JPS603849A - Metal vapor discharge lamp - Google Patents

Metal vapor discharge lamp

Info

Publication number
JPS603849A
JPS603849A JP11095683A JP11095683A JPS603849A JP S603849 A JPS603849 A JP S603849A JP 11095683 A JP11095683 A JP 11095683A JP 11095683 A JP11095683 A JP 11095683A JP S603849 A JPS603849 A JP S603849A
Authority
JP
Japan
Prior art keywords
quartz
luminous tube
tube
discharge lamp
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11095683A
Other languages
Japanese (ja)
Inventor
Katsumi Takatsu
勝美 高津
Hisao Yoshiike
久夫 吉池
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Iwasaki Denki KK
Original Assignee
Iwasaki Denki KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Iwasaki Denki KK filed Critical Iwasaki Denki KK
Priority to JP11095683A priority Critical patent/JPS603849A/en
Publication of JPS603849A publication Critical patent/JPS603849A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J61/00Gas-discharge or vapour-discharge lamps
    • H01J61/82Lamps with high-pressure unconstricted discharge having a cold pressure > 400 Torr
    • H01J61/825High-pressure sodium lamps

Abstract

PURPOSE:To obtain a metal vapor discharge lamp with the low starting voltage and excellent light output life performance by providing a translucent film to prevent the reaction between metal halogenide and a quartz tube wall on the inner surface of a luminous tube except one portion. CONSTITUTION:Luminous metal halogenide, e.g., scandium, sodium, is sealed in a luminous tube 1 made of quartz together with a proper quantity of mercury and rare gas. In addition, a translucent film 3 mainly composed of aluminum phosphate, titanium oxide, aluminum oxide, etc. is formed on the inner surface of the luminous tube 1 made of quartz. A notch 4 to pass impure gas is provided at one portion of this translucent film 3. Accordingly, the reaction between the metal halogenide and quartz tube wall is suppressed by the translucent protective film 3 formed on the inner surface of the luminous tube, on the other hand, the impure gas entering during production, etc. permeates and diffuses outside the luminous tube through the notch 4 to be adsorbed by a getter material 7, thereby the impure gas concentration in the luminous tube is reduced, the starting voltage is lowered, and the light output life performance is improved.

Description

【発明の詳細な説明】 不発明け、水銀及び布ガスとともに金属ハロゲン化物を
封入した石英Xj(“(発光管の内L61に、金属ハロ
ゲン化物と石英管壁との反応を防止するための透光性被
膜を施しだ金属蒸気放電灯の改良に関する。
DETAILED DESCRIPTION OF THE INVENTION Uninvented, quartz Xj ("(L61 inside the arc tube) is made of quartz Xj sealed with a metal halide along with mercury and cloth gas to prevent a reaction between the metal halide and the quartz tube wall. This invention relates to improvements in metal vapor discharge lamps coated with metal coatings.

一51艮に、石英製発光管に金属ハロゲン化物を封入し
た/rk flj灯では、動作中に金属ハロゲン化物と
発光管材料である石英とが反応するため、発光金属の消
失や石英管壁への反応生成物の付着等によって光出力が
低下する。また、−り記反応により発光管内に放出され
たケイ素(Sl)が電極材旧のタングステンと低融点化
合物(合金)を形成し、′Rt44変形を引き起こした
りランプ電圧上昇をもたらす原因となっていた。
In a /rk flj lamp in which a metal halide is sealed in a quartz arc tube, the metal halide and quartz, which is the material of the arc tube, react with each other during operation, causing the luminescent metal to disappear or to the quartz tube wall. The light output decreases due to the adhesion of reaction products. In addition, silicon (Sl) released into the arc tube by the reaction described above forms a low melting point compound (alloy) with tungsten in the electrode material, causing 'Rt44 deformation and an increase in lamp voltage. .

