JPS61104038A - Lightweight wear resistant member - Google Patents

Lightweight wear resistant member

Info

Publication number
JPS61104038A
JPS61104038A JP22640284A JP22640284A JPS61104038A JP S61104038 A JPS61104038 A JP S61104038A JP 22640284 A JP22640284 A JP 22640284A JP 22640284 A JP22640284 A JP 22640284A JP S61104038 A JPS61104038 A JP S61104038A
Authority
JP
Japan
Prior art keywords
dimensional network
wear
resistant member
lightweight
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP22640284A
Other languages
Japanese (ja)
Inventor
Mitsuo Nishimoto
西本 満夫
Teishiro Moriyasu
守安 禎四郎
Tetsuya Nishi
西 徹也
Kazuo Sawada
澤田 和夫
Shungo Konishi
小西 俊吾
Naoyuki Okubo
直幸 大久保
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Electric Industries Ltd
Original Assignee
Sumitomo Electric Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Electric Industries Ltd filed Critical Sumitomo Electric Industries Ltd
Priority to JP22640284A priority Critical patent/JPS61104038A/en
Publication of JPS61104038A publication Critical patent/JPS61104038A/en
Pending legal-status Critical Current

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  • Manufacture Of Alloys Or Alloy Compounds (AREA)

Abstract

PURPOSE:To obtain a lightweight wear resistant member having superior wear resistance and lubricity by incorporating an intermetallic Ni-Sn compound into an Ni-base metallic structure having a three-dimensional network structure and by filling an Al alloy into the voids in the metallic structure. CONSTITUTION:An Ni-base metallic structure having a three-dimensional network structure is coated with Ni and Sn and heat treated to form an Ni-base metallic structure contg. an intermetallic Ni-Sn compound and having a three- dimensional network structure. An Al alloy is filled into the voids in the metallic structure by casting under high pressure, and the structure is subjected to soln. heat treatment and heat treatment to manufacture a wear resistant member.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 この発明は摺動部品、**部品、軸受、エンジン部品な
どの材料として有用な軽量耐摩耗性部材に関するもので
ある。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a lightweight wear-resistant member useful as a material for sliding parts, ** parts, bearings, engine parts, etc.

〈従来の技術〉 摺動部品、摩擦部品、軸受などは耐熱衝撃性、耐腐食性
、耐摩耗性などの性質が要求される部品である。
<Prior Art> Sliding parts, friction parts, bearings, etc. are parts that require properties such as thermal shock resistance, corrosion resistance, and wear resistance.

従来、そのような部品の材料としては、Fe合金系やM
合金系が主として用いられており、またN合金と炭素繊
維や炭化けい素1帷などとの複合体の研究も進められて
いる。
Conventionally, materials for such parts include Fe alloys and M
Alloy systems are mainly used, and research is also progressing on composites of N alloys and carbon fibers, silicon carbide sheets, etc.

〈発明が解決しようとする問題点〉 上記の従来の材料のうち、F@合金系はそれ自体が重い
ため、装置全体が重くなること、また高速回転させるた
めには強度を十分に得なければならず、従って周辺部材
も重員増となるという問題があった。
<Problems to be solved by the invention> Among the conventional materials mentioned above, the F@alloy system is itself heavy, making the entire device heavy, and it is necessary to obtain sufficient strength to rotate at high speed. Therefore, there was a problem in that the weight of peripheral members also increased.

また、N合金系あるいはN合金と炭素繊維などとの複合
体は軽量という点では好ましいが一1耐摩耗性に劣るこ
とが難点とされ、この点の改良が求められている。
Further, although N-alloy systems or composites of N-alloys and carbon fibers are preferable in terms of their light weight, they have a disadvantage of poor wear resistance, and improvements in this respect are desired.

