JPS6119389A - Recording sheet - Google Patents

Recording sheet

Info

Publication number
JPS6119389A
JPS6119389A JP14099084A JP14099084A JPS6119389A JP S6119389 A JPS6119389 A JP S6119389A JP 14099084 A JP14099084 A JP 14099084A JP 14099084 A JP14099084 A JP 14099084A JP S6119389 A JPS6119389 A JP S6119389A
Authority
JP
Japan
Prior art keywords
water
ink
recording sheet
recording
transparent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP14099084A
Other languages
Japanese (ja)
Inventor
Shigehiko Miyamoto
宮本 成彦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Paper Mills Ltd
Original Assignee
Mitsubishi Paper Mills Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Paper Mills Ltd filed Critical Mitsubishi Paper Mills Ltd
Priority to JP14099084A priority Critical patent/JPS6119389A/en
Publication of JPS6119389A publication Critical patent/JPS6119389A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508Supports
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5218Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5236Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5254Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Landscapes

  • Duplication Or Marking (AREA)
  • Paper (AREA)

Abstract

PURPOSE:To obtain a recording sheet suitable for use as a recording medium for an OHP, by a method wherein an aqueous coating liquid is applied to a transparent film, and is dried to provide an ink-receiving layer which is absorbent of a water base ink for ink jet recording and is water-resistant. CONSTITUTION:The recording sheet comprises at least one ink-receiving layer on a base consisting of a transparent film. The layer is a transparent layer formed from an aqueous coating liquid comprising a water-soluble resin and colloidal silica, and the resin/silica ratio is 100/5-100/150, preferably, 100/20-100/120. The water-soluble resin is one which forms a transparent film when being dried, e.g., polyvinyl alcohol, gelatine, a gelatine derivative, hydroxyethyl cellulose, polyvinyl pyrrolidone or etherified starch. Colloidal silica is an anionic colloidal dispersed liquid obtained by dispersing an ultrafine powder of silicic anhydride (silica) in water.

Description

【発明の詳細な説明】 (5)産業上の利用分野 本発明はインク−を用いて記録する記録媒体に関するも
のであり、特Oこオーバーへラドプロジェクタ用等の光
透過性記録媒体に適したインクジェット記録用記録シー
トに関するものである。
Detailed Description of the Invention (5) Field of Industrial Application The present invention relates to a recording medium recorded using ink, and is particularly suitable for a light-transmissive recording medium such as for use in over-the-top projectors. The present invention relates to a recording sheet for inkjet recording.

インクジェット記録方式は、インクの微小液滴を種々の
作動原理(こより飛翔させて、記録媒体Gコ付着させ、
画像、文字などの記録を行うものであるが、記録パター
ンの融通性が大きく、多色化が容易であることから漢字
を含め各種図形及びカラー画像等のハードコピー装置と
して、種々の用途に於いて急速に普及している。特にオ
ーバーへ7ドブロジエクターは写真スライドと共に多く
の会議、講演、説明会及び商品の宣伝等に利用されてい
て、オーバーヘッドプロジェクタ−用の記録媒体全イン
クジェット記録方式で作ることf1優利な点が多い。
The inkjet recording method uses various operating principles (flying minute droplets of ink to adhere to the recording medium G,
It is used for recording images, characters, etc., and because it has great flexibility in recording patterns and can easily be made into multiple colors, it can be used for various purposes as a hard copy device for various figures including kanji, color images, etc. It is rapidly becoming popular. In particular, the Overhead Projector is used in many meetings, lectures, briefings, and product promotions along with photo slides, and there are many advantages to using the inkjet recording method as the recording medium for the overhead projector.