そこで、上述のような金属ハロゲン化物と石英管壁との
反応を防止する目的で石英製発光管の内面に、金属リン
酸塩や金属ヒ酸塩からなる透光性被膜を施すことが提案
さilている。かかる透光性被膜は緻密で化学的にも安
定しており、とh−を施ずことによって、金属ノ・ロゲ
ン化物と石英管1i、τ′との反応はほぼ児全に防止き
れる。、ところが、かかる透光性被膜を施しメこ金4・
べ脂気放′T1i灯):f 、 41!’r I、て始
動特性や動程特性が低下するという事実が1′11明し
た。その原因を調べたところ、前記のような透光性被膜
は一般に水素ガス等の不純ガスを透過させないだめ、製
造時に発光管内に残存する小線ガスや金属ハロゲン化物
などとともに混入する不純ガスが、そのまま発光管内に
残留することに起因することがわかった。
Therefore, it has been proposed to apply a transparent coating made of metal phosphate or metal arsenate to the inner surface of the quartz arc tube in order to prevent the reaction between the metal halide and the quartz tube wall as described above. I'm here. Such a light-transmitting film is dense and chemically stable, and by adding h-, the reaction between the metal nologide and the quartz tube 1i, τ' can be almost completely prevented. However, when such a transparent coating was applied, Mekokin 4.
Fat air release 'T1i lamp): f, 41! It became clear in 1'11 that the starting characteristics and stroke characteristics deteriorate with 'r I. When we investigated the cause of this, we found that the above-mentioned translucent coating generally does not allow impurity gases such as hydrogen gas to pass through, and impurity gases that are mixed in with the small wire gas and metal halides that remain in the arc tube during manufacturing. It was found that this was caused by the particles remaining in the arc tube as they were.

本発明は、上述の欠点を除去するためになされたもので
、金属ハロゲン化物と石英管壁との反応を防止するとと
もに不純ガス等の影響が少なく始動特性の良好な金属蒸
気放電灯を提供することを目r灼とする。
The present invention has been made to eliminate the above-mentioned drawbacks, and provides a metal vapor discharge lamp which prevents the reaction between metal halides and the quartz tube wall, and which is less affected by impurity gases and has good starting characteristics. This is terrifying.

第1図は、本発明を実施した金属蒸気放電灯の△例を示
すもので、1はその両端に電極2a・2bを\ 寸Sしてなる石英製発光管である。この石英製発光管1
の内部には適量の水銀及び希ガスとともに、スカンジウ
ム、ナトリウム等の発光金属ハロゲン化物が封入し7で
ある。また、石英製発光管1の内面には、リン1′I(
アルミニウム、酸化チタン、酸化アルミニウム等を主成
分とする透光性被膜3が形成しである。との透光性被膜
3の一部、例えば発光管内面全体 を通過させるための切欠部4としである。石英製発光管
1の電極周辺の外表面には保温膜5a・5bが形成しで
ある。そして、この石英製発光管1は一対の支持導体6
a・6bによって外球7の内部に支持させである。8は
アルミニウム、ジルコニウム等を主成分とするゲッター
材である。
FIG. 1 shows an example of a metal vapor discharge lamp embodying the present invention, and numeral 1 is a quartz arc tube having electrodes 2a and 2b at both ends. This quartz arc tube 1
A light-emitting metal halide such as scandium or sodium is sealed inside the tube 7 along with an appropriate amount of mercury and a rare gas. Further, on the inner surface of the quartz arc tube 1, phosphorus 1'I (
A translucent coating 3 whose main component is aluminum, titanium oxide, aluminum oxide, etc. is formed. This is a notch 4 for passing a part of the light-transmitting coating 3, for example, the entire inner surface of the arc tube. Heat insulating films 5a and 5b are formed on the outer surface of the quartz arc tube 1 around the electrodes. This quartz arc tube 1 has a pair of supporting conductors 6.
It is supported inside the outer sphere 7 by a and 6b. 8 is a getter material whose main components are aluminum, zirconium, etc.

