JPS61127392A - Image receiver for sublimable transfer - Google Patents
Image receiver for sublimable transferInfo
- Publication number
- JPS61127392A JPS61127392A JP59250832A JP25083284A JPS61127392A JP S61127392 A JPS61127392 A JP S61127392A JP 59250832 A JP59250832 A JP 59250832A JP 25083284 A JP25083284 A JP 25083284A JP S61127392 A JPS61127392 A JP S61127392A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- resin layer
- resins
- thermoplastic resin
- base material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/41—Base layers supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- B41M5/5281—Polyurethanes or polyureas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/529—Macromolecular coatings characterised by the use of fluorine- or silicon-containing organic compounds
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は昇華型熱転写記録に用いられる昇華転写用受像
体に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a sublimation transfer image receptor used in sublimation type thermal transfer recording.
従来の技術
熱転写による感熱記録方法の中で特に昇華性染料を用い
た昇華型ＰＡ伝伝力方式、優れた中間調の記録を得るこ
とができる。Among the conventional thermal recording methods using thermal transfer, the sublimation type PA transmission method using a sublimable dye is particularly capable of obtaining excellent halftone recording.
この記録に用いられる受像体としては、昇華性染料に対
して強い染着性を示す熱可塑性のポリエステル樹脂が主
に用いられている。しかし、上記樹脂は耐熱性が低いた
め記録時に転写体（カラーシート）と融着する。そのた
めに従来、上記樹脂の代わりに耐熱性結着剤、ラジカル
重合性の樹脂と熱可塑性樹脂を混合した組成物層（例え
ば、特開昭５８−２１２９９４．同５８−２１５３９８
）。The image receptor used for this recording is mainly made of thermoplastic polyester resin, which exhibits strong dyeability with sublimable dyes. However, since the above resin has low heat resistance, it fuses with the transfer body (color sheet) during recording. For this purpose, conventionally, instead of the above-mentioned resin, a composition layer containing a mixture of a heat-resistant binder, a radically polymerizable resin, and a thermoplastic resin (for example, JP-A-58-212994, JP-A-58-215398)
).
ポリエステル樹脂と顔料を混合した組成物層（例えば、
特開昭５ａ−１９７０８９）等からなる染着層を有する
受像体が提案されている。A composition layer containing a mixture of polyester resin and pigment (for example,
An image receptor having a dyed layer made of JP-A-5A-197089) has been proposed.
発明が解決しようとする問題点
しかし、従来用いられている受像体は熱融着を解決する
代償として、記録濃度（染着性）が低下する問題がある
。すなわち、耐熱性結着剤はそれ自身の染着性が低い。Problems to be Solved by the Invention However, conventionally used image receptors have a problem in that the recording density (dyeability) decreases at the cost of solving the problem of heat fusion. That is, the heat-resistant binder itself has low dyeability.
またポリエステル樹脂に、ラジカル重合性樹脂あるいは
顔料等の発色性の低い（又は発色性のない）異物を混合
することにより染着性が低下する。本発明は熱融着かな
く、かつ記録濃度の高い受像体を得ることを目的とする
。Furthermore, when a foreign substance having low coloring property (or no coloring property) such as a radically polymerizable resin or a pigment is mixed with the polyester resin, the dyeability is reduced. An object of the present invention is to obtain an image receptor that is free from heat fusion and has a high recording density.
問題点を解決するための手段
基材上に昇華性染料に対して染着性を有する熱可塑性樹
脂層を設け、さらに前記熱可塑性惇・ｆ刷上に硬化性樹
脂の硬化樹脂層を設ける。Means for Solving the Problems A thermoplastic resin layer having dyeability to sublimable dyes is provided on the base material, and a cured resin layer of a curable resin is further provided on the thermoplastic resin.
作 用
表面に設けた硬化樹脂層の耐熱性により融着が防止され
る。The heat resistance of the cured resin layer provided on the working surface prevents fusion.
１だ、実験の結果、染着性の低い樹脂層が染着性の高い
樹脂層の上にあるにもかかわらず、染料が硬化樹脂層を
通過して染着性の強い樹脂層まで到達し、硬化樹脂層に
よる記録濃度の低下はほとんどないため、高い記録濃度
が得られることが判明した。1. As a result of the experiment, even though the resin layer with low dyeability is on top of the resin layer with high dyeability, the dye passes through the cured resin layer and reaches the resin layer with strong dyeability. It has been found that high recording density can be obtained because there is almost no decrease in recording density due to the cured resin layer.
