JPS6024850B2 - Method for manufacturing fused crimped yarn - Google Patents

Method for manufacturing fused crimped yarn

Info

Publication number
JPS6024850B2
JPS6024850B2 JP4351477A JP4351477A JPS6024850B2 JP S6024850 B2 JPS6024850 B2 JP S6024850B2 JP 4351477 A JP4351477 A JP 4351477A JP 4351477 A JP4351477 A JP 4351477A JP S6024850 B2 JPS6024850 B2 JP S6024850B2
Authority
JP
Japan
Prior art keywords
yarn
melting point
fused
low
fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP4351477A
Other languages
Japanese (ja)
Other versions
JPS53130349A (en
Inventor
勇 笠井
和夫 富板
久夫 犬山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP4351477A priority Critical patent/JPS6024850B2/en
Publication of JPS53130349A publication Critical patent/JPS53130349A/en
Publication of JPS6024850B2 publication Critical patent/JPS6024850B2/en
Expired legal-status Critical Current

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Description

【発明の詳細な説明】 〔本発明の技術分野〕 本発明は加熱圧縮流体を使用して、スタッフイング部材
内の嵩高加工を施された融着捲縮糸を製造する方法に関
する。
DETAILED DESCRIPTION OF THE INVENTION Technical Field of the Invention The present invention relates to a method of producing bulked fused crimped yarn in a stuffing member using a heated compressed fluid.

〔従来技術とその問題点〕[Prior art and its problems]

従来、糸条に捲縮を与えて嵩高加工糸を得る方法は知ら
れている。
Conventionally, methods for obtaining bulky textured yarns by crimping yarns have been known.

また糸条に熱処理を施して融着加工糸を得る方法も知ら
れている。しかしスタッフィング部材内において捲縦を
付与しつつ融着する方法においては、未だ満足な方法は
知られていない。
Also known is a method of heat-treating yarn to obtain a fused processed yarn. However, there is still no known satisfactory method for fusing the stuffing member while imparting curling to the stuffing member.

本発明者らは、このような従来の技術に鑑み、捲縦の付
与された嵩高糸でありながら構成繊維は融着部分をも有
していて、布再形成に十分な伸縮性を発現し、さらには
しなやかさとシャリ感とドライタッチのある新規な構造
を有する融着捲縮糸を得る方法を提供せんとして鋭意研
究の結果本発明に到達したものである。
In view of such conventional technology, the present inventors have developed a method in which the constituent fibers also have fused portions, even though they are bulky yarns that have been given warp, and exhibit sufficient elasticity for fabric re-formation. In order to provide a method for obtaining a fused crimped yarn having a novel structure that is flexible, crisp, and dry to the touch, the present invention was achieved as a result of intensive research.

〔本発明の目的〕[Object of the present invention]

すなわち、本発明の目的は前述した如き特徴を有する融
着捲縮糸を加熱圧縮流体を使用して著しい装置の煩雑化
を伴なうことなく高能率、高生産性で製造し得る新規な
融着捲縦糸の製造方法を提供せんとするにある。
That is, the object of the present invention is to provide a novel fusion method that allows the production of fused crimped yarn having the characteristics described above using a heated compressed fluid with high efficiency and high productivity without complicating the equipment considerably. It is an object of the present invention to provide a method for manufacturing a wrapped warp yarn.

〔本発明の構成〕[Configuration of the present invention]

すなわち本発明方法は下記の構成からなる。 That is, the method of the present invention has the following configuration.

