JPS60248799A - Degradation-preventing and flavor-improving material for frying oil - Google Patents

Degradation-preventing and flavor-improving material for frying oil

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Publication number
JPS60248799A
JPS60248799A JP59104166A JP10416684A JPS60248799A JP S60248799 A JPS60248799 A JP S60248799A JP 59104166 A JP59104166 A JP 59104166A JP 10416684 A JP10416684 A JP 10416684A JP S60248799 A JPS60248799 A JP S60248799A
Authority
JP
Japan
Prior art keywords
oil
flavor
frying oil
frying
fried
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP59104166A
Other languages
Japanese (ja)
Inventor
岡本 好晴
鈴木 喜多郎
西尾 賢三
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP59104166A priority Critical patent/JPS60248799A/en
Publication of JPS60248799A publication Critical patent/JPS60248799A/en
Pending legal-status Critical Current

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  • General Preparation And Processing Of Foods (AREA)
  • Fats And Perfumes (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明は、揚げ油の劣化防止と風味の向上物に関するも
のである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a product that prevents deterioration of frying oil and improves its flavor.

近年は健康への配慮から、植物油がスナック菓子、ラー
メン、フライ揚、天ぷらなどに多量に消費されている。
In recent years, vegetable oil has been consumed in large quantities in snack foods, ramen, fried foods, tempura, etc. due to health considerations.

市販の油は精製脱臭のため原料筒中の天然酸化防止剤で
あるトコフェロール17ラボン誘導体、フェノール誘導
体が分離され、はんの微量しか含まれていないことは既
に知られている。この対策として、酸化防止剤や、クエ
ン酸を添加しているが、主に工場出荷時から利用者の使
用迄の期間の変質防止を主目的になされており、揚げ油
の加熱時の劣化については、一定時間の利用で、揚げ油
を廃棄する方法しか対策はない。
It is already known that commercially available oils contain only trace amounts of starch, as natural antioxidants such as tocopherol-17 labone derivatives and phenol derivatives in the raw material are separated for purification and deodorization. As a countermeasure for this, antioxidants and citric acid are added, but the main purpose is to prevent deterioration from the time of shipment from the factory until the time of use by the user. The only countermeasure is to dispose of the frying oil after using it for a certain period of time.

揚げ油の加熱温度は、揚げ物により決まる。一般に13
0〜270℃が揚げ物の行なわれる温度である。このよ
うな高温加熱状態で利用される揚げ油は、揚げ物の影響
と連続加熱により、短時間で油の着色、揚げ物の着色、
油の泡立ち、油の着実により、揚げ物の風味や物性値が
劣化し健康上からも好ましくない。
The heating temperature of frying oil is determined by the type of food being fried. generally 13
The temperature at which fried foods are carried out is 0 to 270°C. The frying oil that is used in such high-temperature heating conditions can quickly discolor the oil, discolor the fried food, and
The bubbling and solidity of the oil deteriorates the flavor and physical properties of fried foods, which is undesirable from a health standpoint.

本発明は、このような欠点を解消するために、麦飯石粉
末と香辛料を用いた揚げ油の劣化防止、風味の向上物を
提供するものである。
In order to eliminate these drawbacks, the present invention provides a product that prevents the deterioration of frying oil and improves its flavor by using maifan stone powder and spices.

なお、麦飯石は薬石として漢方、和漢薬に用いられてい
たが、近年、上水道井水の水質悪化がより一段と早くな
るにつれ、従来からの薬石としての観点を広げた利用法
として、水中の重金属、臭気、塩素イオン、色素の吸着
やミネラルの溶出、PHの中性化等の麦飯石の特徴を有
効に利用したミネラル水製造機が市販されている。
In addition, Maihan stone was used as a medicinal stone in Chinese medicine and Japanese and Chinese medicine, but in recent years, as the water quality of tap water well water has deteriorated more rapidly, it has been used as a medicinal stone in a way that has expanded its use as a medicinal stone. There are mineral water producing machines on the market that effectively utilize the characteristics of Maifan stone, such as odor, chlorine ions, adsorption of pigments, elution of minerals, and neutralization of pH.

さらに、種々の香辛料が利用されているが、その利用目
的は一般に調理前の下ごしらえと調理後の添加で、不快
臭のマスキングと香の向上である。
In addition, various spices are used, but their purpose is generally to mask unpleasant odors and improve flavor in preparation before cooking and addition after cooking.