く問題点を解決するための手段〉 この発明は上記に鑑みて、軽量でしかも耐摩耗性にすぐ
れる部材を得るべく検討の結果、得られたものであって
、陳を主成分とする三次元網状構造の金属構造体中に少
なくともNiとSnの金属間化合物を含有せしめるとと
もに、この構造体に存在する空隙にAlを主成分とする
合金を充lE′せしめた構造を有する部材とすることに
よって耐摩耗性と同時にrRift性にも効果のある軽
量耐摩耗性部材°を得るに至ったものである。
Means for Solving the Problems In view of the above, this invention was obtained as a result of studies to obtain a member that is lightweight and has excellent wear resistance. To obtain a member having a structure in which at least an intermetallic compound of Ni and Sn is contained in a metal structure having an original network structure, and the voids existing in this structure are filled with an alloy mainly composed of Al. This has led to the creation of a lightweight wear-resistant member that is effective in both wear resistance and r-lift performance.

〈作  用〉 この発明の軽量耐摩耗性部材の構造は第1図乃至第3図
にミクロ的に示す通りであるが、それらの構造を部材全
体に有する必要はなく、この軽量耐摩耗性部材の摺動が
予想される部位だけにそのような構造をとりつるよう、
予めN合金鋳造前に必要な部位に必要な量の三次元網状
の金属構造体を配しておけばよい。
<Function> The structure of the lightweight wear-resistant member of the present invention is as shown microscopically in FIGS. In order to install such a structure only in areas where sliding is expected,
The required amount of three-dimensional mesh metal structures may be placed in advance at the required locations before N alloy casting.

く実 施 例〉 次に、この発明を実施例により説明する。Example of implementation Next, the present invention will be explained using examples.

実施例1 ウレタン系発泡樹脂の表面にカーボン等を被覆して導電
処理をしたのち、Niの三次元網状構造体を生成せしめ
た。
Example 1 The surface of a urethane foam resin was coated with carbon or the like to conductivity treatment, and then a three-dimensional network structure of Ni was generated.

次いで、この構造体を N= C1□ 6H202509/ IIS++Cf 
2 2HaO50? /免NHやHら     sot
/l ”HCf(32%)   8牙/吏 の配合のI) H2,5のめっき液にて浴温65℃、電
流密度0.3A/d代てNiとSnを被覆し、次いでh
u熱処理してNiと3霜の金属間化合物を含有するN、
の三次元網状構造体を得た。
Then, convert this structure to N= C1□ 6H202509/IIS++Cf
2 2HaO50? /Men NH and H et al.
Ni and Sn were coated with a H2.5 plating solution at a bath temperature of 65°C and a current density of 0.3 A/d, and then h
u Heat treated N containing Ni and 3 frost intermetallic compounds,
A three-dimensional network structure was obtained.

その後、この構造体にAC4G組成のN合金を1000
ICI!4の高圧下に鋳造して、前記構造体の空隙部に
N合金を充填し、次いで510℃×8時間の溶体処理と
160℃で約6時間の加熱処理をして耐摩耗性部材を作
製した。
After that, 1000% of N alloy of AC4G composition was applied to this structure.
ICI! 4, the voids of the structure were filled with N alloy, followed by solution treatment at 510°C for 8 hours and heat treatment at 160°C for about 6 hours to produce a wear-resistant member. did.

この実施例で得られた部材の組織構造は第1図に示すも
のであり、1がNiとSnの金属間化合物7(図示せず
)を含有するNiの三次元網状構造体であり、2はその
空隙に充填されているN合金である。
The structure of the member obtained in this example is shown in FIG. 1, where 1 is a three-dimensional network structure of Ni containing an intermetallic compound 7 of Ni and Sn (not shown), and 2 is the N alloy filling the void.

実施例2 実施例1と同様にして、第2図Aに示すようにNiとS
nの金属間化合物7(図示せず)を含有する限を主成分
とする三次元網状構造体1を作製し、さらにこの構造体
骨格部分の外層にN(層3をめっきにて被覆したのち、
AC4G組成のN合金を高圧下に鋳造して該構造体の空
隙部に充填した。第2図Bの2が充填したN合金層であ
る。
Example 2 In the same manner as in Example 1, Ni and S were prepared as shown in FIG. 2A.
A three-dimensional network structure 1 mainly containing an intermetallic compound 7 (not shown) of ,
N alloy of AC4G composition was cast under high pressure and filled into the voids of the structure. 2 in FIG. 2B is the filled N alloy layer.