本発明における効果を従来の金属蒸気放f1;1灯の場
合と比較するため、本発明に係る上記のような放電灯(
へ)のほかに、発光管の内面に透光性被Pを全く設けな
い放電灯([3)、及び発光管の内面全体に透光性被膜
を設けた放電灯G)を用意しく何れも、の結果、発光管
内面に透光性被膜を設けない放電灯(B)においては、
点灯時間とともに始動屯IEは第2図03)のように変
化した。1ノこ光出力は約43.(100時間の点灯以
降急激に低下するものがあし、金属ハロゲン化物と石英
管壁との反応の根跡が認められた。
In order to compare the effects of the present invention with the conventional metal vapor discharge lamp f1;
In addition to [3], there are also discharge lamps ([3] in which no transparent coating P is provided on the inner surface of the arc tube, and discharge lamp G in which a transparent coating is provided on the entire inner surface of the arc tube). As a result, in the discharge lamp (B) without a transparent coating on the inner surface of the arc tube,
As the lighting time progressed, the starting tonnage IE changed as shown in Figure 2 03). The light output of one node is approximately 43. (After 100 hours of lighting, there was a sharp drop in the temperature, and evidence of a reaction between the metal halide and the quartz tube wall was observed.

また、発光管内面全体に透光性被膜を設けた放電灯(Q
では・始動1E圧id第2図((錘ように^′・″まま
 1であり、光出力も短時間のうちに著しく低下した。
In addition, a discharge lamp (Q
Then, the starting pressure 1E pressure id (Figure 2) remained at 1, and the light output decreased significantly within a short period of time.

これは、発光管内に混入した不純ガスが透光性被膜3に
より遮られて発光管外へ透過拡散しないために、始動電
圧を高めるとともに電極材料であるタングステンの酸化
−還元反応(水サイクル)を促進し、短時間のうちにタ
ングステンが管壁へ移動して光出力の減退を生じたもの
と推察される。
This is because the impure gas that has entered the arc tube is blocked by the transparent coating 3 and does not permeate and diffuse outside the arc tube, so the starting voltage is increased and the oxidation-reduction reaction (water cycle) of tungsten, which is the electrode material, is increased. It is presumed that the tungsten accelerated and moved to the tube wall within a short period of time, causing a decrease in optical output.

被膜3によって抑制される一方、製造時などに混入した
不純ガスは透光性被BIA3の切欠部4を通して発光管
外に透過拡R+ L、ゲッタ月7に吸着され■;r’、
 IE Ir、J第2し1広)のように変化し、光出力
動程も良好でA−1つだ なお、十に■1各)j、’l、 ’li1.月(A)、
出)、0の各点灯時間毎の発光’#f内の水素ガス8度
を水中捕集法にて分析・定tf) したところ第1表に
示すような結果となった。
While being suppressed by the coating 3, impurity gas mixed during manufacturing is transmitted through the notch 4 of the transparent coating BIA 3 to the outside of the arc tube R+L, and is adsorbed by the getter 7;
IE Ir, J 2nd and 1 wide), the optical output range is also good and A-1, and 10 to 1 each) j, 'l, 'li1. Moon (A),
When the hydrogen gas in the light emission '#f at 8 degrees Celsius was analyzed using an underwater collection method for each lighting time of 0) and 0, the results were as shown in Table 1.

第1表 (発光管内の水素ガス濃度(PPm) )本発
明によれば、発光管内面の一部を残して金属ハロゲン化
物と石英管壁の反応を防ぐ透光性被膜を付設しであるた
め ■金属ハロゲン化物と石英管壁との反応は、付設は、透
光性被膜の切欠部及び石英管壁を透過して外球内に付設
されたゲッタ月に吸着されるので、発光管内の不純ガス
濃度は下がる。
Table 1 (Hydrogen gas concentration in the arc tube (PPm)) According to the present invention, a part of the inner surface of the arc tube is provided with a transparent coating that prevents the reaction between the metal halide and the quartz tube wall. ■The reaction between the metal halide and the quartz tube wall is caused by the impurity inside the arc tube passing through the notch of the transparent coating and the quartz tube wall and being adsorbed by the getter attached to the outer sphere. Gas concentration decreases.

