JPS6118521B2 - - Google Patents
Info
- Publication number
- JPS6118521B2 JPS6118521B2 JP1502379A JP1502379A JPS6118521B2 JP S6118521 B2 JPS6118521 B2 JP S6118521B2 JP 1502379 A JP1502379 A JP 1502379A JP 1502379 A JP1502379 A JP 1502379A JP S6118521 B2 JPS6118521 B2 JP S6118521B2
- Authority
- JP
- Japan
- Prior art keywords
- salts
- insect
- wood
- mercaptobenzothiazole
- termite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 14
- 239000002023 wood Substances 0.000 claims description 12
- 241000238631 Hexapoda Species 0.000 claims description 10
- 241000256602 Isoptera Species 0.000 claims description 8
- -1 alkali metal salts Chemical class 0.000 claims description 8
- 239000004480 active ingredient Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 150000003839 salts Chemical class 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000005871 repellent Substances 0.000 description 5
- 230000002940 repellent Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- HITBOAGYESUOFH-UHFFFAOYSA-N boric acid hydrochloride Chemical compound Cl.OB(O)O HITBOAGYESUOFH-UHFFFAOYSA-N 0.000 description 2
- BIWJNBZANLAXMG-YQELWRJZSA-N chloordaan Chemical compound ClC1=C(Cl)[C@@]2(Cl)C3CC(Cl)C(Cl)C3[C@]1(Cl)C2(Cl)Cl BIWJNBZANLAXMG-YQELWRJZSA-N 0.000 description 2
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 235000005638 Austrian pine Nutrition 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000039951 Lithocarpus glaber Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000008565 Pinus banksiana Nutrition 0.000 description 1
- 244000019397 Pinus jeffreyi Species 0.000 description 1
- 235000013264 Pinus jeffreyi Nutrition 0.000 description 1
- 235000008578 Pinus strobus Nutrition 0.000 description 1
- 235000008585 Pinus thunbergii Nutrition 0.000 description 1
- 235000014030 Podocarpus spicatus Nutrition 0.000 description 1
- 241000700159 Rattus Species 0.000 description 1
- 231100000460 acute oral toxicity Toxicity 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000003049 inorganic solvent Substances 0.000 description 1
- 229910001867 inorganic solvent Inorganic materials 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical compound C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000017985 rocky mountain lodgepole pine Nutrition 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002424 termiticide Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
本発明は、２−メルカプトベンゾチアゾール及
び／又はその塩を有効成分として含有し、人体に
対する安全性が高く効果の優れた木材用防虫防蟻
剤に関する。
木材は加工性、比強度、断熱特性等に富むため
優れた建築用材として、或は紙、パルプの原料で
あるチツプとして重要な資源であるが、腐る、燃
える、虫害を受ける等の欠点がある。
この木材は虫害、蟻害に対しては、従来
DDT、γ−BHC、デルドリン、PCP、クロルデ
ン、ホウ酸塩素等が使用されている。しかし、
DDT、γ−BHC、デルドリン及びPCPのラツト
に対する急性経口毒性はLD50が各々150，125，
46及び146mg／Kgと毒性が高く、比較的安全とさ
れているクロルデンでも283mg／Kgである。ま
た、ホウ酸塩素は低毒性であるが、防蟻効力が小
さいうえ水に溶脱され易く、用途が狭い範囲に限
定されている。これらのことから、防虫防蟻効果
に優れ、人体に対する安全性の高い防虫防蟻剤の
開発が要請されていた。
本発明者等は上記の事情に鑑み研究を重ねた結
果、LD50が2300mg／Kgと極めて安全性の高い２
−メルカプトベンゾチアゾール及び／又はその塩
が優れた防虫防蟻効果を有することを見出した。
本発明で使用できる２−メルカプトベンゾチア
ゾールの塩としては、ナトリウム、カリウム等の
アルカリ金属塩、マグネシウム、カルシウム等の
アルカリ土金属塩その他の金属塩及びアンモニウ
ム塩や通常の脂胞族第１級、第２級及び第３級ア
ミン塩並びに脂環式Ｐミン塩等の水溶性及び非水
溶性塩が挙げられる。
本発明における２−メルカプトベンゾチアゾー
ル及び／又はその塩は有機、無機の溶剤で、又は
界面活性剤等との組合せにより、水溶性剤、可溶
化剤、乳剤、ペースト、油溶性剤等種々の形態で
使用でき、いずれも２−メルカプトベンゾチアゾ
ルとして0.1〜40重量％の範囲の濃度で、木材の
種類、性状、含水率及び木材の処理方法等に応じ
て、その形態及び濃度を選択する。
本発明の防虫防蟻剤による木材の処理方法とし
ては、塗布、スプレー、漬浸、加圧等の一般の木
材の処理方法を適用することができるほか、接着
剤に混合することにより、虫害、蟻害を被る恐れ
のある合板等の多孔性の被着物に防虫、防蟻性を
付与することができ、また安全性が高く農作物等
The present invention relates to an insect and termiticide for wood that contains 2-mercaptobenzothiazole and/or a salt thereof as an active ingredient and is highly safe and effective for the human body. Wood has excellent workability, specific strength, and heat insulation properties, making it an important resource as an excellent building material and as a raw material for paper and pulp, but it has disadvantages such as rotting, burning, and being damaged by insects. . This wood is conventionally resistant to insect and ant damage.