「高融点繊維糸条と低融点繊維糸条とからなる少なくと
も2種以上の糸条を引揃えて融着捲縮糸を製造する方法
において、低融点路繊維糸条の融点温度よりも高くかつ
高融点繊維糸条の融点温度よりも低い温度の加熱圧縮流
体をスタッフィング部材内に噴出すると共に該加熱流体
によって前記引揃え糸条をスタッフィング部村内に導き
、次いで糸条を堆積・充填し、低融点繊維糸条に融着を
与え、かつ高融点繊維糸条に賦型捲縮を付与し、しかる
後、該糸条の融着と賦型捲縮の安定化のために十分に低
い温度の流体流で該糸条を冷却してスタッフィング部材
から引出すことを特徴とする融着捲縞糸の製造方法。」
本発明方法においては、高融点繊維糸条と低融点流繊維
糸条とからなる2種以上の糸条であればどのような組み
合せでもよく、これに他の合成繊維、再生繊維、半合成
繊維、天然繊維等を任意に組み合わせてもよい。
"In a method for producing a fused crimped yarn by aligning at least two types of yarns consisting of a high melting point fiber yarn and a low melting point fiber yarn, the melting point temperature is higher than that of the low melting point fiber yarn and A heated compressed fluid having a temperature lower than the melting point of the high melting point fiber yarn is ejected into the stuffing member, and the heated fluid guides the aligned yarn into the stuffing section, and then the yarn is deposited and filled, and the The melting point fiber yarns are fused and the high melting point fiber yarns are given forming crimps, and then heated at a temperature sufficiently low to fuse the yarns and stabilize the forming crimps. A method for producing a fused wound striped yarn, which comprises cooling the yarn with a fluid stream and pulling it out from a stuffing member.
In the method of the present invention, any combination of two or more types of yarn consisting of a high melting point fiber yarn and a low melting point flow fiber yarn may be used, and in addition to this, other synthetic fibers, recycled fibers, and semi-synthetic fibers may be used. , natural fibers, etc. may be arbitrarily combined.

また合成繊維の溶融紙糸の際に、サイドバィサィド、シ
ンーサャ等のコンジュゲート繊維とした糸条を、高融点
繊維糸条又は低融点繊維糸条のどちらかの成分としても
よい。一方、形状もフィラメント糸スパン糸のいずれで
もよく、特にこれらの素材、形状に限定されるものでは
ない。すなわち、融点の異なる2種以上の成分から構成
された複合繊維でもよく、あるいは2種以上の糸条の混
合または引揃え糸のうち、少なくとも1つの成分が他の
成分の融点温度よりも高い融点温度よりも高い融点を有
するように構成されていればよいものである。このよう
な融点の異なる2種以上の糸条を、少なくとも1種の糸
条の融点温度よりも高い温度の加熱圧縮流体と共に、該
流体の圧力よりも低い圧力の低圧区域を生ぜしめ得るス
タッフィング部村内に噴出せしめ、この膨脹にともなっ
て糸条の構成単繊維を開綾させるとともに、既に嵩高加
工された糸条で形成されている充填・積された糸条物の
一端に衝突させ賦型捲糠加工が施される。
Further, in the case of synthetic fiber melt paper yarn, a yarn made of a conjugate fiber such as side-by-side or thin fiber may be used as a component of either the high-melting point fiber yarn or the low-melting point fiber yarn. On the other hand, the shape may be filament yarn or spun yarn, and is not particularly limited to these materials and shapes. In other words, it may be a composite fiber composed of two or more components with different melting points, or a composite fiber composed of two or more types of yarns, or a mixture or drawn yarn of two or more yarns, in which at least one component has a melting point higher than the melting point temperature of the other components. It is sufficient that the structure has a melting point higher than the temperature. A stuffing unit that can combine two or more types of yarns with different melting points together with a heated compressed fluid having a temperature higher than the melting point temperature of at least one type of yarn to create a low-pressure area with a pressure lower than the pressure of the fluid. The fibers are ejected into the village, and along with this expansion, the constituent single fibers of the yarn are opened and collided with one end of the filled and stacked yarn, which is already made of bulk-processed yarn, to form and wind the yarn. Rice bran processing is applied.

この際加熱流体と共に糸条をスタッフィング部材内に導
入すると、導入部、すなわち図面中、高温流体と接触し
低圧区域9の領域に至る間、糸条は瞬間的に高熱を付与
されるので、低融点を有する糸条成分は収縮を起こし、
全体糸条の中央部に配置する。そして高融点糸条成分は
全体糸条の外側に配置し、この状態でスタッフィング部
材に糸条は充填・堆積される。次いで低融点糸条は融解
を生じ、高融点糸条との相互の接点であるいは低融点糸
条どうしの接点においても融着による接着が開始され、
かつ高融点糸条は堆積による座屈を受けるのである。
At this time, when the yarn is introduced into the stuffing member together with the heating fluid, the yarn is instantaneously heated to a high temperature while it comes into contact with the high-temperature fluid and reaches the low-pressure area 9 in the figure. The yarn component that has a melting point causes shrinkage,
Place it in the center of the entire thread. The high melting point yarn component is arranged outside the entire yarn, and in this state the yarn is filled and deposited in the stuffing member. Next, the low-melting point yarns undergo melting, and adhesion by fusion begins at the points of contact with the high-melting point yarns or even at the points of contact between the low-melting point yarns,
Moreover, the high melting point yarn is subject to buckling due to deposition.