この為に香辛料に含まれている油脂の酸化防止性を有す
ると考えられる成分は、水溶性、油溶性、揮発性と分か
れており、油溶性の成分は、利用されていなかった。ま
た使用温度範囲により有効成分の利用率が変動するが、
一般には低温度による低利用率であった。
For this reason, the components that are considered to have antioxidation properties for fats and oils contained in spices are divided into water-soluble, oil-soluble, and volatile components, and oil-soluble components have not been utilized. In addition, the utilization rate of the active ingredient varies depending on the usage temperature range,
In general, the utilization rate was low due to low temperature.

しかし香辛料だけを揚げ油に加えて、高温加熱調理を行
なうと、数分で揚げ油の着色が促進される欠陥があるが
、麦飯石粉末を同時に加えると、その色素吸着力により
欠陥を解決できた。
However, when only spices are added to frying oil and cooked at high temperatures, the coloring of the frying oil accelerates within a few minutes, but when maifan stone powder is added at the same time, this defect can be solved by its ability to absorb pigments.

て油が変色し、揚げ物に付着して、風味が著しく低下す
る欠陥が生じた。
The oil became discolored and adhered to fried foods, resulting in a defect in which the flavor was significantly reduced.

未発明は、以上の観点より、麦飯石粉末は、色素、臭気
の吸着イオン効換力、等の機構と、香辛料はこれに含ま
れる酸化防止成分を利用するようにした麦飯石粉末と香
辛料混合物を、目の細い通油性を持つ紙状の袋に入れる
事を特徴とした揚げ油の酸イヒ防止と風味の向上物を提
供するものである。
From the above point of view, what has not yet been invented is that Maifanstone powder is a mixture of Maifanstone powder and spices that utilizes mechanisms such as pigments and odor adsorption and ion exchange power, and that spices utilize the antioxidant components contained therein. The present invention provides a product that prevents frying oil from becoming sour and improves its flavor, by placing the oil in a thin-mesh, oil-permeable paper bag.

次に、揚げ油の抗酸化力および劣化試験を説明する。Next, the antioxidant power and deterioration test of frying oil will be explained.

揚げ油の劣化促進状態における、本発明物を市販のサラ
ダ油(ナタネ80%、大豆20%)を使い、揚げ物の標
準調理温度180℃で、劣化促進として室内空気を、油
100g当り1へ送気し、加熱時間は3時間連続で実施
した。
To accelerate the deterioration of frying oil, the present invention was prepared using commercially available salad oil (80% rapeseed, 20% soybean) at a standard cooking temperature for fried foods of 180°C, and indoor air was blown into the air at a rate of 1 per 100 g of oil to promote deterioration. The heating time was 3 hours continuously.

試験結果は、表の通りであり、添加物について説明すれ
ば ■の無添加は、油のみ加熱、■は麦飯石粉末を3g添加
、■は麦飯石粒径8〜1ONMを159添加、■は麦飯
粉末3gとクローズ0.511添加、■は麦飯石粉末3
gとナツメグ0.5 f、■は麦飯石粉末3fとセージ
o、s y、■は無添加で、未加熱の油を、そのまま測
定した。
The test results are as shown in the table, and to explain the additives, (■) without additives, only oil was heated, (■) added 3g of Maifan stone powder, (■) added 159 pieces of Maifan stone particle size 8 to 1 ONM, and (■) added 3g of barley powder and 0.511 added, ■ is barley stone powder 3
g, nutmeg 0.5 f, ■: maifan stone powder 3 f, sage o, sy, ■: additive-free, unheated oil was measured as it was.

酸価は、油脂中に含まれる、遊離脂肪酸を中和するのに
要する水酸化カリクムのq数で表わす。
The acid value is expressed by the q number of potassium hydroxide required to neutralize free fatty acids contained in fats and oils.

油の加熱により熱分解や加水分解で遊離脂肪酸が生成し
酸価は増加する。
When oil is heated, free fatty acids are generated through thermal decomposition and hydrolysis, and the acid value increases.

油に遊離脂肪酸が増加すると、着色や、発煙点及び保存
安定性が低下するので、油の風味が低下し、胸やけが起
きやすく、保存期間が短くなる。
Increased free fatty acids in oils cause discoloration, lower smoke points and storage stability, resulting in lower oil flavor, increased heartburn, and shorter shelf life.