等の効果により、始動1[充圧が低く、光出力動程の良
好な金属蒸気放電灯が得られる。発光看゛内面に形成す
る透光性被膜の総面積は、封入する金絹ハロゲン化物の
稗頬やtf4によって異なり、実験で決定することが必
要であるが、少なくとも発光管の全内面積の約3イ以上
の大きさを必要とする。
As a result of the above effects, a metal vapor discharge lamp with low charging pressure and good light output range can be obtained. The total area of the transparent coating formed on the inner surface of the luminescent tube varies depending on the size of the gold silk halide and tf4 to be sealed, and must be determined experimentally, but it should be at least approximately the total internal area of the luminescent tube. Requires a size of 3 or more.

以上のように、本発明によ、hば、極めて1?11甲、
な手段により、始動1n、圧が低く、光出力jl!l 
fI!の良好な金属蒸気放電灯’c (!Jることがて
きるから、本発明の産業上利用価値は大きい。
As described above, according to the present invention, h is extremely 1 to 11 A,
By this means, the starting time is 1n, the pressure is low, and the light output is jl! l
fI! The present invention has great industrial utility value because it can be used as a metal vapor discharge lamp with good quality.

【図面の簡単な説明】 第1図は本発明を実施した金属蒸気放電灯の一部切欠側
面図、第2図は本発明に係る金FJ%蒸気放電灯と従来
の金属蒸気放電灯の始動電圧の変化曲線図である。 第1図
[Brief Description of the Drawings] Fig. 1 is a partially cutaway side view of a metal vapor discharge lamp embodying the present invention, and Fig. 2 is a starting-up of a gold FJ% vapor discharge lamp according to the present invention and a conventional metal vapor discharge lamp. It is a voltage change curve diagram. Figure 1

Claims (1)

【特許請求の範囲】[Claims] 水銀及び希ガスとともに金属ハロゲン化物を封入した石
英製発光管の内面に、金属ハロゲン化物と石英管壁上の
反応を防1トするための透光1生被膜を施した放電灯に
おいて、前期透光性破膜の一部を欠除ぜしめて発光管内
部からの不純ガスの透過□ を6易ならしめ/こことを
!1゛〒徴とする全絹地?気放也灯。
In a discharge lamp, a transparent coating is applied to the inner surface of a quartz arc tube in which a metal halide is sealed together with mercury and a rare gas to prevent a reaction between the metal halide and the quartz tube wall. Remove a part of the photosensitive membrane and make it easier for impure gas to pass through from inside the arc tube. 1. All silk fabric with a characteristic? Chi release and light.
JP11095683A 1983-06-22 1983-06-22 Metal vapor discharge lamp Pending JPS603849A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11095683A JPS603849A (en) 1983-06-22 1983-06-22 Metal vapor discharge lamp

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11095683A JPS603849A (en) 1983-06-22 1983-06-22 Metal vapor discharge lamp

Publications (1)

Publication Number Publication Date
JPS603849A true JPS603849A (en) 1985-01-10

Family

ID=14548787

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11095683A Pending JPS603849A (en) 1983-06-22 1983-06-22 Metal vapor discharge lamp

Country Status (1)

Country Link
JP (1) JPS603849A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5032757A (en) * 1990-03-05 1991-07-16 General Electric Company Protective metal halide film for high-pressure electrodeless discharge lamps
WO2002037533A3 (en) * 2000-10-31 2003-12-31 Gen Electric Novel materials and methods for application of conducting members on arc tubes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5032757A (en) * 1990-03-05 1991-07-16 General Electric Company Protective metal halide film for high-pressure electrodeless discharge lamps
WO2002037533A3 (en) * 2000-10-31 2003-12-31 Gen Electric Novel materials and methods for application of conducting members on arc tubes

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