JPS6065069A - Black pigment - Google Patents
Black pigmentInfo
- Publication number
- JPS6065069A JPS6065069A JP17287383A JP17287383A JPS6065069A JP S6065069 A JPS6065069 A JP S6065069A JP 17287383 A JP17287383 A JP 17287383A JP 17287383 A JP17287383 A JP 17287383A JP S6065069 A JPS6065069 A JP S6065069A
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- powder
- pressure
- black
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
Abstract
Description
【発明の詳細な説明】
本発明は黒色の色調を有する酸窒化チタン粉末に関する
。 黒色顔料としては現在カーボンブラック粉末と四三
酸化鉄粉末がある。カーボンブラック粉末は黒色度、着
色力ともに優れているが、樹脂とのなじみが悪い、嵩が
極めて大きいので取扱いがむつかしい、また極微量では
あるが、製造方法によっては原料から来る発癌性の３，
４−ベンズピレンを伴なうため、その安全性が問題とな
っている。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a titanium oxynitride powder having a black tone. Currently, black pigments include carbon black powder and triiron tetroxide powder. Carbon black powder has excellent blackness and coloring power, but it does not mix well with resin, is extremely bulky and difficult to handle, and, although in very small amounts, may contain carcinogenic substances derived from raw materials depending on the manufacturing method.
Since it involves 4-benzpyrene, its safety has become an issue.
また、他の顔料に比らべ、比表面積がはるかに大きいた
め、他の顔料と混合して用いると、不均一な分散になり
やすいなどの欠点がある。Furthermore, since it has a much larger specific surface area than other pigments, it has drawbacks such as non-uniform dispersion when mixed with other pigments.
四三酸化鉄粉末は、磁性による凝集があり、分散性に劣
る。耐熱性も劣り、大気中１５０℃付近で茶色の γ−
Ｆｅ２Ｏ３へ酸化される。Triiron tetroxide powder has agglomeration due to magnetism and has poor dispersibility. It also has poor heat resistance and turns brown at around 150℃ in the atmosphere.
Oxidized to Fe2O3.
他の黒色顔料としては低次酸化チタン粉末” ’％ Ｏ
ｈ＞−１（１４ｎ≦１０）がある、これは二酸化チタン
粉末をＴｉ粉末またはＨ２ガスにより１０００℃以上の
温度で還元して得られるが、焼結、粒子成長が著しく、
顔料用としては不適な粗大粒子（１，０ｐｍ以上）とな
ってしまうという基本的な問題がある。Other black pigments include low-order titanium oxide powder"'%O
h>-1 (14n≦10), which is obtained by reducing titanium dioxide powder with Ti powder or H2 gas at a temperature of 1000°C or higher, but sintering and particle growth are significant.
There is a fundamental problem in that the particles become coarse particles (1.0 pm or more) that are unsuitable for use as pigments.
木発明者等は二酸化チタンをアンモニアと反応させると
、酸窒化物が得られ、この物は、組成の変化に従って、
黒色、黒褐色、青黒色、紫黒色、青灰色にわたって、変
化し、白色顔料の二酸化チタン粉末と同様に、従来の黒
色顔料の欠点とする樹脂とのなじみ、分散性、耐熱性、
安全性に優れている。また、製造条件によって、比表面
積をも変化させることができる。When the inventors reacted titanium dioxide with ammonia, they obtained an oxynitride, which, as the composition changed,
It varies from black, blackish brown, blue-black, purple-black, and blue-gray, and like the white pigment titanium dioxide powder, the disadvantages of conventional black pigments are compatibility with resin, dispersibility, heat resistance,
Excellent safety. Further, the specific surface area can also be changed depending on the manufacturing conditions.
