JPS6046457A - Humidity detector - Google Patents
Humidity detectorInfo
- Publication number
- JPS6046457A JPS6046457A JP15432483A JP15432483A JPS6046457A JP S6046457 A JPS6046457 A JP S6046457A JP 15432483 A JP15432483 A JP 15432483A JP 15432483 A JP15432483 A JP 15432483A JP S6046457 A JPS6046457 A JP S6046457A
- Authority
- JP
- Japan
- Prior art keywords
- humidity
- dew condensation
- substrate
- electrodes
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
- G01N27/125—Composition of the body, e.g. the composition of its sensitive layer
- G01N27/126—Composition of the body, e.g. the composition of its sensitive layer comprising organic polymers
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
- G01N27/121—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid for determining moisture content, e.g. humidity, of the fluid
Abstract
Description
【発明の詳細な説明】
(イ)産業上の利用分野
本発明は空調機の制御用信号として空調室内の湿度を検
出する湿度検出器に関する。DETAILED DESCRIPTION OF THE INVENTION (a) Field of Industrial Application The present invention relates to a humidity detector that detects humidity in an air conditioned room as a control signal for an air conditioner.
(ロ)従来技術
湿度検出器の感湿剤として金属酸化物を用いたもの、有
機系の高分子を用いたものがある。金属酸化物を用いた
湿度検出器は結露しても例えば1000以上の加熱クリ
ーニング操作により元の感湿抵抗体の湿度特性に戻すこ
とができる。(b) Conventional Humidity Sensors Some use metal oxides as moisture-sensing agents, while others use organic polymers. Even if a humidity sensor using a metal oxide has dew condensation, it can be restored to the original humidity characteristics of the humidity-sensitive resistor by, for example, 1000 or more heating cleaning operations.
しかしながら、有機系の高分子を用いた湿度検出器はこ
の感湿剤が水溶性である為結露状態となると基板面より
感湿剤が溶解し、て離脱し、湿度特性が変わる(感湿抵
抗値が大きい方向へ移行)欠点を有している。しかも、
結露状態で前述した通常の加熱クリーニングをしようと
しても高分子感湿剤は高熱に弱い為に劣化し、湿度特性
が大きく変化してしまう虞れがあった。However, in humidity sensors that use organic polymers, the moisture-sensitive agent is water-soluble, so when condensation occurs, the moisture-sensitive agent dissolves and separates from the substrate surface, changing the humidity characteristics (humidity-sensing resistance (shifting toward larger values) has a drawback. Moreover,
Even if the above-mentioned normal heating cleaning is attempted in a dew-condensed state, the polymer moisture sensitive agent is susceptible to high heat, so there is a risk that it will deteriorate and the humidity characteristics will change significantly.
(ハ)発明の目的
本発明は有機系高分子の感湿剤を結露状態から保護し、
且つ湿度特性の誤差を僅かに抑えた湿度検出器を提供す
るものである。(c) Purpose of the invention The present invention protects an organic polymer moisture sensitive agent from dew condensation,
In addition, the present invention provides a humidity detector in which errors in humidity characteristics are suppressed to a slight extent.
に)発明の構成
本発明は有機系高分子の感湿剤を電極間に塗布した基板
に、湿度が所定値以上の時に発熱して前記基板の温度を
僅かに上昇させる結露防止用の発熱体を設けて湿度検出
素子を構成したものである。B) Structure of the Invention The present invention provides a heating element for preventing dew condensation, which generates heat to slightly increase the temperature of the substrate when the humidity exceeds a predetermined value, on a substrate coated with an organic polymer moisture sensitive agent between electrodes. A humidity detection element is constructed by providing the following.
斯かる構成により、電極や感湿剤に結露が生じる直前の
高湿度(相対湿度90%以上)K達すると基板を発熱体
で加熱して電極の温度を空調室内の雰囲気温度よりも僅
かに高い温度状態に保持して電極の結露防止を図ると共
に高分子感湿剤の離脱も抑制して湿度特性の誤差を僅か
に抑えるようにしたものである。With this configuration, when a high humidity (relative humidity of 90% or more) K is reached just before dew condensation occurs on the electrodes and moisture sensitive material, the substrate is heated with a heating element to raise the temperature of the electrodes to slightly higher than the ambient temperature in the air-conditioned room. The temperature is maintained to prevent dew condensation on the electrodes, and the detachment of the polymeric desensitizer is also suppressed, thereby minimizing errors in humidity characteristics.
(ホ)実施例
一般に感湿剤として使用される有機系高分子材料として
、可動イオンがナトリウムイオン、カリウムイオン、水
素イオンであるアニオン系高分子材料と、可動イオンが
塩素イオン、臭素イオン等のハロゲンイオンであるカチ
オン系高分子材料と、ポリビニルアルコール等の吸湿し
易い高分子に塩化リチウム等の金属塩を加えたもの9.