■) 従来技術及びその問題点 従来オーバーヘッド用の記録媒体の作り方としては、透
明フィルムの熱収縮による不透明化を利用した方法や電
子複写方式を応用した方法、熱転写方式を利用した方法
及び透明フィルムに直接フェルトペン等で書込む方法等
があるが、多色化が出来なかったり多色化出来ても画像
が暗くなったりして、実用的な多色オーバーヘッド用コ
ピーを作ることは、なかなか困難であった。これらの透
明フィルム等にインクジェット記録をしても、記録面に
゛インク吸収性がないため、従来の水性インクを用いた
記録は、乾燥に長時間を要したり、記録面上で流れ出し
たりして、実用的な記録画像を得ることは、出来なかっ
た。記録画像の見掛は乾燥を速くするため、それらのフ
ィルム表面に顔料粒子を含有する塗工液を塗布して、イ
ンフジエラ1)記録媒体とする方法があるが、これらの
方法ではオーバーへラドプロジェクタ用等の光透過性記
録媒体の作成には不透明性の点で不適当である。
■) Prior art and its problems Conventional methods for making overhead recording media include methods that utilize opacity caused by heat shrinkage of transparent films, methods that apply electronic copying methods, methods that utilize thermal transfer methods, and methods that utilize transparent films. There are methods to write directly with felt-tip pens, etc., but it is difficult to make practical multicolor overhead copies because it is not possible to make multicolors, or even if it is possible to make multicolors, the images are dark. there were. Even when inkjet recording is performed on these transparent films, etc., the recording surface does not have ink absorbency, so recording using conventional water-based inks takes a long time to dry or may run out on the recording surface. Therefore, it was not possible to obtain a practical recorded image. In order to speed up the apparent drying of recorded images, there is a method of applying a coating liquid containing pigment particles to the surface of the film and using it as a recording medium. Due to its opacity, it is unsuitable for producing optically transparent recording media for commercial purposes.

また特開昭57−14091号には透明支持体表面に結
着用樹脂と充填粒子が60重量%以上である多孔性層を
設けたインクジェット記録用媒体の記載があるが、これ
は結着剤が有機溶媒溶性の樹脂であり、かつ、充填剤全
60重量%以上使用しているため、完全な透明層が得ら
れず、ジアゾ第2原図用としては、使えてもオーバーヘ
ッドプロジェクタ−用としては不充分であった。
Furthermore, JP-A-57-14091 describes an inkjet recording medium in which a porous layer containing 60% by weight or more of a binding resin and filler particles is provided on the surface of a transparent support. Because it is an organic solvent-soluble resin and uses more than 60% filler in total, a completely transparent layer cannot be obtained, and although it can be used for diazo second originals, it is not suitable for overhead projectors. It was enough.

(C1発明の目的 本発明は水性塗工液を透明フィルム上番コ塗工乾燥する
ことによって、水性インクジェット用インクの吸収性を
有しながら、耐水性のあるインク受理層を構成した記録
用シー1弓こ関し、特cコオーバーヘッドプロジェクタ
ー用の記録媒体に適した記録用シートに関するものであ
る。
(C1 Purpose of the Invention The present invention provides a recording sheet that has an ink-receiving layer that is water-resistant and absorbs water-based inkjet ink by coating an aqueous coating solution on a transparent film and drying it. This invention relates to a recording sheet suitable as a recording medium for a special overhead projector.

(DJ  発明の構成 即ち、本発明は、支持休止に少なくとも一層のインク受
理層を設けてなる記録用シートで、該支持体が透明フィ
ルムであり、かつインク受理層が水溶性樹脂及びコロイ
ダルシリカから成る水性塗工液から形成した透明な層で
あり、水溶性樹脂/コロイダルシリカの比がl OO1
5〜100/150の範囲、好まL<l”t100/2
0〜100/120の範囲である記録用シートの提供で
ある。
(DJ Structure of the invention, that is, the present invention is a recording sheet comprising at least one ink-receiving layer on a supporting layer, the support is a transparent film, and the ink-receiving layer is made of a water-soluble resin and colloidal silica. It is a transparent layer formed from an aqueous coating liquid with a water-soluble resin/colloidal silica ratio of 1 OO1
Range of 5 to 100/150, preferably L<l”t100/2
It is to provide a recording sheet having a range of 0 to 100/120.