その後、510℃より焼入れ、160℃で加熱処理して
さきに構造体外層にめっき被覆したNi層をN合金と反
応させてNとNiを主成分とする金属間化合物4を構造
体内に生成せしめた。
Thereafter, the Ni layer plated on the outer layer of the structure was reacted with the N alloy by quenching at 510° C. and heat treated at 160° C. to form an intermetallic compound 4 containing N and Ni as main components inside the structure. Ta.

実施例3 第3図Aの組織構造体のNiを1体とする三次元網状構
造体5を溶融Sn浴に短時間浸し、該構造体の骨格部外
周に構造体の表面に有する多孔が埋まらない程度にSl
めっぎ層6を設けたのち、S++の融点温度で加熱処理
して前記N1の二次元網状構造体の骨格部表面に第3図
Bの如< NiとSnよりなる金属間化合物7を生成せ
しめ、この後AC4G組成のN合金を高圧で鋳造し、該
構造体の空隙に第3図CのようにN合金2を充填した。
Example 3 The three-dimensional network structure 5 of the tissue structure shown in FIG. Sl to the extent that
After providing the plating layer 6, heat treatment is performed at the melting point temperature of S++ to form an intermetallic compound 7 made of Ni and Sn as shown in FIG. 3B on the surface of the skeleton of the two-dimensional network structure of N1. After that, N alloy of AC4G composition was cast under high pressure, and the voids of the structure were filled with N alloy 2 as shown in FIG. 3C.

これを520″Cより焼入れ、170℃で加熱保持処理
し、NiとSnの金属化合物のはかNiとMの金属間化
合物4をも構造体内に分布させた。
This was quenched at 520''C and heated and held at 170°C to distribute an intermetallic compound 4 of Ni and M, which is a metallic compound of Ni and Sn, in the structure.

以上実施例1〜3で得られたこの発明の耐摩耗部材を、
比較量としてのA040組成のN鋳物(比較例1)およ
びAC8AC10Mu物(比較例2)とともに大越式耐
摩耗試験機にてIg!糺テステストない、その結果を比
較例1の摩耗量を1とした時の比で示した。
The wear-resistant members of the present invention obtained in Examples 1 to 3 above were
Ig! using an Okoshi type wear resistance tester with N castings of A040 composition (Comparative Example 1) and AC8AC10Mu products (Comparative Example 2) as comparative quantities. The results are shown as a ratio when the wear amount of Comparative Example 1 is set to 1.

第  1  表 く効  果〉 上表から、この発明の耐摩耗性部材は摩耗比が比較例よ
り非常に低く、すぐれた耐摩耗性を示していることが認
められた。
Table 1: Effects> From the table above, it was recognized that the wear-resistant member of the present invention had a much lower wear ratio than the comparative example, indicating excellent wear resistance.

このように、この発明の耐摩耗性部材は軽量であり、耐
摩耗性を特に要求される部分のみにこれを施すことがで
きるほか、NiとSnの金属間化合物が高硬度でかつ自
己01滑性を有しているため、特に耐摩耗性を向上させ
ることができる。なおかつNiとSnの金属間化合物と
NiとNの金属間化合物を共存させることによりこの耐
摩耗性を著しく向上させることができるのである。
As described above, the wear-resistant member of the present invention is lightweight and can be applied only to areas where wear resistance is particularly required. Since it has properties, wear resistance can be particularly improved. Furthermore, this wear resistance can be significantly improved by coexisting an intermetallic compound of Ni and Sn and an intermetallic compound of Ni and N.

そして、このような特性を有する耐摩耗性部材は摺動耐
摩耗性部材、エンジン部品、軸受などに用いることがで
きる。
A wear-resistant member having such characteristics can be used for sliding wear-resistant members, engine parts, bearings, and the like.