DDT, γ-BHC, deldrin, PCP, chlordane, chlorine borate, etc. are used. but,
The acute oral toxicity of DDT, γ-BHC, deldrin, and PCP to rats has an LD50 of 150 , 125,
The toxicity is high at 46 and 146mg/Kg, and even chlordane, which is considered relatively safe, has a toxicity of 283mg/Kg. In addition, although chlorine borate has low toxicity, it has a low anti-termite effect and is easily leached into water, so its use is limited to a narrow range. For these reasons, there has been a demand for the development of insect and termite repellents that have excellent insect and termite repellent effects and are highly safe for the human body. As a result of repeated research in view of the above circumstances, the present inventors have found that 2
- It has been found that mercaptobenzothiazole and/or its salts have excellent insect and termite effects. Examples of the salts of 2-mercaptobenzothiazole that can be used in the present invention include alkali metal salts such as sodium and potassium salts, alkaline earth metal salts such as magnesium and calcium, other metal salts, ammonium salts, and ordinary primary fatty acid salts. Water-soluble and water-insoluble salts such as secondary and tertiary amine salts and alicyclic Pmine salts are included. 2-Mercaptobenzothiazole and/or its salt in the present invention can be used in various forms such as water-soluble agents, solubilizers, emulsions, pastes, and oil-soluble agents by using organic or inorganic solvents or in combination with surfactants, etc. Both can be used at concentrations ranging from 0.1 to 40% by weight as 2-mercaptobenzothiazole, and the form and concentration are selected depending on the type, property, moisture content, wood treatment method, etc. of the wood. As a method for treating wood with the insect repellent and termite repellent of the present invention, general wood treatment methods such as coating, spraying, dipping, and pressurization can be applied.In addition, by mixing it with an adhesive, it can prevent insect damage. It can provide insect and termite repellent properties to porous materials such as plywood that may be subject to ant damage, and is highly safe and can be used for agricultural products, etc.
【表】
これらの薬剤組成物の防虫防蟻効果を次の方法
で試験した。
クロマツ辺材（３cm×３cm×60cm）を各々10本
ずつ試験材とし、
Ａ；組成物を木材表面積１m2当り150ｇになる
ように塗布、
Ｂ；組成物を600mmHg、30分間前排気、15Kg／
cm2、３時間加圧後、600mmHg、30分間後排気
の条件で加圧注入、
Ｃ； 組成物に３分間浸漬、
Ｄ；組成物を木材表面積１m2当り200ｇになる
ように塗布し、20日間風乾したもの、
Ｅ；組成物を、600mmHg、30分間前排気、15
Kg／cm2、３時間加圧の条件で加圧注入、
Ｆ；組成物を木材表面１m2当り150ｇになるよ
うに塗布、
を夫々イエシロアリの巣を中心に半径３ｍの同心
円周上に無処理片と交互になるように配置し、試
験材の長さの2/3を地中に埋設した。そして、１
年経過後地中より抜出して被害度を求めた結果を
第２表に示した。[Table] The insect- and termite-proofing effects of these pharmaceutical compositions were tested by the following method. 10 pieces of black pine sapwood (3 cm x 3 cm x 60 cm) were used as test materials. A: The composition was applied to 150 g per 1 m2 of wood surface area. B: The composition was pre-exhausted at 600 mmHg for 30 minutes, 15 kg/
cm 2 , after pressurizing for 3 hours, pressurized injection at 600 mmHg and post-exhaust for 30 minutes, C: immersed in the composition for 3 minutes, D: Applying the composition to 200 g per 1 m 2 of wood surface area, 20 Air-dried for 15 days.