実施例
図に本発明の一実施例を示す。基材１上に熱可塑性樹脂
層２があり、さらにその上に硬化樹脂層３がある。An embodiment of the present invention is shown in the drawings. A thermoplastic resin layer 2 is disposed on a base material 1, and a cured resin layer 3 is further disposed on the thermoplastic resin layer 2.
基材は特に限定されるものでなく、セルロース紙１合成
紙、高分子フィルム（シートフ、塗工厭（塗工フィルム
）等を用いることができる。特に表面平滑性の優れた紙
２合成紙、ポリプロピレン。The base material is not particularly limited, and cellulose paper (1) synthetic paper, polymer film (sheet, coated film), etc. can be used. Paper (2) has particularly excellent surface smoothness, synthetic paper, polypropylene.
ポリエチレンテレフタレート等が良好な画質を与えるた
め有用である。Polyethylene terephthalate and the like are useful because they provide good image quality.
熱可塑性樹脂は昇華性染料に対し染着性を示す樹脂であ
れば特に限定されるものでなく、例えば、ポリエステル
系樹脂、アクリル系樹脂、エポキシ系樹脂、ナイロン系
樹脂等を用いることができる。The thermoplastic resin is not particularly limited as long as it exhibits dyeability with sublimation dyes, and for example, polyester resins, acrylic resins, epoxy resins, nylon resins, etc. can be used.
硬化性樹脂は、熱、波動エネルギー、あるいは粒子線硬
化性樹脂である。The curable resin is heat, wave energy, or particle beam curable resin.
例えば、各種エポキン樹脂、ンリコーン樹脂。For example, various Epoquine resins and Nuricorn resins.
フェノール樹脂、キシレン樹脂、ユリアｍ脂、メラミン
樹脂、不飽和ポリエステル樹脂、アルキド樹脂、７ラン
樹脂、オリゴアクリレート、アクリレートモノマー等が
ある。Examples include phenol resin, xylene resin, urea resin, melamine resin, unsaturated polyester resin, alkyd resin, 7-run resin, oligoacrylate, acrylate monomer, and the like.
特にオリゴアクリレートとして、例えば、ポリオールア
クリレート、ポリエステルアクリレート。Particularly as oligoacrylates, for example polyol acrylates, polyester acrylates.
エポキンアクリレート、ウレタンアクリレート。Epoquin acrylate, urethane acrylate.
シリコーンアクリレート、ポリアセタールのアクリレー
ト等がある。There are silicone acrylates, polyacetal acrylates, etc.
オリゴアクリレートには、テトラヒドロフルフリルアク
リレート、ジエチレングリコールジメタクリレート等の
アクリレートモノマーを添加して用いることもできる。Acrylate monomers such as tetrahydrofurfuryl acrylate and diethylene glycol dimethacrylate can also be added to the oligoacrylate.
オリゴアクリレートは放射ａあるいはべ／シイルバーオ
キサイド等の硬化触媒、ベンゾフェノン等の増感剤を用
いて加熱あるいは紫外線により硬化させて用いることが
できる。The oligoacrylate can be used by being cured by heating or ultraviolet rays using a curing catalyst such as radiation a or silver peroxide, and a sensitizer such as benzophenone.
エポキシ樹脂の中でも環状樹脂族エポキシ樹脂は、テト
ラエチレンペンタミン等の硬化剤を用いて熱硬化あるい
は芳香族ジアゾニウム塩、芳香族ヨードニウム塩、芳香
族スルホニウム塩等の重合開始剤を用いて紫外線硬（１
，させて使用することができ、耐熱性に優れているため
有用である。例えば、ビニルシクロヘキセンジオキシド
、３．４−エポキシ−６−メチルシクロヘキシルメチル
−３゜４−エポキシ−６−メチルシクロヘキサンカルホ
キ／レイト、３．４−エポキンシクロヘキシルメチル−
３，４−エポキシシクロヘキサンカルボキシレイト等が
ある。Among epoxy resins, cyclic resin epoxy resins are cured by heat using a curing agent such as tetraethylenepentamine, or by UV curing using a polymerization initiator such as an aromatic diazonium salt, an aromatic iodonium salt, or an aromatic sulfonium salt. 1
It is useful because it can be used in various conditions and has excellent heat resistance. For example, vinylcyclohexene dioxide, 3.4-epoxy-6-methylcyclohexylmethyl-3.4-epoxy-6-methylcyclohexane carboxylate, 3.4-epoxy-6-methylcyclohexylmethyl-
Examples include 3,4-epoxycyclohexane carboxylate.
