JPS60258294A - 天然ガスの脱硫精製方法 - Google Patents
天然ガスの脱硫精製方法Info
- Publication number
- JPS60258294A JPS60258294A JP59113087A JP11308784A JPS60258294A JP S60258294 A JPS60258294 A JP S60258294A JP 59113087 A JP59113087 A JP 59113087A JP 11308784 A JP11308784 A JP 11308784A JP S60258294 A JPS60258294 A JP S60258294A
- Authority
- JP
- Japan
- Prior art keywords
- sulfur
- natural gas
- hydrogen sulfide
- gas
- dioxide gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 239000003345 natural gas Substances 0.000 title claims abstract description 54
- 238000006477 desulfuration reaction Methods 0.000 title claims description 12
- 230000023556 desulfurization Effects 0.000 title claims description 12
- 238000007670 refining Methods 0.000 title description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 72
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 59
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 57
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 57
- 239000007789 gas Substances 0.000 claims abstract description 51
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 45
- 239000011593 sulfur Substances 0.000 claims abstract description 45
- 238000000034 method Methods 0.000 claims abstract description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 24
- 239000001301 oxygen Substances 0.000 claims abstract description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000007809 chemical reaction catalyst Substances 0.000 claims abstract description 7
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 238000004064 recycling Methods 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 25
- 238000010521 absorption reaction Methods 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 14
- 238000005984 hydrogenation reaction Methods 0.000 claims description 8
- 150000003464 sulfur compounds Chemical class 0.000 claims description 8
- 238000000746 purification Methods 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 5
- 230000003009 desulfurizing effect Effects 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- 239000003463 adsorbent Substances 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 12
- 229930195733 hydrocarbon Natural products 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 238000002485 combustion reaction Methods 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 6
- 239000001569 carbon dioxide Substances 0.000 description 6
- 238000011084 recovery Methods 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 4
- 150000002898 organic sulfur compounds Chemical class 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000001172 regenerating effect Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- -1 CO3 and C32 Chemical class 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910003296 Ni-Mo Inorganic materials 0.000 description 1
- 241000286209 Phasianidae Species 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- NWJUARNXABNMDW-UHFFFAOYSA-N tungsten vanadium Chemical group [W]=[V] NWJUARNXABNMDW-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Treating Waste Gases (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59113087A JPS60258294A (ja) | 1984-06-04 | 1984-06-04 | 天然ガスの脱硫精製方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59113087A JPS60258294A (ja) | 1984-06-04 | 1984-06-04 | 天然ガスの脱硫精製方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60258294A true JPS60258294A (ja) | 1985-12-20 |
| JPH0428038B2 JPH0428038B2 (enrdf_load_html_response) | 1992-05-13 |
Family
ID=14603146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59113087A Granted JPS60258294A (ja) | 1984-06-04 | 1984-06-04 | 天然ガスの脱硫精製方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60258294A (enrdf_load_html_response) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991004941A1 (en) * | 1989-10-02 | 1991-04-18 | Research Triangle Institute | A method for producing elemental sulfur from sulfur-containing gases |
| US5366717A (en) * | 1989-10-02 | 1994-11-22 | Research Triangle Institute | Method for producing elemental sulfur from sulfur-containing gases |
| US5378441A (en) * | 1993-02-11 | 1995-01-03 | Union Oil Company Of California | Method to scavenge hydrogen sulfide from natural gas |
| US5798088A (en) * | 1993-03-30 | 1998-08-25 | Research Triangle Institute | Method for producing elemental sulfur from sulfur-containing gases |
| WO2002032810A1 (en) * | 2000-10-18 | 2002-04-25 | Jgc Corporation | Method and apparatus for removing sulfur compound in gas containing hydrogen sulfide, mercaptan, carbon dioxide and aromatic hydrocarbon |
| CN110093196A (zh) * | 2019-04-28 | 2019-08-06 | 西安长庆科技工程有限责任公司 | 一种低潜硫天然气站场脱硫方法 |
-
1984
- 1984-06-04 JP JP59113087A patent/JPS60258294A/ja active Granted
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991004941A1 (en) * | 1989-10-02 | 1991-04-18 | Research Triangle Institute | A method for producing elemental sulfur from sulfur-containing gases |
| US5366717A (en) * | 1989-10-02 | 1994-11-22 | Research Triangle Institute | Method for producing elemental sulfur from sulfur-containing gases |
| US5378441A (en) * | 1993-02-11 | 1995-01-03 | Union Oil Company Of California | Method to scavenge hydrogen sulfide from natural gas |
| US5798088A (en) * | 1993-03-30 | 1998-08-25 | Research Triangle Institute | Method for producing elemental sulfur from sulfur-containing gases |
| WO2002032810A1 (en) * | 2000-10-18 | 2002-04-25 | Jgc Corporation | Method and apparatus for removing sulfur compound in gas containing hydrogen sulfide, mercaptan, carbon dioxide and aromatic hydrocarbon |
| JPWO2002032810A1 (ja) * | 2000-10-18 | 2004-02-26 | 日揮株式会社 | 硫化水素、メルカプタン、炭酸ガス、芳香族炭化水素を含むガス中の硫黄化合物の除去方法およびその装置 |
| US6962680B1 (en) | 2000-10-18 | 2005-11-08 | Jgc Corporation | Method and apparatus for removing sulfur compound in gas containing hydrogen sulfide, mercaptans, carbon dioxide and aromatic hydrocarbon |
| CN110093196A (zh) * | 2019-04-28 | 2019-08-06 | 西安长庆科技工程有限责任公司 | 一种低潜硫天然气站场脱硫方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0428038B2 (enrdf_load_html_response) | 1992-05-13 |
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