本発明によれば、酸素４〜３５ｗｔ％、窒素２〜２０ｗ
ｔ％（０／Ｎ重量比１５〜０．２）を含有する黒色酸窒
化チタン粉末が提供される。According to the present invention, 4 to 35 wt% oxygen, 2 to 20 wt% nitrogen
A black titanium oxynitride powder containing t% (0/N weight ratio 15-0.2) is provided.
本発明の顔料粉末は、色調着色力ともに優れている。ま
た前記のように製造条件を変えることにより、青、紫、
茶、等の色調を有する黒色粉末が得られる。The pigment powder of the present invention has excellent color tone and coloring power. In addition, by changing the manufacturing conditions as mentioned above, blue, purple,
A black powder having a color tone such as brown is obtained.
特に有害物質を含まないので、飲食品用プラスチックの
着色材、化粧基材として好適である。In particular, since it does not contain any harmful substances, it is suitable as a coloring agent for plastics for food and beverages and as a base material for cosmetics.
また導電性（１０〜１０’Ωｃｍ）を示し、導電材とし
ての用途もある。It also exhibits electrical conductivity (10 to 10' Ωcm) and is used as a conductive material.
本発明の酸窒化チタンの酸素、窒素の含有量は反応の温
度、時間、ＮＨ３流量、ＮＨ３圧力、等によって変化す
る。The content of oxygen and nitrogen in the titanium oxynitride of the present invention varies depending on the reaction temperature, time, NH3 flow rate, NH3 pressure, etc.
反応温度は５５０°Ｃ〜９５０℃ の範囲が好ましく、
５００℃ 未満では反応が進まず、青灰色となる。９５
０℃を越すと粉末の焼結が著しくなり、粒子が粗大化し
、顔料特性が低下する０反応時間は、温度、ＮＨ３流量
、ＮＨ３の圧力については、常圧でも、充分に反応が進
行し、黒色粉末が得られるが、２〜３ ｋｇ／ ｃ ｍ
２Ｇに加圧することによって、反応速度は大きくなり、
しかも、窒素含有量が増加するため、黒色度の大きな粉
末が得られた。The reaction temperature is preferably in the range of 550°C to 950°C,
If the temperature is lower than 500°C, the reaction will not proceed and the color will turn blue-gray. 95
If the temperature exceeds 0°C, sintering of the powder will become significant, the particles will become coarse, and the pigment properties will deteriorate.At 0 reaction time, the reaction will proceed sufficiently even under normal pressure with regard to temperature, NH3 flow rate, and NH3 pressure. A black powder is obtained, 2-3 kg/cm
By pressurizing to 2G, the reaction rate increases,
Moreover, since the nitrogen content increased, a powder with a high degree of blackness was obtained.
原料となる二酸化チタン粉末については、粒子が小さい
（比表面積が大きい）はど、処理時間は短く、黒色度の
大きい粉末となった。Regarding the titanium dioxide powder used as the raw material, the smaller the particles (the larger the specific surface area), the shorter the processing time, and the resulting powder had a higher degree of blackness.
還元の生成物は立方晶系計ＮａＣ文型のみ、もしくは、
立方晶系ＮａＣｕ型と正方晶系ルチル型または（アナタ
ーゼ型も一部含む）複合体からなっている。The product of reduction is only the cubic NaC pattern, or
It consists of a cubic NaCu type, a tetragonal rutile type, or a composite (including some anatase types).