熱可塑性樹脂層、硬化樹脂層には界面活性剤。Surfactant in thermoplastic resin layer and cured resin layer.
各種微粒子等を必要に応じて添加することができる。Various fine particles and the like can be added as necessary.
又、熱可塑性樹脂に、メラミン樹脂、グリオキザール樹
脂、エポキシ樹脂等を架橋剤として添加して用いること
ができる。Further, melamine resin, glyoxal resin, epoxy resin, etc. can be added to the thermoplastic resin as a crosslinking agent.
なお、以上のような受１８体に対して、昇華性染料とし
ては、４００℃以下の温度で昇華あるいは蒸発を始める
染料を用いることができ、例えば、分散染料、塩基性染
料等がある。For the above-mentioned receiver 18, the sublimable dye may be a dye that starts to sublimate or evaporate at a temperature of 400° C. or lower, such as disperse dyes and basic dyes.
以下、具体的実施例を示す。Specific examples will be shown below.
（実施例１）
上質紙の片面に、水性ポリエステル樹脂〔パイロナール
ＭＤＩ２００．東洋紡績（株）〕を１１５重量部水を３
０重量部からなる塗工液をワイヤーバーで塗工し、厚さ
約５μｍの熱可塑性樹脂層を得た。(Example 1) Water-based polyester resin [Pyronal MDI200. 115 parts by weight of Toyobo Co., Ltd. 3 parts by weight of water
A coating liquid containing 0 parts by weight was applied using a wire bar to obtain a thermoplastic resin layer with a thickness of about 5 μm.
次にオリゴエステルアクリレート樹脂を８重量部、２−
ヒドロキシ−２−メチルグロピオフエンを０．４重量部
、シリコーン界面活性剤を０．１重量部、酢酸エチルを
６０重量部からなる塗工液を、上記熱可塑性樹脂層上に
塗工し、ドライヤーで乾燥後、１ＫＷの高圧水銀灯にて
硬化させ、厚さ１．５μｍの硬化樹脂層を得て受像体を
作製した。Next, 8 parts by weight of oligoester acrylate resin, 2-
Coating a coating liquid consisting of 0.4 parts by weight of hydroxy-2-methylgropiophene, 0.1 parts by weight of a silicone surfactant, and 60 parts by weight of ethyl acetate on the thermoplastic resin layer, After drying with a dryer, it was cured with a 1 KW high-pressure mercury lamp to obtain a cured resin layer with a thickness of 1.5 μm, thereby producing an image receptor.
次に、昇華性染料〔１，５−ビス（ｎ−エチルアミノ）
−４，８−ナフトキノン〕を５重量部、ボリカーボネー
トを５重量部、酸化チタンを４重量部、塩化メチレンを
１００重要部からなるインキを、厚さ１０μｍのポリイ
ミドフィルム上に塗工し転写体を作製した。Next, sublimable dye [1,5-bis(n-ethylamino)
An ink consisting of 5 parts by weight of -4,8-naphthoquinone], 5 parts by weight of polycarbonate, 4 parts by weight of titanium oxide, and 100 parts of methylene chloride was coated on a polyimide film with a thickness of 10 μm to form a transfer material. was created.
この転写体を用いて、上記受像体に以下のサーマルヘッ
ド記録条件で記録させた。Using this transfer member, recording was performed on the image receptor described above under the following thermal head recording conditions.
主および副走査の線密度 ゛ ４ドツト／鵡記 源 電
力 ： ０．７Ｗ／ドツトヘツドの加熱時
間 ＝ ２〜ｓｍｓ受像体は加熱時間８ｍｓまで
まったく転写体と融着せず、又、加熱時間８ｍｓで１．
６の高い記録濃度が得られた。Linear density of main and sub-scanning: 4 dots/min Source power: 0.7 W/dot Head heating time = 2 to sms The image receptor was not fused to the transfer body at all until the heating time was 8 ms, and even after the heating time was 8 ms, 1.
A high recording density of 6 was obtained.
