JPS6027714B2 - 炭化水素の転化方法 - Google Patents
炭化水素の転化方法Info
- Publication number
- JPS6027714B2 JPS6027714B2 JP50039308A JP3930875A JPS6027714B2 JP S6027714 B2 JPS6027714 B2 JP S6027714B2 JP 50039308 A JP50039308 A JP 50039308A JP 3930875 A JP3930875 A JP 3930875A JP S6027714 B2 JPS6027714 B2 JP S6027714B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- catalysts
- pore volume
- volume
- quotient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 44
- 229930195733 hydrocarbon Natural products 0.000 title claims description 36
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 36
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 35
- 238000006243 chemical reaction Methods 0.000 title description 2
- 239000003054 catalyst Substances 0.000 claims description 363
- 239000011148 porous material Substances 0.000 claims description 58
- 238000006477 desulfuration reaction Methods 0.000 claims description 51
- 230000023556 desulfurization Effects 0.000 claims description 51
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 38
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- 229910052759 nickel Inorganic materials 0.000 claims description 19
- 230000000694 effects Effects 0.000 claims description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 17
- 229910052717 sulfur Inorganic materials 0.000 claims description 17
- 239000011593 sulfur Substances 0.000 claims description 17
- 230000003197 catalytic effect Effects 0.000 claims description 16
- 229910052720 vanadium Inorganic materials 0.000 claims description 12
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 150000002739 metals Chemical class 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000003921 oil Substances 0.000 description 70
- 238000002474 experimental method Methods 0.000 description 46
- 229910052739 hydrogen Inorganic materials 0.000 description 20
- 239000001257 hydrogen Substances 0.000 description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 18
- 239000000203 mixture Substances 0.000 description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 9
- 238000009826 distribution Methods 0.000 description 9
- 238000011068 loading method Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 229910052750 molybdenum Inorganic materials 0.000 description 8
- 239000011733 molybdenum Substances 0.000 description 8
- 239000010941 cobalt Substances 0.000 description 7
- 229910017052 cobalt Inorganic materials 0.000 description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
- 239000010779 crude oil Substances 0.000 description 7
- HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 description 7
- 238000004821 distillation Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 229910002651 NO3 Inorganic materials 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical group [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 150000001869 cobalt compounds Chemical class 0.000 description 2
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 125000000101 thioether group Chemical group 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 150000003658 tungsten compounds Chemical class 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241000692870 Inachis io Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- LXASOGUHMSNFCR-UHFFFAOYSA-D [V+5].[V+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O Chemical compound [V+5].[V+5].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O LXASOGUHMSNFCR-UHFFFAOYSA-D 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- -1 cobaltnomlybdenum Chemical compound 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- UAMZXLIURMNTHD-UHFFFAOYSA-N dialuminum;magnesium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Mg+2].[Al+3].[Al+3] UAMZXLIURMNTHD-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NLAANVRAGE7404948,A NL187641C (nl) | 1974-04-11 | 1974-04-11 | Werkwijze voor het katalytisch hydrogenerend ontzwavelen zonder katalysatorverversing van residuale koolwaterstofolien. |
| NL7404948 | 1974-04-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS50136302A JPS50136302A (no) | 1975-10-29 |
| JPS6027714B2 true JPS6027714B2 (ja) | 1985-07-01 |
Family
ID=19821155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50039308A Expired JPS6027714B2 (ja) | 1974-04-11 | 1975-04-02 | 炭化水素の転化方法 |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS6027714B2 (no) |
| BE (1) | BE827492A (no) |
| CA (1) | CA1060370A (no) |
| DE (1) | DE2512294A1 (no) |
| DK (1) | DK129375A (no) |
| ES (1) | ES435948A1 (no) |
| FR (1) | FR2267359B1 (no) |
| GB (1) | GB1504586A (no) |
| IT (1) | IT1034407B (no) |
| NL (1) | NL187641C (no) |
| NO (1) | NO144424C (no) |