酸価の試験結果は、■の無添加に比べ■の麦飯石粒を除
き、いずれも増加率が60%以下であり、40%の効果
が出た。
The acid value test results showed that the rate of increase was 60% or less in all cases, except for the maifan stone grains (■), compared to (■) without additives, indicating an effect of 40%.

麦飯石粉末と香辛料の2種混合物の■■■は■の麦飯石
粒より、増加率が低いだけではなく、添加量も4以下な
ので、効率は4倍以上となった。
The two-type mixture of maifan stone powder and spices ■■■ not only had a lower increase rate than the maifan stone grains (■), but also had an additive amount of less than 4, so the efficiency was more than 4 times higher.

化防止と風味向上に極めて好都合である。It is extremely convenient for preventing oxidation and improving flavor.

ヨウ素価は油脂中の不飽和酸の二重結合の数を示す数値
でヨウ素価が高い事は二重結合が多い事を表わす。
The iodine value is a numerical value that indicates the number of double bonds in unsaturated acids in fats and oils, and a high iodine value indicates that there are many double bonds.

油脂は加熱する事で熱酸化、加水分解が進み、油脂中の
二重結合が減少しヨウ素価が低下し、安定性も低下する
When fats and oils are heated, thermal oxidation and hydrolysis proceed, the double bonds in the fats and oils decrease, the iodine value decreases, and the stability also decreases.

ヨウ素価が低下すれば、酸化が進み、分子量の増加によ
シ油の粘度も上昇する。
As the iodine value decreases, oxidation progresses and the viscosity of the oil increases due to the increase in molecular weight.

粘度が上昇した揚げ物に、揚げ物を入れると、小さな泡
が油面に広がり、揚げ物を取シ出した後も、しばらく残
り、揚げ物も充分に揚らず、しかも揚げ物の表面に揚げ
ムラが生じ、極めて不都合である。
When fried food is added to fried food whose viscosity has increased, small bubbles spread on the oil surface and remain for a while even after the fried food is removed, resulting in the food not being fried sufficiently and causing uneven frying on the surface of the fried food. This is extremely inconvenient.

ヨウ素価の試験結果は、■の無添加に比べ、いずれも低
下しており、麦飯石粉末と香辛料の2種混合物の■■■
は■の麦飯石粒より減少率が低く、さらに無添加と比べ
30〜80%の減少率を示した。
The iodine value test results were all lower than those without additives in ■■■
The reduction rate was lower than that of Maihan stone grains (3), and the reduction rate was 30 to 80% compared to the case without additives.

以上のように本発明物を少量使用してヨウ素価を効率良
く改善できた。
As described above, the iodine value could be efficiently improved by using a small amount of the product of the present invention.

過酸化物価は油脂の酸化によって生成する過酸化物を油
脂1 kV当りのミIJ当量数で表わす。不飽和脂肪酸
が酸化変質したものは臭いの劣化と栄養価が低下し、さ
らに酸化が進んだ油は健康を害することが知られている
The peroxide value is expressed as the number of IJ equivalents per 1 kV of fat and oil peroxide produced by oxidation of fat and oil. It is known that oils with unsaturated fatty acids that have been oxidized have a deteriorated odor and nutritional value, and that oils that have undergone further oxidation are harmful to health.

厚生省では、菓子に含まれる油脂の酸価が3をこえ、か
つ過酸化物価が加をこえてはならないと指導している。
The Ministry of Health and Welfare has instructed that the acid value of fats and oils contained in sweets must not exceed 3, and the peroxide value must not exceed 3.

過酸化物価の試験結果は、■の無添加に比べ■の麦飯石
粒を除き、いずれも増加率が60%以下であり、40%
の効果が出た。
The test results of the peroxide value show that the increase rate in all cases is less than 60% compared to the non-additive in (■), except for the maifan stone grain in (■), which is 40%.
The effect was obtained.

以上のように、本発明物■■■の使用により、油の変質
防止と健康にとって良好な成果か得られた。
As described above, the use of the present invention product ■■■ resulted in prevention of oil deterioration and good health benefits.

各試験の完了後、じゃがいも、白味魚、肉、それぞれ3
011を、■から■の油で揚げて、揚げ物の風味を見た
After completing each test, potatoes, white fish, meat, 3 each
011 was fried in oil from ■ to ■ to check the flavor of the fried food.

