JPS6041002B2 - 過酸化水素の循環式製造方法 - Google Patents
過酸化水素の循環式製造方法Info
- Publication number
- JPS6041002B2 JPS6041002B2 JP56003305A JP330581A JPS6041002B2 JP S6041002 B2 JPS6041002 B2 JP S6041002B2 JP 56003305 A JP56003305 A JP 56003305A JP 330581 A JP330581 A JP 330581A JP S6041002 B2 JPS6041002 B2 JP S6041002B2
- Authority
- JP
- Japan
- Prior art keywords
- acid
- aqueous solution
- hydrogen peroxide
- alkali
- organophosphonic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims description 45
- 238000004519 manufacturing process Methods 0.000 title claims description 13
- 239000002253 acid Substances 0.000 claims description 38
- 238000000605 extraction Methods 0.000 claims description 23
- 239000007864 aqueous solution Substances 0.000 claims description 22
- 230000003647 oxidation Effects 0.000 claims description 20
- 238000007254 oxidation reaction Methods 0.000 claims description 20
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 229910017604 nitric acid Inorganic materials 0.000 claims description 13
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 9
- 229910002651 NO3 Inorganic materials 0.000 claims description 8
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- -1 quinone compound Chemical class 0.000 claims description 6
- 239000012224 working solution Substances 0.000 claims description 6
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 3
- 239000000243 solution Substances 0.000 description 23
- 229910052782 aluminium Inorganic materials 0.000 description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 20
- 238000005260 corrosion Methods 0.000 description 15
- 230000007797 corrosion Effects 0.000 description 15
- 150000007513 acids Chemical class 0.000 description 7
- 239000008346 aqueous phase Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000012074 organic phase Substances 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- XGFPOHQJFNFBKA-UHFFFAOYSA-B tetraaluminum;phosphonato phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O XGFPOHQJFNFBKA-UHFFFAOYSA-B 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 4
- 238000007086 side reaction Methods 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 3
- 235000011180 diphosphates Nutrition 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 229940048084 pyrophosphate Drugs 0.000 description 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 3
- 229940048086 sodium pyrophosphate Drugs 0.000 description 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 235000019820 disodium diphosphate Nutrition 0.000 description 2
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 2
- 229940038485 disodium pyrophosphate Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000000622 liquid--liquid extraction Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- PCFMUWBCZZUMRX-UHFFFAOYSA-N 9,10-Dihydroxyanthracene Chemical compound C1=CC=C2C(O)=C(C=CC=C3)C3=C(O)C2=C1 PCFMUWBCZZUMRX-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 210000005056 cell body Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 210000001061 forehead Anatomy 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229940085991 phosphate ion Drugs 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 238000003969 polarography Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/013—Separation; Purification; Concentration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8000707A FR2473488A1 (fr) | 1980-01-14 | 1980-01-14 | Procede cyclique de production de peroxyde d'hydrogene |
| FR8000707 | 1980-01-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56100106A JPS56100106A (en) | 1981-08-11 |
| JPS6041002B2 true JPS6041002B2 (ja) | 1985-09-13 |
Family
ID=9237501
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56003305A Expired JPS6041002B2 (ja) | 1980-01-14 | 1981-01-14 | 過酸化水素の循環式製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4606905A (show.php) |
| EP (1) | EP0032338B2 (show.php) |
| JP (1) | JPS6041002B2 (show.php) |
| DE (1) | DE3060763D1 (show.php) |
| ES (1) | ES8200622A1 (show.php) |
| FR (1) | FR2473488A1 (show.php) |
| OA (1) | OA06721A (show.php) |
| TR (1) | TR20862A (show.php) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE447895B (sv) * | 1983-06-13 | 1986-12-22 | Gnii Khim | Forfarande for framstellning av veteperoxid |