本発明で云う水溶性樹脂とは、ポリビニルアル ゛コー
ル、ゼラチン、及びゼラチン誘導体、ヒドロキ    
   9ジエチルセルロース、ポリビニルピロリドン、
エーテル化澱粉等の水溶性で、乾燥した時透明な皮膜を
与える樹脂全天う。特に本発明【こ於いては、ポリビニ
ルアルコール及びゼラチンが好ましく、ポリビニルアル
コールとしては、重合度400〜2200、好韮仁くは
1ooo〜2000、ケン化度1−t80%〜99.9
%、好ましくは95%以上のものである。
The water-soluble resins used in the present invention include polyvinyl alcohol, gelatin, gelatin derivatives, and hydroxyl resins.
9 diethylcellulose, polyvinylpyrrolidone,
Water-soluble resins such as etherified starch that form a transparent film when dry. Particularly in the present invention, polyvinyl alcohol and gelatin are preferred, and polyvinyl alcohol has a degree of polymerization of 400 to 2200, preferably 100 to 2000, and a degree of saponification of 1-t80% to 99.9.
%, preferably 95% or more.

本発明で使用さ?Cるコロイダルシリカとは、無水珪W
<シリカ)の超微粒子を安定に水に分散させた、アニオ
ン性のコロイド状分散液で、DuPont社のLudo
x 、 Mon5anto社の5yton 、  Na
1c。
Used in this invention? Colloidal silica is anhydrous silicon W
DuPont's Ludo is an anionic colloidal dispersion in which ultrafine particles of silica are stably dispersed in water.
x, 5yton from Mon5anto, Na
1c.

社のNalcoag 、8産化学■のスノーテックス等
の銘柄名で市場に供給されている。これらのコロイダル
シリカは各種の製法があるが、一般的にはイオン交換樹
脂を用いる方法で、ケイ酸ナトリウム水溶液を陽イオン
交換、樹脂【こ通して5i02/Na2Oが60〜13
0のゾルとし、これt−60℃以上に加熱熟成して独立
分散粒子まで成長させ、これに新たにイオン交換樹脂層
を通したゾル?添加することにより重合沈積させて、3
mμ〜20C1lμの平均粒子径にまで成長させ安定し
たゾルとする方法である。これらのコロイダルシリカ粒
子ハ、シロキサン構造をもち、通常はシリカの各粒子が
お互いに反発し合うのに十分な負電荷(アニオン性)′
ftもっている。これらのものは本発明で使用出来るコ
ロイダルシリカであるが、好ましくは粒子径7mμ〜6
0711μ、よ咬好ましくは8′n′Lμ〜30mμの
ものである。
It is supplied to the market under brand names such as Nalcoag by the Company and Snowtex by Yasusan Kagaku ■. There are various methods for manufacturing these colloidal silicas, but the general method is to use an ion exchange resin.
0 sol, heated and aged at t-60°C or higher to grow independently dispersed particles, and then passed through a new ion exchange resin layer to create a sol. By adding 3
This is a method of growing a stable sol to an average particle diameter of mμ to 20C1lμ. These colloidal silica particles have a siloxane structure and usually have sufficient negative charge (anionicity) to cause each silica particle to repel each other.
I have ft. These colloidal silicas can be used in the present invention, but the particle size is preferably 7 mμ to 6 μm.
0711μ, preferably 8'n'Lμ to 30mμ.

前記水溶性樹脂とコロイダルシリカを前述の比率で混合
し、塗布、乾燥した皮膜がなぜインク吸収性で水あるい
は温水に対して、不溶性になり、かつ、透明であるのか
、その理由は定かではない。
It is not clear why the film obtained by mixing the water-soluble resin and colloidal silica in the above-mentioned ratio, coating and drying is ink absorbent, insoluble in water or hot water, and transparent. .

ただこの範囲をはずれてコロイダルシリカが少なくなる
と皮膜は水に溶けるよう0こなり、また、逆【こコロイ
ダルシリカが多すぎると皮膜の光透過性は低下し、どち
らにしてもオーバーヘッドプロジェクタ−用の記録媒体
としては好ましくない。
However, if the amount of colloidal silica decreases outside of this range, the film will become soluble in water, and vice versa. It is not preferred as a recording medium.