| SE (1) | SE408431B (no) |
| ZA (1) | ZA751655B (no) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6215231U (no) * | 1985-07-11 | 1987-01-29 | ||
| JPH0311812U (no) * | 1989-06-21 | 1991-02-06 |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5492684A (en) * | 1993-07-06 | 1996-02-20 | Mobil Oil Corporation | Graded-bed system for improved separations |
| JP3802106B2 (ja) | 1995-06-08 | 2006-07-26 | 日本ケッチェン株式会社 | 炭化水素油の水素化処理触媒とその製造方法およびその活性化方法 |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US10655074B2 (en) | 2017-02-12 | 2020-05-19 | Mag{hacek over (e)}m{hacek over (a)} Technology LLC | Multi-stage process and device for reducing environmental contaminates in heavy marine fuel oil |
| US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
-
1974
- 1974-04-11 NL NLAANVRAGE7404948,A patent/NL187641C/xx not_active IP Right Cessation
-
1975
- 1975-02-24 CA CA220,643A patent/CA1060370A/en not_active Expired
- 1975-03-13 GB GB10508/75A patent/GB1504586A/en not_active Expired
- 1975-03-13 NO NO750853A patent/NO144424C/no unknown
- 1975-03-14 SE SE7502921A patent/SE408431B/xx not_active IP Right Cessation
- 1975-03-18 ZA ZA00751655A patent/ZA751655B/xx unknown
- 1975-03-18 IT IT21422/75A patent/IT1034407B/it active
- 1975-03-20 DE DE19752512294 patent/DE2512294A1/de active Granted
- 1975-03-24 ES ES435948A patent/ES435948A1/es not_active Expired
- 1975-03-26 DK DK129375A patent/DK129375A/da not_active IP Right Cessation
- 1975-03-26 FR FR7509481A patent/FR2267359B1/fr not_active Expired
- 1975-04-02 JP JP50039308A patent/JPS6027714B2/ja not_active Expired
- 1975-04-03 BE BE1006570A patent/BE827492A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6215231U (no) * | 1985-07-11 | 1987-01-29 | ||
| JPH0311812U (no) * | 1989-06-21 | 1991-02-06 |
Also Published As
| Publication number | Publication date |
|---|---|
| NO144424C (no) | 1981-08-26 |
| IT1034407B (it) | 1979-09-10 |
| SE408431B (sv) | 1979-06-11 |
| AU7921175A (en) | 1976-09-23 |
| BE827492A (nl) | 1975-10-03 |
| NO750853L (no) | 1975-10-14 |
| NO144424B (no) | 1981-05-18 |
| DE2512294C2 (no) | 1987-08-27 |
| NL7404948A (nl) | 1975-10-14 |
| DE2512294A1 (de) | 1975-10-23 |
| NL187641C (nl) | 1991-12-02 |
| DK129375A (no) | 1975-10-12 |
| NL187641B (nl) | 1991-07-01 |
| JPS50136302A (no) | 1975-10-29 |
| CA1060370A (en) | 1979-08-14 |
| SE7502921L (sv) | 1975-10-13 |
| FR2267359B1 (no) | 1982-03-19 |
| ES435948A1 (es) | 1976-12-16 |
| ZA751655B (en) | 1976-02-25 |
| FR2267359A1 (no) | 1975-11-07 |
| GB1504586A (en) | 1978-03-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR0183394B1 (ko) | 디젤 비점-범위 탄화수소 공급원료 내 방향족 탄화수소 및 황-함유 탄화수소의 수소화 방법 | |
| US4588709A (en) | Catalyst for removing sulfur and metal contaminants from heavy crudes and residues | |
| US2880171A (en) | Hydrodesulfurization of hydrocarbons with catalyst composed of molybdenum and two members of the iron group metals | |
| US3114701A (en) | Catalytic hydrodenitrification process | |
| US4374020A (en) | Catalytic hydroconversion process with catalyst retainer | |
| US3997473A (en) | Hydrodesulfurization catalysts supported on carbon | |
| US3814683A (en) | Hydrodesulfurization process with catalysts whose pore sizes are concentrated in a narrow range | |
| US4707246A (en) | Hydrotreating catalyst and process | |
| GB1580854A (en) | Catalyst and process for the hydro-desulphurisation of hydrocarbon feeds | |
| US2967204A (en) | Hydrogenation of aromatics with a tungsten and nickel sulfide, supported on alumina, catalyst composite | |
| EP0759964B1 (en) | Stacked bed catalyst system for deep hydrosulfurization | |
| US4098682A (en) | Hydrodesulfurization catalyst and method of preparation | |
| JPS6240059B2 (no) | ||
| US4318801A (en) | Supported nickel-molybdenum catalyst, preparation thereof, and hydrodesulfurization of hydrocarbon fractions using same | |
| JPH0555187B2 (no) | ||
| US4585751A (en) | Hydrotreating catalysts | |
| US4032435A (en) | Hydrodesulfurization of petroleum residuum utilizing a carbon-supported catalyst | |
| US4642179A (en) | Catalyst for removing sulfur and metal contaminants from heavy crudes and residues | |
| US3322666A (en) | Chemical process for hydrocracking and hydrorefining of hydrocarbon oils | |
| JPS6027714B2 (ja) | 炭化水素の転化方法 | |
| AU634428B2 (en) | Hydrodenitrification process | |
| EP0024199B1 (en) | Catalyst having low volume of large pores and hydrocarbon hydroconversion process using same | |
| JPS63289092A (ja) | 水素化精製法 | |
| EP0159097B1 (en) | Process for the catalytic conversion of heavy hydrocarbon oils | |
| US4399058A (en) | Impregnating solution for hydrogenation catalyst manufacture and production thereof |