| BE1005199A3 (fr) * | 1991-08-27 | 1993-05-25 | Interox Internat Sa | Procede pour l'obtention de solutions aqueuses de peroxyde d'hydrogene. |
| US5495042A (en) * | 1993-11-04 | 1996-02-27 | Cytogen Corporation | Non-alkaline purification of aminophosphonic acids |
| FI97465C (fi) † | 1995-02-10 | 1996-12-27 | Kemira Chemicals Oy | Menetelmä vetyperoksidin valmistamiseksi |
| FR2730985B1 (fr) * | 1995-02-28 | 1997-08-01 | Chemoxal Sa | Procede et installation de production de peroxyde d'hydrogene |
| US20030095917A1 (en) * | 2001-07-27 | 2003-05-22 | Debra Wilcox | Chemical composition and process |
| EP1403219A1 (en) † | 2002-09-30 | 2004-03-31 | Degussa AG | Novel aqueous hydrogen peroxide solutions |
| US7722847B2 (en) | 2002-09-30 | 2010-05-25 | Evonik Degussa Gmbh | Aqueous hydrogen peroxide solutions and method of making same |
| US7459005B2 (en) * | 2002-11-22 | 2008-12-02 | Akzo Nobel N.V. | Chemical composition and method |
| US20080226541A1 (en) * | 2007-03-15 | 2008-09-18 | Fmc Corporation | Recovery of Aqueous Hydrogen Peroxide in Auto-Oxidation H2O2 Production |
| US10099924B2 (en) * | 2013-10-02 | 2018-10-16 | Solvay Sa | Process for manufacturing a purified aqueous hydrogen peroxide solution |
| WO2016114273A1 (ja) * | 2015-01-16 | 2016-07-21 | 三菱瓦斯化学株式会社 | 殺菌剤及びそれを用いた殺菌方法 |
| US9899765B2 (en) * | 2016-05-04 | 2018-02-20 | Sentinel Connector Systems, Inc. | Large conductor industrial plug |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1025798A (fr) * | 1950-03-09 | 1953-04-20 | Buffalo Electro Chem Co | Procédé pour la préparation du peroxyde d'hydrogène par hydrogénation cyclique et oxydation d'anthraquinones alcoylées |
| US2537516A (en) * | 1950-03-09 | 1951-01-09 | Buffalo Electro Chem Co | Process of producing hydrogen peroxide by the alternate reduction and oxidation of alkylated anthraquinones |
| US2782100A (en) * | 1951-01-13 | 1957-02-19 | Fmc Corp | Method of improving stability of concentrated hydrogen peroxide in contact with stainless steel and aluminum alloys |
| US2935381A (en) * | 1957-04-19 | 1960-05-03 | Fmc Corp | Manufacture of hydrogen peroxide |
| NL242785A (show.php) * | 1958-09-06 | 1900-01-01 | ||
| FR1405861A (fr) * | 1964-04-16 | 1965-07-16 | Oxysynthese | Perfectionnement au procédé cyclique de production d'eau oxygénée |
| US3387939A (en) * | 1966-07-06 | 1968-06-11 | Du Pont | Stannate stabilizer compositions containing an alkylidene diphosphonic acid, their preparation and hydrogen peroxide solutions stabilized therewith |
| US3477953A (en) * | 1966-11-29 | 1969-11-11 | Hooker Chemical Corp | Sequestration of metal ions with hydroxyalkyl phosphine oxides |
| BE756013A (fr) * | 1969-09-10 | 1971-02-15 | Degussa | Procede pour l'extraction de peroxyde d'hydrogene des solutionsde travail du procede a l'anthraquinone |
| US3903244A (en) * | 1973-02-02 | 1975-09-02 | Fmc Corp | Stabilized hydrogen peroxide |
| BE818616A (fr) * | 1973-08-30 | 1975-02-10 | Solutions aqueuses stabilisees de peroxyde d'hydrogene | |
| US4304762A (en) * | 1978-09-27 | 1981-12-08 | Lever Brothers Company | Stabilization of hydrogen peroxide |
-
1980
- 1980-01-14 FR FR8000707A patent/FR2473488A1/fr active Granted
- 1980-12-19 EP EP80401834A patent/EP0032338B2/fr not_active Expired
- 1980-12-19 DE DE8080401834T patent/DE3060763D1/de not_active Expired
-
1981
- 1981-01-07 US US06/223,115 patent/US4606905A/en not_active Expired - Lifetime
- 1981-01-13 TR TR20862A patent/TR20862A/xx unknown
- 1981-01-13 ES ES498467A patent/ES8200622A1/es not_active Expired
- 1981-01-14 OA OA57297A patent/OA06721A/xx unknown
- 1981-01-14 JP JP56003305A patent/JPS6041002B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES498467A0 (es) | 1981-11-01 |
| FR2473488A1 (fr) | 1981-07-17 |
| EP0032338B1 (fr) | 1982-08-11 |
| JPS56100106A (en) | 1981-08-11 |
| OA06721A (fr) | 1982-06-30 |
| EP0032338B2 (fr) | 1988-03-23 |
| DE3060763D1 (en) | 1982-10-07 |
| ES8200622A1 (es) | 1981-11-01 |
| FR2473488B1 (show.php) | 1983-07-22 |
| TR20862A (tr) | 1982-11-09 |
| EP0032338A1 (fr) | 1981-07-22 |
| US4606905A (en) | 1986-08-19 |
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