揚げ物の風味は、本発明物を添加した■■■が揚げ油臭
くなく、カランと揚がった。■の無添加では、揚がりが
劣り、油の泡立ちが多かった。
Regarding the flavor of the fried food, ■■■ to which the product of the present invention was added did not have the smell of frying oil and was fried crisply. In case (2) without additives, the frying was poor and there was a lot of oil foaming.

■及び■の麦飯石だけでは、■■■に近い具合に揚がっ
た。
Only the maifan stones of ■ and ■ were fried to a degree similar to ■■■.

本発明物の使用方法は、揚げ鍋の形状に関係なく、また
どの様な材質の鍋でも、油に入れるだけで、効果が得ら
れる。
The product of the present invention can be used regardless of the shape of the deep-frying pan, and regardless of the material of the pan, the effect can be obtained simply by placing it in oil.

本発明物の好ましい使用量は、油に対して、麦飯石粉末
は、05〜5重量%で、香辛料は、α2〜2重量%であ
るが、香辛料は、生産地や気候や、根、茎、葉、花など
使用部によりさらに変動する。なお、香辛料は、2種類
以上の組合せによるものでも利用でき、誠に便利で゛あ
り、且つ効果も大である。
The preferred amount of the product of the present invention to be used is 05 to 5% by weight of maifan stone powder and α2 to 2% by weight of spices, based on the oil. , leaves, flowers, etc. will further vary depending on the parts used. Incidentally, spices can be used in combination of two or more types, which is very convenient and highly effective.

麦飯石粉末は粉砕時に粉砕機などによる金属粉を混入せ
ずに微粉砕したものを、好ましくは、100〜300メ
シユのものを、充分乾燥滅菌して使う。
The maifan stone powder is finely pulverized by a pulverizer or the like without mixing metal powder, preferably 100 to 300 mesh, and is sufficiently dried and sterilized before use.

麦飯石粉末と香辛料の包装は、通油性が有シかつ、微粒
子を通過させない1開の、うすい布状の包装材を使用す
る。材質としては、揚げ油が130〜270″Cに加熱
されるから、この温度で通油性と1開が著しく変化しな
いもので、紙、綿、合成樹脂などを使ったものが使用で
きる。なお、ティバッグ状に包装したものには、一部に
細い紐を適当な長さに取シつけて利用するのも良い。
For packaging the maifan stone powder and spices, use a thin, cloth-like packaging material that is oil-permeable and has a single opening that does not allow fine particles to pass through. Since the frying oil is heated to 130 to 270"C, materials that do not noticeably change oil permeability and opening at this temperature can be used, such as paper, cotton, or synthetic resin. It is also a good idea to attach a thin string of appropriate length to a part of the packaged bag.

Claims (1)

【特許請求の範囲】[Claims] 麦飯石粉末と香辛料の混合物を通油性と微粒子のしゃへ
い性のある、紙、綿、合成樹脂などの布状物で包み、揚
げ油中に漬けるようにしたことを特徴とした揚げ油の劣
化防止と風味の向上物
Prevention of deterioration and flavor of frying oil, characterized by wrapping a mixture of maifan stone powder and spices in a cloth-like material such as paper, cotton, synthetic resin, etc. that is permeable to oil and shielding particles, and immersed in the oil. improvement of
JP59104166A 1984-05-23 1984-05-23 Degradation-preventing and flavor-improving material for frying oil Pending JPS60248799A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP59104166A JPS60248799A (en) 1984-05-23 1984-05-23 Degradation-preventing and flavor-improving material for frying oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP59104166A JPS60248799A (en) 1984-05-23 1984-05-23 Degradation-preventing and flavor-improving material for frying oil

Publications (1)

Publication Number Publication Date
JPS60248799A true JPS60248799A (en) 1985-12-09

Family

ID=14373460

Family Applications (1)

Application Number Title Priority Date Filing Date
JP59104166A Pending JPS60248799A (en) 1984-05-23 1984-05-23 Degradation-preventing and flavor-improving material for frying oil

Country Status (1)

Country Link
JP (1) JPS60248799A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6474956A (en) * 1987-09-14 1989-03-20 Hajime Takahashi Prevention of oxidation of edible oil
JP2014109000A (en) * 2012-12-03 2014-06-12 Shingo Kawano Oil deterioration inhibitor made from shirasu, and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6474956A (en) * 1987-09-14 1989-03-20 Hajime Takahashi Prevention of oxidation of edible oil
JP2014109000A (en) * 2012-12-03 2014-06-12 Shingo Kawano Oil deterioration inhibitor made from shirasu, and manufacturing method thereof

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