とがある。(e) Examples Organic polymer materials generally used as moisture sensitive agents include anionic polymer materials whose mobile ions are sodium ions, potassium ions, and hydrogen ions, and anionic polymer materials whose mobile ions are chlorine ions, bromide ions, etc. 9. A cationic polymer material that is a halogen ion, a moisture-absorbing polymer such as polyvinyl alcohol, and a metal salt such as lithium chloride added.9.
There is.
以下本発明の実施例として、感湿剤にカチオン系高分子
材料を用いた場合について説明する。Hereinafter, as an example of the present invention, a case where a cationic polymer material is used as a moisture sensitive agent will be described.
第1図(イ)は湿度検出器の正面図、同図(ロ)は同検
出器の背面図で、アルミナ基板(1)の表面に印刷した
金製の櫛型電極(2)(21間にカチオン系導電剤モノ
マーであるメタクリルアミドプロピルトリメチルアンモ
ニウムクロライドと酢酸ビニルを1=2(モル比)で重
合して製造した感湿剤(3)が塗布され、アルミナ基板
(1)の背面には一般の電気ヒータからなる結露防止用
の発熱体(4)が埋設されている。Figure 1 (A) is a front view of the humidity detector, and Figure 1 (B) is a rear view of the same detector. A moisture sensitive agent (3) prepared by polymerizing methacrylamide propyltrimethylammonium chloride, which is a cationic conductive agent monomer, and vinyl acetate at a molar ratio of 1=2 (mole ratio) is coated on the back surface of the alumina substrate (1). A heating element (4) for preventing dew condensation consisting of a general electric heater is buried.
(5)(5)は電極(2)(2)から導出されこの電極
間の抵抗を測定する為の検出用リード線、(6)(6)
は空調室内の相対湿度が90%以上になると2200の
発熱体(4)に5Vの電圧を供給し、90%未満に低下
すると電圧の供給を停止する給電用リード線である。(5) (5) is a detection lead wire derived from the electrodes (2) (2) and used to measure the resistance between the electrodes, (6) (6)
is a power supply lead wire that supplies a voltage of 5V to the heating element (4) of 2200 when the relative humidity in the air conditioned room becomes 90% or more, and stops supplying the voltage when it drops below 90%.
而して、上述の如く構成された湿度検出器は最終的には
シリコンフェス中に浸漬後、乾燥させてシリコン薄膜で
被覆された状態で使用される。Thus, the humidity detector constructed as described above is finally used after being immersed in a silicone film, dried, and covered with a silicone thin film.
このようにして完成された本発明の湿度検出器と、発熱
体(4)のない従来の湿度検出器とを用いて同一雰囲気
の湿度−抵抗特性を測定した結果、第2図、第3図の特
性が得られた。The humidity-resistance characteristics of the same atmosphere were measured using the humidity detector of the present invention completed in this way and a conventional humidity detector without a heating element (4), and the results are shown in Figs. The following characteristics were obtained.
即ち、測定装置として底部に水を溜めた密閉容器の水面
上に本発明と従来の湿度検出器を夫々30日間静置させ
、I KHz4.5 Vの交流電圧を検出用リード線(
5)(5)に加えて湿度−抵抗特性を測定したもので、
第2図に示すように本発明による湿度検出器では相対湿
度が90%以上になった時発熱体(4)K通電して基板
(1)を加熱し、この熱伝導によって感湿剤(3)及び
電極(2)+2)を結露しない程度に温めた結果、(a
)初期特性、と比較して(b) 14日経過後の特性、
(c) 30日経過後の特性、は僅がづつ抵抗値の低い
方向へずれるものの初期特性と極めて近い特性を維持し
ていることが判明し、結露による影響が少ないことが裏
付けされた。That is, the humidity detector of the present invention and the conventional humidity detector were each left for 30 days on the water surface of a sealed container with water stored at the bottom as a measuring device, and an AC voltage of I KHz 4.5 V was connected to the detection lead wire (
5) In addition to (5), humidity-resistance characteristics were measured,
As shown in FIG. 2, in the humidity detector according to the present invention, when the relative humidity reaches 90% or more, the heating element (4) K is energized to heat the substrate (1), and the humidity sensitive agent (3) is ) and electrodes (2) + 2) to a degree that does not condense, (a
) initial characteristics, compared with (b) characteristics after 14 days,
(c) It was found that the characteristics after 30 days shifted slightly toward lower resistance values, but remained very close to the initial characteristics, proving that the influence of dew condensation was small.
これに対して、従来の湿度検出器では第3図に示すよう
K(a)初期特性、と比較して(b)14日経過後の特
性、(c) 30日経過後の特性は抵抗値の高い方向へ
大きくずれ、結露の影響を受けて大きな誤差が生じるこ
とが確認された。In contrast, with conventional humidity detectors, as shown in Figure 3, K (a) initial characteristics, (b) characteristics after 14 days, and (c) characteristics after 30 days have higher resistance values. It was confirmed that there was a large deviation in the direction and a large error occurred due to the influence of dew condensation.