（実施例２）
ポリプロピレン合成紙の片面に下記の塗工液１を塗工乾
燥後、さら忙この塗膜（厚さ１０μｍ）上に下記の塗工
液２を塗工し、６０℃で約１時間放置して硬化樹脂層（
厚さ０．６μｍ）を設は受像体を作製した。(Example 2) Coating liquid 1 below was coated on one side of polypropylene synthetic paper, and after drying, coating liquid 2 below was coated on this coating film (thickness 10 μm) and heated at 60°C to approx. Leave it for 1 hour to harden the resin layer (
An image receptor was prepared with a thickness of 0.6 μm.
塗工液１
バイロン−２００〔東洋紡績（株）〕 ・・・・・・６
６重量部塩化メチレン ・・・・・・・・・・・・
・・・・・・３ＯＮ量部塗工液２
エポキシ樹脂〔エピコー）８２８ニジエル化学（株）〕
・・・・・・・・・・・・・・・・・・１１０重量部硬
化剤トリエチレンテトラミン） ・・・・・・・・・・
・・１重量部ア セ ト ン ・・・・・・・・
・・・・・・・・・・５０重量部この受像体に実施例１
の転写体を用い、又、実施例１の記録条件にて記録させ
た結果、受像体は加熱時間８ｍｓ＋までまったく転写体
と融着せず、又、８ｍｇで１．６の高い記録濃度が得ら
れた。Coating liquid 1 Byron-200 [Toyobo Co., Ltd.] ・・・・・・6
6 parts by weight methylene chloride ・・・・・・・・・・・・
...3ON parts Coating liquid 2 Epoxy resin [Epicor] 828 Nigel Chemical Co., Ltd.]
・・・・・・・・・・・・・・・・・・110 parts by weight Curing agent triethylenetetramine) ・・・・・・・・・・・・
...1 part by weight acetone...
......50 parts by weight Example 1 to this image receptor
As a result of recording using the transfer body and under the recording conditions of Example 1, the image receptor did not fuse with the transfer body at all until the heating time was 8 ms+, and a high recording density of 1.6 was obtained with 8 mg. Ta.
（比較例１）
上質紙の片面に実施例１と同じ熱可塑性樹脂層（厚さ約
５μｍ）を設けて受像体を作製した。(Comparative Example 1) An image receptor was prepared by providing the same thermoplastic resin layer (thickness: about 5 μm) as in Example 1 on one side of high-quality paper.
この受像体と実施例１の転写体を用い実施例１の記録条
件にて記録させた結果、加熱時間３ｍ１Ｂで転写体と受
像体が融着した。As a result of recording under the recording conditions of Example 1 using this image receptor and the transfer body of Example 1, the transfer body and image receptor were fused together in a heating time of 3 m1B.
（比較例２）
上質紙の片面にパイロナールＭＤ１２００ｔ−４６重量
部、炭酸カルシウムを１５重量部、水を９０重量部から
なる塗工液をワイヤーバーで塗工し、厚さ約５μｍの染
着層金有する受像体を作製した。(Comparative Example 2) A coating solution consisting of 46 parts by weight of Pyronal MD 1200t, 15 parts by weight of calcium carbonate, and 90 parts by weight of water was applied to one side of high-quality paper using a wire bar to form a dyed layer with a thickness of about 5 μm. An image receptor containing gold was prepared.
比較例と同一条件で記録させた結果、この受像体は加熱
時間７ｍｓ と８ｍｇで少し融着を発生し、８ ｍ
Ｂの記録濃度は１．３であった。As a result of recording under the same conditions as the comparative example, this image receptor showed slight fusion at 7 ms heating time and 8 mg, and 8 m
The recording density of B was 1.3.
発明の効果
本発明は、熱融着を解決する代償に記録濃度が低下する
問題を、下層に染着性の熱可塑性樹脂層、上層に硬化樹
脂層を設ける構成によって解決し、その結果、熱融着が
なく、かつ記録濃度の高い受像体を得ることができる。Effects of the Invention The present invention solves the problem of reduced recording density at the cost of solving thermal adhesion by providing a dyeable thermoplastic resin layer as a lower layer and a hardening resin layer as an upper layer. It is possible to obtain an image receptor with no fusion and high recording density.