支持体としては、透明な熱可塑性樹脂フィルムや、ポリ
ビニルアルコールのフィルム、セルロール誘導体のフィ
ルム等が用いられる。
As the support, a transparent thermoplastic resin film, a polyvinyl alcohol film, a cellulose derivative film, etc. are used.

熱可塑性樹脂フィルムとしては、ポリエステル、ポリス
チレン、ポリ塩化ビニル、ポリメチルメタクリレート、
酢酸セルロース、ポリエチレン、ポリカーボネート等の
フィルム及びこれらの樹脂表面とインク受理層の接着を
改善するための下引層を施したフィルムや、コロナ放電
加工等を施したフィルムが用いられる。
Thermoplastic resin films include polyester, polystyrene, polyvinyl chloride, polymethyl methacrylate,
Films such as cellulose acetate, polyethylene, and polycarbonate, films coated with a subbing layer to improve the adhesion between the surface of these resins and the ink receiving layer, and films coated with corona discharge processing are used.

これらの支持体上番こ水溶性樹脂及びコロイダルシリカ
から成るインク受理層全形成するには、水、水溶性樹脂
、コロイダルシリカ及び必要なら消泡剤、染料、PHE
節剤防剤防腐剤添加した塗工液を、一般に用いられてい
るブレードコーター、エアナイフコーター、ロールコー
タ−、フラッシュコーター、カーテンコーター、バーコ
ーター、グラビアコーター、スプレー装置等を用いて、
塗布、乾燥することで得られる。インク受理層は0,5
黛/イ〜30f/m1、好ましくはI El−/m 〜
15 g−/frL s とすることで本発明の記録用
シートとすることが出来る。
To form the entire ink-receiving layer consisting of a water-soluble resin and colloidal silica on these supports, water, water-soluble resin, colloidal silica, and if necessary an antifoaming agent, dye, and PHE are added.
A coating solution containing a moderating agent and preservative is coated using a commonly used blade coater, air knife coater, roll coater, flash coater, curtain coater, bar coater, gravure coater, spray device, etc.
Obtained by coating and drying. The ink receiving layer is 0.5
Mayuzumi/I~30f/m1, preferably I El-/m~
The recording sheet of the present invention can be obtained by setting it to 15 g-/frLs.

(El  実施例 以下に本発明の実施例を挙げて説明するがこれらの例に
限定されるものではない。
(El) Examples The present invention will be described below with reference to examples, but the present invention is not limited to these examples.

尚実施例に於いて示す部及び%は重量部J☆び重量%全
意味する。
In the examples, parts and percentages refer to all parts by weight and percentages by weight.

実施例1゜ コロナ処理をした75μmのポリエステルフィルムに、
ポリビニルアルコール(クラレ社製pvA117)10
0部、コロイダルシリカ(日産化学社製スノーテックス
−〇)140部(固型分)よりなる水溶液を固型分で2
?/イになるようにエアーナイフコーターで塗布、乾燥
して実施例1の記録シートとした。この記録シートヲ用
い、キャノン社Wインクジェットプリンター(A121
0)【こより画像を記録したところインクの広がりや滲
みがなく、高解像で色濃度の高い記録画像が得られた。
Example 1 A 75 μm polyester film subjected to corona treatment was
Polyvinyl alcohol (pvA117 manufactured by Kuraray) 10
0 parts and 140 parts (solid content) of colloidal silica (Nissan Chemical Co., Ltd. Snowtex-〇).
? The recording sheet of Example 1 was obtained by coating with an air knife coater so as to obtain a coating film of /A and drying. Using this recording sheet, Canon W inkjet printer (A121
0) [When an image was recorded from this, there was no spreading or bleeding of the ink, and a recorded image with high resolution and high color density was obtained.