(へ)発明の効果
不発BJ]Kよれば、湿度が所定値以上になると発熱体
で基板の温度を僅かに上昇させて感湿剤及び電極の結露
を防止するようKしたので、結露忙よる影響をはとんと
受けず、且つ僅かな温度上昇により感湿剤が劣化するこ
ともなく、湿度特性の誤差を小さく抑えることができる
。According to BJ] K, when the humidity exceeds a predetermined value, the temperature of the substrate is slightly raised by a heating element to prevent condensation on the moisture sensitive agent and electrodes, so that condensation does not occur. In addition, the moisture sensitive agent does not deteriorate due to a slight temperature rise, and errors in humidity characteristics can be suppressed to a small level.
しかも発熱体を基板に設けるだけで良く、且つ発熱体へ
の通電量も僅かで良い為低コストで済む等、実用上有益
である。In addition, the heating element only needs to be provided on the substrate, and the amount of current applied to the heating element is also small, so the cost can be reduced, which is advantageous in practical terms.
第1図は本発明の実施例を示し、同図(イ)は湿度検出
器の正面図、同図(ロ)は湿度検出器の背面図、第2図
は本発明の湿度検出器による相対湿度−抵抗特性図、第
3図は従来の湿度検出器による相対湿度−抵抗特性図で
ある。
(1)・・・基板、 (2)・・・電極、 (3)・・
・感湿剤、 (4)・・・発熱体。
出願人 三洋電機株式会社 外1名
代理人 弁理士 佐 野 静 夫
第1図
(イ) (り)
第2図
−袷xT三竪岨%ノFIG. 1 shows an embodiment of the present invention; FIG. 1A is a front view of the humidity detector, FIG. 2B is a rear view of the humidity detector, and FIG. Humidity-Resistance Characteristic Diagram FIG. 3 is a relative humidity-resistance characteristic diagram obtained by a conventional humidity detector. (1)...Substrate, (2)...Electrode, (3)...
- Moisture sensitive agent, (4)...Heating element. Applicant Sanyo Electric Co., Ltd. and one other representative Patent attorney Shizuo Sano Figure 1 (a) (ri) Figure 2 - 袷xT三田岨%ノ
Claims (1)
に、湿度が所定値以上の時に発熱して前記基板を温める
結露防止用の発熱体を設けて1よる湿度検出器。(1) A humidity detector comprising a substrate coated with an organic polymer moisture sensitive agent between electrodes, and a heating element for preventing dew condensation that generates heat to warm the substrate when the humidity exceeds a predetermined value.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15432483A JPS6046457A (en) | 1983-08-23 | 1983-08-23 | Humidity detector |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15432483A JPS6046457A (en) | 1983-08-23 | 1983-08-23 | Humidity detector |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS6046457A true JPS6046457A (en) | 1985-03-13 |
Family
ID=15581647
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15432483A Pending JPS6046457A (en) | 1983-08-23 | 1983-08-23 | Humidity detector |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6046457A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6163149U (en) * | 1984-10-01 | 1986-04-28 | ||
EP0371774A2 (en) * | 1988-11-29 | 1990-06-06 | Ngk Spark Plug Co., Ltd | A humidity measurement device by use of an electrochemical cell |
JPH0599877A (en) * | 1991-06-25 | 1993-04-23 | Yamatake Honeywell Co Ltd | Humidity sensing apparatus |
JPH05346415A (en) * | 1992-06-15 | 1993-12-27 | Daikin Ind Ltd | Humidity sensor |
JP2002039983A (en) * | 2000-07-21 | 2002-02-06 | Denso Corp | Humidity sensor |
WO2015194295A1 (en) * | 2014-06-16 | 2015-12-23 | アルプス電気株式会社 | Frost detector and frosting state detection device using said frost detector |
DE102017125265A1 (en) * | 2017-10-27 | 2019-05-02 | Phoenix Contact E-Mobility Gmbh | Charging plug and charging station for a motor vehicle |
-
1983
- 1983-08-23 JP JP15432483A patent/JPS6046457A/en active Pending
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6163149U (en) * | 1984-10-01 | 1986-04-28 | ||
EP0371774A2 (en) * | 1988-11-29 | 1990-06-06 | Ngk Spark Plug Co., Ltd | A humidity measurement device by use of an electrochemical cell |
JPH0599877A (en) * | 1991-06-25 | 1993-04-23 | Yamatake Honeywell Co Ltd | Humidity sensing apparatus |
JPH05346415A (en) * | 1992-06-15 | 1993-12-27 | Daikin Ind Ltd | Humidity sensor |
JP2002039983A (en) * | 2000-07-21 | 2002-02-06 | Denso Corp | Humidity sensor |
WO2015194295A1 (en) * | 2014-06-16 | 2015-12-23 | アルプス電気株式会社 | Frost detector and frosting state detection device using said frost detector |
DE102017125265A1 (en) * | 2017-10-27 | 2019-05-02 | Phoenix Contact E-Mobility Gmbh | Charging plug and charging station for a motor vehicle |
US11005221B2 (en) | 2017-10-27 | 2021-05-11 | Phoenix Contact E-Mobility Gmbh | Charging plug and charging station for a motor vehicle |
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