図は、本発明の一実施例である受像体の断面模式図であ
る。
１・・・・・・基材、２・・・・・・熱可塑性樹脂層、
３・・・・・・硬化樹脂層。The figure is a schematic cross-sectional view of an image receptor that is an embodiment of the present invention. 1...Base material, 2...Thermoplastic resin layer,
3... Cured resin layer.
Claims (1)
を有する熱可塑性樹脂層と、前記熱可塑性樹脂上に設け
た硬化性樹脂の硬化樹脂層とを備えた昇華転写用受像体
。For sublimation transfer, comprising a base material, a thermoplastic resin layer provided on the base material and having dyeability to a sublimable dye, and a cured resin layer of a curable resin provided on the thermoplastic resin. Image receptor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59250832A JPS61127392A (en) | 1984-11-28 | 1984-11-28 | Image receiver for sublimable transfer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59250832A JPS61127392A (en) | 1984-11-28 | 1984-11-28 | Image receiver for sublimable transfer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61127392A true JPS61127392A (en) | 1986-06-14 |
| JPH051150B2 JPH051150B2 (en) | 1993-01-07 |
Family
ID=17213683
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59250832A Granted JPS61127392A (en) | 1984-11-28 | 1984-11-28 | Image receiver for sublimable transfer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61127392A (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62173295A (en) * | 1986-01-27 | 1987-07-30 | Nisshinbo Ind Inc | Sublimation-type thermal transfer image-receiving paper |
| JPS62297183A (en) * | 1986-06-18 | 1987-12-24 | Nisshinbo Ind Inc | Sublimation type thermal transfer recording method and color sheet and image-receiving paper for use in said method |
| JPS6330293A (en) * | 1986-07-24 | 1988-02-08 | Nisshinbo Ind Inc | Sublimation type thermal transfer image receiving paper having protective layer |
| JPS6367189A (en) * | 1986-09-10 | 1988-03-25 | Mitsubishi Rayon Co Ltd | Recording material in sublimation thermal transfer recording system |
| JPS6374693A (en) * | 1986-09-18 | 1988-04-05 | Mitsubishi Rayon Co Ltd | Body to be recorded in sublimation-type thermal transfer recording method |
| JPS6374694A (en) * | 1986-09-18 | 1988-04-05 | Mitsubishi Rayon Co Ltd | Body to be recorded in sublimation-type thermal transfer recording method |
| JPS6442284A (en) * | 1987-08-11 | 1989-02-14 | Mitsubishi Rayon Co | Recording material for sublimation-type thermal transfer recording system |
| JPH01113289A (en) * | 1987-10-27 | 1989-05-01 | Kanzaki Paper Mfg Co Ltd | Image-receiving sheet for thermal transfer recording |
| JPH01202497A (en) * | 1988-02-09 | 1989-08-15 | Ricoh Co Ltd | Image-receiving medium for sublimation thermal transfer recording |
| US4939118A (en) * | 1988-06-15 | 1990-07-03 | Basf Aktiengesellschaft | Transfer of azo dyes having a pyridine coupling component |
| US4940692A (en) * | 1988-04-12 | 1990-07-10 | Basf Aktiengesellschaft | Transfer of dyes |
| JPH02279387A (en) * | 1989-04-21 | 1990-11-15 | Oji Paper Co Ltd | Dye thermal transfer image receiving sheet |
| JPH0349991A (en) * | 1989-07-18 | 1991-03-04 | Oji Paper Co Ltd | Dye thermal transfer image receiving sheet |
| US5037798A (en) * | 1988-05-31 | 1991-08-06 | Basf Aktiengesellschaft | Transfer of AZO dyes |
| US5101035A (en) * | 1989-08-26 | 1992-03-31 | Basf Aktiengesellschaft | Merocyanine-like thiazole dyes and thermal transfer thereof |
| US5151506A (en) * | 1989-08-16 | 1992-09-29 | Basf Aktiengesellschaft | Phenoneazo dyes |
| US5155089A (en) * | 1990-12-14 | 1992-10-13 | Basf Aktiengesellschaft | Anthraquinone dyes for thermal transfer printing |
| US5294484A (en) * | 1991-08-03 | 1994-03-15 | Sony Corporation | Polyvinyl aromatic carboxylic acid ester and video printing paper |