実施例2゜ コロナ処理ケした75μmのポリエステルフィルムに、
ポリビニルアルコール(クラレ社IMPvA117)1
00部、コロイダルシリカ(日産化学社製スノーテック
スC)20部(固型分)よりなろ水溶液を固型分で8デ
/−にな・るように、エアーナイフコーターで塗布乾燥
し、実施例2の記録シートとした。この記録シートを用
い、シャープ社製インクジェットプリンター(10−7
00)により画像を記録したところ、インクの広がりや
滲みがなく、高解像度で色濃度の高い、記録画像が得ら
れた。
Example 2 A 75 μm polyester film subjected to corona treatment was
Polyvinyl alcohol (Kuraray IMPvA117) 1
00 parts of colloidal silica (Nissan Chemical Co., Ltd. Snowtex C) 20 parts (solid content) was coated with an aqueous solution using an air knife coater so that the solid content was 8 de/-, and dried. 2 recording sheet. Using this recording sheet, use a Sharp inkjet printer (10-7).
When an image was recorded using 00), a recorded image with high resolution and high color density was obtained without ink spreading or bleeding.

実施例3゜ ニトロセルロース下引きをしたポリエステルフィルム【
こ、ゼラチンIK−36Kにツヒ製)100部、jロイ
ダルシリカ(日産化学社製、スノーテックス0L)10
0部、(固型分)よりなる水溶液全固型分で5?/−に
なるように、エアナイフコーターで塗布、乾燥し、実施
例3の記録シートとした。この記録シートを用いシャー
プ社製インクジェットプリンター(10−700)によ
り画像を記録したところ、インクの広がりや滲みがなく
、高解像度で色濃度の高い、記録画像が得られた。
Example 3 Polyester film with nitrocellulose subbing [
Gelatin IK-36K (manufactured by Tsuhi) 100 parts, J Roidal Silica (manufactured by Nissan Chemical Co., Ltd., Snowtex 0L) 10
0 parts, (solid content) Aqueous solution consisting of total solid content of 5? The recording sheet of Example 3 was prepared by coating with an air knife coater and drying so as to give a coating of /-. When an image was recorded using this recording sheet using an inkjet printer (10-700) manufactured by Sharp Corporation, a recorded image with high resolution and high color density was obtained without spreading or bleeding of the ink.

(F)  発明の効果 本発明は、透明支持体上に、透明なインク受理層が得ら
れ、水に不溶性の皮膜で、かつ、インクジェット用イン
クを吸収する能力を有しているため、高解像度で色濃度
の高い、オーバーヘッドプロジェクタ−用記録媒体とし
て極めて優れた記録シートが得られる。
(F) Effects of the Invention The present invention provides a transparent ink-receiving layer on a transparent support, which is a water-insoluble film and has the ability to absorb inkjet ink. A recording sheet having high color density and excellent as a recording medium for an overhead projector can be obtained.

手続ネ市正書輸発) 昭和60年 6月14日  刈Procedures Nei City Official Book Export) June 14th, 1985

Claims (2)

【特許請求の範囲】[Claims] (1)支持体上に少なくとも一層のインク受理層を設け
てなる記録用シートに於いて、該支持体が透明媒体であ
り、かつインク受理層が水溶性樹脂及びコロイダルシリ
カから成る透明な層であることを特徴とする記録用シー
ト。
(1) In a recording sheet comprising at least one ink-receiving layer provided on a support, the support is a transparent medium, and the ink-receiving layer is a transparent layer made of a water-soluble resin and colloidal silica. A recording sheet with certain characteristics.
(2)水溶性樹脂がポリビニルアルコール又はゼラチン
から選ばれた少なくとも一種であり、かつ、水溶性樹脂
/コロイダルシリカの比が100/5〜100/150
の範囲である特許請求の範囲第一項記載の記録用シート
(2) The water-soluble resin is at least one selected from polyvinyl alcohol or gelatin, and the water-soluble resin/colloidal silica ratio is 100/5 to 100/150.
A recording sheet according to claim 1, which falls within the scope of claim 1.
JP14099084A 1984-07-06 1984-07-06 Recording sheet Pending JPS6119389A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14099084A JPS6119389A (en) 1984-07-06 1984-07-06 Recording sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14099084A JPS6119389A (en) 1984-07-06 1984-07-06 Recording sheet

Publications (1)

Publication Number Publication Date
JPS6119389A true JPS6119389A (en) 1986-01-28

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP14099084A Pending JPS6119389A (en) 1984-07-06 1984-07-06 Recording sheet