実施例１
攪拌羽を有する反応Ｐ（内経３０ ｃ ｍ 、高さ１３
０ ｃ ｍ）に二酸化チタン粉末（東北化学社製、商標
名ＴＣＡ５５５．比表面積９．４ｒｎ’／ｇ（平均粒子
径０．１６１Ｌｍ）４ｋｇを装入し、ＮＨ３ガスを炉内
線速度３Ｃ騰／ｓｅｃで流し、１５ｒｐｍの攪拌速度で
攪拌しながら、炉内温度温度８００８Ｃで６時間の反応
を行った。 回収した粉末は３．１ｋｇであり、紫黒色
を呈していた。黒色度はＬ値（スガ試験機（株）社製カ
ラコンピューター５Ｍ−３で測色）１２．比表面積は９
．０ｍ″／ｇ（平均粒子径０ 、２１Ｌｍ）であった、
また、酸素と窒素の含有はそれぞれＯ：’２０ｗｔ％、
Ｎ：１３ｗｔ％で、Ｘ線回折によれば、正方晶系／立方
晶系の強度比は、１／２０であった。Example 1 Reaction P with stirring blade (inner diameter 30 cm, height 13
0 cm) was charged with 4 kg of titanium dioxide powder (manufactured by Tohoku Kagaku Co., Ltd., trade name: TCA555. Specific surface area: 9.4 rn'/g (average particle diameter: 0.161 Lm), and NH3 gas was heated at a linear velocity of 3 C/sec in the furnace. The reaction was carried out for 6 hours at a furnace temperature of 8008 C while stirring at a stirring speed of 15 rpm.The recovered powder weighed 3.1 kg and had a purple-black color.The degree of blackness was determined by the L value (Suga Color measurement using Color Computer 5M-3 manufactured by Shikenki Co., Ltd.) 12. Specific surface area is 9
．． 0 m''/g (average particle size 0, 21 Lm),
In addition, the content of oxygen and nitrogen is O: '20wt%, respectively.
According to X-ray diffraction, the intensity ratio of tetragonal system/cubic system was 1/20 at N: 13 wt%.
実施例２〜４
装置と二酸化チタン粉末は同じで、その他の反応条件を
変えて黒色粉末を得た。その結果を表１に示す。Examples 2 to 4 Black powder was obtained using the same apparatus and titanium dioxide powder, but changing other reaction conditions. The results are shown in Table 1.
実施例５〜６
実施例１と同じ装置を用い、比表面積４０ｒｎ”／ｇ（
平均粒径０．０４ＩＬｍ）の二酸化チタン粉末（帝国化
工社製、商標名ＭＴ−５００Ｂ）を反応条件を変えてア
ンモニアと反応させて黒色粉末を得た。その結果を表１
に示す。Examples 5 to 6 Using the same equipment as in Example 1, the specific surface area was 40 rn”/g (
Titanium dioxide powder (manufactured by Teikoku Kako Co., Ltd., trade name MT-500B) having an average particle size of 0.04 ILm was reacted with ammonia under different reaction conditions to obtain a black powder. Table 1 shows the results.
Shown below.
特許出願人 三菱金属株式会社 代理人 弁理士 松井政広Patent applicant Mitsubishi Metals Corporation Agent: Patent Attorney Masahiro Matsui
Claims (1)
重量比１５〜０．２）を含有する黒色酸窒化チタン粉末
。1. Oxygen 4-35wt%, nitrogen 2-20wt% (0/N
A black titanium oxynitride powder containing a weight ratio of 15 to 0.2).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17287383A JPS6065069A (en) | 1983-09-21 | 1983-09-21 | Black pigment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17287383A JPS6065069A (en) | 1983-09-21 | 1983-09-21 | Black pigment |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6065069A true JPS6065069A (en) | 1985-04-13 |
| JPH0351645B2 JPH0351645B2 (en) | 1991-08-07 |
Family
ID=15949883
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17287383A Granted JPS6065069A (en) | 1983-09-21 | 1983-09-21 | Black pigment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6065069A (en) |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60264313A (en) * | 1984-06-12 | 1985-12-27 | Teikoku Kako Kk | Production of titanium nitride powder |
| JPS6253915A (en) * | 1985-08-31 | 1987-03-09 | Pentel Kk | Black liquid cosmetic |
| JPS62179579A (en) * | 1986-01-31 | 1987-08-06 | Pentel Kk | Black pigment ink |
| JPS62260864A (en) * | 1986-05-07 | 1987-11-13 | Mitsubishi Metal Corp | Black pigment |
| WO2005037926A1 (en) * | 2003-10-15 | 2005-04-28 | Toray Industries, Inc. | Black composition, black coating composition, resin black matrix, color filter for liquid crystal display and liquid crystal display |
| JP2006182627A (en) * | 2004-12-28 | 2006-07-13 | Ishihara Sangyo Kaisha Ltd | Blackish titanium oxynitride |