この状態のままで糸条の融着と座屈捲縮を安定化させる
のに十分な時間と温度で保った後、前記融着と捲縦を安
定化させるのに十分に低い温度の流体を供給して、前記
糸条を冷却して、しかる後スタッフィング部材内から引
きとるのである。すなわち、低融点繊維糸条と高融点繊
維糸条とを引き揃えてスタッフィング部材内で処理する
と、糸条導入部において低融点繊維が収縮し、糸条の中
心部分に配置し、次いでスタッフイング部材内で融着さ
れる。
After remaining in this state for a time and temperature sufficient to stabilize the welding and buckling crimp of the yarn, a fluid of a temperature low enough to stabilize the welding and curling is applied. The yarn is then cooled and then withdrawn from the stuffing member. That is, when a low-melting point fiber thread and a high-melting point fiber thread are aligned and processed in a stuffing member, the low-melting point fiber is shrunk at the thread introduction part and placed in the center of the thread, and then processed in the stuffing member. It is fused inside.

一方、高融点繊維は糸条の外周部に配置し、かつ座屈に
よる捲縦が付与されるため、更に外周部を被覆した状態
となる。従って座屈された糸条同士が轍着することはな
い。次いで糸条全体は冷却されるので、前記糸条の芯部
に融着状態で存在する低融点成分は冷却結晶化され、通
常の糸条として得る状態に戻る。すなわち加熱城で融着
状態で堆積・充填されているが、冷却により結晶化され
、独立の糸条として取り出せる状態となる。本発明の方
法で使用される加熱圧縮流体としては、たとえば熱風、
水蒸気等があるが、少なくとも低融点糸条の融点温度よ
り高く、高融点糸条の融点温度よりも低い温度の熱流体
を必要とするため、熱効率、操業性、経済性の面から加
熱蒸気が最も望ましい。
On the other hand, since the high melting point fibers are arranged on the outer periphery of the yarn and are given warp by buckling, the outer periphery is further covered. Therefore, the buckled yarns do not rub against each other. Next, the entire yarn is cooled, so that the low melting point component present in a fused state in the core of the yarn is cooled and crystallized, returning to the state obtained as a normal yarn. That is, it is deposited and filled in a fused state in a heated castle, but is crystallized by cooling and can be taken out as an independent thread. The heated compressed fluid used in the method of the invention includes, for example, hot air,
There is steam, etc., but heating fluid is required at least at a temperature higher than the melting point of the low-melting point yarn and lower than the melting point of the high-melting point yarn. Most desirable.

特にナイロン6などは蒸気温度140℃から融解を生じ
、蒸気による熱作用の効果は大きい。加熱圧縮流体を使
用して、糸条に嵩高捲縮加工を施す流体処理装置は、少
なくともジェットノズルとスタッフィング部材とで構成
されていることが必要である。
Particularly, nylon 6 and the like melt at a steam temperature of 140° C., and the thermal effect of steam has a large effect. A fluid treatment device that performs a bulky crimp process on a yarn using a heated compressed fluid needs to include at least a jet nozzle and a stuffing member.