Kg/cm 2 , pressurized injection for 3 hours, F: Apply the composition to 150 g per 1 m 2 of the wood surface, untreated on a concentric circle with a radius of 3 m centered on the nest of termites. The specimens were placed alternately with each other, and two-thirds of the length of the specimen was buried underground. And 1
Table 2 shows the results of extracting the soil from the ground after a year and determining the degree of damage.
【表】
実施例 ２
ナラ辺材（１cm×５cm×10cm）各10枚を、実施
例１と同様にＡ〜Ｆの処理を行い、20日間風乾
後、二枚のヒラタキクイムシ加害ナラ辺材ではさ
み込んで、温度27±１℃、湿度70±５％で飼育
し、２ケ月後食害状況を前記と同様に観察し、第
３表の如き結果を得た。[Table] Example 2 10 pieces each of oak sapwood (1 cm x 5 cm x 10 cm) were treated in A to F in the same manner as in Example 1, and after air-drying for 20 days, they were treated with two pieces of oak sapwood that had been attacked by Japanese oak beetles. They were kept between the cages and reared at a temperature of 27±1°C and a humidity of 70±5%, and after two months, the feeding damage status was observed in the same manner as above, and the results shown in Table 3 were obtained.
【表】
以上の実施例により、２−メルカプトベンゾチ
アゾール及び／又はその塩を有効成分とする防虫
防蟻剤は木材に対して優れた効果を示すことが明
らかであり、また人体及び農作物等に対する或全
性が高く、従来の如く環境汚染等の問題を起さ
ず、種々の形態で手軽に適用することができる。[Table] From the above examples, it is clear that insect and termite repellents containing 2-mercaptobenzothiazole and/or its salt as an active ingredient exhibit excellent effects on wood, and are also effective against humans and agricultural products. It has high integrity, does not cause problems such as environmental pollution unlike conventional methods, and can be easily applied in various forms.
Claims (1)
ルカリ金属塩、アルカリ土金属塩、アンモニウム
塩、アミン塩から選ばれる１種以上の化合物を有
効成分として含有することを特徴とする木材用防
虫防蟻剤。1. An insect and termite agent for wood, comprising as an active ingredient one or more compounds selected from 2-mercaptobenzothiazole and its alkali metal salts, alkaline earth metal salts, ammonium salts, and amine salts.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1502379A JPS55108805A (en) | 1979-02-14 | 1979-02-14 | Repellent for insect and termite |
| DE19792919792 DE2919792C2 (en) | 1978-05-19 | 1979-05-16 | Wood preservatives |
| GB7917185A GB2025769B (en) | 1978-05-19 | 1979-05-17 | Wood preservative composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1502379A JPS55108805A (en) | 1979-02-14 | 1979-02-14 | Repellent for insect and termite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS55108805A JPS55108805A (en) | 1980-08-21 |
| JPS6118521B2 true JPS6118521B2 (en) | 1986-05-13 |
Family
ID=11877239
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1502379A Granted JPS55108805A (en) | 1978-05-19 | 1979-02-14 | Repellent for insect and termite |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS55108805A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5798303A (en) * | 1980-12-12 | 1982-06-18 | Sanyo Wood Preserving | Conservative agent for wood |
| JP7236067B2 (en) * | 2018-06-22 | 2023-03-09 | 早川ゴム株式会社 | Pyrethroid-free anti-termite material and method for producing the same |
-
1979
- 1979-02-14 JP JP1502379A patent/JPS55108805A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS55108805A (en) | 1980-08-21 |
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