【図面の簡単な説明】[Brief explanation of drawings]

第1図乃至第3図は何れもこの発明の耐摩耗性部材の組
織構造を示す模式図である。 1.5・・・Niを主成分とする三次元網状構造体2・
・・N合金層  3・・・Niめつき層4・・・Niど
Nの金属間化合物層 6・・・Snめっき層
FIGS. 1 to 3 are all schematic diagrams showing the structure of the wear-resistant member of the present invention. 1.5...Three-dimensional network structure mainly composed of Ni 2.
...N alloy layer 3...Ni plating layer 4...Ni and N intermetallic compound layer 6...Sn plating layer

Claims (4)

【特許請求の範囲】[Claims] (1)Niを主成分とする三次元網状構造の金属構造体
中に少なくともNiとSnの金属間化合物を含有せしめ
るとともに、この構造体に存在する空隙にAlを主成分
とする合金を充填せしめた構造を有する軽量耐摩耗性部
材。
(1) At least an intermetallic compound of Ni and Sn is contained in a metal structure with a three-dimensional network structure mainly composed of Ni, and the voids existing in this structure are filled with an alloy mainly composed of Al. A lightweight, wear-resistant member with a durable structure.
(2)Niを主成分とする三次元網状構造の金属構造体
中にNiとSnの金属間化合物とともに、さらにNiと
Alよりなる金属間化合物を含有せしめた特許請求の範
囲第1項記載の軽量耐摩耗性部材。
(2) A three-dimensional network structure metal structure mainly composed of Ni contains an intermetallic compound of Ni and Sn as well as an intermetallic compound of Ni and Al. Lightweight and wear-resistant material.
(3)Niを主成分とする三次元網状構造の金属構造体
はその骨格の外周にNi層を有する特許請求の範囲第1
項または第2項記載の軽量耐摩耗性部材。
(3) A metal structure having a three-dimensional network structure mainly composed of Ni has a Ni layer on the outer periphery of its skeleton.
The lightweight wear-resistant member according to item 1 or 2.
(4)Niを主成分とする三次元網状構造の金属構造体
は、その骨格の外周にSn層を有する特許請求の範囲第
1項ないし第3項の何れかの項に記載の軽量耐摩耗性部
材。
(4) The lightweight and wear-resistant metal structure according to any one of claims 1 to 3, wherein the metal structure with a three-dimensional network structure mainly composed of Ni has a Sn layer on the outer periphery of its skeleton. sexual parts.
JP22640284A 1984-10-27 1984-10-27 Lightweight wear resistant member Pending JPS61104038A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22640284A JPS61104038A (en) 1984-10-27 1984-10-27 Lightweight wear resistant member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22640284A JPS61104038A (en) 1984-10-27 1984-10-27 Lightweight wear resistant member

Publications (1)

Publication Number Publication Date
JPS61104038A true JPS61104038A (en) 1986-05-22

Family

ID=16844556

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22640284A Pending JPS61104038A (en) 1984-10-27 1984-10-27 Lightweight wear resistant member

Country Status (1)

Country Link
JP (1) JPS61104038A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012124012A (en) * 2010-12-08 2012-06-28 Sumitomo Electric Ind Ltd Method for manufacturing porous structure of metal having high corrosion resistance
JP2012132083A (en) * 2010-12-24 2012-07-12 Sumitomo Electric Ind Ltd Metallic porous body having high corrosion resistance, and method for manufacturing therefor
US10164262B2 (en) 2010-12-08 2018-12-25 Sumitomo Electric Industries, Ltd. Method for producing a porous metal body

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012124012A (en) * 2010-12-08 2012-06-28 Sumitomo Electric Ind Ltd Method for manufacturing porous structure of metal having high corrosion resistance
US10164262B2 (en) 2010-12-08 2018-12-25 Sumitomo Electric Industries, Ltd. Method for producing a porous metal body
JP2012132083A (en) * 2010-12-24 2012-07-12 Sumitomo Electric Ind Ltd Metallic porous body having high corrosion resistance, and method for manufacturing therefor

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