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JP (1) JPS6119389A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0305478A1 (en) * 1987-02-24 1989-03-08 Am Int Recording transparency and method for its production.
JPH03102051A (en) * 1989-09-18 1991-04-26 Komori Corp Display method for article of inferior quality of printed matter and device thereof
US5198306A (en) * 1987-02-24 1993-03-30 Xaar Limited Recording transparency and method
JPH05132898A (en) * 1991-04-12 1993-05-28 Moore Business Forms Inc Coated base material and its preparation
JPH06316146A (en) * 1990-03-02 1994-11-15 Xerox Corp Transparent body
JP2002038095A (en) * 2000-07-24 2002-02-06 Sumitomo Osaka Cement Co Ltd Coating material for forming transparent printingsubstrate film, the transparent printing- substrate film, and method of printing
US6398827B1 (en) 1999-07-02 2002-06-04 Nissan Chemical Industries, Ltd. Polishing composition
US6632489B1 (en) 1998-09-10 2003-10-14 Nissan Chemical Industries, Ltd. Moniliform silica sol, process for producing the same, and ink-jet recording medium
EP2028237A1 (en) 2007-08-22 2009-02-25 Mimaki Engineering Co., Ltd. Coating agent for UV curable inkjet printing
WO2019039434A1 (en) 2017-08-23 2019-02-28 三菱製紙株式会社 Paper for total heat exchanging element and total heat exchanging element
WO2020166653A1 (en) 2019-02-14 2020-08-20 三菱製紙株式会社 Enthalpy exchange element paper and enthalpy exchange element

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55146786A (en) * 1979-05-02 1980-11-15 Fuji Photo Film Co Ltd Ink-jet recording sheet
JPS5714091A (en) * 1980-06-30 1982-01-25 Ricoh Co Ltd Recording medium for ink jet recording
JPS5865692A (en) * 1981-10-16 1983-04-19 Mitsubishi Paper Mills Ltd Recording paper

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55146786A (en) * 1979-05-02 1980-11-15 Fuji Photo Film Co Ltd Ink-jet recording sheet
JPS5714091A (en) * 1980-06-30 1982-01-25 Ricoh Co Ltd Recording medium for ink jet recording
JPS5865692A (en) * 1981-10-16 1983-04-19 Mitsubishi Paper Mills Ltd Recording paper

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0305478A1 (en) * 1987-02-24 1989-03-08 Am Int Recording transparency and method for its production.
US5198306A (en) * 1987-02-24 1993-03-30 Xaar Limited Recording transparency and method
JPH03102051A (en) * 1989-09-18 1991-04-26 Komori Corp Display method for article of inferior quality of printed matter and device thereof
JPH06316146A (en) * 1990-03-02 1994-11-15 Xerox Corp Transparent body
JPH05132898A (en) * 1991-04-12 1993-05-28 Moore Business Forms Inc Coated base material and its preparation
US6632489B1 (en) 1998-09-10 2003-10-14 Nissan Chemical Industries, Ltd. Moniliform silica sol, process for producing the same, and ink-jet recording medium
US6398827B1 (en) 1999-07-02 2002-06-04 Nissan Chemical Industries, Ltd. Polishing composition
JP2002038095A (en) * 2000-07-24 2002-02-06 Sumitomo Osaka Cement Co Ltd Coating material for forming transparent printingsubstrate film, the transparent printing- substrate film, and method of printing
EP2028237A1 (en) 2007-08-22 2009-02-25 Mimaki Engineering Co., Ltd. Coating agent for UV curable inkjet printing
US8104884B2 (en) 2007-08-22 2012-01-31 Mimaki Engineering Co., Ltd. Coating agent for UV curable inkjet printing
WO2019039434A1 (en) 2017-08-23 2019-02-28 三菱製紙株式会社 Paper for total heat exchanging element and total heat exchanging element
WO2020166653A1 (en) 2019-02-14 2020-08-20 三菱製紙株式会社 Enthalpy exchange element paper and enthalpy exchange element

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