かかるジェットノズルは、加熱圧縮流体と共に糸条を前
方に噴出することが可能であって、前記ノズルの噴出端
は前記流体の膨脹を増し、糸条の構成単繊総の開綾を増
大させ得るようにした形状のものが望ましい。またスタ
ッフィング部材は、前記ノズルから噴出された流体の一
部を抽出し得る抽気孔を設け、流体の一部を抽出し、該
流体の圧力よりも低い圧力の低圧区域を積極的に形成さ
せる段階と、糸条を前記低圧区域内で噴出流体の急激な
膨脹にともなって関織させ、既に嵩高加工された糸条で
形成された充填・堆積された糸条の一端に衝突し堆積さ
せる段階と、前記抽出流体以外の残された流体で、前記
糸条を前方に搬出し、糸条の融着と座屈捲縮の熱固定に
十分な時間と温度で維持する段階と、前記糸条の雛着と
座屈捲縦の安定化を促進するのに十分な低い温度の流体
で冷却する段階を有する如き構造が望ましいが、特にこ
れらの構造を有するスタッフイング部材に限定されるも
のではなく、たとえば同一方法に移動する無端ベルト間
、スリットあるいは絹状物等で形成された管状物等で糸
条の堆積をなし得る構造を有するスタッフィング部材等
であってもよい。さらに一方、嵩高加工を容易にする目
的で、供給糸条にあらかじめホットロール、加熱板等を
使用して加熱する方法、あるいはスタッフィング部材に
加熱装置を設け、糸条の融着や座屈捲縮の熱固定を十分
liする方法等もまた有効な手段であり、これらの機能
を有する装置を用してもよい。
Such a jet nozzle is capable of ejecting the yarn forward together with a heated compressed fluid, and the jetting end of the nozzle can increase the expansion of the fluid and increase the open twill of all the single fibers constituting the yarn. It is desirable to have a shape like this. Further, the stuffing member is provided with a bleed hole capable of extracting a portion of the fluid ejected from the nozzle, and the step of extracting a portion of the fluid and actively forming a low-pressure area having a pressure lower than the pressure of the fluid. and a step of causing the yarn to weave in the low-pressure area with the rapid expansion of the ejected fluid, colliding with one end of the filled and deposited yarn formed by the already bulked yarn and depositing it. carrying out the yarn forward with a remaining fluid other than the extraction fluid and maintaining the yarn at a time and temperature sufficient for fusing the yarn and heat fixing buckling and crimp; Stuffing members having these structures are desirable, but are not particularly limited to, structures that include a cooling stage with a fluid at a temperature sufficiently low to promote stabilization of chicking and buckling. For example, it may be a stuffing member or the like having a structure in which threads can be deposited between endless belts that move in the same manner, or with a slit or a tubular member formed of a silk-like material or the like. On the other hand, in order to facilitate bulk processing, there is a method in which the supplied yarn is heated in advance using a hot roll, a heating plate, etc., or a heating device is installed in the stuffing member to prevent fusing, buckling, and crimp of the yarn. A method of sufficiently heat fixing is also an effective means, and a device having these functions may also be used.

次に袋鷹を図示の例によって更に細に説明する。第1図
はこの発明を実施して、融着捲縮糸を製造し得る1態様
例を示したものである。
Next, Fukurotaka will be explained in more detail using illustrated examples. FIG. 1 shows an example of an embodiment in which a fused crimped yarn can be produced by implementing the present invention.

