-15 | 2017-06-23 | 乐金显示有限公司 | Light control device, the transparent display including it and its manufacture method |
| CN106886116B (en) * | 2015-12-15 | 2021-04-23 | 乐金显示有限公司 | Light control device, transparent display device including the same, and method of manufacturing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH041413B2 (en) | 1992-01-13 |
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