| JP2008260927A (en) * | 2007-03-20 | 2008-10-30 | Toray Ind Inc | Black resin composition, resin black matrix, color filter, and liquid crystal display |
| JP2008266045A (en) * | 2007-04-17 | 2008-11-06 | Mitsubishi Materials Corp | High resistance black powder and its dispersed liquid, paint and black film |
| EP2103966A2 (en) | 2008-03-18 | 2009-09-23 | FUJIFILM Corporation | Photosensitive resin composition, light-shielding color filter, method of producing the same and solid-state image sensor |
| EP2105792A1 (en) | 2008-03-28 | 2009-09-30 | FUJIFILM Corporation | Photosensitive resin composition, light-shielding color filter and production process therefor, and image sensor |
| WO2009122789A1 (en) | 2008-03-31 | 2009-10-08 | 富士フイルム株式会社 | Polymerizable composition, light-blocking color filter for solid-state imaging device, and solid-state imaging device |
| EP2112182A1 (en) | 2008-04-25 | 2009-10-28 | FUJIFILM Corporation | Polymerizable composition, light-shielding color filter, black curable composition, light-shielding color filter for solid-state image pickup device and method of producing the same, and solid-state image pickup device |
| EP2120094A2 (en) | 2008-05-12 | 2009-11-18 | Fujifilm Corporation | Black photosensitive resin composition, and color filter and method of producing the same |
| EP2141206A1 (en) | 2008-06-30 | 2010-01-06 | FUJIFILM Corporation | Novel compound, polymerizable composition, color filter and production method thereof, solid-state imaging device, and planographic printing plate precursor |
| WO2010038836A1 (en) | 2008-10-03 | 2010-04-08 | 富士フイルム株式会社 | Dispersed composition, polymerizable composition, light shielding color filter, solid-state imaging element, liquid crystal display device, wafer-level lens, and imaging unit |
| EP2221665A2 (en) | 2009-02-19 | 2010-08-25 | Fujifilm Corporation | Dispersion composition, photosensitive resin composition for light- shielding color filter, light-shielding color filter, method of producing the same, and solid-state image sensor having the color filter |
| US7785501B2 (en) | 2004-12-28 | 2010-08-31 | Dai Nippon Printing Co., Ltd. | Black resin composition for display device, and member for display device |
| EP2302454A1 (en) | 2009-09-28 | 2011-03-30 | Fujifilm Corporation | Dispersion composition and method of producing the same, photosensitive resin composition and method of producing the same, light-shielding color filter and method of producing the same, and solid-state image sensor |
| WO2011092950A1 (en) | 2010-01-27 | 2011-08-04 | 富士フイルム株式会社 | Polymerizable composition for solder resist, and solder resist pattern formation method |
| EP2390272A1 (en) | 2010-05-31 | 2011-11-30 | FUJIFILM Corporation | Polymerizable composition, cured film, color filter, method of producing color filter and solid-state image sensor |
| WO2012015076A1 (en) | 2010-07-29 | 2012-02-02 | Fujifilm Corporation | Polymerizable composition |
| EP2472330A1 (en) | 2010-12-28 | 2012-07-04 | Fujifilm Corporation | Titanium black dispersion composition for forming light blocking film and method of producing the same, black radiation-sensitive composition, black cured film, solid-state imaging element, and method of producing black cured film |
| KR101240091B1 (en) * | 2004-12-28 | 2013-03-06 | 이시하라 산교 가부시끼가이샤 | Black titanium oxynitride |
| WO2014087901A1 (en) | 2012-12-03 | 2014-06-12 | 富士フイルム株式会社 | Ir-cut filter and manufacturing method thereof, solid state image pickup device, and light blocking film formation method |