高低両融点糸のパッケージ1,2から引き出した2糸条
を給糸ローラ3,4からそれぞれ、ジェットノズル5に
供給し、加熱器6により加熱され加熱蒸気と共に、スタ
ッフアパイプ7内に噴出せしめる。この際、前記流体の
一部を柚気孔8で抽出し、低圧区域9を形成することに
より、前記流体の急激な膨脹にともなって、前記糸条は
構成単繊維に開綾される。この状態で糸条は既に嵩高加
工された糸条で形成された糸塊101こ衝突し、座屈し
ながらスタッフィングパイプ内に連続的に堆積された後
、前記抽出流体以外の残りの流体で前記糸塊を前方に搬
出するとともに、流体の熱作用で糸条の融着と座屈捲縮
の熱固定を十分に行ない。冷却装置11から低い温度の
流体を、前記糸魂に供給し、十分冷却後、引き取りロー
ル12で引き取り、巻取機13に巻き取るものである。
第1図において給糸ロールを2個設けた目的は、高低両
融点糸の混用の場合、該糸の給糸速度を異ならしめ得ら
れる鎚着ケン縮糸の外観形態に変化を付与するものであ
り、特に高融点糸を週長給糸を過長給糸することにより
、ネツプ、スラブ等の形成した意匠効果のある雛着捲縦
糸を得ることも可能である。〔本発明の効果〕 本発明で得られる融着捲縮糸の構造を例示すれば、第2
図に示した如く融点の異なる2成分からなる嵩高加工さ
れた融着捲縮糸であって、主として融着成分糸がシン部
14を、非融着成分糸がサャ部15を形成していて、か
つ座属捲縞を有しており、ノントルクであって優れたシ
ャリ感とドライタッチを有するものである。
Two yarns pulled out from packages 1 and 2 of high and low melting point yarns are supplied from yarn feeding rollers 3 and 4 to a jet nozzle 5, respectively, heated by a heater 6, and jetted into a stuffer pipe 7 together with heated steam. . At this time, by extracting a portion of the fluid through the pores 8 and forming a low-pressure area 9, the yarn is opened into constituent single fibers as the fluid rapidly expands. In this state, the yarn collides with the yarn mass 101 formed from the yarn that has already been bulked, and is continuously deposited in the stuffing pipe while being buckled. While carrying the mass forward, the thermal action of the fluid sufficiently fuses the threads and heat-fixes the buckling crimp. A low-temperature fluid is supplied from a cooling device 11 to the yarn core, and after cooling it sufficiently, it is taken up by a take-up roll 12 and wound up by a winder 13.
The purpose of providing two yarn feeding rolls in Fig. 1 is to vary the yarn feeding speed of the yarns when high and low melting point yarns are mixed, thereby changing the appearance of the resulting hammered curled yarn. In particular, by feeding a high-melting point yarn over a weekly length or an excessive length, it is also possible to obtain a warp yarn with a design effect such as neps or slabs. [Effects of the present invention] To illustrate the structure of the fused crimped yarn obtained by the present invention, the second
As shown in the figure, it is a bulky fused crimped yarn consisting of two components with different melting points, with the fused component yarn mainly forming the thin part 14 and the non-fused component yarn forming the sash part 15. , and has curly stripes, is non-torque, and has an excellent crisp feel and dry touch.

またリネンラィクも呈する。以上説明した装置の融着捲
縮糸の製造方法によれば、すぐれた特性を有する融着捲
縦糸を簡便にかつ高能率、高生産性で製造し得るもので
ある。
It also has a linen-like appearance. According to the method for manufacturing fused crimped yarn using the apparatus described above, fused crimped warp yarns having excellent properties can be easily manufactured with high efficiency and high productivity.

実施例 1第1図に示した如き態様の装置を用いて、ナ
フロン6フィラメント糸70デニール−24フィラメン
ト、ナイロン24フィラメントの2種の糸条を使用して
、次の条件で加工した。
Example 1 Using the apparatus shown in FIG. 1, two types of yarns, a 70-denier 24-filament Naflon 6-filament yarn and a 24-filament nylon filament, were processed under the following conditions.

処理速度;50仇奴/in 加熱蒸気;190qo×5k9/嫌 スタッフィングパィプ径;80側 冷却用流体;圧縮空気(室温)2k9/仇引き取り速度
;410の/min 上記条件において、スタッフイングボックス内の加熱部
の帯蟹時間は5.釘砂、冷却部の帯留時間は4.6秒で
あった。
Processing speed: 50 m/min Heating steam: 190 qo x 5 k9/stuffing pipe diameter: 80 Side cooling fluid: Compressed air (room temperature) 2 k9/millimeter Take-up speed: 410 m/min Under the above conditions, inside the stuffing box The cooking time of the heating section is 5. The retention time of the nail sand in the cooling section was 4.6 seconds.