| US5312926A (en) * | 1990-03-30 | 1994-05-17 | Basf Aktiengesellschaft | Indonaphthol dyes and thermal transfer thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58177392A (en) * | 1982-04-10 | 1983-10-18 | Kanzaki Paper Mfg Co Ltd | Heat-sensitive recording medium and manufacture thereof |
| JPS58212994A (en) * | 1982-06-07 | 1983-12-10 | Sony Corp | Photographic paper for sublimation transfer type color hard copy |
| JPS59165688A (en) * | 1983-03-11 | 1984-09-18 | Shin Nisso Kako Co Ltd | Thermal transfer recording material |
-
1984
- 1984-11-28 JP JP59250832A patent/JPS61127392A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58177392A (en) * | 1982-04-10 | 1983-10-18 | Kanzaki Paper Mfg Co Ltd | Heat-sensitive recording medium and manufacture thereof |
| JPS58212994A (en) * | 1982-06-07 | 1983-12-10 | Sony Corp | Photographic paper for sublimation transfer type color hard copy |
| JPS59165688A (en) * | 1983-03-11 | 1984-09-18 | Shin Nisso Kako Co Ltd | Thermal transfer recording material |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62173295A (en) * | 1986-01-27 | 1987-07-30 | Nisshinbo Ind Inc | Sublimation-type thermal transfer image-receiving paper |
| JPH0548758B2 (en) * | 1986-01-27 | 1993-07-22 | Nisshin Spinning | |
| JPS62297183A (en) * | 1986-06-18 | 1987-12-24 | Nisshinbo Ind Inc | Sublimation type thermal transfer recording method and color sheet and image-receiving paper for use in said method |
| JPS6330293A (en) * | 1986-07-24 | 1988-02-08 | Nisshinbo Ind Inc | Sublimation type thermal transfer image receiving paper having protective layer |
| JPS6367189A (en) * | 1986-09-10 | 1988-03-25 | Mitsubishi Rayon Co Ltd | Recording material in sublimation thermal transfer recording system |
| JPS6374693A (en) * | 1986-09-18 | 1988-04-05 | Mitsubishi Rayon Co Ltd | Body to be recorded in sublimation-type thermal transfer recording method |
| JPS6374694A (en) * | 1986-09-18 | 1988-04-05 | Mitsubishi Rayon Co Ltd | Body to be recorded in sublimation-type thermal transfer recording method |
| JPS6442284A (en) * | 1987-08-11 | 1989-02-14 | Mitsubishi Rayon Co | Recording material for sublimation-type thermal transfer recording system |
| JPH01113289A (en) * | 1987-10-27 | 1989-05-01 | Kanzaki Paper Mfg Co Ltd | Image-receiving sheet for thermal transfer recording |
| JPH01202497A (en) * | 1988-02-09 | 1989-08-15 | Ricoh Co Ltd | Image-receiving medium for sublimation thermal transfer recording |
| US4940692A (en) * | 1988-04-12 | 1990-07-10 | Basf Aktiengesellschaft | Transfer of dyes |
| US5037798A (en) * | 1988-05-31 | 1991-08-06 | Basf Aktiengesellschaft | Transfer of AZO dyes |
| US4939118A (en) * | 1988-06-15 | 1990-07-03 | Basf Aktiengesellschaft | Transfer of azo dyes having a pyridine coupling component |
| JPH02279387A (en) * | 1989-04-21 | 1990-11-15 | Oji Paper Co Ltd | Dye thermal transfer image receiving sheet |
| JPH0349991A (en) * | 1989-07-18 | 1991-03-04 | Oji Paper Co Ltd | Dye thermal transfer image receiving sheet |
| US5151506A (en) * | 1989-08-16 | 1992-09-29 | Basf Aktiengesellschaft | Phenoneazo dyes |
| US5101035A (en) * | 1989-08-26 | 1992-03-31 | Basf Aktiengesellschaft | Merocyanine-like thiazole dyes and thermal transfer thereof |
| US5312926A (en) * | 1990-03-30 | 1994-05-17 | Basf Aktiengesellschaft | Indonaphthol dyes and thermal transfer thereof |
| US5155089A (en) * | 1990-12-14 | 1992-10-13 | Basf Aktiengesellschaft | Anthraquinone dyes for thermal transfer printing |
| US5294484A (en) * | 1991-08-03 | 1994-03-15 | Sony Corporation | Polyvinyl aromatic carboxylic acid ester and video printing paper |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH051150B2 (en) | 1993-01-07 |
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