| WO2014087900A1 (en) | 2012-12-03 | 2014-06-12 | 富士フイルム株式会社 | Solid-state image capture element retaining substrate and fabrication method therefor, and solid-state image capture device |
| WO2022210175A1 (en) | 2021-03-29 | 2022-10-06 | 富士フイルム株式会社 | Black photosensitive composition, manufacturing method of black photosensitive composition, cured film, color filter, light-shielding film, optical element, solid-state image capturing element, and headlight unit |
| US11561469B2 (en) | 2017-04-07 | 2023-01-24 | Showa Denko K.K. | Photosensitive resin composition |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5264350B2 (en) * | 2008-07-29 | 2013-08-14 | 三菱マテリアル株式会社 | Black titanium oxynitride powder and production method and use thereof |
| JP5264351B2 (en) * | 2008-07-29 | 2013-08-14 | 三菱マテリアル株式会社 | Black titanium oxynitride powder and production method and use thereof |
| WO2014181838A1 (en) * | 2013-05-09 | 2014-11-13 | 三菱マテリアル株式会社 | Black powder and method for producing same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56158836A (en) * | 1980-05-12 | 1981-12-07 | Matsushita Electric Ind Co Ltd | Electrically conductive material |
| JPS5891037A (en) * | 1981-11-27 | 1983-05-30 | Mitsubishi Metal Corp | Manufacture of titanium oxide powder |
-
1983
- 1983-09-21 JP JP17287383A patent/JPS6065069A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56158836A (en) * | 1980-05-12 | 1981-12-07 | Matsushita Electric Ind Co Ltd | Electrically conductive material |
| JPS5891037A (en) * | 1981-11-27 | 1983-05-30 | Mitsubishi Metal Corp | Manufacture of titanium oxide powder |
Cited By (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60264313A (en) * | 1984-06-12 | 1985-12-27 | Teikoku Kako Kk | Production of titanium nitride powder |
| JPH0525812B2 (en) * | 1984-06-12 | 1993-04-14 | Teikoku Kako Co Ltd | |
| JPS6253915A (en) * | 1985-08-31 | 1987-03-09 | Pentel Kk | Black liquid cosmetic |
| JPS62179579A (en) * | 1986-01-31 | 1987-08-06 | Pentel Kk | Black pigment ink |
| JPS62260864A (en) * | 1986-05-07 | 1987-11-13 | Mitsubishi Metal Corp | Black pigment |
| WO2005037926A1 (en) * | 2003-10-15 | 2005-04-28 | Toray Industries, Inc. | Black composition, black coating composition, resin black matrix, color filter for liquid crystal display and liquid crystal display |
| US8476351B2 (en) | 2003-10-15 | 2013-07-02 | Toray Industries, Inc. | Black composition, black coating composition, resin black matrix, color filter for liquid crystal display and liquid crystal display |
| JP2006182627A (en) * | 2004-12-28 | 2006-07-13 | Ishihara Sangyo Kaisha Ltd | Blackish titanium oxynitride |
| US7785501B2 (en) | 2004-12-28 | 2010-08-31 | Dai Nippon Printing Co., Ltd. | Black resin composition for display device, and member for display device |
| KR101240091B1 (en) * | 2004-12-28 | 2013-03-06 | 이시하라 산교 가부시끼가이샤 | Black titanium oxynitride |
| JP2008260927A (en) * | 2007-03-20 | 2008-10-30 | Toray Ind Inc | Black resin composition, resin black matrix, color filter, and liquid crystal display |
| JP2008266045A (en) * | 2007-04-17 | 2008-11-06 | Mitsubishi Materials Corp | High resistance black powder and its dispersed liquid, paint and black film |
| EP2204677A1 (en) | 2008-03-18 | 2010-07-07 | Fujifilm Corporation | Photosensitive resin composition, light-shielding color filter, method of producing the same and solid-state image sensor |
| EP2103966A2 (en) | 2008-03-18 | 2009-09-23 | FUJIFILM Corporation | Photosensitive resin composition, light-shielding color filter, method of producing the same and solid-state image sensor |