この値は、通常の仮ョリ工法における加熱部・冷却部の
滞留時間の各0.4秒以下に比べて、1ぴ音以上の範囲
であり、これにより捲縮安定性、融着強固性が得られた
。得られた融着捲縮糸は、非旋回性嵩高加工糸であって
、主としてシン部は融着されたナイロン6で形成され、
サャ部は座屈捲縞を有するナイロン66で形成された2
層構造を有する糸であって、シヤリ味とドライタッチを
有するすぐれたものであった。
This value is in the range of more than 1 peep compared to the residence time of 0.4 seconds or less in the heating and cooling parts in the normal crimp method, which improves crimp stability and fusion strength. was gotten. The obtained fused crimped yarn is a non-rotating bulky yarn, and the thin part is mainly formed of fused nylon 6,
The sill part is made of nylon 66 with buckling stripes.
The yarn had a layered structure and had an excellent silky feel and dry touch.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の融着捲縮糸の製造方法の一実施態様例
を示す概略図、第2図は本発明の融着捲縦糸の製造方法
で得られる糸の構造例を示すモデル図である。 1,2…供給用パッケージ、3,4…給糸ロール、5・
・・ジェットノズル、6・・・加熱器、7・・・スタッ
フィングパィプ、8・・・柚気孔、9・・・低圧区域、
10…充填・堆積された糸条物、11・・・冷却装置、
12・・・引取りロール、13巻取機、14・・・シン
部、15…サャ部。 オー図 オ2図
FIG. 1 is a schematic diagram showing an embodiment of the method for manufacturing a fused crimped yarn of the present invention, and FIG. 2 is a model diagram showing an example of the structure of a yarn obtained by the method for manufacturing a fused warp yarn of the present invention. It is. 1, 2... Supply package, 3, 4... Yarn feeding roll, 5.
... Jet nozzle, 6 ... Heater, 7 ... Stuffing pipe, 8 ... Yuzu pore, 9 ... Low pressure area,
10...Filled and deposited yarn material, 11...Cooling device,
12... take-up roll, 13 winder, 14... thin section, 15... sagging section. O diagram O 2 diagram

Claims (1)

【特許請求の範囲】[Claims] 1 高融点繊維糸条と低融点繊維糸条とからなる少なく
とも2種以上の糸条を引揃えて融着捲縮糸を製造する方
法において、低融点繊維糸条の融点温度よりも高くかつ
高融点繊維糸条の融点温度よりも低い温度の加熱圧縮流
体をスタツフイング部材内に噴出すると共に該加熱流体
によつて前記引揃え糸条をスタツフイング部材内に導き
、次いで糸条を堆積・充填し、低融点繊維糸条に融着を
与え、かつ高融点繊維糸条に賦型捲縮を付与し、しかる
後、該糸条の融着と賦型捲縮の安定化のために十分に低
い温度の流体流で該糸条を冷却してスタツフイング部材
から引出すことを特徴とする融着捲縮糸の製造方法。
1. In a method for producing a fused crimped yarn by aligning at least two types of yarns consisting of a high melting point fiber yarn and a low melting point fiber yarn, the melting point temperature is higher than that of the low melting point fiber yarn and the A heated compressed fluid having a temperature lower than the melting point of the melting point fiber yarn is ejected into the stuffing member, and the heated fluid guides the aligned yarn into the stuffing member, and then the yarn is deposited and filled. The low-melting point fiber yarn is fused and the high-melting point fiber yarn is given a forming crimp, and then sufficient heat is applied to fuse the yarn and stabilize the forming crimp. A method for producing a fused crimped yarn, which comprises cooling the yarn with a low-temperature fluid stream and pulling it out from a stuffing member.
JP4351477A 1977-04-18 1977-04-18 Method for manufacturing fused crimped yarn Expired JPS6024850B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4351477A JPS6024850B2 (en) 1977-04-18 1977-04-18 Method for manufacturing fused crimped yarn

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4351477A JPS6024850B2 (en) 1977-04-18 1977-04-18 Method for manufacturing fused crimped yarn

Publications (2)

Publication Number Publication Date
JPS53130349A JPS53130349A (en) 1978-11-14
JPS6024850B2 true JPS6024850B2 (en) 1985-06-14

Family

ID=12665833

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4351477A Expired JPS6024850B2 (en) 1977-04-18 1977-04-18 Method for manufacturing fused crimped yarn

Country Status (1)

Country Link
JP (1) JPS6024850B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10982139B2 (en) 2017-06-14 2021-04-20 Denka Company Limited Fluoride phosphor and light-emitting device using same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4932108A (en) * 1983-04-21 1990-06-12 Ppg Industries, Inc. Process for high speed bulking of glass fiber strands

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10982139B2 (en) 2017-06-14 2021-04-20 Denka Company Limited Fluoride phosphor and light-emitting device using same

Also Published As

Publication number Publication date
JPS53130349A (en) 1978-11-14

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