| EP2105792A1 (en) | 2008-03-28 | 2009-09-30 | FUJIFILM Corporation | Photosensitive resin composition, light-shielding color filter and production process therefor, and image sensor |
| WO2009122789A1 (en) | 2008-03-31 | 2009-10-08 | 富士フイルム株式会社 | Polymerizable composition, light-blocking color filter for solid-state imaging device, and solid-state imaging device |
| EP2112182A1 (en) | 2008-04-25 | 2009-10-28 | FUJIFILM Corporation | Polymerizable composition, light-shielding color filter, black curable composition, light-shielding color filter for solid-state image pickup device and method of producing the same, and solid-state image pickup device |
| EP2120094A2 (en) | 2008-05-12 | 2009-11-18 | Fujifilm Corporation | Black photosensitive resin composition, and color filter and method of producing the same |
| EP2141206A1 (en) | 2008-06-30 | 2010-01-06 | FUJIFILM Corporation | Novel compound, polymerizable composition, color filter and production method thereof, solid-state imaging device, and planographic printing plate precursor |
| WO2010038836A1 (en) | 2008-10-03 | 2010-04-08 | 富士フイルム株式会社 | Dispersed composition, polymerizable composition, light shielding color filter, solid-state imaging element, liquid crystal display device, wafer-level lens, and imaging unit |
| EP2221665A2 (en) | 2009-02-19 | 2010-08-25 | Fujifilm Corporation | Dispersion composition, photosensitive resin composition for light- shielding color filter, light-shielding color filter, method of producing the same, and solid-state image sensor having the color filter |
| EP2302454A1 (en) | 2009-09-28 | 2011-03-30 | Fujifilm Corporation | Dispersion composition and method of producing the same, photosensitive resin composition and method of producing the same, light-shielding color filter and method of producing the same, and solid-state image sensor |
| WO2011092950A1 (en) | 2010-01-27 | 2011-08-04 | 富士フイルム株式会社 | Polymerizable composition for solder resist, and solder resist pattern formation method |
| EP2390272A1 (en) | 2010-05-31 | 2011-11-30 | FUJIFILM Corporation | Polymerizable composition, cured film, color filter, method of producing color filter and solid-state image sensor |
| WO2012015076A1 (en) | 2010-07-29 | 2012-02-02 | Fujifilm Corporation | Polymerizable composition |
| EP2472330A1 (en) | 2010-12-28 | 2012-07-04 | Fujifilm Corporation | Titanium black dispersion composition for forming light blocking film and method of producing the same, black radiation-sensitive composition, black cured film, solid-state imaging element, and method of producing black cured film |
| WO2014087901A1 (en) | 2012-12-03 | 2014-06-12 | 富士フイルム株式会社 | Ir-cut filter and manufacturing method thereof, solid state image pickup device, and light blocking film formation method |
| WO2014087900A1 (en) | 2012-12-03 | 2014-06-12 | 富士フイルム株式会社 | Solid-state image capture element retaining substrate and fabrication method therefor, and solid-state image capture device |
| US11561469B2 (en) | 2017-04-07 | 2023-01-24 | Showa Denko K.K. | Photosensitive resin composition |
| WO2022210175A1 (en) | 2021-03-29 | 2022-10-06 | 富士フイルム株式会社 | Black photosensitive composition, manufacturing method of black photosensitive composition, cured film, color filter, light-shielding film, optical element, solid-state image capturing element, and headlight unit |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0351645B2 (en) | 1991-08-07 |
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